CN111321500A - Anti-radiation fabric and preparation method thereof - Google Patents
Anti-radiation fabric and preparation method thereof Download PDFInfo
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- CN111321500A CN111321500A CN202010243666.5A CN202010243666A CN111321500A CN 111321500 A CN111321500 A CN 111321500A CN 202010243666 A CN202010243666 A CN 202010243666A CN 111321500 A CN111321500 A CN 111321500A
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
- D03D13/008—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft characterised by weave density or surface weight
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/533—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0006—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using woven fabrics
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/04—Properties of the materials having electrical or magnetic properties
- D06N2209/048—Electromagnetic interference shielding
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
- D10B2101/10—Inorganic fibres based on non-oxides other than metals
- D10B2101/12—Carbon; Pitch
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
- D10B2101/10—Inorganic fibres based on non-oxides other than metals
- D10B2101/12—Carbon; Pitch
- D10B2101/122—Nanocarbons
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
- D10B2101/20—Metallic fibres
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/20—Cellulose-derived artificial fibres
- D10B2201/28—Cellulose esters or ethers, e.g. cellulose acetate
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
- D10B2211/04—Silk
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/20—Protein-derived artificial fibres
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/14—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polycondensates of cyclic compounds, e.g. polyimides, polybenzimidazoles
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
Abstract
The invention belongs to the technical field of textile fabric preparation, and particularly relates to a radiation-proof fabric and a preparation method thereof. The fabric comprises nano silver fibers, milk fibers, bamboo charcoal fibers, radiation-proof fibers, recombinant spider silk protein fibers and animal protein fibers, all components in the fabric supplement each other, and the fabric makes up for deficiencies of each other, so that the fabric not only has good comfortable softness and radiation-proof effect, but also has good comfort, antibacterial property and air permeability. In addition, because the market price of the nano-silver fiber is higher, the nano-silver fiber is controlled to be matched with other fibers, so that the using amount of the nano-silver fiber can be reduced, the radiation protection effect and the antibacterial property of the fabric brought by the nano-silver fiber can be ensured, and the production cost of the fabric is obviously reduced.
Description
Technical Field
The invention belongs to the technical field of textile fabric preparation, and particularly relates to a radiation-proof fabric and a preparation method thereof.
Background
Along with the continuous improvement of living standard of people, people pay more and more attention to green and health care textile. Modern clothes and household textiles are developed towards the directions of health, environmental protection, fashion and functionalization, the requirements of people on the textiles are not limited to the original basic characteristics of warm keeping, comfort and the like, the eyes are focused on functional fabrics with special functions of health care, safety and the like, and the radiation-proof fabrics are one of the fabrics.
The electromagnetic wave radiation can be released to a certain extent by televisions, refrigerators, air conditioners, microwave ovens, computers, mobile phones, electronic instruments, medical equipment and the like around people, and people who work, study and live in an environment with concentrated radiation sources are easy to have symptoms of insomnia, dreaminess, hypomnesis, weakness, hypoimmunity and the like. For pregnant women who may cause miscarriage, elderly people with cardiac pacemakers may disable the device, threatening life. Therefore, the elderly, children, pregnant women, or people who are sensitive to electromagnetic radiation and who work in an environment with an overdose of electromagnetic radiation for a long time should take necessary preventive measures.
The most direct way for preventing electromagnetic wave radiation in the prior art is to wear radiation-proof clothes, and the purpose of reducing or completely isolating electromagnetic wave radiation is achieved through special radiation-proof fibers or radiation-proof coating metal in the clothes. However, the metal wires are directly implanted into the fabric, so that the purpose of preventing electromagnetic wave radiation can be achieved, but due to the diversity of the combination modes of the metal wires and the fabric fibers, the hand feeling of the fabric of the clothes is poor due to some treatment modes, skin infection or discomfort can be caused if the metal wires are directly contacted with the skin, and the service performance of the clothes is reduced.
Chinese patent document CN110074490A discloses a radiation-proof fabric and a preparation method thereof, the radiation-proof fabric comprises raw materials of recombinant spidroin protein fiber, chitin fiber, nano-silver fiber and aureobasidium polysaccharide fiber, the nano-silver fiber in the radiation-proof fabric is high in price, which leads to high production cost of the fabric, if the nano-silver fiber content is further reduced in the patent, the radiation-proof property of the fabric is significantly reduced, and the radiation-proof fabric has certain softness and comfort, but is still difficult to meet the requirement of people on comfort level. Therefore, how to reduce the production cost on the basis of ensuring that the radiation-proof fabric has better radiation-proof performance and enable the radiation-proof fabric to have more excellent softness and comfort becomes one of the research hotspots of the technical personnel in the field.
