CN111333510A - High-temperature-resistant lubricant, and preparation method and application thereof - Google Patents
High-temperature-resistant lubricant, and preparation method and application thereof Download PDFInfo
- Publication number
- CN111333510A CN111333510A CN202010146442.2A CN202010146442A CN111333510A CN 111333510 A CN111333510 A CN 111333510A CN 202010146442 A CN202010146442 A CN 202010146442A CN 111333510 A CN111333510 A CN 111333510A
- Authority
- CN
- China
- Prior art keywords
- temperature
- resistant lubricant
- acid
- reaction
- lubricant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000314 lubricant Substances 0.000 title claims abstract description 58
- 238000002360 preparation method Methods 0.000 title claims description 6
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical group CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 claims abstract description 12
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 11
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 238000005886 esterification reaction Methods 0.000 claims description 13
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 13
- 229920006351 engineering plastic Polymers 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 claims description 9
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 claims description 9
- 235000021314 Palmitic acid Nutrition 0.000 claims description 9
- 235000021355 Stearic acid Nutrition 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 9
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 9
- 239000008117 stearic acid Substances 0.000 claims description 9
- 239000003054 catalyst Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 230000035484 reaction time Effects 0.000 claims description 6
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical compound [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 claims description 6
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 6
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 3
- 239000008096 xylene Substances 0.000 claims description 3
- 229920001169 thermoplastic Polymers 0.000 claims description 2
- 239000004416 thermosoftening plastic Substances 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract description 7
- 230000001050 lubricating effect Effects 0.000 abstract description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract description 2
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 238000000354 decomposition reaction Methods 0.000 description 8
- 239000002253 acid Substances 0.000 description 6
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 238000002411 thermogravimetry Methods 0.000 description 4
- 230000004580 weight loss Effects 0.000 description 4
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 239000012760 heat stabilizer Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a high-temperature-resistant lubricant which has a structure shown in a formula (I):
wherein, C15H31COO-is palmitate radical, C17H35COO-is stearate, C21H41COO-is a erucic acid group; a. b and c are 0.1 to 3.6, d is 0.2 to 3.7, and a + b + c + d is 4. The high-temperature-resistant lubricant provided by the invention has excellent high-temperature resistance and lubricating effect because the molecule of the high-temperature-resistant lubricant contains a plurality of fatty chains with more than 12 carbon atoms and has large molecular weight and no hydrogen atom on the quaternary carbon atom position, and has better application in the field of engineering plasticsAnd 4, application prospect.
Description
Technical Field
The invention relates to the technical field of material processing aid lubricants, in particular to a high-temperature-resistant lubricant and a preparation method and application thereof.
Background
The processing of polymers is usually carried out above their crystalline melting point, and for amorphous polymers above the glass transition temperature, the macromolecular structure of these substances often leads to very high melt viscosities. The processing of these polymers and their deformation or setting requires pressure, and the shear forces generated during processing lead to a dispersion of mechanical energy, especially in those cases where the melt resistance is high, the heat generated by the resistance can accelerate the degradation reaction or can have an adverse effect on the dispersion of the multiphase system.
The possibilities of optimizing the processing of plastics by selecting suitable monomers, controlling the molecular weight and the structure of the macromolecules are limited. The main methods for solving these problems include not only the rational selection of various machines and dies in the processing process, but also the selection of proper lubricants for improving the melt rheology of the polymer into the desired state, so that the processing of the polymer can be smoothly carried out.
For engineering plastics, the output and processing temperatures with modern processing equipment have increased in recent years. Therefore, it is very necessary to use a high temperature resistant lubricant.
Disclosure of Invention
The present invention is directed to solving at least one of the problems of the prior art. Therefore, the invention provides a high-temperature-resistant lubricant, a preparation method and an application thereof, and the high-temperature-resistant lubricant has higher thermal stability and better application prospect in the field of engineering plastics.
The technical scheme adopted by the invention is as follows:
in a first aspect of the present invention, there is provided a high temperature resistant lubricant having the structure of formula (i):
wherein a, b and c are 0.1-3.6, d is 0.2-3.7, and a + b + c + d is 4.
Wherein C is15H31COO-is palmitate radical, C17H35COO-stearate radical, C21H41COO-is a erucic acid group.
