CN111303802A - High-strength ceramic tile back glue - Google Patents
High-strength ceramic tile back glue Download PDFInfo
- Publication number
- CN111303802A CN111303802A CN202010101627.1A CN202010101627A CN111303802A CN 111303802 A CN111303802 A CN 111303802A CN 202010101627 A CN202010101627 A CN 202010101627A CN 111303802 A CN111303802 A CN 111303802A
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- parts
- agent
- back glue
- strength
- tile back
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J125/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Adhesives based on derivatives of such polymers
- C09J125/02—Homopolymers or copolymers of hydrocarbons
- C09J125/04—Homopolymers or copolymers of styrene
- C09J125/08—Copolymers of styrene
- C09J125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J109/00—Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09J109/06—Copolymers with styrene
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a high-strength tile back glue which comprises the following components in parts by weight: 75-98 parts of polymer emulsion, 0.2-2 parts of ZnO, 0.2-20 parts of filler, 0.5-1.2 parts of coupling agent, 0.1-0.5 part of wetting agent, 0.3-0.6 part of defoaming agent, 0.1-0.5 part of preservative and 0.3-0.6 part of thickening agent. The high-strength ceramic tile back glue provided by the invention has better wettability and delayed viscosity, and greatly improves the phenomena of shrinkage cavity, hollowing, brick falling and the like caused by the fact that the back glue is coated on a ceramic tile and the later strength is not enough.
Description
Technical Field
The invention relates to a ceramic tile adhesive, in particular to a high-strength ceramic tile back adhesive.
Background
With the improvement of living standard, people pursue building beauty more and more, and various wall decoration materials such as ceramic tiles and the like are applied to decoration in a large quantity. Therefore, some problems in construction and application such as construction efficiency, durability in use, safety, and the like are also caused. In traditional construction, the ceramic tile is mostly adopted cement yellow sand with the bonding of wall, and its cohesiveness is poor, produces the hollowing easily, and the long-time ceramic tile easily drops, and the maintenance is got up the difficulty, and the ceramic tile that falls down from the eminence in addition injures the people easily by a crashing object, has very big potential safety hazard.
The tile glue is produced by adding a high-performance auxiliary agent for modification on the basis of cement sand, so that the water retention and the bonding performance of the cement sand are improved on a certain basis, and the problem of poor bonding of cement mortar is solved to a certain extent. At present, the application of ceramic tile glue is more general, but current ceramic tile gum is poor, the wettability keeps not good late viscidity, and the roughness of building is not meticulous enough in addition usually, and master workers still are used to thick subsides, lead to the shrink hollowing that can appear certain degree, and this has also increased the risk that the hollowing falls the brick to a certain extent.
Disclosure of Invention
The invention aims to provide the high-strength ceramic tile back glue with good late adhesion, difficult degumming later period and good wettability aiming at the defects of the prior art.
In order to achieve the purpose, the invention adopts the technical scheme that: the high-strength tile back glue comprises the following components in parts by weight: 75-98 parts of polymer emulsion, 0.2-2 parts of ZnO, 0.2-20 parts of filler, 0.5-1.2 parts of coupling agent, 0.1-0.5 part of wetting agent, 0.3-0.6 part of defoaming agent, 0.1-0.5 part of preservative and 0.3-0.6 part of thickening agent.
As a preferred embodiment of the high-strength tile back glue, the high-strength tile back glue comprises the following components in parts by weight: 77-89 parts of polymer emulsion, 1-1.5 parts of ZnO, 7-20 parts of filler, 0.5-1 part of coupling agent, 0.3-0.5 part of wetting agent, 0.3-0.6 part of defoaming agent, 0.4-0.5 part of preservative and 0.3-0.6 part of thickening agent.
As a preferred embodiment of the high-strength tile back glue, the high-strength tile back glue comprises the following components in parts by weight: 77 parts of polymer emulsion, 1 part of ZnO, 20 parts of filler, 0.5 part of coupling agent, 0.3 part of wetting agent, 0.5 part of defoaming agent, 0.4 part of preservative and 0.3 part of thickening agent.
As a preferred embodiment of the high-strength tile back glue, the high-strength tile back glue comprises the following components in parts by weight: 83.5 parts of polymer emulsion, 1.5 parts of ZnO, 12.2 parts of filler, 1.0 part of coupling agent, 0.5 part of wetting agent, 0.3 part of defoaming agent, 0.5 part of preservative and 0.5 part of thickening agent.
