CN111322519A - Solid hydrogen storage container - Google Patents

Solid hydrogen storage container Download PDF

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Publication number
CN111322519A
CN111322519A CN202010240273.9A CN202010240273A CN111322519A CN 111322519 A CN111322519 A CN 111322519A CN 202010240273 A CN202010240273 A CN 202010240273A CN 111322519 A CN111322519 A CN 111322519A
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CN
China
Prior art keywords
hydrogen storage
communicated
cooling
pipelines
flow guide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202010240273.9A
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Chinese (zh)
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CN111322519B (en
Inventor
凌兆蔚
刘新
杨兴锋
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SHENZHEN JIAHUA LIDAO NEW TECHNOLOGY DEVELOPMENT CO LTD
Original Assignee
SHENZHEN JIAHUA LIDAO NEW TECHNOLOGY DEVELOPMENT CO LTD
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Priority to CN202010240273.9A priority Critical patent/CN111322519B/en
Priority claimed from CN202010240273.9A external-priority patent/CN111322519B/en
Publication of CN111322519A publication Critical patent/CN111322519A/en
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Publication of CN111322519B publication Critical patent/CN111322519B/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C11/00Use of gas-solvents or gas-sorbents in vessels
    • F17C11/005Use of gas-solvents or gas-sorbents in vessels for hydrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L53/00Heating of pipes or pipe systems; Cooling of pipes or pipe systems
    • F16L53/70Cooling of pipes or pipe systems
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C13/00Details of vessels or of the filling or discharging of vessels
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C13/00Details of vessels or of the filling or discharging of vessels
    • F17C13/06Closures, e.g. cap, breakable member
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/01Shape
    • F17C2201/0147Shape complex
    • F17C2201/0166Shape complex divided in several chambers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2205/00Vessel construction, in particular mounting arrangements, attachments or identifications means
    • F17C2205/03Fluid connections, filters, valves, closure means or other attachments
    • F17C2205/0302Fittings, valves, filters, or components in connection with the gas storage device
    • F17C2205/0352Pipes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/01Pure fluids
    • F17C2221/012Hydrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/01Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
    • F17C2223/0107Single phase
    • F17C2223/0138Single phase solid
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/32Hydrogen storage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P90/00Enabling technologies with a potential contribution to greenhouse gas [GHG] emissions mitigation
    • Y02P90/45Hydrogen technologies in production processes

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)

Abstract

The invention discloses a solid hydrogen storage container, which comprises a container main body, an end cover, a liquid inlet, a liquid outlet, a gas inlet and a gas outlet, wherein the end cover is arranged on the container main body; a plurality of hydrogen storage pipelines and cooling pipelines which are communicated with the container main body are arranged in the container main body, the hydrogen storage pipelines are communicated with one another, and each hydrogen storage pipeline is at least arranged adjacent to one cooling pipeline; end covers are arranged at two opposite ends of the container main body, flow guide channels which are not communicated with the hydrogen storage pipelines are arranged on the surfaces of the end covers facing the container main body, and the plurality of cooling pipelines are communicated through the flow guide channels; the liquid inlet and the liquid outlet are communicated with the cooling pipeline, and the gas inlet and the gas outlet are communicated with the hydrogen storage pipeline, so that the flow of cooling liquid and the transmission of hydrogen are realized; the advantage of this scheme lies in that part quantity and welding part all reduce by a wide margin, has not only reduced the production degree of difficulty and improved sealing performance for solid-state hydrogen storage container's factor of safety can improve, still be convenient for maintain in the future and overhaul, brought important help for the development of solid-state hydrogen storage technique.

Description

Solid hydrogen storage container
Technical Field
The invention relates to a technical scheme in the field of hydrogen energy sources, in particular to a solid hydrogen storage container.
Background
Most of the existing solid hydrogen storage containers are made of steel pipes or steel plates to form tubular shells, then the tubular shells are welded with parts such as joints through end covers, and a plurality of hydrogen storage tanks are connected in parallel to improve the hydrogen storage capacity meeting the requirements.
