CN111331127A - Preparation method of graphene/copper composite wire - Google Patents
Preparation method of graphene/copper composite wire Download PDFInfo
- Publication number
- CN111331127A CN111331127A CN201811550044.6A CN201811550044A CN111331127A CN 111331127 A CN111331127 A CN 111331127A CN 201811550044 A CN201811550044 A CN 201811550044A CN 111331127 A CN111331127 A CN 111331127A
- Authority
- CN
- China
- Prior art keywords
- graphene
- copper
- copper composite
- powder
- composite wire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 64
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 60
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 60
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 43
- 239000010949 copper Substances 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 26
- 238000001125 extrusion Methods 0.000 claims abstract description 18
- 239000000843 powder Substances 0.000 claims abstract description 17
- 238000002156 mixing Methods 0.000 claims abstract description 13
- 238000005516 engineering process Methods 0.000 claims abstract description 12
- 238000010622 cold drawing Methods 0.000 claims abstract description 7
- 239000007790 solid phase Substances 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 238000010924 continuous production Methods 0.000 abstract description 5
- 239000011159 matrix material Substances 0.000 abstract description 5
- 239000006185 dispersion Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000005266 casting Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000011812 mixed powder Substances 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 238000004663 powder metallurgy Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001192 hot extrusion Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- B22F1/0003—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C37/00—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
- B21C37/04—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of bars or wire
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/14—Treatment of metallic powder
- B22F1/145—Chemical treatment, e.g. passivation or decarburisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/20—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces by extruding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F5/12—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of wires
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/05—Mixtures of metal powder with non-metallic powder
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/02—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
- H01B1/026—Alloys based on copper
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The invention relates to a preparation method of a graphene/copper composite wire, and belongs to the field of composite material processing and preparation. The method comprises the following steps: (1) mixing graphene and copper powder in a solid phase to obtain composite powder; (2) carrying out reduction treatment on the composite powder; (3) preparing a graphene/copper composite material wire blank by adopting a continuous extrusion technology; (4) and preparing the graphene/copper composite wire by adopting a multi-pass cold drawing technology. The method adopts the continuous extrusion technology to prepare the composite material wire blank, realizes the continuous production of the wire blank, simultaneously adopts the multi-pass drawing technology to realize the further dispersion and orientation of the graphene in the copper matrix, and improves the performance of the composite wire. The graphene/copper composite wire prepared by the method has higher electrical conductivity while obviously improving the tensile strength; the method has the advantages of less procedures, continuous production and high production efficiency.
Description
Technical Field
The invention relates to a preparation method of a composite material wire, in particular to a preparation method of a graphene/copper composite wire, and belongs to the field of composite material processing and preparation.
Background
With the development of aerospace, mechanical and electronic industries, the demand for cables with light weight, high strength and high conductivity is more and more urgent. The graphene provides possibility for improving the performance of light, high-strength and high-wire cables.
The graphene is a two-dimensional nano material composed of carbon atoms, is a nano material with the highest specific strength in the world, is known at present, has the strength of 130GPa, and is more than 100 times that of steel; the thermal conductivity can reach 5000W/(m.K), which is 3 times of that of diamond; its resistivity is also only about 10n Ω · m. Compared with other nano carbon materials, the graphene has a larger specific surface area and a large contact area with a substrate; although graphene is also agglomerated by van der waals forces, it can slip relatively under external forces, and further dispersion and orientation distribution in the matrix can be achieved during large deformation. Therefore, the graphene is compounded with copper to prepare a light, high-strength and high-wire cable by utilizing the high strength and high conductivity of the graphene, and the requirements of the aerospace and electronic information fields on high-end cables can be expected to be met.
The preparation method of the graphene/copper composite wire comprises a melt casting method and a powder metallurgy method. When a melt casting method is adopted, due to the fact that the density difference between graphene and copper is large, an interface is not wet, and graphene is difficult to uniformly disperse in a copper matrix; when the powder metallurgy method is adopted, a plurality of processes such as hot extrusion after hot-pressing sintering are required, the process is complex, and continuous preparation cannot be realized. Therefore, there is a need to develop a new process for continuously producing graphene/copper composite wires.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention provides a novel method for preparing the graphene/copper composite wire by adopting continuous extrusion and multi-pass drawing, the continuous preparation of the composite material wire blank can be realized by adopting the continuous extrusion technology, and the further dispersion and orientation of the graphene in the copper matrix can be realized by adopting the multi-pass drawing, so that the performance of the wire is improved.