As a preferred embodiment of the high-strength tile back glue, the high-strength tile back glue comprises the following components in parts by weight: 89 parts of polymer emulsion, 1.0 part of ZnO, 7.2 parts of filler, 0.8 part of coupling agent, 0.4 part of wetting agent, 0.6 part of defoaming agent, 0.4 part of preservative and 0.6 part of thickening agent.
As a preferred embodiment of the high-strength tile back glue, the polymer emulsion is at least one of styrene-acrylic emulsion and styrene-butadiene emulsion, and the glass transition temperature of the polymer emulsion is-40 ℃ to-15 ℃. The polymer emulsion with a core-shell structure is selected as the polymer emulsion, and the emulsion with low glass transition temperature (Tg) generally has good initial viscosity but poor late viscosity, so that the subsequent strength is low and bricks are easy to fall off. The emulsion with the core-shell structure is adopted in the invention, so that the initial hand-sticking property can be ensured, and the later strength can be ensured due to the core-shell structure in the emulsion.
The added ZnO can form a crosslinking effect with the polymer emulsion, and has the effect of increasing the strength. As a preferred embodiment of the high-strength tile back glue, the filler is at least one of calcium carbonate, talcum powder, quartz powder, silica fume powder and titanium dioxide.
As a preferred embodiment of the high-strength tile back glue of the present invention, the coupling agent is a silane compound, such as: KH-570. In the invention, the addition of the coupling agent can increase the adhesive force of the gum and improve the strength.
As a preferred embodiment of the high-strength tile back glue of the present invention, the wetting agent is at least one of silicone modified polysiloxane (e.g., meta mat 348), acrylic copolymer (e.g., EDAPLAN LA403), and esters (e.g., meta mat 368). According to the invention, the addition of the wetting agent can reduce the problem of shrinkage cavity of the back glue on the back of the ceramic tile, and ensure that the whole ceramic tile is coated with the back glue without shrinkage cavity.
In a preferred embodiment of the high-strength tile back adhesive of the present invention, the defoaming agent is at least one of silicone (e.g., G60 defoaming agent) and mineral oil (e.g., NXZ defoaming agent).
As a preferable embodiment of the high-strength tile back glue of the present invention, the preservative is an efficient and environment-friendly mildew-proof and bacteria-proof type bactericide, and the active ingredient of the preservative is an isothiazolinone compound, such as cason.
As a preferred embodiment of the high-strength tile back glue of the present invention, the thickener is at least one of cellulose ether (e.g., HPMC), associated alkali swelling thickener (e.g., TRM-206), and polyurethane thickener (e.g., RJ-640).
The high-strength tile back glue is prepared by the following method:
adding a specified amount of polymer emulsion into a kettle type stirrer, starting a machine, then sequentially adding a filler and ZnO, stirring for 10-30 min to ensure that no particles agglomerate, then sequentially adding a wetting agent, a defoaming agent, a coupling agent and a preservative, stirring uniformly, finally adding a thickening agent for thickening, stirring for 5-10 min, and ensuring that dispersion thickening is completed.
The high-strength ceramic tile back glue adopts the specific formula, the polymer emulsion with the core-shell structure is selected, ZnO is added to form a crosslinking effect with the polymer emulsion, the wetting agent is added to reduce the shrinkage phenomenon, the ceramic tile back glue formed by the high-strength ceramic tile back glue has better strength and wettability, and the problems of easy degumming, brick falling, shrinkage and the like in the later period commonly existing in the ceramic tile back glue in the prior art can be effectively solved.
The high-strength ceramic tile back glue with good delayed adhesion and good wettability can better avoid the problem that the ceramic tile glue is hollow and falls off during construction.
Detailed Description
To better illustrate the objects, technical solutions and advantages of the present invention, the present invention will be further described with reference to specific examples.
Example 1
In an embodiment of the high-strength tile back glue of the present invention, the high-strength tile back glue comprises the following components in parts by weight: 75 parts of polymer emulsion, 20 parts of filler, 0.2 part of ZnO, 1.2 parts of coupling agent, 0.1 part of wetting agent, 0.4 part of defoaming agent, 0.3 part of preservative and 0.4 part of thickening agent.