And because the hydrogen storage material can release or absorb a large amount of heat energy when absorbing and desorbing hydrogen, the shell-and-tube solid hydrogen storage container with the existing structure also needs to be provided with a heat exchange liquid flow passage structure inside or directly pass through the outer surface of the tank body to be used as a heat transfer interface.
However, in the shell-and-tube type container, the shell, the end cover and the joint are connected and sealed by welding to solve the sealing problem, the number of parts is greatly increased due to the parallel connection of a plurality of hydrogen storage tanks, the production cost is increased due to excessive welding parts, various air tightness problems are more likely to occur, and the daily maintenance is not convenient, so that a technical scheme capable of solving the problems is urgently needed.
Disclosure of Invention
The invention aims to provide a solid hydrogen storage container to solve the problems of difficult production and poor sealing performance caused by excessive components in the prior art.
In order to solve the technical problem, the invention provides a solid hydrogen storage container, which comprises a container main body, an end cover, a liquid inlet, a liquid outlet, a gas inlet and a gas outlet; a plurality of hydrogen storage pipelines and a plurality of cooling pipelines are arranged in the container main body, the hydrogen storage pipelines and the cooling pipelines are communicated with two opposite ends of the container main body, the hydrogen storage pipelines are communicated, and each hydrogen storage pipeline is arranged adjacent to at least one cooling pipeline; the end covers are arranged at two opposite ends of the container main body, flow guide channels are arranged on the surfaces, facing the container main body, of the end covers, the flow guide channels are not communicated with the hydrogen storage pipelines, and two opposite ends of each cooling pipeline are respectively communicated with the flow guide channels on the two end covers, so that the cooling pipelines are communicated; the liquid inlet is communicated with one of the flow guide channels, and the liquid outlet is communicated with the same or the other flow guide channel; the gas inlet is communicated with one of the hydrogen storage pipelines, and the gas outlet is communicated with the same or the other hydrogen storage pipeline.
In one embodiment, the gas inlet is connected with one end of one hydrogen storage pipeline in a sealing manner, the gas outlet is connected with one end of one hydrogen storage pipeline in a sealing manner, each end of the rest hydrogen storage pipelines is provided with a sealing cover, and the sealing covers are sealed between the hydrogen storage pipelines and the end covers.
In one embodiment, a boss is arranged on the inner wall of the port for hydrogen storage conduction, and the sealing cover abuts against the boss.
In one embodiment, a plurality of the hydrogen storage pipes are arranged in a matrix arrangement, and at least a part of the cooling pipes are arranged adjacent to four of the hydrogen storage pipes at the same time.
In one embodiment, the cooling pipes include a main cooling pipe disposed adjacent to four of the hydrogen storage pipes at the same time, and a sub cooling pipe disposed adjacent to an outer surface of the container main body, the sub cooling pipe being disposed adjacent to two of the hydrogen storage pipes at the same time.
In one embodiment, two adjacent hydrogen storage pipelines are arranged side by side, and the pipe wall of each hydrogen storage pipeline is provided with a through hole which connects and conducts the adjacent hydrogen storage pipelines.
In one embodiment, the through holes are formed at two opposite ends of each hydrogen storage pipe.
In one embodiment, the side wall of the container body is provided with a plurality of processing holes, the processing holes penetrate through the inside and the outside of the container body, each processing hole is internally provided with a plugging piece, and the hydrogen storage pipeline is provided with the through hole at a position aligned with the processing hole.
In one embodiment, the end cap comprises a first end cap and a second end cap, and the flow guide passage comprises a first flow guide passage, a second flow guide passage and a third flow guide passage; the first flow guide channel is arranged on the first end cover and communicated with all the cooling pipelines; the second flow guide channel and the third flow guide channel are arranged on the second end cover and are not communicated with each other; the second flow guide channel is communicated with a part of the cooling pipeline, and is also communicated with the liquid inlet; the third diversion channel is communicated with the rest of the cooling pipelines, and the third diversion channel is also communicated with the liquid outlet, so that the cooling liquid input through the liquid inlet can be output through the liquid outlet after flowing through all the cooling pipelines.
