CN111322618A - Roasting furnace for treating industrial waste salt and treatment method thereof - Google Patents

Roasting furnace for treating industrial waste salt and treatment method thereof Download PDF

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Publication number
CN111322618A
CN111322618A CN202010258415.4A CN202010258415A CN111322618A CN 111322618 A CN111322618 A CN 111322618A CN 202010258415 A CN202010258415 A CN 202010258415A CN 111322618 A CN111322618 A CN 111322618A
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China
Prior art keywords
cone
furnace
roasting furnace
discharging
roasting
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CN202010258415.4A
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Chinese (zh)
Inventor
陈天虎
汪家权
胡孔元
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Anhui Ke'an Waste Salt Recycling Co ltd
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Anhui Ke'an Waste Salt Recycling Co ltd
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Priority to CN202010258415.4A priority Critical patent/CN111322618A/en
Publication of CN111322618A publication Critical patent/CN111322618A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • F23G5/0273Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage using indirect heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/08Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
    • F23G5/12Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating using gaseous or liquid fuel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/44Details; Accessories
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/44Details; Accessories
    • F23G5/442Waste feed arrangements
    • F23G5/444Waste feed arrangements for solid waste
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/50Control or safety arrangements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2204/00Supplementary heating arrangements
    • F23G2204/10Supplementary heating arrangements using auxiliary fuel
    • F23G2204/103Supplementary heating arrangements using auxiliary fuel gaseous or liquid fuel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2205/00Waste feed arrangements
    • F23G2205/14Waste feed arrangements using hopper or bin
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2207/00Control
    • F23G2207/10Arrangement of sensing devices
    • F23G2207/101Arrangement of sensing devices for temperature

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Gasification And Melting Of Waste (AREA)

Abstract

The invention discloses a roasting furnace for treating industrial waste salt and a treatment method thereof, wherein the roasting furnace is a vertical indirect heating roasting furnace and is formed by assembling a bottom discharge cone, a middle roasting furnace cylinder body and an upper blanking mechanism in three sections, a pyrolysis cavity for roasting and pyrolyzing the industrial waste salt and a closed cavity for flowing hot air of a burner are respectively formed in the roasting furnace cylinder body, and all parts in contact with high-temperature salt in the roasting furnace are provided with high-temperature chlorine salt corrosion resistant protective layers. The roasting furnace equipment can realize roasting recycling of industrial waste salt, and solves the problems of corrosion to the equipment and secondary pollution in pyrolysis roasting of the waste salt.