In the embodiment, the polymer emulsion is a styrene-acrylic emulsion with a core-shell structure, and the glass transition temperature of the polymer emulsion is-40 ℃ to-15 ℃; the filler is calcium carbonate; the coupling agent is a silane compound; the wetting agent is organosilicon modified polysiloxane; the defoaming agent is an organic silicon defoaming agent; the preservative is an efficient environment-friendly mildew-proof and bacteria-proof bactericide, and the active component of the preservative is an isothiazolinone compound; the thickening agent is a cellulose ether thickening agent.
Example 2
In an embodiment of the high-strength tile back glue of the present invention, the high-strength tile back glue comprises the following components in parts by weight: 77 parts of polymer emulsion, 1 part of ZnO, 20 parts of filler, 0.5 part of coupling agent, 0.3 part of wetting agent, 0.5 part of defoaming agent, 0.4 part of preservative and 0.3 part of thickening agent.
In the embodiment, the polymer emulsion is a styrene-butadiene emulsion with a core-shell structure, and the glass transition temperature of the polymer emulsion is-40 ℃ to-15 ℃; the filler is quartz powder; the coupling agent is a silane compound; the wetting agent is an acrylic acid copolymer; the defoaming agent is mineral oil defoaming agent; the preservative is an efficient environment-friendly mildew-proof and bacteria-proof bactericide, and the active component of the preservative is an isothiazolinone compound; the thickening agent is a polyurethane thickening agent.
Example 3
In an embodiment of the high-strength tile back glue of the present invention, the high-strength tile back glue comprises the following components in parts by weight: 83.5 parts of polymer emulsion, 1.5 parts of ZnO, 12.2 parts of filler, 1.0 part of coupling agent, 0.5 part of wetting agent, 0.3 part of defoaming agent, 0.5 part of preservative and 0.5 part of thickening agent.
In the embodiment, the polymer emulsion is a styrene-butadiene emulsion with a core-shell structure, and the glass transition temperature of the polymer emulsion is-40 ℃ to-15 ℃; the filler is talcum powder; the coupling agent is a silane compound; the wetting agent is an ester; the defoaming agent is an organic silicon defoaming agent; the preservative is an efficient environment-friendly mildew-proof and bacteria-proof bactericide, and the active component of the preservative is an isothiazolinone compound; the thickening agent is a polyurethane thickening agent.
Example 4
In an embodiment of the high-strength tile back glue of the present invention, the high-strength tile back glue comprises the following components in parts by weight: 89 parts of polymer emulsion, 1.0 part of ZnO, 7.2 parts of filler, 0.8 part of coupling agent, 0.4 part of wetting agent, 0.6 part of defoaming agent, 0.4 part of preservative and 0.6 part of thickening agent.
In the embodiment, the polymer emulsion is a styrene-acrylic emulsion with a core-shell structure, and the glass transition temperature of the polymer emulsion is-40 ℃ to-15 ℃; the filler is silica fume; the coupling agent is a silane compound; the wetting agent is organosilicon modified polysiloxane; the defoaming agent is mineral oil defoaming agent; the preservative is an efficient environment-friendly mildew-proof and bacteria-proof bactericide, and the active component of the preservative is an isothiazolinone compound; the thickener is an associated alkali swelling thickener.
Example 5
In an embodiment of the high-strength tile back glue of the present invention, the high-strength tile back glue comprises the following components in parts by weight: 97.2 parts of polymer emulsion, 0.5 part of ZnO, 0.2 part of filler, 1.0 part of coupling agent, 0.2 part of wetting agent, 0.5 part of defoaming agent, 0.1 part of preservative and 0.5 part of thickening agent.
In the embodiment, the polymer emulsion is styrene-butadiene emulsion and styrene-acrylic emulsion with core-shell structures, and the glass transition temperature of the polymer emulsion is-40 ℃ to-15 ℃; the filler is titanium dioxide; the coupling agent is a silane compound; the wetting agent is organosilicon modified polysiloxane; the defoaming agent is an organic silicon defoaming agent; the preservative is an efficient environment-friendly mildew-proof and bacteria-proof bactericide, and the active component of the preservative is an isothiazolinone compound; the thickening agent is a cellulose ether thickening agent.
Example 6
In an embodiment of the high-strength tile back glue of the present invention, the high-strength tile back glue comprises the following components in parts by weight: 80.9 parts of polymer emulsion, 2 parts of ZnO, 15 parts of filler, 0.9 part of coupling agent, 0.3 part of wetting agent, 0.3 part of defoaming agent, 0.3 part of preservative and 0.3 part of thickening agent.