In a second aspect of the present invention, there is provided a method for preparing the above high temperature resistant lubricant, comprising the following steps:
taking reaction raw materials containing palmitic acid, stearic acid, erucic acid and pentaerythritol;
and adding a catalyst and a water-carrying agent into the reaction raw materials to perform esterification reaction.
According to some embodiments of the present invention, further comprising the step of determining the acid number of the esterification reaction system. Whether the end point of the esterification reaction was reached was judged by measuring the acid value.
Further according to some embodiments of the present invention, after the esterification reaction is finished, the method further comprises the step of removing the water-carrying agent by distillation under reduced pressure.
According to some embodiments of the invention, the reaction feed comprises, in the reaction feed, palmitic acid: the molar ratio of pentaerythritol is (0.1-3.6): 1, stearic acid: the molar ratio of pentaerythritol is (0.1-3.6): 1, erucic acid: the molar ratio of pentaerythritol is (0.1-3.6): 1.
according to some embodiments of the invention, the catalyst comprises at least one of phosphoric acid, phosphorous acid, p-toluenesulfonic acid, and stannous oxide.
According to some embodiments of the invention, the water-carrying agent comprises at least one of toluene, xylene and cyclohexane.
According to some embodiments of the invention, the esterification reaction is carried out at a reaction temperature of 120 ℃ to 200 ℃.
According to some embodiments of the invention, the esterification reaction is carried out for a reaction time of 2 to 5 hours.
In a third aspect of the invention, there is provided a lubricant composition comprising the high temperature resistant lubricant described above.
In a fourth aspect of the invention, there is provided the use of a high temperature resistant lubricant as described above or a lubricant composition as described above in the preparation of an engineering plastic.
According to some embodiments of the invention, the engineering plastic is a thermoplastic engineering plastic or a modified engineering plastic.
The embodiment of the invention has the beneficial effects that:
the embodiment of the invention provides a high-temperature-resistant lubricant which is prepared by carrying out catalytic reaction on reaction raw materials containing palmitic acid (16 carbon atoms in a molecular chain), stearic acid (18 carbon atoms in the molecular chain), erucic acid (22 carbon atoms in the molecular chain) and pentaerythritol. The lubricant contains multiple fatty chains with more than 12 carbon atoms in the structure, and has effective lubricating effect. Because quaternary carbon atoms in the molecules of the lubricating grease have no hydrogen atoms, the lubricating grease has excellent high-temperature resistance and lubricating effect, and has better application prospect in the field of engineering plastics.
Drawings
FIG. 1 is a graph of the thermal weight loss of the high temperature resistant lubricant of example 1;
FIG. 2 is a graph of the thermal weight loss of the high temperature resistant lubricant of example 2;
FIG. 3 is a graph of the thermal weight loss of the high temperature resistant lubricant of example 3;
fig. 4 is a graph of the thermal weight loss of the high temperature resistant lubricant of example 4.
Detailed Description
The concept and technical effects of the present invention will be clearly and completely described below in conjunction with the embodiments to fully understand the objects, features and effects of the present invention. It is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments, and those skilled in the art can obtain other embodiments without inventive effort based on the embodiments of the present invention, and all embodiments are within the protection scope of the present invention.
Example 1
This example provides a high temperature resistant lubricant, prepared according to the following steps:
38.46g (0.15mol) of palmitic acid, 68.28g (0.24mol) of stearic acid, 162.51g (0.48mol) of erucic acid and 40.85g (0.3mol) of pentaerythritol are added into a 500mL four-neck flask provided with a stirrer, a thermometer and a water diversion condensation reflux device, 0.5g of phosphoric acid is added as a catalyst, 15g of toluene is added as a water carrying agent, the mixture is heated to 120 ℃ for esterification reaction, the reaction time is 5 hours, the acid value is 1.52mg KOH/g, the reaction is at the end point, and the reaction is finished. And (3) distilling under reduced pressure to remove residual water-carrying agent and water, and drying the product to obtain the high-temperature-resistant lubricant, wherein the structural formula of the product is as follows:
the high-temperature-resistant lubricant prepared in the example is taken and subjected to thermogravimetric analysis, and the result is shown in fig. 1, wherein the initial decomposition temperature of the product measured by a thermogravimetric analyzer is 419.4 ℃, which indicates that the decomposition temperature of the product is high, meets the high-temperature-resistant requirement, and is suitable for being used as the high-temperature-resistant lubricant.