Description

Roasting furnace for treating industrial waste salt and treatment method thereof
Technical Field
The invention belongs to the field of solid waste and hazardous waste treatment, and particularly relates to equipment and a method for recycling industrial waste salt.
Background
Many processes produce large quantities of waste salts containing organic materials, such as: the tail end of the device for producing phenol, acetone, formic acid, vitamin C and the like can generate a large amount of waste salt; the organic matter in the total solid dissolved by the waste salt generated in the vitamin production accounts for nearly 30 percent. Many waste salts are listed in national hazardous waste lists, and the yield of the waste salts is continuously increased along with the development of important fine chemical engineering and intermediate products. Because the waste salt contains harmful substances, the waste salt cannot be directly used as an industrial raw material, the waste salt is difficult to dispose and high in cost, and a large amount of land is occupied because many enterprises continuously build warehouses for storage. Therefore, how to treat the waste and miscellaneous salt in a harmless way with low investment and low cost and utilize the waste and miscellaneous salt as resources becomes a major problem to be solved urgently.
① extraction of organic matters, namely, extracting the organic matters by using a solvent to remove toxic and harmful chemical substances in the waste salt as much as possible, wherein the application range of the method is small, the extractant can generate secondary pollution, and the organic matters are not completely removed, ② high-temperature oxidation method is that the waste salt is calcined at a high temperature of more than 800 ℃ by using a rotary kiln, a fluidized bed furnace and other thermal equipment, so that the organic matters in the waste salt are decomposed and oxidized into gaseous components at a high temperature, but the melting point of some miscellaneous salts is low, the phenomena of melting, ring formation, caking and the like occur, so that the normal operation of the rotary kiln or the fluidized bed furnace equipment is influenced, ③ molten state treatment method is that salt slag is heated to a melting point by thermal equipment, the organic matters are thermally decomposed and oxidized into harmful impurities, the method has the defects of high equipment investment, complex process, high energy consumption and the like, ④ medium-low-temperature pyrolysis method is characterized in that the salt slag is treated by a pyrolysis furnace at a temperature of less than 600 ℃, the organic matters are thermally decomposed, the organic matters are separated from the volatile tail gas, and the decomposed solid components are remained on the surface of the solid salt, the defects are that.
One of the difficulties of the pyrolysis roasting of the waste salt is that the equipment is seriously corroded due to the reaction of the chloride with metal and metal oxide at high temperature, so the structural design and corrosion resistance of the equipment are the first problems to be solved. Secondly, the reaction of chloride with metal oxide and organic matters at high temperature can form toxic and harmful organic pollutants, and how to reduce or eliminate secondary pollution is another difficult problem of roasting mixed salt and realizing resource utilization.
Disclosure of Invention
Based on the defects of the prior art, the invention discloses a roasting furnace for treating industrial waste salt and a treatment method thereof, so as to solve the problems of corrosion to equipment and secondary pollution in waste salt pyrolysis roasting.
In order to realize the purpose of the invention, the following technical scheme is adopted:
a roasting furnace for treating industrial waste salt is a vertical indirect heating roasting furnace and is characterized in that: the roasting furnace is formed by assembling a bottom discharging cone, a middle roasting furnace cylinder and an upper discharging mechanism in three sections;
a cover plate is arranged at the top of the roasting furnace cylinder;
a cone is arranged in the roasting furnace barrel, the bottom of the cone is fixedly communicated with a bottom round basin, an air inlet pipe used for being communicated with an outlet pipe of a combustor is arranged on the side surface of the bottom round basin, and a combustion waste gas exhaust pipe is connected to the top of the cone; the air inlet pipe, the bottom round basin, the cone and the combustion waste gas exhaust pipe form a closed cavity for hot air flow of the combustor to flow; an air distribution round table is arranged in the conical cavity; an opening for leading out a combustion waste gas exhaust pipe is formed in the cover plate;