Disclosure of Invention
Therefore, the invention aims to overcome the defects of poor softness and comfort, poor antibacterial property, poor air permeability, poor radiation protection effect and the like of the radiation protection fabric in the prior art, and provides the radiation protection fabric and the preparation method thereof.
Therefore, the invention provides the following technical scheme.
The invention provides an anti-radiation fabric, which comprises a fabric substrate and a coating coated on the fabric substrate;
the fabric substrate comprises, by weight, 3-9 parts of nano-silver fibers, 2-4 parts of milk fibers, 10-20 parts of bamboo charcoal fibers, 2-4 parts of radiation-proof fibers, 1-3 parts of recombinant spider silk protein fibers and 3-9 parts of animal protein fibers.
The fabric substrate comprises warp yarns and weft yarns;
the warp yarn comprises, by weight, 3-9 parts of nano-silver fibers, 2-4 parts of milk fibers and 10-20 parts of bamboo charcoal fibers;
the raw materials of the weft yarn comprise, by weight, 2-4 parts of radiation-proof fibers, 1-3 parts of recombinant spider silk protein fibers and 3-9 parts of animal protein fibers;
the radiation-proof fiber comprises, by weight, 4-10 parts of graphene-based carbon nanofiber, 3-9 parts of polyaniline fiber, 2-4 parts of acetate fiber, 3-9 parts of barium sulfate and 6-16 parts of metal oxide.
The radiation-proof fiber also comprises 5-12 parts of ethanol.
The coating comprises the following raw materials in percentage by mass (2-3): (2-3): (0.5-1.5): (1-3): (1-3) calcium carbonate, soybean lecithin, diatom, polytetrafluoroethylene and silica.
The density of the warp yarns is 100-120 yarns/in;
the density of the weft yarns is 70-80 per in;
the fineness of the fabric is 45-55D.
The raw materials of the warp yarn also comprise 2-6 parts of natural silk fiber.
The raw materials of the weft yarn also comprise 4-12 parts of aureobasidium polysaccharide fiber and 4-10 parts of shielding fiber;
the shielding fiber is made of metal.
The metal oxide is prepared from (4-10) by mass: (2-6) tin oxide and iron oxide.
The invention also provides a preparation method of the radiation-proof fabric, which comprises the following steps,
making bamboo charcoal fiber, nano silver fiber and milk fiber into warp yarn;
preparing the radiation-proof fiber, the recombinant spider silk protein fiber and the animal protein fiber into weft yarn;
and the warp yarns and the weft yarns are vertically interwoven, then the coating is respectively sprayed on the front surface and the back surface, the coating is sprayed again after the first drying, and the radiation-proof fabric is obtained after the second drying.
The warp yarns also comprise silk fibers;
the weft yarns also comprise aureobasidium pullulans fibers and shielding fibers.
The first drying temperature is 50-60 ℃, and the time is 10-16 min;
the temperature of the second drying is 100-130 ℃, and the time is 15-25 min.
The technical scheme of the invention has the following advantages:
1. the radiation-proof fabric provided by the invention comprises nano silver fibers, milk fibers, bamboo charcoal fibers, radiation-proof fibers, recombinant spider silk protein fibers and animal protein fibers, all the components in the fabric supplement each other, and the components make up for each other to make the fabric have good comfortable softness and radiation-proof effects, and also have good comfort, antibacterial property and air permeability. In addition, because the market price of the nano-silver fiber is higher, the nano-silver fiber is controlled to be matched with other fibers, so that the using amount of the nano-silver fiber can be reduced, the radiation protection effect and the antibacterial property of the fabric brought by the nano-silver fiber can be ensured, and the production cost of the fabric is obviously reduced.
2. The radiation-proof fabric provided by the invention has good radiation resistance, and also has good comfort, antibacterial property and air permeability; the reason is that the radiation resistance and the antibacterial property of the warp yarns can be improved by adding the nano silver fibers into the warp yarns of the fabric substrate; the addition of the milk fiber can obviously improve the softness and comfort of the warp; the antibacterial property of the warp yarns can be improved by adding the bamboo charcoal fibers, the bamboo charcoal fibers also have moisture absorption and air permeability, the fabric has better air permeability and moisture resistance, and the warp yarns have better radiation resistance, comfort, antibacterial property and moisture resistance by exerting a synergistic effect and making up for deficiencies of the nano silver fibers, the milk fibers and the bamboo charcoal fibers. The radiation-proof fibers are added into weft yarns of the fabric substrate, under the action of the graphene nanofibers, the polyaniline fibers, the acetate fibers, the barium sulfate and the metal oxide, the radiation-proof fibers have good radiation resistance and wear resistance, and are not easy to wear and break in the using process; the addition of the recombinant spider silk protein fiber and the animal protein fiber can ensure that the weft yarn has better softness and comfort. Warp and woof in this surface fabric base member have better compliance simultaneously, have improved the surface fabric that the material that makes the surface fabric have certain intensity and hardness that the radiation protection exists and cause is harder, not soft travelling comfort problem greatly, can satisfy people to the higher requirement of travelling comfort, as the surface fabric of baby and pregnant woman dress etc.. After the warp and the weft are woven into the fabric, all raw materials in the warp and the weft are interwoven together, the advantages of the raw materials can be fully exerted, the defects of other raw materials are overcome, the fabric is integrally soft and comfortable, the phenomenon of local stiffness cannot occur, and the softness, the radiation resistance, the antibacterial property, the air permeability and the wear resistance of the fabric are further improved.