The purpose of the invention can be realized by the following technical scheme:
a continuous preparation method of a graphene/copper composite wire comprises the following steps:
(1) mixing graphene and copper powder in a solid phase to obtain composite powder;
(2) carrying out reduction treatment on the composite powder;
(3) preparing a graphene/copper composite material wire blank by adopting a continuous extrusion technology;
(4) and preparing the graphene/copper composite wire by adopting a multi-pass cold drawing technology.
In the step (1), the addition amount of the graphene is less than 5 wt%, and the addition amount of the graphene is preferably less than 3 wt%; the minimum addition amount of the graphene is preferably more than 0.005 wt%; more preferably from 0.005% to 1% by weight.
In the step (1), the particle size of the copper powder is 50 to 500 μm, and the particle size of the copper powder is preferably 200 to 400 μm.
In the step (1), the solid phase mixing method comprises: mechanical mixing and pneumatic mixing.
In the step (2), the composite powder reduction treatment method comprises the following steps: reducing for 1-4 h under the condition of hydrogen at the temperature of 400-600 ℃.
In the step (3), a continuous extruder is adopted to prepare the graphene/copper composite material wire blank, and the composite powder is continuously added through a vibration funnel at a speed of 20-40 g/s.
In the step (3), continuous extrusion is carried out under the conditions that the temperature is 650-750 ℃, the rotating speed of an extrusion wheel is 5-15 rpm, and the extrusion ratio is 10-30. The diameter of the prepared graphene/copper composite material wire blank is 1 cm-3 cm.
In the step (4), the composite material wire blank is subjected to multi-pass cold drawing, and the deformation rate is 60-99%. The diameter of the prepared graphene/copper composite wire is 0.1 cm-2 cm.
The invention adopts the continuous extrusion technology to prepare the composite material wire blank, realizes the continuous production of the wire blank, simultaneously adopts the multi-pass drawing technology to realize the further dispersion and orientation of the graphene in the copper matrix, and improves the performance of the composite wire. The graphene/copper composite wire prepared by the method has higher electrical conductivity while obviously improving the tensile strength; the method has the advantages of less procedures, continuous production and high production efficiency.
Detailed Description
The present invention will be described in detail with reference to specific examples. The following examples will assist those skilled in the art in further understanding the invention, but are not intended to limit the invention in any way. It should be noted that variations and modifications can be made by persons skilled in the art without departing from the spirit of the invention. All falling within the scope of the present invention.
The invention discloses a continuous preparation method of a graphene/copper composite wire, which comprises the following steps:
(1) mixing graphene and copper powder by adopting a solid phase; the mass ratio of the graphene is less than 5 wt%; the particle size of the copper powder is 50-500 mu m; the solid phase mixing method comprises mechanical mixing and pneumatic mixing;
(2) the composite powder is subjected to reduction treatment, and the reduction treatment method comprises the following steps: reducing for 1-4 h under the condition of hydrogen at the temperature of 400-600 ℃;
(3) preparing a graphene/copper composite material wire blank by adopting a continuous extruder, adding composite powder into a feed chute of the continuous extruder through a vibration funnel, continuously adding mixed powder through the vibration funnel at a speed of 20-40 g/s, and continuously extruding at 650-750 ℃, an extrusion wheel rotating speed of 5-15 rpm and an extrusion ratio of 10-30;
(4) and preparing the graphene/copper composite wire by adopting a multi-pass cold drawing technology. And (3) performing multi-pass cold drawing on the composite material wire blank, wherein the deformation rate is 60-99%.
Example 1
(1) 995g of copper powder with the particle size of 200-400 mu m and 5g of graphene powder (the mass ratio of graphene is 0.5 wt%) are weighed and put into a roller stirrer to be mixed, and the rotation speed is 12rpm and the mixture is mixed for 1 hour.
(2) And taking out the mixed powder, putting the powder into a reduction box filled with hydrogen, reducing the powder for 2 hours at 600 ℃, cooling and taking out the powder.