In one embodiment, the liquid inlet, the liquid outlet, the gas inlet and the gas outlet are all disposed on the second end cap, and the gas inlet and the gas outlet are respectively connected and communicated with different hydrogen storage pipelines.
The invention has the following beneficial effects:
because the container main body is internally provided with a plurality of hydrogen storage pipelines and a plurality of cooling pipelines, and the two opposite ends of the container main body are provided with the end covers, the cooling and storing structure of the invention is arranged in the container main body, the welding part only exists between the end cover and the container main body, the number of parts and the welding part are greatly reduced, the production difficulty is reduced, the sealing performance is improved, the safety coefficient of the solid hydrogen storage container is improved, the later maintenance and repair are convenient, and the important help is brought to the development of the solid hydrogen storage technology.
Drawings
In order to more clearly illustrate the technical solution of the present invention, the drawings needed to be used in the embodiments will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art that other drawings can be obtained according to the drawings without creative efforts.
FIG. 1 is a schematic structural view of a first embodiment of a solid state hydrogen storage vessel of the present invention;
FIG. 2 is a schematic disassembled view of FIG. 1;
FIG. 3 is a first schematic view of the arrangement of hydrogen storage conduits and cooling conduits;
FIG. 4 is a second schematic view showing the arrangement of the hydrogen storage piping and the cooling piping;
FIG. 5 is a schematic view of the vessel body construction of a second embodiment of the solid state hydrogen storage vessel of the present invention;
FIG. 6 is a schematic view of the vessel body construction of a third embodiment of the solid state hydrogen storage vessel of the present invention;
FIG. 7 is a schematic view of the vessel body construction of a fourth embodiment of the solid state hydrogen storage vessel of the present invention;
FIG. 8 is a schematic disassembled view of a fifth embodiment of the solid state hydrogen storage vessel of the present invention;
FIG. 9 is a schematic view of the first end cap construction of FIG. 8;
FIG. 10 is a schematic view of the second end cap construction of FIG. 8;
FIG. 11 is a schematic disassembled view of a sixth embodiment of the solid state hydrogen storage vessel of the present invention;
FIG. 12 is a schematic disassembled view of a seventh embodiment of the solid state hydrogen storage vessel of the present invention;
FIG. 13 is a schematic structural view of an eighth embodiment of a solid state hydrogen storage vessel according to the present invention;
FIG. 14 is a schematic diagram of a configuration of three solid-state hydrogen storage vessels of the present invention connected in parallel;
FIG. 15 is a schematic diagram of a configuration of four solid-state hydrogen storage vessels of the present invention connected in parallel.
The reference numbers are as follows:
10. a container body; 11. a hydrogen storage conduit; 12. a cooling duct; 121. a primary cooling conduit; 122. a secondary cooling conduit; 13. a through hole; 14. machining a hole; 15. a blocking member; 16. a boss;
20. an end cap; 201. a first end cap; 202. a second end cap; 21. a flow guide channel; 211. a first flow guide passage; 212. a second flow guide channel; 213. a third flow guide channel; 22. an exhaust port;
31. a liquid outlet; 32. a liquid inlet;
41. an air inlet; 42. an air outlet;
50. a sealing cover;
61. an air inlet joint; 62. an air outlet joint;
70. a multi-body stent.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention.
A first embodiment of the solid-state hydrogen storage vessel of the present invention is shown in fig. 1 and 2, and comprises a vessel body 10, an end cap 20, a liquid inlet 32, a liquid outlet 31, a gas inlet 41 and a gas outlet 42.
Regarding the container main body 10, a plurality of hydrogen storage pipelines 11 and a plurality of cooling pipelines 12 are arranged in the container main body 10, the hydrogen storage pipelines 11 and the cooling pipelines 12 both link up two opposite ends of the container main body 10, the plurality of hydrogen storage pipelines 11 are connected and conducted, and each hydrogen storage pipeline 11 is at least arranged adjacent to one cooling pipeline 12.