the blanking mechanism comprises a blanking hopper, and a blanking screw rod driven by a driving motor is arranged in the blanking hopper; an opening for leading in an outlet of the blanking hopper is formed in the cover plate, and the outlet of the blanking hopper penetrates through the cover plate and extends into the furnace body;
a pyrolysis cavity for roasting and pyrolyzing industrial waste salt is formed between the furnace body shell of the roasting furnace cylinder and the cone; an upper distributing cone and a lower distributing cone are arranged in the pyrolysis cavity;
a pyrolysis gas exhaust pipe is arranged on the cover plate and communicated to the pyrolysis cavity;
the discharging cone is communicated and assembled at the bottom of the roasting furnace cylinder, and a discharging port control inserting plate is arranged at the outlet of the discharging cone; and an outlet for leading out the air inlet pipe is arranged on one side of the discharging cone.
Furthermore, protective layers resistant to high-temperature chlorine salt corrosion are arranged on the inner surface of the furnace body shell, the inner surface of the cover plate, the inner surface of the discharge cone shell, the inner surface of the pyrolysis gas exhaust pipe, the outer surface of the combustion waste gas exhaust pipe, the outer surfaces of the upper distributing cone and the lower distributing cone and the surface of the discharge port control inserting plate; the protective layer can be formed by lining ceramic and refractory bricks or by casting or coating kiln castable, and the content of iron oxide in the castable is less than or equal to 0.5 percent.
Furthermore, the conical cavity and the bottom round basin are made of silicon carbide and are formed by sintering silicon carbide powder after casting molding.
Further, the outlet of the combustion waste gas exhaust pipe is inserted into the blanking hopper.
Furthermore, the cover plate and the roasting furnace cylinder body and the discharging cone body are connected through flanges, and sealing gaskets are arranged.
Further, a material distribution circular table is arranged right below the outlet of the blanking hopper and fixed on the outer wall of the combustion waste gas exhaust pipe; the upper part of the air distribution round platform is fixed at the bottom of the air distribution round platform through a hanging rod.
Furthermore, a plurality of thermocouple temperature measuring points are arranged at different heights of the furnace body shell; and an observation hole is formed in the middle lower part of the furnace body shell.
Furthermore, the blanking hopper is fixed on the cover plate through a plurality of first supporting columns; the bottom round basin is fixed on the shell of the discharging cone through a plurality of second support columns; and a plurality of third supporting columns for supporting the material to the ground are arranged below the discharging cone.
Furthermore, the outer surfaces of the parts of the second supporting column and the third supporting column, which are positioned in the pyrolysis cavity, are provided with protective layers resistant to high-temperature chlorine salt corrosion.
The method for treating the industrial waste salt by using the roasting furnace comprises the following steps:
conveying industrial waste salt to be treated into a feed hopper through a hoister, and discharging the industrial waste salt into a pyrolysis cavity through a discharging screw rod under the driving of a driving motor; the materials are dispersed and scattered through the upper distributing cone and the lower distributing cone and slide down along the surfaces of the upper distributing cone, the lower distributing cone and the cone by means of gravity;
the outlet pipe of the burner is connected and sealed with the inlet pipe of the bottom round basin, the hot air flow of fuel combustion spirally rises in the gap between the cone and the air distribution round platform by means of the air pressure of the burner, and the heat of the hot air flow exchanges heat with the wall of the bottom round basin through the cone to heat the material in the pyrolysis cavity; after heat exchange, hot air flow is discharged from a combustion waste gas exhaust pipe, can be directly discharged because the hot air flow is not polluted, and can also be introduced into a blanking hopper to preheat materials;
the temperature of the highest temperature area outside the bottom round basin is controlled to be 500-;
in the sliding process, the temperature of the material rises, and the organic matters are heated and decomposed into volatile gas and carbon; the pyrolysis gas is led out from the pyrolysis gas exhaust pipe, cooled, purified by an internal dry method of a bag type dust collector to remove nitrogen oxides, sulfur dioxide and salt particles, and then conveyed to a combustor to be combusted as fuel, or independently combusted and purified to reach the standard and then discharged.