Example 2
This example provides a high temperature resistant lubricant, prepared according to the following steps:
276.93g (1.08mol) of palmitic acid, 8.53g (0.03mol) of stearic acid, 10.16g (0.03mol) of erucic acid and 40.85g (0.3mol) of pentaerythritol are added into a 500mL four-neck flask provided with a stirrer, a thermometer and a water diversion condensation reflux device, 0.5g of phosphorous acid is added as a catalyst, 15g of xylene is added as a water-carrying agent, the mixture is heated to 150 ℃ for esterification reaction, the reaction time is 4 hours, the acid value is 1.03mgKOH/g, the reaction is at the end point, and the reaction is finished. And (3) distilling under reduced pressure to remove residual water-carrying agent and water, and drying the product to obtain the high-temperature-resistant lubricant, wherein the structural formula of the product is as follows:
the high-temperature-resistant lubricant prepared in the example is taken and subjected to thermogravimetric analysis, and the result is shown in fig. 2, wherein the initial decomposition temperature of the product measured by a thermogravimetric analyzer is 416.3 ℃, which shows that the decomposition temperature of the product is high, meets the high-temperature-resistant requirement, and is suitable for being used as the high-temperature-resistant lubricant.
Example 3
This example provides a high temperature resistant lubricant, prepared according to the following steps:
30.77g (0.12mol) of palmitic acid, 34.14g (0.12mol) of stearic acid, 121.89g (0.36mol) of erucic acid and 163.38g (1.2mol) of pentaerythritol are added into a 500mL four-neck flask provided with a stirrer, a thermometer and a water diversion condensation reflux device, 0.5g of p-toluenesulfonic acid is added as a catalyst, 15g of cyclohexane is added as a water carrying agent, the mixture is heated to 180 ℃ for esterification reaction, the reaction time is 3 hours, the acid value is measured to be 0.89mgKOH/g, the reaction is at the end point, and the reaction is finished. And (3) distilling under reduced pressure to remove residual water-carrying agent and water, and drying the product to obtain the high-temperature-resistant lubricant, wherein the structural formula of the product is as follows:
the high temperature resistant lubricant prepared in the example was taken and subjected to thermogravimetric analysis, and the result is shown in fig. 3, wherein the initial decomposition temperature of the product measured by a thermogravimetric analyzer was 417.2 ℃, which indicates that the decomposition temperature of the product is high, meets the high temperature resistant requirement, and is suitable for being used as a high temperature resistant lubricant.
Example 4
This example provides a high temperature resistant lubricant, prepared according to the following steps:
115.39g (0.45mol) of palmitic acid, 102.41g (0.36mol) of stearic acid, 81.26g (0.24mol) of erucic acid and 40.85g (0.3mol) of pentaerythritol are added into a 500mL four-neck flask provided with a stirrer, a thermometer and a water diversion condensation reflux device, 0.5g of stannous oxide is added as a catalyst, 15g of cyclohexane is added as a water carrying agent, the mixture is heated to 200 ℃ for esterification reaction, the reaction time is 2 hours, the acid value is measured to be 0.58mgKOH/g, the reaction reaches the end point, and the reaction is finished. And (3) distilling under reduced pressure to remove residual water-carrying agent and water, and drying the product to obtain the high-temperature-resistant lubricant, wherein the structural formula of the product is as follows:
the high-temperature-resistant lubricant prepared in the example is taken and subjected to thermogravimetric analysis, and the result is shown in fig. 4, wherein the initial decomposition temperature of the product measured by a thermogravimetric analyzer is 418.6 ℃, which indicates that the decomposition temperature of the product is high, meets the high-temperature-resistant requirement, and is suitable for being used as the high-temperature-resistant lubricant.
Effect example 1
60g of PVC, 1.8g of calcium-zinc composite heat stabilizer and 0.6g of the high-temperature-resistant lubricant prepared in the embodiment 1 are uniformly mixed to form a PVC/high-temperature-resistant lubricant sample, the PVC/high-temperature-resistant lubricant sample is placed in a torque rheometer, and the dynamic thermal stability of the PVC/high-temperature-resistant lubricant sample is tested at 180 ℃ and a rotating speed of 45r/min, wherein the calcium-zinc composite heat stabilizer is a product of Guangdong Weilinnacidae technologies GmbH in the embodiment. The lubricating effect of the high temperature resistant lubricant on PVC was evaluated based on the plasticizing torque, the equilibrium torque and the plasticizing time, and the results are shown in table 1.
