CN108910860A - A kind of depth purifying plant of carbon materials - Google Patents

A kind of depth purifying plant of carbon materials Download PDF

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Publication number
CN108910860A
CN108910860A CN201811019414.3A CN201811019414A CN108910860A CN 108910860 A CN108910860 A CN 108910860A CN 201811019414 A CN201811019414 A CN 201811019414A CN 108910860 A CN108910860 A CN 108910860A
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CN
China
Prior art keywords
furnace body
carbon materials
combustion chamber
upper furnace
lower furnace
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201811019414.3A
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Chinese (zh)
Inventor
胡潇鸿
钱勇励
钱五仁
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Inner Mongolia Litai Bioligical Energy Co Ltd
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Inner Mongolia Litai Bioligical Energy Co Ltd
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Priority to CN201811019414.3A priority Critical patent/CN108910860A/en
Publication of CN108910860A publication Critical patent/CN108910860A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/05Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00Heat treatments such as Calcining; Fusing ; Pyrolysis
    • B01J6/001Calcining
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/08Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Coke Industry (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The present invention relates to a kind of depth purifying plants of carbon materials, including raw material cabin, upper furnace body, lower furnace body and combustion chamber.Wherein, the upper furnace body is equipped with feed end, the lower furnace body is equipped with discharge end, and the outlet of the raw material cabin is connect with the feed end, for conveying carbon materials into the upper furnace body, the upper furnace body and lower furnace body are arranged along the vertical direction, the combustion chamber is equipped with the material cavity of perforation, carbon materials are after raw material cabin entrance between the upper furnace body and lower furnace body in the upper furnace body, lower furnace body and combustion chamber, successively pass through upper furnace body, combustion chamber and lower furnace body, is exported from discharge end.Smokeless, odorless, tasteless and nonirritant volatilization gas when carbon materials after processing burn, and be easy to light, combustion efficiency and Matter Composition can be used as the use of clean carbon fuel close to carbo lignius.The device is purified especially suitable for the roasting of semi-coke.

Description

A kind of depth purifying plant of carbon materials
Technical field
The present invention relates to technical field of industrial equipment, and in particular to a kind of depth purifying plant of carbon materials.
Background technique
Carbon materials include the substances such as coal, coke, semi-coke, petroleum coke, charcoal, graphite.In the carbon materials as fuel In, often containing substances such as coal tar, sulphur, nitrogen, ammonia, phosphorus.Burn the pernicious gases such as ammonia, sulfur dioxide, the nitrogen oxide generated, Environment is not only polluted, and irritation and toxicity are generated to the respiratory system of people, influences human health.
Wherein, semi-coke is the novel carbon materials of one kind made of cleaned coal is fired, specific resistance height, change high with fixed carbon Activity height, characteristic low containing ash, aluminium sulphur phosphorus element content is low are learned, has gradually replaced metallurgical coke and has been widely used in calcium carbide, iron The production of the products such as alloy, ferrosilicon, silicon carbide becomes a kind of irreplaceable carbon material.Semi-coke can replace coke (metallurgy It is burnt) and it is widely used in the industries such as chemical industry, smelting, gas making.In recent years, pushing away with the work of Environmental air contaminant treatment Row, for semi-coke as a kind of clean fuel, product has progressively reached national environmental protection type fuel standard requirement, and has been used as domestic fuel Come into public lives.
But semi-coke is when as domestic fuel, greatest drawback, and is at present coal chemical industry insurmountable one A problem is:Semi-coke can release niff in burning, and this smell has irritation and poison to the respiratory system of people Property, and to a certain extent in the presence of pollution environment space, the problems such as polluting food materials, influence the health of people.This problem is long Phase hampers the alternative fuel of semi-coke and its product as carbo lignius, and the extensive use in civil field.Pass through detection point Analysis, semi-coke is interior containing substances such as a small amount of coal tar, sulphur, nitrogen, ammonia, phosphorus, and when semi-coke is burnt, these substances are sent out under high temperature environment Angerization, and evaporate into air.