The solid product is discharged through the outlet of the discharge cone.
The invention has the beneficial effects that:
1. the roasting furnace is a vertical indirect heating roasting furnace and is formed by assembling a bottom discharge cone, a middle roasting furnace cylinder and an upper blanking mechanism in three sections, so that equipment is convenient to transport and install.
2. The cone, the bottom circular basin and the related pipelines inside the roasting furnace cylinder are assembled into a whole to be used as an inner cavity for the flowing of the hot air flow of the burner, the organic matter in the waste salt is pyrolyzed by adopting an indirect heating mode, and the contact of the hot air flow of the burner with miscellaneous salt and the pyrolysis gas of the organic matter is isolated. The hot air flow of the burner with large air flow can be directly discharged without any pollution, the pyrolysis gas flow is small, and the purification treatment is independently carried out, so that the difficulty of the treatment of the waste gas generated by roasting mixed salt is reduced, and the treatment cost and the secondary pollution risk are reduced.
3. The cone inside the roasting furnace barrel and the round basin at the bottom of the roasting furnace barrel are cast and molded by silicon carbide powder with high temperature chlorine corrosion resistance and large heat conductivity coefficient and then are sintered at high temperature, all parts in the roasting furnace barrel, which are contacted with high-temperature salt, are provided with a protective layer with high temperature chlorine salt corrosion resistance, so that the problem of high temperature chlorine salt corrosion caused by mixed salt roasting is solved, the whole roasting furnace has no metal surface and variable-valence metal oxide and high-temperature salt materials with the temperature of more than 300 ℃, and the oxidation-reduction reaction and the associated reaction of the chlorine salt and the metal oxide at high temperature are avoided.
4. The miscellaneous salt pyrolysis gas is cooled, purified by a dry method in a bag type dust collector to remove nitrogen oxides, sulfur dioxide and chlorine salt fine particles carried by airflow, and then conveyed to a combustor to be combusted at a high temperature of more than 1000 ℃ to reach the standard and be discharged, so that secondary pollution caused by roasting miscellaneous salt is completely avoided.
5. The furnace wall is provided with a thermocouple temperature measuring point, the outlet of the pyrolysis gas exhaust pipe can be also provided with an oxygen content measuring instrument and a pressure gauge, the high-precision thermocouple temperature measuring instrument, the oxygen measuring instrument, the micro-pressure gauge and the like are adopted to measure the parameters of the temperature, the oxygen content, the total pressure and the like in the furnace, and the whole process is accurately and automatically controlled.
Drawings
Fig. 1 is a schematic structural diagram of a roasting furnace for industrial waste salt treatment according to the present invention, wherein the reference numbers are as follows: 1-furnace body shell, 2-protective layer, 3-cone, 4-bottom round basin, 4A-air inlet pipe, 5-air distribution round platform, 6-suspension rod, 7-driving motor, 8-blanking screw, 9-blanking hopper, 10-combustion waste gas exhaust pipe, 11-pyrolysis gas exhaust pipe, 12-upper distribution cone, 13-lower distribution cone, 14-discharge cone, 14A-discharge port control plug board, 15-cover board, 16-sealing gasket, 17-air distribution round platform, 18-thermocouple temperature measurement point, 19-observation hole, 20C-first support column, 20B-second support column, and 20A-third support column.
Detailed Description
The following examples are given for the detailed implementation and specific operation of the present invention, but the scope of the present invention is not limited to the following examples.
Example 1
As shown in fig. 1, the roasting furnace for treating industrial waste salt in the embodiment is a vertical indirect heating roasting furnace, and is formed by assembling a bottom discharge cone, a middle roasting furnace cylinder and an upper blanking mechanism in three sections;
a cover plate 15 is arranged at the top of the roasting furnace cylinder;
a cone 3 is arranged in the roasting furnace barrel, the bottom of the cone 3 is fixedly communicated with a bottom round basin 4, the side surface of the bottom round basin 4 is provided with an air inlet pipe 4A for communicating with an outlet pipe of a burner, and the top of the cone 3 is connected with a combustion waste gas exhaust pipe 10; a closed cavity for flowing hot air of the burner is formed by an air inlet pipe 4A, a bottom round basin 4, a cone 3 and a combustion waste gas exhaust pipe 10; an air distribution round table 5 is arranged in the conical cavity 3; an opening for leading out the combustion waste gas exhaust pipe 10 is arranged on the cover plate 15;