Specifically, nine hydrogen storage pipelines 11 are provided, four cooling pipelines 12 are provided, the nine hydrogen storage pipelines 11 are arranged in a matrix in a nine-grid shape, and each cooling pipeline 12 is arranged between the four hydrogen storage pipelines 11, so that the purpose of radiating heat by using one cooling pipeline 12 as the four hydrogen storage pipelines 11 is realized; the arrangement mode has the advantages that the structural compactness among the pipelines can be improved, the arrangement quantity of the cooling pipelines 12 is reduced as far as possible, if more schemes of the hydrogen storage pipelines 11 need to be designed in the future, the requirement that the plurality of hydrogen storage pipelines 11 are arranged in a matrix arrangement mode is met, at least part of the cooling pipelines 12 are arranged in a mode of being adjacent to the four hydrogen storage pipelines 11 at the same time, and the same beneficial effect can be obtained.
Of course, the arrangement of the hydrogen storage pipes 11 and the cooling pipes 12 is not limited to the above example, as shown in fig. 3, in this case, four hydrogen storage pipes 11 and three cooling pipes 12 are provided, and the hydrogen storage pipes 11 and the cooling pipes 12 are alternately arranged from left to right, so that the hydrogen storage pipes 11 and the cooling pipes 12 are uniformly arranged on the same plane; as shown in fig. 4, two hydrogen storage pipelines 11 are arranged above and side by side, two cooling pipelines 12 are arranged below and side by side, and each hydrogen storage pipeline 11 is respectively arranged adjacent to one cooling pipeline 12 from top to bottom; that is, the arrangement of the hydrogen storage pipe 11 and the cooling pipe 12 may be adjusted by those skilled in the art according to specific requirements.
In addition, the connection and conduction among the hydrogen storage pipelines 11 have various implementation manners, for example, a connection pipeline can be arranged in the container main body 10, and two ends of the connection pipeline are respectively connected and conducted with the two hydrogen storage pipelines 11, so that the connection pipeline is prevented from being connected with the cooling pipeline 12 in a staggered manner.
However, in order to simplify the internal structure of the container main body 10, two adjacent hydrogen storage pipelines 11 may be arranged side by side, a through hole 13 is formed on the pipe wall of each hydrogen storage pipeline 11, and the through holes 13 connect and conduct the adjacent hydrogen storage pipelines 11; specifically, in the horizontal direction, the through hole 13 connects and conducts the hydrogen storage pipes 11 on the left and right sides, in the vertical direction, the through hole 13 conducts the hydrogen storage pipes 11 on the upper and lower sides, and at the moment, the hydrogen storage pipes 11 on the second row are only needed to be conducted up and down, so that the mutual conduction among nine hydrogen storage pipes 11 can be realized, and the number of the through holes 13 is reduced.
Regarding the end caps 20, the end caps 20 are mounted at two opposite ends of the container body 10, the surface of the end cap 20 facing the container body 10 is provided with a flow guide channel 21, the flow guide channel 21 is not communicated with the hydrogen storage pipeline 11, and two opposite ends of each cooling pipeline 12 are respectively communicated with the flow guide channels 21 on the end caps 20, so that the cooling pipelines 12 are communicated with each other.
Specifically, at this time, the setting track of the flow guide channel 21 should bypass the hydrogen storage pipeline 11, which makes the flow guide channel 21 and the hydrogen storage pipeline 11 not opposite to each other, and then the flow guide channel 21 and the hydrogen storage pipeline 11 are not communicated with each other after the end of the hydrogen storage pipeline 11 is capped by the surface of the end cap 20.
Since the cooling pipes 12 are connected and communicated through the flow guide passage 21, when the cooling pipes 12 are filled with cooling liquid, the cooling liquid can circulate among the cooling pipes 12, thereby cooling and radiating the hydrogen storage pipes 11.
Regarding the liquid inlet 32 and the liquid outlet 31, in this embodiment, the liquid inlet 32 is connected and communicated with the flow guide channel 21 on one end cover 20, and the liquid outlet 31 is connected and communicated with the flow guide channel 21 on the other end cover 20, since the cooling pipe 12 realizes the communication of the flow guide channels 21 on the two end covers 20, the cooling liquid input through the liquid inlet 32 can be output through the liquid outlet 31 inevitably.