TABLE 1 rheological parameters of PVC/high temperature resistant Lubricant samples
As can be seen from Table 1, the plasticizing torque, the balance torque and the plasticizing time of a PVC/high-temperature-resistant lubricant sample formed by adding the high-temperature-resistant lubricant are lower than those of a sample without adding the high-temperature-resistant lubricant, and the thermal stability time of the formed PVC/high-temperature-resistant lubricant sample is obviously longer than that of the sample without adding the high-temperature-resistant lubricant.
Claims (10)
1. A high temperature resistant lubricant characterized by having the structure of formula (i):
wherein C is15H31COO-is palmitate radical, C17H35COO-is stearate, C21H41COO-is a erucic acid group; a. b and c are 0.1 to 3.6, d is 0.2 to 3.7, and a + b + c + d is 4.
2. The method of preparing a high temperature resistant lubricant according to claim 1, comprising the steps of:
taking reaction raw materials containing palmitic acid, stearic acid, erucic acid and pentaerythritol;
and adding a catalyst and a water-carrying agent into the reaction raw materials to perform esterification reaction.
3. The method for preparing the high-temperature-resistant lubricant according to claim 2, wherein, in the reaction raw materials, the ratio of palmitic acid: the molar ratio of pentaerythritol is (0.1-3.6): 1, stearic acid: the molar ratio of pentaerythritol is (0.1-3.6): 1, erucic acid: the molar ratio of pentaerythritol is (0.1-3.6): 1.
4. the method of claim 2, wherein the catalyst comprises at least one of phosphoric acid, phosphorous acid, p-toluene sulfonic acid, and stannous oxide.
5. The method of claim 2, wherein the water-carrying agent comprises at least one of toluene, xylene, and cyclohexane.
6. The method of any of claims 2 to 5, wherein the esterification reaction is carried out at a temperature of 120 ℃ to 200 ℃.
7. The method for preparing the high-temperature-resistant lubricant according to claim 6, wherein the reaction time of the esterification reaction is 2 to 5 hours.
8. A lubricant composition comprising the high temperature resistant lubricant of claim 1.
9. Use of the high temperature resistant lubricant of claim 1 or the lubricant composition of claim 8 in the preparation of engineering plastics.
10. Use according to claim 9, wherein the engineering plastic is a thermoplastic engineering plastic or a modified engineering plastic.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010146442.2A CN111333510A (en) | 2020-03-05 | 2020-03-05 | High-temperature-resistant lubricant, and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010146442.2A CN111333510A (en) | 2020-03-05 | 2020-03-05 | High-temperature-resistant lubricant, and preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111333510A true CN111333510A (en) | 2020-06-26 |
Family
ID=71178096
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010146442.2A Pending CN111333510A (en) | 2020-03-05 | 2020-03-05 | High-temperature-resistant lubricant, and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111333510A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114181764A (en) * | 2021-12-17 | 2022-03-15 | 马鞍山中集瑞江润滑油有限公司 | High-temperature forming lubricant |
| CN114369067A (en) * | 2021-12-29 | 2022-04-19 | 广东科力新材料有限公司 | Acylamino uracil and preparation method and application thereof |
| CN114394899A (en) * | 2021-12-29 | 2022-04-26 | 广东科力新材料有限公司 | Dipentaerythritol ester and preparation method and application thereof |
| CN114409534A (en) * | 2021-12-29 | 2022-04-29 | 广东科力新材料有限公司 | Pentaerythritol ester and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1345895A (en) * | 2000-09-28 | 2002-04-24 | 奇美实业股份有限公司 | Transparent phonylethylene resin composition |
| JP2014084428A (en) * | 2012-10-25 | 2014-05-12 | Kao Corp | Lubricant for a polycarbonate resin |
| CN105237400A (en) * | 2015-11-12 | 2016-01-13 | 湖北科技学院 | Plastic lubricant synthesis method |
| JP2018141100A (en) * | 2017-02-28 | 2018-09-13 | 理研ビタミン株式会社 | Mold release agent for polycarbonate resin |
| WO2018235716A1 (en) * | 2017-06-20 | 2018-12-27 | 理研ビタミン株式会社 | Polycarbonate resin releasing agent |