3. According to the radiation-proof fabric provided by the invention, the coating is coated on the fabric, the raw materials of the coating comprise calcium carbonate, soybean lecithin, diatom, polytetrafluoroethylene and silicon oxide, the radiation-proof property of the fabric can be further improved by coating the coating on a fabric substrate, and the soybean lecithin and the diatom are also contained in the coating, so that the coating has certain flexibility and the softness and comfort of the fabric are not influenced.
4. According to the radiation-proof fabric provided by the invention, the raw materials of the warp yarns also comprise natural silk fibers, wherein the natural silk fibers can further improve the softness and comfort of the warp yarns.
5. According to the radiation-proof fabric provided by the invention, the aureobasidium polysaccharide fiber and the shielding fiber are added into the weft yarn, and are matched with the recombinant spider silk protein fiber to improve the fireproof and heat-insulating properties of the fabric; the aureobasidium polysaccharide fiber can also be matched with the animal protein fiber to improve the softness and comfort of the fabric;
the shielding fibers and the radiation-proof fibers play a synergistic effect to further improve the radiation resistance of the weft yarns, and the fabric can also have a good antistatic effect.
6. The preparation method of the radiation-proof fabric provided by the invention is simple to operate and easy to realize, the coating and the fabric substrate can have better fitting property by controlling the temperature and time of the first drying and the second drying, and the coating is not easy to fall off in the using process.
Acetate fibers in the radiation-proof fibers in the fabric and polytetrafluoroethylene in the radiation-proof coating can be crosslinked in the second drying process, so that the binding force between the fabric and the coating is improved, and the integrity of the fabric and the coating is enhanced.
Detailed Description
The following examples are provided to further understand the present invention, not to limit the scope of the present invention, but to provide the best mode, not to limit the content and the protection scope of the present invention, and any product similar or similar to the present invention, which is obtained by combining the present invention with other prior art features, falls within the protection scope of the present invention.
The examples do not show the specific experimental steps or conditions, and can be performed according to the conventional experimental steps described in the literature in the field. The reagents or instruments used are not indicated by manufacturers, and are all conventional reagent products which can be obtained commercially.
Example 1
The embodiment provides a fabric and a preparation method thereof, wherein the fabric comprises a fabric substrate and a coating coated on the fabric substrate;
the fabric base body comprises warp yarns and weft yarns, and the warp yarns comprise 3kg of nano-silver fibers, 2kg of milk fibers, 10kg of bamboo charcoal fibers and 2kg of natural silk fibers;
the raw materials of the weft yarn comprise 2kg of radiation-proof fiber, 1kg of recombinant spider silk protein fiber, 3kg of animal protein fiber, 4kg of aureobasidium pullulans fiber and 4kg of copper shielding fiber; wherein the radiation-proof fibers comprise graphene carbon nanofibers, polyaniline fibers, cellulose acetate fibers, tin dioxide, nano barium sulfate, ferric oxide and ethanol in a mass ratio of 4:3:2:4:3:2: 5;
the raw materials of the coating comprise 3kg of calcium carbonate, 2kg of soybean lecithin, 1kg of diatom, 2kg of polytetrafluoroethylene and 2kg of nano-scale silicon dioxide powder.
The preparation method of the fabric comprises the following steps,
adding bamboo charcoal fiber, nano silver fiber, natural silk fiber and milk fiber into a spinning machine to prepare warp;
adding animal protein fiber, recombinant spider silk protein fiber, aureobasidium polysaccharide fiber, nano metal shielding fiber and radiation-proof fiber into a spinning machine to prepare weft;
adding the warps and the wefts into a interweaving machine to be vertically interwoven to prepare a fabric substrate;
uniformly spraying radiation-proof coatings on the front side and the back side of the fabric substrate, and then putting the fabric substrate into a dryer for drying at the drying temperature of 50 ℃ for 10 min; and spraying a layer of radiation-proof coating for drying at the drying temperature of 100 ℃ for 15min to obtain the radiation-proof fabric.