the blanking mechanism comprises a blanking hopper 9, and a blanking screw 8 driven by a driving motor 7 is arranged in the blanking hopper 9; an opening for introducing an outlet of the lower hopper 9 is formed in the cover plate 15, and the outlet of the lower hopper 9 penetrates through the cover plate 15 and extends into the furnace body;
a pyrolysis cavity for roasting and pyrolyzing industrial waste salt is formed between the furnace body shell 1 and the cone 3 of the roasting furnace cylinder; an upper distributing cone 12 and a lower distributing cone 13 are arranged in the pyrolysis cavity;
a pyrolysis gas exhaust pipe 11 is arranged on the cover plate 15, and the pyrolysis gas exhaust pipe 11 is communicated to the pyrolysis cavity;
the discharge cone 14 is communicated and assembled at the bottom of the roasting furnace cylinder, and a discharge port control inserting plate 14A is arranged at the outlet of the discharge cone 14; an outlet for the inlet pipe 4A is provided at one side of the outlet cone 14.
In the specific implementation, the inner surface of the furnace body shell 1, the inner surface of the cover plate 15, the inner surface of the shell of the discharging cone 14, the inner surface of the pyrolysis gas exhaust pipe 11, the outer surface of the combustion waste gas exhaust pipe 10, the outer surfaces of the upper distributing cone 12 and the lower distributing cone 13, and the surface of the discharging port control inserting plate 14A are all provided with a high-temperature chlorine salt corrosion resistant protective layer 2. The protective layer can be formed by lining ceramic and refractory bricks or by casting or coating kiln castable, and the content of iron oxide in the castable is less than or equal to 0.5 percent.
In specific implementation, the conical cavity 3 and the bottom circular basin 4 are made of silicon carbide and are formed by casting and firing silicon carbide powder.
In specific implementation, the outlet of the exhaust pipe 10 for the combustion waste gas can be inserted into the discharging hopper 9, or can be directly emptied. The hot air current is discharged from the burning waste gas blast pipe after the heat transfer, because of not polluted, can directly discharge, also can introduce down the hopper in to preheat the material.
In the specific implementation, the cover plate 15 and the roasting furnace cylinder and the discharge cone 14 are connected by flanges, and the gaps at the flange connection positions are sealed by sealing gaskets 16.
In specific implementation, a cloth circular table 17 is arranged right below an outlet of the blanking hopper 9, and the cloth circular table 17 is fixed on the outer wall of the combustion waste gas exhaust pipe 10; the upper part of the air distribution round platform 5 is fixed at the bottom of the air distribution round platform 17 through a hanging rod.
In specific implementation, an inlet pipe and an outlet pipe of the combustion waste gas exhaust pipe 10 are connected up and down and are not on the same straight line, the position is set under an outlet of the blanking hopper 9, and a cloth circular table is convenient to arrange at the position of a horizontal pipe.
In specific implementation, a plurality of thermocouple temperature measuring points 18 are arranged at different heights of the furnace body shell 1, and the specific positions and the number can be set as required; an observation hole 19 is arranged at the middle lower part of the furnace body shell 1, and the specific position can be arranged as required.
In specific implementation, the blanking hopper 9 is fixed on the cover plate 15 through a plurality of first supporting columns 20C; the bottom round basin 4 is fixed on the shell of the discharging cone 14 through a plurality of second support columns 20B; a plurality of third support columns 20A which are supported to the ground are arranged below the discharging cone 14. In order to make the support more stable, the first support column directly supports the upper surface of the lower hopper, the second support column passes through the protective layer and supports the shell of the discharging cone 14, and the third support column supports the upper flange surface of the discharging cone.