In the embodiment, the polymer emulsion is a styrene-acrylic emulsion with a core-shell structure, and the glass transition temperature of the polymer emulsion is-40 ℃ to-15 ℃; the filler is quartz powder; the coupling agent is a silane compound; the wetting agent is an acrylic acid copolymer; the defoaming agent is mineral oil defoaming agent; the preservative is an efficient environment-friendly mildew-proof and bacteria-proof bactericide, and the active component of the preservative is an isothiazolinone compound; the thickening agent is a polyurethane thickening agent.
Comparative examples 1 to 4
The tile backsize of comparative examples 1 to 4 contained the respective components and their parts by weight as shown in Table 1.
TABLE 1 COMPARATIVE EXAMPLES 1-4 Tile BACK ADHESIVE FORMULATIONS
Example 7
Performance test of the high-strength tile back glue
According to ceramic tile adhesive (JC/T547-2017), the performance of the ceramic tile back adhesives of examples 1-6 and comparative examples 1-4 is detected, and the specific detection results are shown in Table 2.
Table 2 detection results of back adhesive performance of each group of tiles
The results in this example show that, when the styrene-acrylic emulsion or styrene-butadiene emulsion having a core-shell structure is selected as the polymer emulsion in the present application, compared with other choices, the polymer emulsion has better initial viscosity and higher later strength. The ZnO can form a crosslinking effect with the polymer emulsion, and has the effect of increasing the strength. The addition of the coupling agent can increase the adhesive force of the gum and improve the strength.
Finally, it should be noted that the above embodiments are only used for illustrating the technical solutions of the present invention and not for limiting the protection scope of the present invention, and although the present invention is described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions can be made on the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention.
Claims (10)
1. The high-strength ceramic tile back glue is characterized by comprising the following components in parts by weight: 75-98 parts of polymer emulsion, 0.2-2 parts of ZnO, 0.2-20 parts of filler, 0.5-1.2 parts of coupling agent, 0.1-0.5 part of wetting agent, 0.3-0.6 part of defoaming agent, 0.1-0.5 part of preservative and 0.3-0.6 part of thickening agent.
2. The high-strength tile back glue of claim 1, wherein the high-strength tile back glue comprises the following components in parts by weight: 77-89 parts of polymer emulsion, 1-1.5 parts of ZnO, 7-20 parts of filler, 0.5-1 part of coupling agent, 0.3-0.5 part of wetting agent, 0.3-0.6 part of defoaming agent, 0.4-0.5 part of preservative and 0.3-0.6 part of thickening agent.
3. The high-strength tile back glue of claim 1, wherein the high-strength tile back glue comprises the following components in parts by weight: 77 parts of polymer emulsion, 1 part of ZnO, 20 parts of filler, 0.5 part of coupling agent, 0.3 part of wetting agent, 0.5 part of defoaming agent, 0.4 part of preservative and 0.3 part of thickening agent; or
The high-strength tile back glue comprises the following components in parts by weight: 83.5 parts of polymer emulsion, 1.5 parts of ZnO, 12.2 parts of filler, 1.0 part of coupling agent, 0.5 part of wetting agent, 0.3 part of defoaming agent, 0.5 part of preservative and 0.5 part of thickening agent; or
The high-strength tile back glue comprises the following components in parts by weight: 89 parts of polymer emulsion, 1 part of ZnO, 7.2 parts of filler, 0.8 part of coupling agent, 0.4 part of wetting agent, 0.6 part of defoaming agent, 0.4 part of preservative and 0.6 part of thickening agent.
4. The high-strength tile back glue of any one of claims 1 to 3, wherein the polymer emulsion is at least one of styrene-acrylic emulsion and styrene-butadiene emulsion, and the glass transition temperature of the polymer emulsion is-40 ℃ to-15 ℃.
5. The high-strength tile back glue of any one of claims 1 to 3, wherein the filler is at least one of calcium carbonate, talc powder, quartz powder, silica fume powder and titanium dioxide.
6. The high-strength tile backing adhesive according to any one of claims 1 to 3, wherein the coupling agent is a silane compound.
7. The high-strength tile back glue of any one of claims 1 to 3, wherein the wetting agent is at least one of silicone modified polysiloxane, acrylic acid copolymer and ester.
8. The high-strength tile back glue of any one of claims 1 to 3, wherein the defoaming agent is at least one of silicone and mineral oil.