(3) And adding the composite powder into a feed chute of a continuous extruder through a vibrating funnel, wherein the adding speed is 20g/s, the rotating speed of an extrusion wheel is 7rpm, the temperature is about 650 ℃, the extrusion ratio is 10, and continuously extruding to obtain a composite wire blank with the diameter of 3 mm.
(4) And (3) carrying out multi-pass fine drawing on the obtained 3mm composite wire blank until the wire diameter is 1mm, wherein the deformation rate is 89%, so as to obtain the graphene/copper composite material wire.
The tensile strength of the lead can reach 450MPa, and the conductivity can reach 98.5% IACS.
Example 2
The difference from the embodiment 1 is that the mass ratio of the graphene in the step (1) is 1 wt%, the tensile strength of the composite wire prepared by the method can reach 500MPa, and the conductivity can reach 96.7% IACS.
Example 3
The difference from example 1 is that in step (3), the addition rate was 40g/s, the rotation speed of the extrusion wheel was 12rpm, the temperature was around 700 ℃, and the extrusion ratio was 20. The tensile strength of the lead can reach 430MPa, and the conductivity can reach 98% IACS.
Example 4
The difference from example 1 is that in step (4), fine drawing was carried out until the final wire diameter was 0.5mm and the deformation ratio was 97%. The tensile strength of the lead can reach 462MPa, and the conductivity can reach 98% IACS.
The embodiment shows that the graphene/copper composite wire prepared by the method has higher electrical conductivity while obviously improving the tensile strength; the method has the advantages of less procedures, continuous production and high production efficiency.
Claims (10)
1. A continuous preparation method of a graphene/copper composite wire comprises the following steps:
(1) mixing graphene and copper powder in a solid phase to obtain composite powder;
(2) carrying out reduction treatment on the composite powder;
(3) preparing a graphene/copper composite material wire blank by adopting a continuous extrusion technology;
(4) and preparing the graphene/copper composite wire by adopting a multi-pass cold drawing technology.
2. The continuous preparation method of the graphene/copper composite wire according to claim 1, wherein: the addition amount of the graphene is less than 5 wt%.
3. The continuous preparation method of the graphene/copper composite wire according to claim 1, wherein: the particle size of the copper powder is 50-500 mu m.
4. The continuous preparation method of the graphene/copper composite wire according to claim 1, wherein: the solid phase mixing method comprises mechanical mixing and pneumatic mixing.
5. The continuous preparation method of the graphene/copper composite wire according to claim 1, wherein: the reduction treatment method of the composite powder comprises the following steps: reducing for 1-4 h under the condition of hydrogen at the temperature of 400-600 ℃.
6. The continuous preparation method of the graphene/copper composite wire according to claim 1, wherein: the graphene/copper composite material wire blank is prepared by adopting a continuous extruder, and composite powder is continuously added through a vibration funnel at the speed of 20-40 g/s.
7. The continuous preparation method of the graphene/copper composite wire according to claim 6, wherein: and continuously extruding at 650-750 ℃, the rotating speed of the extrusion wheel is 5-15 rpm, and the extrusion ratio is 10-30.
8. The continuous preparation method of the graphene/copper composite wire according to claim 1, wherein: the diameter of the prepared graphene/copper composite material wire blank is 1 cm-3 cm.
9. The continuous preparation method of the graphene/copper composite wire according to claim 1, wherein: and (3) performing multi-pass cold drawing on the composite material wire blank, wherein the deformation rate is 60-99%.