Example 2
The embodiment provides a fabric and a preparation method thereof, wherein the fabric comprises a fabric substrate and a coating coated on the fabric substrate;
the fabric base body comprises warp yarns and weft yarns, and the warp yarns comprise 9kg of nano-silver fibers, 4kg of milk fibers, 20kg of bamboo charcoal fibers and 6kg of natural silk fibers;
the raw materials of the weft yarn comprise 2kg of radiation-proof fiber, 3kg of recombinant spider silk protein fiber, 9kg of animal protein fiber, 12kg of aureobasidium pullulans fiber and 10kg of nickel shielding fiber; wherein the radiation-proof fibers comprise graphene carbon nanofibers, polyaniline fibers, cellulose acetate fibers, tin dioxide, nano barium sulfate, ferric oxide and ethanol in a mass ratio of 10:9:4:10:9:6: 12;
the raw materials of the coating comprise 3kg of calcium carbonate, 2kg of soybean lecithin, 1kg of diatom, 2kg of polytetrafluoroethylene and 2kg of nano-scale silicon dioxide powder.
The preparation method of the fabric comprises the following steps,
adding bamboo charcoal fiber, nano silver fiber, natural silk fiber and milk fiber into a spinning machine to prepare warp;
adding animal protein fiber, recombinant spider silk protein fiber, aureobasidium polysaccharide fiber, nano metal shielding fiber and radiation-proof fiber into a spinning machine to prepare weft;
adding the warps and the wefts into a interweaving machine to be vertically interwoven to prepare a fabric substrate;
uniformly spraying radiation-proof coatings on the front side and the back side of the fabric substrate, and then putting the fabric substrate into a dryer for drying at the drying temperature of 60 ℃ for 16 min; and spraying a layer of radiation-proof coating for drying at the temperature of 130 ℃ for 25min to obtain the radiation-proof fabric.
Example 3
The embodiment provides a fabric and a preparation method thereof, wherein the fabric comprises a fabric substrate and a coating coated on the fabric substrate;
the fabric base body comprises warp yarns and weft yarns, and the warp yarns comprise 4kg of nano-silver fibers, 3kg of milk fibers, 12kg of bamboo charcoal fibers and 3kg of natural silk fibers;
the raw materials of the weft yarn comprise 3kg of radiation-proof fiber, 2kg of recombinant spider silk protein fiber, 4kg of animal protein fiber, 6kg of aureobasidium pullulan fiber and 5kg of copper shielding fiber; wherein the radiation-proof fibers comprise graphene carbon nanofibers, polyaniline fibers, cellulose acetate fibers, tin dioxide, nano barium sulfate, ferric oxide and ethanol in a mass ratio of 5:4:2:5:4:3: 6;
the raw materials of the coating comprise 3kg of calcium carbonate, 2kg of soybean lecithin, 1kg of diatom, 2kg of polytetrafluoroethylene and 2kg of nano-scale silicon dioxide powder.
The preparation method of the fabric comprises the following steps,
adding bamboo charcoal fiber, nano silver fiber, natural silk fiber and milk fiber into a spinning machine to prepare warp;
adding animal protein fiber, recombinant spider silk protein fiber, aureobasidium polysaccharide fiber, nano metal shielding fiber and radiation-proof fiber into a spinning machine to prepare weft;
adding the warps and the wefts into a interweaving machine to be vertically interwoven to prepare a fabric substrate;
uniformly spraying radiation-proof coatings on the front surface and the back surface of the fabric substrate, and then putting the fabric substrate into a dryer for drying at the drying temperature of 52 ℃ for 12 min; and spraying a layer of radiation-proof coating for drying at the drying temperature of 110 ℃ for 18min to obtain the radiation-proof fabric.
Example 4
The embodiment provides a fabric and a preparation method thereof, wherein the fabric comprises a fabric substrate and a coating coated on the fabric substrate;
the fabric base body comprises warp yarns and weft yarns, and the warp yarns comprise 8kg of nano-silver fibers, 4kg of milk fibers, 18kg of bamboo charcoal fibers and 5kg of natural silk fibers;
the raw materials of the weft yarn comprise 3kg of radiation-proof fiber, 2kg of recombinant spider silk protein fiber, 8kg of animal protein fiber, 10kg of aureobasidium pullulans fiber and 9kg of copper shielding fiber; the radiation-proof fibers comprise graphene carbon nanofibers, polyaniline fibers, cellulose acetate fibers, tin dioxide, nano barium sulfate, ferric oxide and ethanol in a mass ratio of 8:8:3:8:8:5: 10;
the raw materials of the coating comprise 3kg of calcium carbonate, 2kg of soybean lecithin, 1kg of diatom, 2kg of polytetrafluoroethylene and 2kg of nano-scale silicon dioxide powder.