In specific implementation, the outer surfaces of the portions of the second supporting column 20B and the third supporting column 20C in the pyrolysis chamber are provided with the protective layer 2 resistant to corrosion of high-temperature chlorine salt. The roasting furnace is characterized in that a high-temperature chlorine salt corrosion resistant protective layer is arranged at each part in the roasting furnace cylinder body, which is contacted with high-temperature salt, and a cone and a bottom circular basin in the roasting furnace cylinder body are made of silicon carbide materials with high-temperature chlorine corrosion resistance and high heat conductivity coefficient, so that the problem of high-temperature chlorine salt corrosion caused by roasting of miscellaneous salt is solved, the whole roasting furnace has no metal surface, and the valence-variable metal oxide is contacted with the high-temperature salt material with the temperature of more than 300 ℃, so that the oxidation-reduction reaction and the associated reaction of the chlorine salt and the metal oxide at.
In the specific implementation, the protective layer below the upper distributing cone 12 and the lower distributing cone 13 is thickened to form a boss, and an annular supporting steel sheet is arranged inside the boss, so that the upper distributing cone 12 and the lower distributing cone 13 are formed.
Specifically, in this embodiment, a small prototype of the roasting furnace is manufactured according to fig. 1, and a bottom discharge cone, a middle roasting furnace cylinder, an upper blanking mechanism and key components thereof are manufactured respectively. A furnace body shell 1 of a roasting furnace cylinder body is formed by rolling a 310S stainless steel plate with the thickness of 5mm, a 6cm long chicken claw-shaped tooth nail is welded inside the furnace body shell, and a casting material is poured to form a protective layer 2; pulping by using silicon carbide powder, manufacturing a mould according to the shapes of an inner cone 3 and a bottom round basin 4 with an air inlet pipe, casting and sintering; the internal gas distribution circular platform 5, the suspender 6 of the gas distribution circular platform, the upper distributing cone 12, the lower distributing cone 13 and the support column 20B are made of high-temperature-resistant 310S stainless steel; the driving motor is a variable frequency motor, and the blanking screw rod and the blanking hopper are made of stainless steel; the shell of the discharge cone 14, the combustion waste gas exhaust pipe 10, the pyrolysis gas exhaust pipe 11 and the discharge hole control inserting plate 14A are made of carbon steel; the inner surface of the pyrolysis gas exhaust pipe 11 is coated with a protective layer with the thickness of 2mm of castable, and the other corresponding parts contacting with the miscellaneous salts are coated with protective layers with the thickness of 5cm of castable. The thermocouple uses a silicon carbide ceramic tube as a protective sleeve, and the observation hole is made of the silicon carbide ceramic tube. The sealing washer 16 is made of high-temperature-resistant mullite cotton. The whole roasting furnace has no metal surface and the contact of the valence-variable metal oxide and the high-temperature salt material, so that the oxidation-reduction reaction and the related reaction of the chlorine salt and the metal oxide at high temperature are avoided.
The method for treating the industrial waste salt by using the roasting furnace comprises the following steps:
industrial waste salt to be treated is conveyed into a feed hopper 9 through a hoister, and is fed into a pyrolysis cavity through a feeding screw 8 under the drive of a drive motor 7; the materials are dispersed and scattered through the upper distributing cone 12 and the lower distributing cone 13 and slide down along the surfaces of the upper distributing cone, the lower distributing cone and the cone 3 by means of gravity;
an outlet pipe of the burner is connected and sealed with an inlet pipe 4A of the bottom round basin 4, hot air flow generated by fuel combustion spirally rises in a gap between the cone 3 and the air distribution round platform 5 by means of air pressure of the burner, and heat of the hot air flow exchanges heat through the cone and the wall of the bottom round basin, so that materials in the pyrolysis cavity are heated; the hot air flow after heat exchange is discharged from a combustion waste gas exhaust pipe 10;
measuring the temperature by a thermocouple, and controlling the temperature outside the bottom round basin 4 to be 600-650 ℃;
in the sliding process, the temperature of the material rises, and the organic matters are heated and decomposed into volatile gas and carbon; the pyrolysis gas is led out from the pyrolysis gas exhaust pipe 11, cooled, purified by an internal dry method of a bag type dust collector to remove nitrogen oxides, sulfur dioxide and salt particles, and then conveyed to a combustor to be combusted as fuel, or independently combusted and purified to reach the standard and then discharged.
The solid product is discharged through the outlet of the discharge cone 14.
The device and the method can realize roasting recycling of industrial waste salt, and solve the problems of corrosion to the device and secondary pollution in pyrolysis roasting of the waste salt.