However, it should be noted that the liquid inlet 32 and the liquid outlet 31 are not necessarily respectively disposed on the two end caps 20, even if the liquid inlet 32 and the liquid outlet 31 are both disposed on the same end cap 20, because both ends of each cooling pipeline 12 are communicated with the flow guide channels 21 on the two end caps 20, the liquid inlet 32 can still convey the cooling liquid to each cooling pipeline 12, and the liquid outlet 31 can still extract the cooling liquid from each cooling pipeline 12 for output, that is, only the liquid inlet 32 needs to be connected and communicated with one of the flow guide channels 21, and the liquid outlet 31 is communicated with the same or the other flow guide channel 21, so that the normal flow of the cooling liquid can be realized.
Regarding the gas inlet 41 and the gas outlet 42, in this embodiment, the gas inlet 41 and the gas outlet 42 are respectively disposed on the two end caps 20, and the gas inlet 41 and the gas outlet 42 are respectively connected and conducted with different hydrogen storage pipelines 11, because the hydrogen storage pipelines 11 are conducted with each other, the hydrogen gas input through the gas inlet 41 can inevitably flow into each hydrogen storage pipeline 11 for storage, and the hydrogen gas stored in each hydrogen storage pipeline 11 can also inevitably be output through the gas outlet 42.
However, it should be noted that the gas inlet 41 and the gas outlet 42 are not necessarily connected and conducted with different hydrogen storage pipelines 11, for example, the gas inlet 41 and the gas outlet 42 may be connected and conducted with two opposite ends of the same hydrogen storage pipeline 11, at this time, the hydrogen gas input through the gas inlet 41 can still be conveyed into each hydrogen storage pipeline 11, the hydrogen gas stored in each hydrogen storage pipeline 11 can still be output through the gas outlet 42, that is, only the gas inlet 41 needs to be connected and conducted with one of the hydrogen storage pipelines 11, and the gas outlet 42 is conducted with the same or another hydrogen storage pipeline 11, so that the normal circulation of the hydrogen gas can be realized.
When the solid hydrogen storage container is applied, hydrogen is input into each hydrogen storage pipeline 11 through the gas inlet 41 for storage, or hydrogen in the hydrogen storage pipelines 11 is output through the gas outlet 42, since the cooling liquid is input into each cooling pipeline 12 through the liquid inlet 32 and is output through the liquid outlet 31, namely the cooling liquid can be discharged in time after absorbing heat of the hydrogen storage pipelines 11, so as to ensure the timeliness of heat dissipation.
Compared with the prior art, the cooling and storage structure is arranged in the container main body 10, the welding part only exists between the end cover 20 and the container main body 10, the number of parts and the welding part are greatly reduced, the production difficulty is reduced, the sealing performance is improved, the safety coefficient of the solid hydrogen storage container is improved, the maintenance and the overhaul in the future are facilitated, and the important help is brought to the development of the solid hydrogen storage technology.
A second embodiment of the solid-state hydrogen storage vessel of the present invention is shown in fig. 5, and differs from the first embodiment in that the cooling pipes 12 include a main cooling pipe 121 and a sub cooling pipe 122, the main cooling pipe 121 being disposed adjacent to four hydrogen storage pipes 11 at the same time, the sub cooling pipe 122 being disposed adjacent to the outer surface of the vessel body 10, and the sub cooling pipe 122 being disposed adjacent to two hydrogen storage pipes 11 at the same time.
Specifically, at this time, the number of the hydrogen storage pipelines 11 is nine, the number of the main cooling pipelines 121 is four, the number of the auxiliary cooling pipelines 122 is eight, the four main cooling pipelines 121 are arranged in the internal gaps of the nine hydrogen storage pipelines 11, and the eight auxiliary cooling pipelines 122 are arranged adjacent to the outer sides of the eight hydrogen storage pipelines 11.
The advantage of this arrangement is that can ensure that every cooling pipeline 12 all can dispel the heat to two hydrogen storage pipelines 11 to under the prerequisite that does not increase and decrease cooling pipeline 12 quantity by a wide margin, realize the heat dissipation simultaneously of the many sides of hydrogen storage passageway.