The preparation method of the fabric comprises the following steps,
adding bamboo charcoal fiber, nano silver fiber, natural silk fiber and milk fiber into a spinning machine to prepare warp;
adding animal protein fiber, recombinant spider silk protein fiber, aureobasidium polysaccharide fiber, nano metal shielding fiber and radiation-proof fiber into a spinning machine to prepare weft;
adding the warps and the wefts into a interweaving machine to be vertically interwoven to prepare a fabric substrate;
uniformly spraying radiation-proof coatings on the front side and the back side of the fabric substrate, and then putting the fabric substrate into a dryer for drying at the drying temperature of 58 ℃ for 13 min; and spraying a layer of radiation-proof coating for drying at the temperature of 120 ℃ for 22min to obtain the radiation-proof fabric.
Example 5
The embodiment provides a fabric and a preparation method thereof, wherein the fabric comprises a fabric substrate and a coating coated on the fabric substrate;
the fabric base body comprises warp yarns and weft yarns, and the warp yarns comprise 6kg of nano-silver fibers, 3kg of milk fibers, 15kg of bamboo charcoal fibers and 4kg of natural silk fibers;
the raw materials of the weft yarn comprise 3kg of radiation-proof fiber, 2kg of recombinant spider silk protein fiber, 6kg of animal protein fiber, 8kg of aureobasidium pullulans fiber and 7kg of copper shielding fiber; the radiation-proof fibers comprise graphene carbon nanofibers, polyaniline fibers, acetate fibers, tin dioxide, nano barium sulfate, ferric oxide and ethanol in a mass ratio of 7:6:3:7:6:4: 8;
the raw materials of the coating comprise 3kg of calcium carbonate, 2kg of soybean lecithin, 1kg of diatom, 2kg of polytetrafluoroethylene and 2kg of nano-scale silicon dioxide powder.
The preparation method of the fabric comprises the following steps,
adding bamboo charcoal fiber, nano silver fiber, natural silk fiber and milk fiber into a spinning machine to prepare warp;
adding animal protein fiber, recombinant spider silk protein fiber, aureobasidium polysaccharide fiber, nano metal shielding fiber and radiation-proof fiber into a spinning machine to prepare weft;
adding the warps and the wefts into a interweaving machine to be vertically interwoven to prepare a fabric substrate;
uniformly spraying radiation-proof coatings on the front side and the back side of the fabric substrate, and then putting the fabric substrate into a dryer for drying at the drying temperature of 55 ℃ for 13 min; and spraying a layer of radiation-proof coating for drying at 115 ℃ for 20min to obtain the radiation-proof fabric.
Example 6
The embodiment provides a fabric and a preparation method thereof, wherein the fabric comprises a fabric substrate and a coating coated on the fabric substrate;
the fabric base body comprises warp yarns and weft yarns, and the warp yarns comprise 6kg of nano-silver fibers, 3kg of milk fibers and 15kg of bamboo charcoal fibers;
the raw materials of the weft yarn comprise 3kg of radiation-proof fiber, 2kg of recombinant spider silk protein fiber and 6kg of animal protein fiber; wherein the radiation-proof fibers comprise graphene carbon nanofibers, polyaniline fibers, cellulose acetate fibers, tin dioxide, nano barium sulfate, ferric oxide and ethanol in a mass ratio of 7:6:3:7:6:4: 8;
the raw materials of the coating comprise 3kg of calcium carbonate, 2kg of soybean lecithin, 1kg of diatom, 2kg of polytetrafluoroethylene and 2kg of nano-scale silicon dioxide powder.
The preparation method of the fabric comprises the following steps,
adding bamboo charcoal fiber, nano silver fiber and milk fiber into a spinning machine to prepare warp;
adding the animal protein fiber, the recombinant spider silk protein fiber and the radiation-proof fiber into a spinning machine to prepare weft;
adding the warps and the wefts into a interweaving machine to be vertically interwoven to prepare a fabric substrate;
uniformly spraying radiation-proof coatings on the front side and the back side of the fabric substrate, and then putting the fabric substrate into a dryer for drying at the drying temperature of 55 ℃ for 13 min; and spraying a layer of radiation-proof coating for drying at 115 ℃ for 20min to obtain the radiation-proof fabric.