Current domestic all semi-coke manufacturers, all because of the object phase composition of semi-coke, controlling of production process condition, equipment Can etc. factors limitation and influence, can not be thoroughly by complete extracting and developings of substances such as coal tar, sulphur, nitrogen, ammonia in semi-coke or thorough Bottom removal.Therefore current all producers for carrying out coal fundamental mode charcoal production, it can not all produce, burning close with carbo lignius composition Effect is suitable, and when burning does not pollute food materials, can directly contact with food materials, for being baked, baking food materials, when burning is smokeless, odorless, The coal fundamental mode charcoal product of tasteless and nonirritant volatilization gas.
In consideration of it, the present invention is specifically proposed.
Summary of the invention
The purpose of the present invention is to provide a kind of depth purifying plants of carbon materials.
To achieve the above object, technical scheme is as follows:
The present invention relates to a kind of depth purifying plants of carbon materials, including raw material cabin, upper furnace body, lower furnace body and burning Room,
Wherein, the upper furnace body is equipped with feed end, and the lower furnace body is equipped with discharge end,
The outlet of the raw material cabin is connect with the feed end, for conveying carbon materials into the upper furnace body,
The upper furnace body and lower furnace body are arranged along the vertical direction, the combustion chamber be located at the upper furnace body and lower furnace body it Between, the material cavity of perforation is equipped in the upper furnace body, lower furnace body and combustion chamber,
Carbon materials successively pass through upper furnace body, combustion chamber and lower furnace body after raw material cabin entrance, export from discharge end.
Preferably, described device further includes feedstock transportation mechanism, feedstock transportation mechanism one end and the raw material cabin Outlet connection, the other end are connect with the feed end of the upper furnace body, for providing power for the carbon materials of feeding upper furnace body.
Preferably, described device further includes exhaust collection output mechanism, and the exhaust collection output mechanism is located on described Furnace body top, the flue gas discharge for will be generated in the upper furnace body, lower furnace body and combustion chamber.
Preferably, described device further includes cooling jacket, and the cooling jacket is located at the periphery of the lower furnace body, for cold But the carbon materials after roasting.
Preferably, described device further includes conveying body, the entrance of the conveying body and the lower furnace body Discharge end connection, for for output lower furnace body carbon materials power is provided.
Preferably, described device further includes cylinder round sifter structure, and the entrance of the cylinder round sifter structure and the discharging are defeated The outlet connection of mechanism out, for being sieved to the carbon materials of output.
Preferably, described device further includes air supply tube, and the air supply tube and the combustion chamber penetrate through, for being the burning Room provides combustion-supporting gas.
Preferably, the number of the air supply tube is 3~6.
Preferably, the upper furnace body surface is equipped with upper observation hole, and the lower furnace body surface is equipped with lower observation hole.
Preferably, the upper observation hole and lower observation hole are respectively positioned on close to the position of the combustion chamber.
The invention further relates to application of the described device in semi-coke roasting purification process.
Beneficial effects of the present invention:
The present invention provides a kind of depth purifying plant of carbon materials, the device is by carrying out high temperature roasting to carbon materials It burns, increases its specific surface area and porosity, density and strength reduction become so that making the burning point of carbon materials significantly reduces It is readily burned, while making hot environment of the solid matters such as remaining coal tar, sulphur, nitrogen, ammonia at >=1000 DEG C in carbon materials Angerization and volatilization are issued, is separated from carbon materials, controls its content in carbon materials within 0.2%.
Smokeless, odorless, tasteless and nonirritant volatilization gas when carbon materials after processing burn, and be easy to light, Combustion efficiency and Matter Composition close to carbo lignius, when burning to food materials, it is pollution-free to space, long-time service will not be to the body of people Health has an adverse effect, and can be used as the use of clean carbon fuel.The device is purified especially suitable for the roasting of semi-coke.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this hair Bright some embodiments for those of ordinary skill in the art without creative efforts, can be with root Other attached drawings are obtained according to these attached drawings.