10. The continuous preparation method of the graphene/copper composite wire according to claim 1, wherein: the diameter of the prepared graphene/copper composite wire is 0.1 cm-2 cm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811550044.6A CN111331127A (en) | 2018-12-18 | 2018-12-18 | Preparation method of graphene/copper composite wire |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811550044.6A CN111331127A (en) | 2018-12-18 | 2018-12-18 | Preparation method of graphene/copper composite wire |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111331127A true CN111331127A (en) | 2020-06-26 |
Family
ID=71175818
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811550044.6A Pending CN111331127A (en) | 2018-12-18 | 2018-12-18 | Preparation method of graphene/copper composite wire |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111331127A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112359244A (en) * | 2020-10-21 | 2021-02-12 | 有研工程技术研究院有限公司 | High-strength high-conductivity graphene copper composite wire and preparation method thereof |
Citations (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101948988A (en) * | 2010-10-28 | 2011-01-19 | 江西省电力科学研究院 | Method for manufacturing CNT (carbon nanotube) composite transmission conductor |
| CN103882257A (en) * | 2014-03-26 | 2014-06-25 | 武汉理工大学 | TiAl-graphene-Ti3SiC2 self-lubricating composite material and preparation method thereof |
| CN104711443A (en) * | 2015-03-18 | 2015-06-17 | 上海和伍新材料科技有限公司 | Graphene/copper composite and preparation method thereof |
| CN104862512A (en) * | 2015-04-21 | 2015-08-26 | 中国科学院宁波材料技术与工程研究所 | Method for improving graphene and copper basal body binding force in copper-based graphene composite material |
| CN105177379A (en) * | 2015-08-19 | 2015-12-23 | 合肥市田源精铸有限公司 | Graphene oxide composite material |
| US20150368535A1 (en) * | 2013-01-28 | 2015-12-24 | United Technologies Corporation | Graphene composites and methods of fabrication |
| CN105624457A (en) * | 2016-03-22 | 2016-06-01 | 北京工业大学 | Graphene enhanced magnesium-based composite and preparing method thereof |
| CN105838913A (en) * | 2016-04-08 | 2016-08-10 | 上海和伍复合材料有限公司 | Graphene/nickel composite material and preparation method thereof |
| CN106226365A (en) * | 2016-08-11 | 2016-12-14 | 安徽省宁国天成电工有限公司 | A kind of graphene/copper composite material and its preparation method and application |
| CN106548831A (en) * | 2016-12-10 | 2017-03-29 | 西北有色金属研究院 | A kind of preparation method of Graphene copper composite wire material |
| CN106744857A (en) * | 2016-12-30 | 2017-05-31 | 尹宗杰 | 3D printing Graphene metallic composite, preparation method and application |
| CN106784828A (en) * | 2016-12-30 | 2017-05-31 | 尹宗杰 | A kind of layer type casting moulding Graphene metallic composite and preparation method |
| CN108145169A (en) * | 2017-11-27 | 2018-06-12 | 中国船舶重工集团公司第七二五研究所 | A kind of high-strength highly-conductive graphene enhancing Cu-base composites and preparation method and application |
| CN108231273A (en) * | 2016-12-09 | 2018-06-29 | 北京有色金属研究总院 | A kind of method for improving copper aluminum composite material interface |
| CN108330340A (en) * | 2018-03-15 | 2018-07-27 | 哈尔滨工业大学 | A kind of preparation method of graphene reinforced aluminum matrix composites micrometer fibers |
| CN108326314A (en) * | 2017-12-25 | 2018-07-27 | 新疆烯金石墨烯科技有限公司 | A kind of preparation method and its continuous extrusion apparatus of composite material |
| CN108637247A (en) * | 2018-04-04 | 2018-10-12 | 常州日月机械有限公司 | The processing method of powder state non-ferrous metal |
-
2018
- 2018-12-18 CN CN201811550044.6A patent/CN111331127A/en active Pending
Patent Citations (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101948988A (en) * | 2010-10-28 | 2011-01-19 | 江西省电力科学研究院 | Method for manufacturing CNT (carbon nanotube) composite transmission conductor |
| US20150368535A1 (en) * | 2013-01-28 | 2015-12-24 | United Technologies Corporation | Graphene composites and methods of fabrication |
| CN103882257A (en) * | 2014-03-26 | 2014-06-25 | 武汉理工大学 | TiAl-graphene-Ti3SiC2 self-lubricating composite material and preparation method thereof |
| CN104711443A (en) * | 2015-03-18 | 2015-06-17 | 上海和伍新材料科技有限公司 | Graphene/copper composite and preparation method thereof |
| CN104862512A (en) * | 2015-04-21 | 2015-08-26 | 中国科学院宁波材料技术与工程研究所 | Method for improving graphene and copper basal body binding force in copper-based graphene composite material |
| CN105177379A (en) * | 2015-08-19 | 2015-12-23 | 合肥市田源精铸有限公司 | Graphene oxide composite material |