Example 7
The embodiment provides a fabric and a preparation method thereof, wherein the fabric comprises a fabric substrate and a coating coated on the fabric substrate;
the fabric base body comprises warp yarns and weft yarns, and the warp yarns comprise 3kg of nano-silver fibers, 2kg of milk fibers, 10kg of bamboo charcoal fibers and 2kg of natural silk fibers;
the raw materials of the weft yarn comprise 2kg of radiation-proof fiber, 1kg of recombinant spider silk protein fiber, 3kg of animal protein fiber, 4kg of aureobasidium pullulans fiber and 4kg of copper shielding fiber; wherein the radiation-proof fibers comprise graphene carbon nanofibers, polyaniline fibers, cellulose acetate fibers, tin dioxide, nano barium sulfate, ferric oxide and ethanol in a mass ratio of 4:3:2:4:3:2: 5;
the raw materials of the coating comprise 2kg of calcium carbonate, 3kg of soybean lecithin, 1.5kg of diatom, 1kg of polytetrafluoroethylene and 3kg of nano-scale silicon dioxide powder.
The preparation method of the fabric comprises the following steps,
adding bamboo charcoal fiber, nano silver fiber, natural silk fiber and milk fiber into a spinning machine to prepare warp;
adding animal protein fiber, recombinant spider silk protein fiber, aureobasidium polysaccharide fiber, nano metal shielding fiber and radiation-proof fiber into a spinning machine to prepare weft;
adding the warps and the wefts into a interweaving machine to be vertically interwoven to prepare a fabric substrate;
uniformly spraying radiation-proof coatings on the front side and the back side of the fabric substrate, and then putting the fabric substrate into a dryer for drying at the drying temperature of 50 ℃ for 10 min; and spraying a layer of radiation-proof coating for drying at the drying temperature of 100 ℃ for 15min to obtain the radiation-proof fabric.
Example 8
The embodiment provides a fabric and a preparation method thereof, wherein the fabric comprises a fabric substrate and a coating coated on the fabric substrate;
the fabric base body comprises warp yarns and weft yarns, and the warp yarns comprise 3kg of nano-silver fibers, 2kg of milk fibers, 10kg of bamboo charcoal fibers and 2kg of natural silk fibers;
the raw materials of the weft yarn comprise 2kg of radiation-proof fiber, 1kg of recombinant spider silk protein fiber, 3kg of animal protein fiber, 4kg of aureobasidium pullulans fiber and 4kg of copper shielding fiber; wherein the radiation-proof fibers comprise graphene carbon nanofibers, polyaniline fibers, cellulose acetate fibers, tin dioxide, nano barium sulfate, ferric oxide and ethanol in a mass ratio of 4:3:2:4:3:2: 5;
the raw materials of the coating comprise 3kg of calcium carbonate, 2kg of soybean lecithin, 0.5kg of diatom, 3kg of polytetrafluoroethylene and 1kg of nano-scale silicon dioxide powder.
The preparation method of the fabric comprises the following steps,
adding bamboo charcoal fiber, nano silver fiber, natural silk fiber and milk fiber into a spinning machine to prepare warp;
adding animal protein fiber, recombinant spider silk protein fiber, aureobasidium polysaccharide fiber, nano metal shielding fiber and radiation-proof fiber into a spinning machine to prepare weft;
adding the warps and the wefts into a interweaving machine to be vertically interwoven to prepare a fabric substrate;
uniformly spraying radiation-proof coatings on the front side and the back side of the fabric substrate, and then putting the fabric substrate into a dryer for drying at the drying temperature of 50 ℃ for 10 min; and spraying a layer of radiation-proof coating for drying at the drying temperature of 100 ℃ for 15min to obtain the radiation-proof fabric.
Comparative example 1
The comparative example provides a fabric and a preparation method thereof, the fabric comprises a fabric substrate and a coating coated on the fabric substrate;
the fabric base body comprises warp yarns and weft yarns, and the warp yarns comprise 3kg of nano-silver fibers, 10kg of bamboo charcoal fibers and 2kg of natural silk fibers;
the raw materials of the weft yarn comprise 1kg of recombinant spider silk protein fiber, 3kg of animal protein fiber, 4kg of aureobasidium polysaccharide fiber and 4kg of copper shielding fiber;
the raw materials of the coating comprise 3kg of calcium carbonate, 2kg of soybean lecithin, 1kg of diatom, 2kg of polytetrafluoroethylene and 2kg of nano-scale silicon dioxide powder.
The preparation method of the fabric comprises the following steps,
adding bamboo charcoal fiber, nano silver fiber and natural silk fiber into a spinning machine to prepare warp;
adding animal protein fiber, recombinant spider silk protein fiber, nano metal shielding fiber and aureobasidium polysaccharide fiber into a spinning machine to prepare weft;
adding the warps and the wefts into a interweaving machine to be vertically interwoven to prepare a fabric substrate;
uniformly spraying radiation-proof coatings on the front side and the back side of the fabric substrate, and then putting the fabric substrate into a dryer for drying at the drying temperature of 50 ℃ for 10 min; and spraying a layer of radiation-proof coating for drying at the drying temperature of 100 ℃ for 15min to obtain the radiation-proof fabric.