Fig. 1 is the structural schematic diagram of the depth purifying plant of carbon materials.
1- raw material cabin in figure;
2- upper furnace body;
21- upper observation hole;
3- lower furnace body;
31- lower observation hole;
The combustion chamber 4-;
5- feedstock transportation mechanism;
6- exhaust collection output mechanism;
7- cooling jacket;
8- conveying body;
9- cylinder round sifter structure;
10- air supply tube.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, technical solution of the present invention will be carried out below Detailed description.Obviously, the described embodiment is only a part of the embodiment of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art without making creative work it is obtained it is all its Its embodiment belongs to the range that the present invention is protected.
As shown in Figure 1, the present embodiments relate to a kind of depth purifying plant of carbon materials, including raw material cabin 1, upper furnace Body 2, lower furnace body 3 and combustion chamber 4.Feed end is equipped at the top of upper furnace body 2,3 bottom of lower furnace body is equipped with discharge end.Raw material cabin 1 Outlet is connect with feed end, hopper wall vibrator can be arranged inside raw material cabin 1, be conveyed using shaftless spiral shell blade into upper furnace body Carbon materials.Upper furnace body 2, lower furnace body 3 and combustion chamber 4 use integrated design.Upper furnace body 2 and lower furnace body 3 are along the vertical direction Setting, combustion chamber 4 are equipped with the object of perforation between upper furnace body 2 and lower furnace body 3 in upper furnace body 2, lower furnace body 3 and combustion chamber 4 Expect chamber.Arrow direction in Fig. 1 indicates the flow direction of material in the device.It can be seen that carbon materials enter from raw material cabin 1 Afterwards, roasting purification is carried out into combustion chamber 4 by upper furnace body 2, then cooling down is carried out in lower furnace body 3, finally from discharge end Output.
It is possible to further according to the variation of temperature, apparatus main body is divided into three sections, respectively preheating section, burning zone and Cooling section.Wherein, (1) preheating section, i.e. 2 part of upper furnace body, are welded using general steel plate;(2) furnace zone, i.e. combustion chamber 4 Part, layer is respectively adopted high-alumina brick, refractory brick, other refractory materials and thermal insulation material etc. and builds from inside to outside;(3) cooling Section, i.e. 3 part of lower furnace body, the hollow circular cylinder being welded as liner, ordinary steel as shell using boiler plate.Three Section continuous perforation up and down, in addition to that can be equipped with other than air supply tube 10 is aerated in furnace zone, in production process upper furnace body 2 and under Furnace body 3 is sealing state.
In one embodiment of the invention, which further includes feedstock transportation mechanism 5.One end of feedstock transportation mechanism 5 It is connect with the outlet of raw material cabin 1, the other end is connect with the feed end of upper furnace body 2.Feedstock transportation mechanism 5 is vertically mentioned including closed The equipment such as the machine of liter, distributing device.Vertical elevator can also complete drying to material and cold while being lifted up material But.Material can be distributed in as required on shaft furnace cross section by distributing device, be one of the key equipment of shaft furnace production.
In one embodiment of the invention, which further includes exhaust collection output mechanism 6.Exhaust collection output mechanism 6 are made of blast cap, air-introduced machine, air hose, cyclone dust removal equipment etc..Exhaust collection output mechanism 6 is located at 2 top of upper furnace body, can be with The tail gas generated in upper furnace body 2, lower furnace body 3 and combustion chamber 4 is all collected, is delivered to after dedusting in the kiln of burning, it is right After part fuel gas recycles, residual gas is finally sent into exhaust treatment system, is discharged after index is up to standard.
In one embodiment of the invention, which further includes cooling jacket 7.Cooling jacket 7 is located at the outer of lower furnace body 3 Week, and lower furnace body 3 is coated.It uses recirculated cooling water by modes such as conduction, convection current, to the carbon materials after roasting It is cooled down, conveying body 8 will not be damaged.