Claims (10)

1. A roasting furnace for treating industrial waste salt is a vertical indirect heating roasting furnace, and is characterized in that: the roasting furnace is formed by assembling a bottom discharging cone, a middle roasting furnace cylinder and an upper discharging mechanism in three sections;
a cover plate (15) is arranged at the top of the roasting furnace cylinder;
a cone (3) is arranged in the roasting furnace barrel, the bottom of the cone (3) is fixedly communicated with a bottom round basin (4), an air inlet pipe (4A) for communicating with an outlet pipe of a burner is arranged on the side surface of the bottom round basin (4), and the top of the cone (3) is connected with a combustion waste gas exhaust pipe (10); a closed cavity for hot airflow of the burner to flow is formed by the air inlet pipe (4A), the bottom round basin (4), the cone (3) and the combustion waste gas exhaust pipe (10); an air distribution circular table (5) is arranged in the conical cavity (3); an opening for leading out the combustion waste gas exhaust pipe (10) is arranged on the cover plate (15);
the blanking mechanism comprises a blanking hopper (9), and a blanking screw (8) driven by a driving motor (7) is arranged in the blanking hopper (9); an opening for introducing an outlet of the discharging hopper (9) is formed in the cover plate (15), and the outlet of the discharging hopper (9) penetrates through the cover plate (15) and extends into the furnace body;
a pyrolysis cavity for roasting and pyrolyzing industrial waste salt is formed between the furnace body shell (1) of the roasting furnace cylinder and the cone (3); an upper distributing cone (12) and a lower distributing cone (13) are arranged in the pyrolysis cavity;
a pyrolysis gas exhaust pipe (11) is arranged on the cover plate (15), and the pyrolysis gas exhaust pipe (11) is communicated to the pyrolysis cavity;
the discharging cone (14) is communicated and assembled at the bottom of the roasting furnace cylinder, and a discharging port control inserting plate (14A) is arranged at an outlet of the discharging cone (14); an outlet for leading out the air inlet pipe (4A) is arranged on one side of the discharging cone (14).
2. The furnace of claim 1, wherein: the internal surface of furnace body shell (1) the internal surface of apron (15) the internal surface of ejection of compact cone (14) shell the internal surface of pyrolysis gas blast pipe (11) the surface of combustion gas blast pipe (10) go up cloth awl (12) with the surface of lower cloth awl (13) reaches the surface of discharge gate control picture peg (14A) all is provided with high temperature resistant chlorine salt corrosion's protective layer (2).
3. The furnace of claim 1, wherein: the conical cavity (3) and the bottom round basin (4) are made of silicon carbide.
4. The furnace of claim 1, wherein: the outlet of the combustion waste gas exhaust pipe (10) is inserted into the discharging hopper (9).
5. The furnace of claim 1, wherein: the cover plate (15) is connected with the roasting furnace cylinder body and the roasting furnace cylinder body is connected with the discharging cone body through flanges, and sealing gaskets (16) are arranged.
6. The furnace of claim 1, wherein: a cloth circular table (17) is arranged right below the outlet of the discharging hopper (9), and the cloth circular table (17) is fixed on the outer wall of the combustion waste gas exhaust pipe (10); the upper part of the air distribution round platform (5) is fixed at the bottom of the air distribution round platform (17) through a hanging rod.
7. The furnace of claim 1, wherein: a plurality of thermocouple temperature measuring points (18) are arranged at different heights of the furnace body shell (1); an observation hole (19) is arranged at the middle lower part of the furnace body shell (1).
8. The furnace of claim 1, wherein: the blanking hopper (9) is fixed on the cover plate (15) through a plurality of first supporting columns (20C); the bottom round basin (4) is fixed on the shell of the discharging cone (14) through a plurality of second supporting columns (20B); and a plurality of third supporting columns (20A) which are supported to the ground are arranged below the discharging cone (14).
9. The furnace of claim 1, wherein: the outer surfaces of the parts, located in the pyrolysis cavity, of the second supporting column (20B) and the third supporting column (20C) are provided with a high-temperature chlorine salt corrosion resistant protective layer (2).
10. A method for treating industrial waste salt by using the roasting furnace of any one of claims 1 to 9, characterized in that:
industrial waste salt to be treated is conveyed into a feed hopper (9) through a hoister, and is discharged into a pyrolysis cavity through a discharging screw rod (8) under the drive of a drive motor (7); the materials are dispersed and scattered through an upper distributing cone (12) and a lower distributing cone (13) and slide down along the surfaces of the upper distributing cone, the lower distributing cone and the cone (3) by means of gravity;
an outlet pipe of the burner is connected and sealed with an inlet pipe (4A) of the bottom round basin (4), hot air flow generated by fuel combustion spirally rises in a gap between the cone (3) and the air distribution round platform (5) by means of air pressure of the burner, and heat of the hot air flow exchanges heat through the cone and the wall of the bottom round basin to heat materials in the pyrolysis cavity; the hot air flow is discharged from a combustion waste gas exhaust pipe (10) after heat exchange;
the temperature of the outside of the bottom round basin (4) is controlled at 500-;
in the sliding process, the temperature of the material rises, and the organic matters are heated and decomposed into volatile gas and carbon; the pyrolysis gas is led out from a pyrolysis gas exhaust pipe (11), cooled, purified by a bag type dust collector internal dry method to remove nitrogen oxides, sulfur dioxide and salt particles, and then conveyed to a combustor to be combusted as fuel, or independently combusted and purified to reach the standard and then discharged;
the solid product is discharged through the outlet of the discharge cone (14).
CN202010258415.4A 2020-04-03 2020-04-03 Roasting furnace for treating industrial waste salt and treatment method thereof Pending CN111322618A (en)

Priority Applications (1)

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CN202010258415.4A CN111322618A (en) 2020-04-03 2020-04-03 Roasting furnace for treating industrial waste salt and treatment method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010258415.4A CN111322618A (en) 2020-04-03 2020-04-03 Roasting furnace for treating industrial waste salt and treatment method thereof

Publications (1)

Publication Number Publication Date
CN111322618A true CN111322618A (en) 2020-06-23

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010258415.4A Pending CN111322618A (en) 2020-04-03 2020-04-03 Roasting furnace for treating industrial waste salt and treatment method thereof

Country Status (1)

Country Link
CN (1) CN111322618A (en)

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