Comparative example 2
The comparative example provides a fabric and a preparation method thereof, the fabric comprises a fabric substrate and a coating coated on the fabric substrate;
the fabric base body comprises warp yarns and weft yarns, and the warp yarns comprise 2kg of milk fibers, 10kg of bamboo charcoal fibers and 2kg of natural silk fibers;
the raw materials of the weft yarn comprise 2kg of radiation-proof fiber, 1kg of recombinant spider silk protein fiber, 4kg of aureobasidium pullulans fiber and 4kg of copper shielding fiber; wherein the radiation-proof fibers comprise graphene carbon nanofibers, polyaniline fibers, cellulose acetate fibers, tin dioxide, nano barium sulfate, ferric oxide and ethanol in a mass ratio of 4:3:2:4:3:2: 5;
the raw materials in the coating comprise 3kg of calcium carbonate, 2kg of soybean lecithin, 1kg of diatom, 2kg of polytetrafluoroethylene and 2kg of nano-scale silicon dioxide powder.
The preparation method of the fabric comprises the following steps,
adding bamboo charcoal fiber, silk fiber and milk fiber into a spinning machine to prepare warp;
adding animal protein fiber, aureobasidium pullulans fiber, nano metal shielding fiber and radiation-proof fiber into a spinning machine to prepare weft;
adding the warps and the wefts into a interweaving machine to be vertically interwoven to prepare a fabric substrate;
uniformly spraying radiation-proof coatings on the front side and the back side of the fabric substrate, and then putting the fabric substrate into a dryer for drying at the drying temperature of 50 ℃ for 10 min; and spraying a layer of radiation-proof coating for drying at the drying temperature of 100 ℃ for 15min to obtain the radiation-proof fabric.
Test examples
The test example provides performance tests and test results of the radiation-proof fabrics prepared in examples 1-8 and comparative examples 1-2,
the method for testing the air permeability of the radiation-proof fabric comprises the following steps: GB/T5453-1997 determination of the air Permeability of textile fabrics;
the method for testing the degerming rate of the radiation-proof fabric comprises the following steps: GB/T31713 and 2015 requirements for safety and sanitation of antibacterial textiles; the width of the inhibition zone is used for indirectly representing the bacteria removal rate, and the smaller the width value of the inhibition zone is, the better the bacteria inhibition is, namely the higher the bacteria removal rate is.
The test method for the ultraviolet radiation prevention effect of the radiation protection fabric comprises the following steps: GB/T18830-2009 evaluation of ultraviolet resistance of textiles;
the method for testing the radiation-proof heat effect of the radiation-proof fabric comprises the following steps: GB/T38453-2019 protective clothing thermal insulation suit;
the comfort test method of the fabric comprises the following steps: GB/T11048-.
Table 1 performance test results of radiation protection fabrics obtained in examples and comparative examples
In table 1, as compared with comparative example 1, it can be seen that the fabric performance is obviously reduced after the formula of the invention is changed by removing the milk fiber in the warp and the radiation-proof fiber in the weft.
Compared with the comparative example 2, the example 1 shows that when the nano silver fibers are removed from the warp yarns and the recombinant spider silk protein fibers are removed from the weft yarns, the performance of the fabric is obviously reduced after the formula of the invention is changed.
It should be understood that the above examples are only for clarity of illustration and are not intended to limit the embodiments. Other variations and modifications will be apparent to persons skilled in the art in light of the above description. And are neither required nor exhaustive of all embodiments. And obvious variations or modifications of the invention may be made without departing from the spirit or scope of the invention.
Claims (10)
1. An anti-radiation fabric is characterized by comprising a fabric substrate and a coating coated on the fabric substrate;
the fabric substrate comprises, by weight, 3-9 parts of nano-silver fibers, 2-4 parts of milk fibers, 10-20 parts of bamboo charcoal fibers, 2-4 parts of radiation-proof fibers, 1-3 parts of recombinant spider silk protein fibers and 3-9 parts of animal protein fibers.
2. The radiation protective fabric of claim 1, wherein the fabric base comprises warp yarns and weft yarns;
the warp yarn comprises, by weight, 3-9 parts of nano-silver fibers, 2-4 parts of milk fibers and 10-20 parts of bamboo charcoal fibers;
the raw materials of the weft yarn comprise, by weight, 2-4 parts of radiation-proof fibers, 1-3 parts of recombinant spider silk protein fibers and 3-9 parts of animal protein fibers;
the radiation-proof fiber comprises, by weight, 4-10 parts of graphene-based carbon nanofiber, 3-9 parts of polyaniline fiber, 2-4 parts of acetate fiber, 3-9 parts of barium sulfate and 6-16 parts of metal oxide.