In one embodiment of the invention, which further includes conveying body 8.Conveying body 8 can be used Sealed Shaftless screw conveyor, entrance are connect with the discharge end of lower furnace body 3, for the carbon materials to export lower furnace body 3 Power is provided.In the present invention, time switch is can be used in feedstock transportation mechanism 5 and conveying body 8, to input and output material frequency and Time is controlled.By flexibly controlling disengaging doses, can flexibly, be accurately controlled raw material in upper furnace body 2,3 and of lower furnace body Drying, roasting and the cooling time of flowing velocity and raw material carbon materials in combustion chamber 4.
In one embodiment of the invention, which further includes cylinder round sifter structure 9.Cylinder round sifter structure 9 is by roller Sieve, sieve vibrator, water vapour spray equipment etc. form, it can be achieved that screening out powder, avoiding sieve bridging, discharge port to finished product material The purpose of carrying out steam smoothering, cooling.The entrance of cylinder round sifter structure 9 is connect with the outlet of discharging output mechanism 8, for defeated Carbon materials out are sieved, and clean carbon materials are exported.
In one embodiment of the invention, since upper furnace body 2 and lower furnace body 3 are substantially at closed state, the device It further include air supply tube 10.Air supply tube 10 and combustion chamber 4 penetrate through, for providing combustion-supporting gas, such as air or oxygen for combustion chamber 4, The carbon materials in combustion chamber 4 are made to be in stable combustion state.The number of air supply tube 10 can be set according to the scale of device It sets, to guarantee that the oxygen in combustion chamber 4 is uniform, preferably the number of air supply tube 10 is 3~6 and is symmetrical arranged.
In one embodiment of the invention, in order to observe the state and operation of carbon materials in upper furnace body 2 and lower furnace body 3 Speed is equipped with upper observation hole 21 on 2 surface of upper furnace body, and 3 surface of lower furnace body is equipped with lower observation hole 31.It can be by 21 He of upper observation hole Lower observation hole 31 is arranged at the position of close combustion chamber 4 in order to observe.Upper observation hole 21 and lower observation hole 31 can produce The short time opens in the process, and closes after use.
The production process of carbon materials depth purifying plant includes the following steps:
(1) full automatic mechanical pipelining is used, carbon materials enter from raw material cabin 1, send through feedstock transportation mechanism 5 Enter upper furnace body 2 and carries out drying and dewatering.Simultaneously because flue gas rises in combustion chamber 4, carbon materials gradually preheat simultaneously in upper furnace body 2 Downlink flows into combustion chamber 4.
(2) oxygen-enriched air roasting occurs in combustion chamber 4 for carbon materials, and for maturing temperature up to 1000~1200 DEG C, calcining time can Regulated and controled by discharging frequency and charging and discharging speed, usually 1~2h.Remaining coal tar in carbon materials in roasting process The solid matters such as oil, sulphur, nitrogen, ammonia through oxygen-enriched air roasting, gasification, volatilize away from hole under high temperature environment, realize carbon material The depth of material purifies and taste removal.Operation and the combustion case of carbon materials are monitored by upper observation hole 21 and lower observation hole 31.
(3) after the completion of roasting, carbon materials enter lower furnace body 3 from combustion chamber 4, burn with stopping after oxygen-barrier.Pass through Cooling jacket 7 cools down carbon materials, its temperature is made to be down to 300 DEG C or less.Carbon materials after cooling are from 3 bottom of lower furnace body End sequentially enters conveying body 8 and cylinder round sifter structure 9, and the ash content and carbon materials powder that burning is generated are from block Separation obtains clean carbon materials finished product after finally carrying out cooling again with pure water vapour.
The whole design of the device has the following advantages that:Building specification can be zoomed in or out on year-on-year basis, and scale becomes Change flexible;It designs production capacity and variation production capacity adjustable proportion is big;Capital investment is few, and it is low to build difficulty;The mechanization of production process, High degree of automation, failure rate is low, and plant maintenance is easy with maintenance, the expense of generation is low;Equipment energy consumption is low, and the environment of generation is dirty Contaminate object it is few, run smoothly, manipulate it is easy to learn;The labor operation personnel for needing to be equipped with are few;To the applicable model of raw materials for production specification It encloses wide;The recovery utilization rates such as the waste heat, the combustible gas that generate in production process are high;Finished product output capacity is high, and loss rate of raw materials is low.