The third embodiment of the solid hydrogen storage container of the present invention is shown in fig. 6, and is different from the second embodiment in that the two opposite ends of each hydrogen storage pipeline 11 are provided with through holes 13, that is, the front and rear ends of each hydrogen storage pipeline 11 can be connected and conducted between two adjacent hydrogen storage pipelines 11, so as to increase the hydrogen exchange efficiency between the hydrogen storage pipelines 11, that is, to improve the filling and storing efficiency of hydrogen and the output efficiency of hydrogen.
A fourth embodiment of the solid hydrogen storage container according to the present invention is shown in fig. 7, and is different from the third embodiment in that a plurality of processing holes 14 are formed in the side wall of the container body 10, the processing holes 14 penetrate the inside and outside of the container body 10, a plugging member 15 is installed in each processing hole 14, and a hydrogen storage pipe 11 is provided with a through hole 13 at a position aligned with the processing hole 14.
Specifically, eight machining holes 14 are provided in the embodiment, three machining holes 14 are provided in the front end of the left side wall of the container body 10, and the three machining holes 14 are aligned with the through holes 13 in the upper, middle and lower horizontal planes of the front end of the container body 10, respectively; the other three processing holes 14 are arranged at the rear end of the left side of the container body 10, and the three processing holes 14 are respectively aligned with the through holes 13 of the upper, middle and lower horizontal planes at the rear end of the container body 10; the last two processing holes 14 are respectively arranged at the front end and the rear end of the top surface of the container body 10, one processing hole 14 is aligned with the three through holes 13 in the vertical direction at the front end of the container body 10, and the other processing hole 14 is aligned with the three through holes 13 in the vertical direction at the rear end of the container body 10.
The purpose of arranging the processing holes 14 is to reduce the processing difficulty, because the equipment such as a drill bit can extend into the hydrogen storage pipelines 11 when the processing holes 14 are arranged, thereby realizing the drilling processing of a plurality of hydrogen storage pipelines 11 and forming the through holes 13; after the through hole 13 is processed, the sealing piece 15 is welded and fixed only by the processing hole 14, so that the sealing performance of the solid hydrogen storage container can be ensured not to be reduced.
A fifth embodiment of the solid state hydrogen storage vessel of the present invention is shown in fig. 8-10, which differs from the fourth embodiment in that the end cap comprises a first end cap 201 and a second end cap 202, and the flow guide passage comprises a first flow guide passage 211, a second flow guide passage 212, and a third flow guide passage 213; the first flow guide channel 211 is arranged on the first end cover 201, and the first flow guide channel 211 is communicated with all the cooling pipelines 12; the second flow guide channel 212 and the third flow guide channel 213 are arranged on the second end cover 202, and the second flow guide channel 212 and the third flow guide channel 213 are not communicated with each other; the second diversion channel 212 is communicated with a part of the cooling pipeline 12, and the second diversion channel 212 is also communicated with the liquid inlet 32; the third diversion channel 213 is communicated with the rest of the cooling pipes 12, and the third diversion channel 213 is further communicated with the liquid outlet 31, so that the cooling liquid input through the liquid inlet 32 can be output through the liquid outlet 31 after passing through all the cooling pipes 12.
Specifically, at this time, the first flow guide channel 211 comprises four horizontal flow channels and a vertical flow channel, the four horizontal flow channels are arranged at intervals from top to bottom, the vertical flow channel connects and conducts the four horizontal flow channels, and the purpose of conducting with the plurality of cooling pipelines 12 simultaneously is achieved after the first flow guide channel 211 is designed like this.
The second flow guide channel 212 includes two horizontal flow channels and a vertical flow channel, the two horizontal flow channels are arranged from top to bottom at intervals, the vertical flow channel connects and communicates the two horizontal flow channels, and the second flow guide channel 212 is designed in such a way, so that the purpose of communicating with the upper cooling pipeline 12 at the same time is achieved.
The third flow guiding channel 213 includes two horizontal flow channels and a vertical flow channel, the two horizontal flow channels are arranged from top to bottom at intervals, the vertical flow channel connects and communicates the two horizontal flow channels, and the third flow guiding channel 213 is designed in such a way, so as to achieve the purpose of communicating with the lower cooling pipeline 12 at the same time.