3. The radiation-proof fabric according to claim 1 or 2, wherein the coating comprises the following raw materials in percentage by mass (2-3): (2-3): (0.5-1.5): (1-3): (1-3) calcium carbonate, soybean lecithin, diatom, polytetrafluoroethylene and silica.
4. The radiation protective fabric of claim 2 or 3, wherein the density of the warp yarns is 100-120 yarns/in;
the density of the weft yarns is 70-80 per in;
the fineness of the fabric is 45-55D.
5. The radiation protection fabric of any one of claims 2-4, wherein the warp yarns are made of 2-6 parts of natural silk fibers.
6. The radiation protective fabric of any one of claims 2 to 5, wherein the raw materials of the weft yarn further comprise 4 to 12 parts of aureobasidium pullulans fiber and 4 to 10 parts of shielding fiber;
the shielding fiber is made of metal.
7. The radiation protective fabric according to claim 2, wherein the metal oxide is a mixture of metal oxide and metal oxide in a mass ratio of (4-10): (2-6) tin oxide and iron oxide.
8. A method for preparing the radiation protective fabric of any one of claims 1-7, comprising,
making bamboo charcoal fiber, nano silver fiber and milk fiber into warp yarn;
preparing the radiation-proof fiber, the recombinant spider silk protein fiber and the animal protein fiber into weft yarn;
and the warp yarns and the weft yarns are vertically interwoven, then the coating is respectively sprayed on the front surface and the back surface, the coating is sprayed again after the first drying, and the radiation-proof fabric is obtained after the second drying.
9. The method according to claim 8, wherein the warp yarns further comprise silk fibers;
the weft yarns also comprise aureobasidium pullulans fibers and shielding fibers.
10. The preparation method according to claim 8 or 9, wherein the temperature of the first drying is 50-60 ℃ and the time is 10-16 min;
the temperature of the second drying is 100-130 ℃, and the time is 15-25 min.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111979625A (en) * | 2020-08-25 | 2020-11-24 | 湖南尚珂伊针纺有限公司 | Chemical fiber composite fiber and processing method thereof |
| CN114561727A (en) * | 2022-02-28 | 2022-05-31 | 青铜峡市仁和纺织科技有限公司 | Radiation-proof yarn combining wave-absorbing technology and shielding technology |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104005153A (en) * | 2014-05-04 | 2014-08-27 | 南通环宇丝绸有限公司 | Pleated super-soft anti-microbial fabric for radiation-proof clothes for pregnant woman |
| CN108085832A (en) * | 2017-12-21 | 2018-05-29 | 河南新野纺织股份有限公司 | A kind of graphene radiation resistant fiber yarn fabric |
| CN108285658A (en) * | 2017-08-10 | 2018-07-17 | 江苏新瑞贝科技股份有限公司 | A kind of preparation method of antiradiation coating |
| WO2018205306A1 (en) * | 2017-05-12 | 2018-11-15 | 海安睿华纺织科技有限公司 | Antibacterial and anti-radiation textile fabric |
| CN110074490A (en) * | 2019-02-28 | 2019-08-02 | 李春 | A kind of radiation-proof fabric and preparation method thereof |
-
2020
- 2020-03-31 CN CN202010243666.5A patent/CN111321500A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104005153A (en) * | 2014-05-04 | 2014-08-27 | 南通环宇丝绸有限公司 | Pleated super-soft anti-microbial fabric for radiation-proof clothes for pregnant woman |
| WO2018205306A1 (en) * | 2017-05-12 | 2018-11-15 | 海安睿华纺织科技有限公司 | Antibacterial and anti-radiation textile fabric |
| CN108285658A (en) * | 2017-08-10 | 2018-07-17 | 江苏新瑞贝科技股份有限公司 | A kind of preparation method of antiradiation coating |
| CN108085832A (en) * | 2017-12-21 | 2018-05-29 | 河南新野纺织股份有限公司 | A kind of graphene radiation resistant fiber yarn fabric |
| CN110074490A (en) * | 2019-02-28 | 2019-08-02 | 李春 | A kind of radiation-proof fabric and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 刘建平主编: "《染整助剂综合实训》", vol. 1, 东华大学出版社, pages: 179 - 181 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111979625A (en) * | 2020-08-25 | 2020-11-24 | 湖南尚珂伊针纺有限公司 | Chemical fiber composite fiber and processing method thereof |
| CN114561727A (en) * | 2022-02-28 | 2022-05-31 | 青铜峡市仁和纺织科技有限公司 | Radiation-proof yarn combining wave-absorbing technology and shielding technology |
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