Using the device of the invention, roasting purification is carried out to same a batch of semi-coke of Shenmu County's production and taste removal is handled, The performance parameter variations of semi-coke are as shown in table 1:
Table 1
As known from Table 1, calcination process is carried out to semi-coke using the device of the invention, specific surface area and the hole of semi-coke can be made Gap rate increases, and density reduces, and makes being readily burned for semi-coke change.The solids such as remaining coal tar, sulphur, nitrogen, ammonia in semi-coke simultaneously Matter under high temperature environment through oxygen-enriched air roasting, gasification, volatilize away from hole, content is reduced within 0.2%, when lighting without Cigarette is tasteless.Simultaneously as roasting eliminates the interior water (crystallization water) and outer water (Natural Water) of semi-coke, so that fuel value is in certain journey It is improved on degree.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any Those familiar with the art in the technical scope disclosed by the present invention, can easily think of the change or the replacement, and should all contain Lid is within protection scope of the present invention.Therefore, protection scope of the present invention should be based on the protection scope of the described claims.

Claims (10)

1. a kind of depth purifying plant of carbon materials, which is characterized in that including raw material cabin, upper furnace body, lower furnace body and combustion chamber,
Wherein, the upper furnace body is equipped with feed end, and the lower furnace body is equipped with discharge end,
The outlet of the raw material cabin is connect with the feed end, for conveying carbon materials into the upper furnace body,
The upper furnace body and lower furnace body are arranged along the vertical direction, the combustion chamber between the upper furnace body and lower furnace body, The material cavity of perforation is equipped in the upper furnace body, lower furnace body and combustion chamber,
Carbon materials successively pass through upper furnace body, combustion chamber and lower furnace body after raw material cabin entrance, export from discharge end.
2. the apparatus according to claim 1, which is characterized in that described device further includes feedstock transportation mechanism, the raw material Conveying mechanism one end is connect with the outlet of the raw material cabin, and the other end is connect with the feed end of the upper furnace body, for being to be sent into The carbon materials of upper furnace body provide power.
3. the apparatus according to claim 1, which is characterized in that described device further includes exhaust collection output mechanism, described Exhaust collection output mechanism is located at the upper furnace body top, the cigarette for will generate in the upper furnace body, lower furnace body and combustion chamber Gas discharge.
4. the apparatus according to claim 1, which is characterized in that described device further includes cooling jacket, the cooling jacket Positioned at the periphery of the lower furnace body, for the carbon materials after cooling roasting.
5. the apparatus according to claim 1, which is characterized in that described device further includes conveying body, the discharging The entrance of conveying mechanism is connect with the discharge end of the lower furnace body, for providing power for the carbon materials of output lower furnace body.
6. the apparatus according to claim 1, which is characterized in that described device further includes cylinder round sifter structure, the roller The entrance of screening mechanism is connect with the outlet of the discharging output mechanism, for sieving to the carbon materials of output.
7. the apparatus according to claim 1, which is characterized in that described device further includes air supply tube, the air supply tube and institute Combustion chamber perforation is stated, for providing combustion-supporting gas for the combustion chamber.
8. the apparatus according to claim 1, which is characterized in that the upper furnace body surface is equipped with upper observation hole, the lower furnace Body surface face is equipped with lower observation hole.
9. device according to claim 8, which is characterized in that the upper observation hole and lower observation hole are respectively positioned on close to described The position of combustion chamber.
10. application of any one of claim 1 to 9 described device in semi-coke roasting purification process.
CN201811019414.3A 2018-09-03 2018-09-03 A kind of depth purifying plant of carbon materials Pending CN108910860A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113941293A (en) * 2021-10-15 2022-01-18 生命珍宝有限公司 Combustion chamber for deep purification of carbon material

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