-
2020
- 2020-03-05 CN CN202010146442.2A patent/CN111333510A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1345895A (en) * | 2000-09-28 | 2002-04-24 | 奇美实业股份有限公司 | Transparent phonylethylene resin composition |
| JP2014084428A (en) * | 2012-10-25 | 2014-05-12 | Kao Corp | Lubricant for a polycarbonate resin |
| CN105237400A (en) * | 2015-11-12 | 2016-01-13 | 湖北科技学院 | Plastic lubricant synthesis method |
| JP2018141100A (en) * | 2017-02-28 | 2018-09-13 | 理研ビタミン株式会社 | Mold release agent for polycarbonate resin |
| WO2018235716A1 (en) * | 2017-06-20 | 2018-12-27 | 理研ビタミン株式会社 | Polycarbonate resin releasing agent |
Non-Patent Citations (1)
| Title |
|---|
| 《化工百科全书》编辑委员会, 化学工业出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114181764A (en) * | 2021-12-17 | 2022-03-15 | 马鞍山中集瑞江润滑油有限公司 | High-temperature forming lubricant |
| CN114369067A (en) * | 2021-12-29 | 2022-04-19 | 广东科力新材料有限公司 | Acylamino uracil and preparation method and application thereof |
| CN114394899A (en) * | 2021-12-29 | 2022-04-26 | 广东科力新材料有限公司 | Dipentaerythritol ester and preparation method and application thereof |
| CN114409534A (en) * | 2021-12-29 | 2022-04-29 | 广东科力新材料有限公司 | Pentaerythritol ester and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111333510A (en) | High-temperature-resistant lubricant, and preparation method and application thereof | |
| CN109486179B (en) | Nylon 6 composition and application thereof in thin-wall long flow channel product | |
| CN111171455B (en) | Thermal-aging-resistant polypropylene composite material and preparation method thereof | |
| CN105949508B (en) | A kind of heat stabilizer for PVC and its preparation method and application | |
| CN109521054B (en) | Characterization method of entanglement degree of high molecular weight polyethylene | |
| JPH0149297B2 (en) | ||
| CN111825898B (en) | Rubber anti-aging agent and preparation method thereof | |
| Sabet et al. | Electron-beam irradiation of low density polyethylene/ethylene vinyl acetate blends | |
| CN108129825B (en) | high-CTI high-heat-resistance halogen-free flame-retardant PC/ABS composition and preparation method thereof | |
| CN104098833A (en) | Antioxidant heat-resistant masterbatch used for polypropylene and preparation method thereof | |
| CN109337188B (en) | Irradiation crosslinking high-temperature-resistant heat-shrinkable sleeve and production method thereof | |
| CN113527877A (en) | high-CTI-value black red phosphorus flame-retardant reinforced nylon 66 and preparation method thereof | |
| CN114014980B (en) | Maleic anhydride graft polymerization process | |
| CN114426728A (en) | Silane crosslinking type cable insulation material capable of being extruded efficiently | |
| RU2292366C1 (en) | Polymeric composition used as structural material | |
| CN112852154A (en) | High-temperature-resistant easy-to-process thermoplastic transparent polyimide resin material with low thermal expansion coefficient and preparation method thereof | |
| CN112778575A (en) | Heat stabilizer composition for transparent PVC and application thereof | |
| CN109337263B (en) | Irradiation crosslinking high-temperature-resistant cable accessory capable of being processed at low temperature and production method thereof | |
| CN110204870A (en) | A kind of resistance to PTT 3D printing wire rod and preparation method thereof for shrinking warpage | |
| CN116041872B (en) | Migration-precipitation-resistant and aging-resistant PVC cable material composition | |
| CN112300510B (en) | Styrene copolymer composition | |
| Wang et al. | Non-isothermal degradation kinetics for polycarbonate/polymethylphenylsilsesquioxane composites | |
| CN116554697B (en) | Processing technology for preparing high-toughness composite material by glass fiber composite PA single 6 | |
| CN110078917B (en) | Thermoplastic soluble polyimide and preparation method and application thereof | |
| EP1332168A4 (en) | Process for devolatilizing an acrylic resin, process for preparing a powder coating composition and composition capable of being formed into a powder coating composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200626 |