Therefore, after the cooling liquid is inputted through the liquid inlet 32, the cooling liquid is inputted into the upper cooling pipe 12 through the second diversion channel 212, and then the cooling liquid moves into the lower cooling pipe 12 through the first diversion channel 211, and finally the cooling liquid is outputted through the liquid outlet 31 by the third diversion channel 213.
The advantage of this arrangement is that it can be ensured that the cooling liquid must flow through all the cooling pipes 12, i.e. the flow direction of the cooling liquid is controlled, and an important guarantee is provided for the effectiveness of the cooling liquid flowing and heat dissipation.
A sixth embodiment of the solid hydrogen storage container of the present invention is shown in fig. 11, which is different from the fifth embodiment in that the liquid inlet 32, the liquid outlet 31, the gas inlet 41 and the gas outlet 42 are all disposed on the second end cap 202, and the gas inlet 41 and the gas outlet 42 are respectively connected and communicated with different hydrogen storage pipelines 11.
The advantage of this mode of setting up lies in that various imports and exports can concentrate the arrangement, are convenient for carry on the operation such as circuit, connection management, have brought very big facility for the equipment of solid-state hydrogen storage container, maintenance operation.
A seventh embodiment of the solid-state hydrogen storage container of the present invention is shown in fig. 12, which is different from the sixth embodiment in that the gas inlet 41 is hermetically connected to one end of a hydrogen storage pipe 11, the gas outlet 42 is hermetically connected to one end of a hydrogen storage pipe 11, each end of the remaining hydrogen storage pipes 11 is provided with a sealing cap 50, and the sealing cap 50 is sealed between the hydrogen storage pipe 11 and the end cap 20.
Specifically, at this time, the air inlet 41 is connected and communicated with the hydrogen storage pipeline 11 at the lower left by using the air inlet joint 61, and the air inlet joint 61 is in sealed connection with the hydrogen storage pipeline 11; the gas outlet 42 is communicated with the hydrogen storage pipeline 11 at the upper left by using a gas outlet joint 62, and the gas outlet joint 62 is hermetically connected with the hydrogen storage pipeline 11; the shape of the sealing cover 50 is matched with the shape of the port of the hydrogen storage pipeline 11, so that the sealing effect is improved, and the air tightness of the hydrogen storage pipeline 11 is further improved; in addition, in order to facilitate the installation and fixation of the sealing cover 50, a boss 16 may be disposed on the inner wall of the port of the hydrogen storage pipeline 11, the sealing cover 50 abuts against the boss 16, and after the sealing cover 50 is limited and abutted by the boss 16, the sealing cover 50 is more conveniently welded and fixed.
In addition, at this time, the end cover 20 is further provided with an air outlet 22, and the air outlet 22 is connected and communicated with one of the cooling pipelines 12, so that when the cooling pipeline 12 is filled with cooling liquid, air in the cooling pipeline 12 can be discharged through the air outlet 22, and after the air is completely discharged, the air outlet 22 is sealed, so that the absence of air in the cooling pipeline 12 is ensured.
An eighth embodiment of the solid-state hydrogen storage container of the present invention is shown in fig. 13, and the difference between the eighth embodiment and the seventh embodiment is that two solid-state hydrogen storage containers are arranged side by side, and the two solid-state hydrogen storage containers are welded and fixed by a multi-body bracket 70, and the multi-body bracket 70 is provided with screw holes, so that the solid-state hydrogen storage containers can be conveniently hoisted.
The above embodiment shows that a plurality of solid-state hydrogen storage containers can be connected and fixed by a multi-body bracket 70, that is, the number of the solid-state hydrogen storage containers is not limited, as shown in fig. 14, at this time, three solid-state hydrogen storage containers are arranged side by side, and any two adjacent solid-state hydrogen storage containers are welded and fixed by the multi-body bracket 70; as shown in fig. 15, four solid-state hydrogen storage containers are arranged in a matrix form, and any two adjacent solid-state hydrogen storage containers are welded and fixed by a multi-body bracket 70 in the horizontal or vertical direction.