9. The high-strength tile back glue of any one of claims 1 to 3, wherein the preservative is an efficient environment-friendly mildew-proof and bacteria-proof bactericide, and the active component of the preservative is an isothiazolinone compound.
10. The high strength tile backsize according to any one of claims 1 to 3, wherein the thickener is at least one of cellulose ether, associative alkali swelling thickener, and polyurethane thickener.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010101627.1A CN111303802A (en) | 2020-02-19 | 2020-02-19 | High-strength ceramic tile back glue |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010101627.1A CN111303802A (en) | 2020-02-19 | 2020-02-19 | High-strength ceramic tile back glue |
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| CN111303802A true CN111303802A (en) | 2020-06-19 |
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| CN202010101627.1A Pending CN111303802A (en) | 2020-02-19 | 2020-02-19 | High-strength ceramic tile back glue |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111849393A (en) * | 2020-07-27 | 2020-10-30 | 三棵树涂料股份有限公司 | Environment-friendly water-resistant single-component ceramic tile interface treating agent and preparation method thereof |
| CN111925694A (en) * | 2020-08-19 | 2020-11-13 | 武汉德邦仕建材有限公司 | Energy-saving powerful type repairing glue for tile stone system |
| CN113234418A (en) * | 2021-05-27 | 2021-08-10 | 河南伯高节能科技有限公司 | Tile back glue and preparation method thereof |
| CN113881370A (en) * | 2021-09-14 | 2022-01-04 | 科建高分子材料（上海）股份有限公司 | Tile back glue convenient to identify and using method |
| CN113930191A (en) * | 2020-06-29 | 2022-01-14 | 苏州金螳螂建筑装饰股份有限公司 | Super-strong water-resistant bonding reinforcing agent and preparation method and construction method thereof |
| CN114702937A (en) * | 2022-03-31 | 2022-07-05 | 华润水泥技术研发有限公司 | High-strength ceramic tile gum |
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| CN1084199A (en) * | 1992-09-11 | 1994-03-23 | 罗姆和哈斯公司 | The improved acrylic acid series caulking joint of adhesive performance composition |
| CN106381098A (en) * | 2016-10-21 | 2017-02-08 | 广东金能建筑节能材料科技有限公司 | Special adhesive for ceramic tiles and preparation method thereof |
| CN106634720A (en) * | 2016-12-30 | 2017-05-10 | 河南中包科技有限公司 | Normal-temperature and quick-bonding waterproof adhesive for paper product and preparation method of normal-temperature and quick-bonding waterproof adhesive |
| CN110607148A (en) * | 2019-10-30 | 2019-12-24 | 佛山市言信建材有限公司 | Paste ceramic tile back glue, preparation method and use method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US4059551A (en) * | 1972-11-08 | 1977-11-22 | Tile Council Of America, Inc. | Mortar compositions |
| CN1084199A (en) * | 1992-09-11 | 1994-03-23 | 罗姆和哈斯公司 | The improved acrylic acid series caulking joint of adhesive performance composition |
| CN106381098A (en) * | 2016-10-21 | 2017-02-08 | 广东金能建筑节能材料科技有限公司 | Special adhesive for ceramic tiles and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113930191A (en) * | 2020-06-29 | 2022-01-14 | 苏州金螳螂建筑装饰股份有限公司 | Super-strong water-resistant bonding reinforcing agent and preparation method and construction method thereof |
| CN113930191B (en) * | 2020-06-29 | 2022-11-01 | 苏州金螳螂建筑装饰股份有限公司 | Super-strong water-resistant bonding reinforcing agent and preparation method and construction method thereof |
| CN111849393A (en) * | 2020-07-27 | 2020-10-30 | 三棵树涂料股份有限公司 | Environment-friendly water-resistant single-component ceramic tile interface treating agent and preparation method thereof |
| CN111925694A (en) * | 2020-08-19 | 2020-11-13 | 武汉德邦仕建材有限公司 | Energy-saving powerful type repairing glue for tile stone system |
| CN113234418A (en) * | 2021-05-27 | 2021-08-10 | 河南伯高节能科技有限公司 | Tile back glue and preparation method thereof |
| CN113881370A (en) * | 2021-09-14 | 2022-01-04 | 科建高分子材料（上海）股份有限公司 | Tile back glue convenient to identify and using method |
| CN114702937A (en) * | 2022-03-31 | 2022-07-05 | 华润水泥技术研发有限公司 | High-strength ceramic tile gum |
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Application publication date: 20200619 |