| CN105624457A (en) * | 2016-03-22 | 2016-06-01 | 北京工业大学 | Graphene enhanced magnesium-based composite and preparing method thereof |
| CN105838913A (en) * | 2016-04-08 | 2016-08-10 | 上海和伍复合材料有限公司 | Graphene/nickel composite material and preparation method thereof |
| CN106226365A (en) * | 2016-08-11 | 2016-12-14 | 安徽省宁国天成电工有限公司 | A kind of graphene/copper composite material and its preparation method and application |
| CN108231273A (en) * | 2016-12-09 | 2018-06-29 | 北京有色金属研究总院 | A kind of method for improving copper aluminum composite material interface |
| CN106548831A (en) * | 2016-12-10 | 2017-03-29 | 西北有色金属研究院 | A kind of preparation method of Graphene copper composite wire material |
| CN106744857A (en) * | 2016-12-30 | 2017-05-31 | 尹宗杰 | 3D printing Graphene metallic composite, preparation method and application |
| CN106784828A (en) * | 2016-12-30 | 2017-05-31 | 尹宗杰 | A kind of layer type casting moulding Graphene metallic composite and preparation method |
| CN108145169A (en) * | 2017-11-27 | 2018-06-12 | 中国船舶重工集团公司第七二五研究所 | A kind of high-strength highly-conductive graphene enhancing Cu-base composites and preparation method and application |
| CN108326314A (en) * | 2017-12-25 | 2018-07-27 | 新疆烯金石墨烯科技有限公司 | A kind of preparation method and its continuous extrusion apparatus of composite material |
| CN108330340A (en) * | 2018-03-15 | 2018-07-27 | 哈尔滨工业大学 | A kind of preparation method of graphene reinforced aluminum matrix composites micrometer fibers |
| CN108637247A (en) * | 2018-04-04 | 2018-10-12 | 常州日月机械有限公司 | The processing method of powder state non-ferrous metal |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112359244A (en) * | 2020-10-21 | 2021-02-12 | 有研工程技术研究院有限公司 | High-strength high-conductivity graphene copper composite wire and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108396168B (en) | A kind of preparation method of high-strength highly-conductive creep resistant graphene enhancing aluminum alloy materials | |
| Hidalgo-Manrique et al. | Copper/graphene composites: a review | |
| CN111451491B (en) | Preparation method of graphene reinforced copper-based composite material | |
| CN105112699A (en) | Preparation method of graphene/aluminum alloy composite material | |
| CN105112700A (en) | Graphene/aluminum composite material | |
| CN110331316B (en) | High-strength heat-resistant graphene-aluminum composite conductor material and preparation method thereof | |
| CN110760709B (en) | Preparation method of graphene reinforced magnesium composite material | |
| CN109694970B (en) | Aluminum-based composite material, electric wire using same, and method for producing aluminum-based composite material | |
| WO2019153953A1 (en) | Copper material and preparation method therefor | |
| JP6342871B2 (en) | Aluminum-based composite material and method for producing the same | |
| CN110449590B (en) | Preparation method and product of graphene-copper-based composite material | |
| CN109554565A (en) | A kind of interface optimization method of carbon nanotube enhanced aluminium-based composite material | |
| CN105112745A (en) | Graphene/aluminum alloy composite material | |
| CN102888525A (en) | Processing method of high-obdurability and high-conductivity copper magnesium alloy | |
| WO2015186423A1 (en) | Aluminum-based composite material and manufacturing method therefor | |
| CN111088441A (en) | Preparation method of high-electric-conductivity heat-conduction metal-based composite material | |
| CN101086923A (en) | A making method of silver/graphite electrical contact | |
| CN105112701A (en) | Preparation method of graphene/aluminum composite material | |
| CN1710124A (en) | Method for preparing reactive hot-press in-situ autogenesis copper-base composite material | |
| CN111331127A (en) | Preparation method of graphene/copper composite wire | |
| CN108588458A (en) | A kind of high preparation method for leading high-strength wearable copper-based material | |
| CN105112733A (en) | Method for preparing graphene/aluminum alloy composite material | |
| CN113088763A (en) | Graphene/aluminum alloy composite material and preparation method thereof | |
| Li et al. | Particle morphology dependence of the mechanical and electrical properties in the in-situ graphene reinforced Cu matrix composites | |
| CN105112734B (en) | A kind of graphene/aluminum composite material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200626 |
|
| RJ01 | Rejection of invention patent application after publication |