While the foregoing is directed to the preferred embodiment of the present invention, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention.

Claims (10)

1. A solid-state hydrogen storage container is characterized in that,
comprises a container main body, an end cover, a liquid inlet, a liquid outlet, a gas inlet and a gas outlet;
a plurality of hydrogen storage pipelines and a plurality of cooling pipelines are arranged in the container main body, the hydrogen storage pipelines and the cooling pipelines are communicated with two opposite ends of the container main body, the hydrogen storage pipelines are communicated, and each hydrogen storage pipeline is arranged adjacent to at least one cooling pipeline;
the end covers are arranged at two opposite ends of the container main body, flow guide channels are arranged on the surfaces, facing the container main body, of the end covers, the flow guide channels are not communicated with the hydrogen storage pipelines, and two opposite ends of each cooling pipeline are respectively communicated with the flow guide channels on the two end covers, so that the cooling pipelines are communicated;
the liquid inlet is communicated with one of the flow guide channels, and the liquid outlet is communicated with the same or the other flow guide channel;
the gas inlet is communicated with one of the hydrogen storage pipelines, and the gas outlet is communicated with the same or the other hydrogen storage pipeline.
2. The solid-state hydrogen storage container according to claim 1, wherein the gas inlet is hermetically connected to one end of one of the hydrogen storage pipes, the gas outlet is hermetically connected to one end of one of the hydrogen storage pipes, and each end of the remaining hydrogen storage pipes is provided with a sealing cap which is sealed between the hydrogen storage pipe and the end cap.
3. The solid-state hydrogen storage container according to claim 2, wherein a boss is provided on an inner wall of the port through which hydrogen is stored, and the sealing cover abuts against the boss.
4. The solid state hydrogen storage vessel of claim 1, wherein a plurality of said hydrogen storage conduits are arranged in a matrix arrangement, at least a portion of said cooling conduits being arranged adjacent four of said hydrogen storage conduits simultaneously.
5. The solid state hydrogen storage vessel of claim 4 wherein the cooling conduits include primary cooling conduits disposed adjacent four of the hydrogen storage conduits simultaneously and secondary cooling conduits disposed adjacent an exterior surface of the vessel body, the secondary cooling conduits disposed adjacent two of the hydrogen storage conduits simultaneously.
6. The solid-state hydrogen storage container according to claim 1, wherein two adjacent hydrogen storage pipes are arranged side by side, and a pipe wall of each hydrogen storage pipe is provided with a through hole for connecting and communicating the adjacent hydrogen storage pipes.
7. The solid state hydrogen storage vessel of claim 6, wherein each of said hydrogen storage tubes is provided with said through-hole at opposite ends.
8. The solid hydrogen storage container according to claim 6, wherein a plurality of processing holes are provided in the side wall of the container body, the processing holes pass through the inside and outside of the container body, a block piece is installed in each of the processing holes, and the hydrogen storage pipe is provided with the through hole at a position aligned with the processing hole.
9. The solid state hydrogen storage vessel of claim 1,
the end covers comprise a first end cover and a second end cover, and the flow guide channels comprise a first flow guide channel, a second flow guide channel and a third flow guide channel;
the first flow guide channel is arranged on the first end cover and communicated with all the cooling pipelines;
the second flow guide channel and the third flow guide channel are arranged on the second end cover and are not communicated with each other; the second flow guide channel is communicated with a part of the cooling pipeline, and is also communicated with the liquid inlet; the third diversion channel is communicated with the rest of the cooling pipelines, and the third diversion channel is also communicated with the liquid outlet, so that the cooling liquid input through the liquid inlet can be output through the liquid outlet after flowing through all the cooling pipelines.
10. The solid-state hydrogen storage container of claim 9, wherein the liquid inlet, the liquid outlet, the gas inlet and the gas outlet are all disposed on the second end cap, and the gas inlet and the gas outlet are respectively connected and communicated with different hydrogen storage pipelines.
CN202010240273.9A 2020-03-30 Solid hydrogen storage container Active CN111322519B (en)

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