CN104277671A - Water-based thermal insulating coating with good wear resistance weather resistance and preparation method of water-based thermal insulating coating - Google Patents
Water-based thermal insulating coating with good wear resistance weather resistance and preparation method of water-based thermal insulating coating Download PDFInfo
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- CN104277671A CN104277671A CN201410590776.3A CN201410590776A CN104277671A CN 104277671 A CN104277671 A CN 104277671A CN 201410590776 A CN201410590776 A CN 201410590776A CN 104277671 A CN104277671 A CN 104277671A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
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- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a water-based thermal insulating coating with good wear resistance weather resistance. The water-based thermal insulating coating is characterized by being prepared from the following raw materials in parts by weight: 28-35 parts of water-soluble epoxy resin, 4-6 parts of elastic rubber powder, 1-2 parts of 2,2,4-trimethyl-1,3-pentanediol single isobutyric acid ester, 31-35 parts of water-based fluorocarbon resin, 2-3 parts of ceramic microspheres, 2-3 parts of aluminum acetate, 1-3 parts of expanded perlite, 1-2 parts of sterilization fungicide, 10-14 parts of pure acrylic resin emulsion, 1-2 parts of carboxymethyl cellulose, 0.2-0.4 part of simethicone, 0.3-0.5 part of polyether modified polysiloxane, 0.5-0.8 part of polyvinyl methyl ether, 1-3 parts of hexadecyl trimethyl ammonium bromide, 2-4 parts of dipropylene glycol butyl ether, 7-9 parts of thermal insulating slurry and 14-18 parts of deionized water. The water-based coating disclosed by the invention is high in elasticity, excellent in waterproofness, heat-insulating property, sterilizing and anti-mold properties and antistatic property, high in adhesive force, not easy to peel off, high in ageing-resistant performance, not easy to atomize, wide in use, green and worthy of popularization.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, Water-based thermal insulation coating that particularly a kind of wear-resisting weather-proof is good and preparation method thereof.
Background technology
Along with the enhancing of environmental consciousness, countries in the world have worked out the limit standard and regulation that volatile organic matter (VOC) discharges all in succession.Solvent based coating is the important sources of VOC, causes very large pollution, bring great harm to human body to environment, there is the potential safety hazards such as inflammable, explosive in construction, storage, transport simultaneously.Water-borne coatings has green, energy-conservation, safety, acts on feature easily, obtains develop rapidly in countries in the world.Compared with traditional solvent based coating, water-borne coatings has that price is low, use safety, saving resource and the energy, reduces the advantage such as environmental pollution and public hazards, because becoming the Main way of current development coatings industry.Water tolerance, the weather resisteant of common exterior wall latex paint are not enough, particularly affect comparatively large by rainwater, sewage, greatly compromise the attractive in appearance of buildings.Water-borne heat-insulating functional paint, the advantage of water-borne coatings, hydrophobic coating and thermal insulating coating three kinds of coating that its collection is neat, possesses good hydrophobic heat-proof quality, and the problem solving environmental pollution, waste energy, be a kind of green environmental friendly coatings.Along with energy-saving and emission-reduction, the becoming increasingly conspicuous of environmental protection problem, water-soluble multifunctional coating will be a large focus in the development of following coating.
Summary of the invention
The object of this invention is to provide good Water-based thermal insulation coating of a kind of wear-resisting weather-proof and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
The Water-based thermal insulation coating that a kind of wear-resisting weather-proof is good, be made up of the raw material of following weight part: water-soluble epoxy resin 28-35, elastic caoutchouc powder 4-6, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 1-2, water-based fluorocarbon resin 31-35, ceramic microsphere 2-3, cruel sour aluminum fiber 2-3, pearlstone 1-3, biocide mildewcide 1-2, pure acrylic acid Resin emulsion 10-14, carboxymethyl cellulose 1-2, dimethyl silicone oil 0.2-0.4, Siloxane-Oxyalkylene Copolymers 0.3-0.5, polyvinylmethyl ethers 0.5-0.8, cetyl trimethylammonium bromide 1-3, dipropylene 2-4, heat-insulating slurry 7-9, deionized water 14-18,
Described heat-insulating slurry is made up of the raw material of following weight part: nano ceramic fibers 5-7, aluminous cement 20-25, quartz sand mine tailing 20-25, wilkinite 3-5, pearlstone 6-8, polyvinyl alcohol 2-3, aluminum phosphate 4-5, rock wool fibers 5-7, silicon powder 2-4, polyoxyethylenated alcohol sodium sulfate 1-2, lauryl methacrylate(LMA) 12-15, Silane coupling agent KH550 1-2, ethanol 20-30, distilled water 30-40, preparation method is that lauryl methacrylate(LMA) is added in ethanol and fully dissolves by (1), add quartz sand mine tailing again, wilkinite, pearlstone and silicon powder carry out pre-dispersed in 0.3-0.6 hour to stir under 400-600 rev/min, add Silane coupling agent KH550 again to stir and to be added in sand mill that to carry out grinding to form slurry for subsequent use after 15-25 minute, (2) by nano ceramic fibers, rock wool fibers, polyoxyethylenated alcohol sodium sulfate and distilled water mix and blend, high speed shear pulp body, (3) step (1) product is mixed with step (2) product, add all the other remaining components, stir 2-3 hour with the speed of 300-500 rev/min and get final product.
The Water-based thermal insulation coating that a kind of wear-resisting weather-proof of the present invention is good, be made up of following concrete steps:
(1) under the rotating speed of 1000-2000 rev/min, disperse 20-30 minute to obtain the material of fineness at 20-30um deionized water, ceramic microsphere, cruel sour aluminum fiber, pearlstone, then add heat-insulating slurry continuation stirring 20-30 minute;
(2) water-soluble epoxy resin, elastic caoutchouc powder, water-based fluorocarbon resin, pure acrylic acid Resin emulsion, polyvinylmethyl ethers, dipropylene are added to mixing and stirring in Scattered Kettle and are heated to 40-60 ° of C, then the slurry added in carboxymethyl cellulose and step (1) is to continue under the rotating speed of 300-500 rev/min to stir 30-50 minute;
(3) in the reaction system of step (2), add all the other surplus materialss, be added to grinding distribution in sand mill after stirring even, filter and package.
Advantage of the present invention is: water-borne coatings elasticity of the present invention is high, waterproof, heat insulation, fungus and mildew resistance, the excellent performance such as antistatic, and sticking power is high, incrust, and ageing-resistant performance is high, not easily efflorescence, of many uses and environmental protection, is worthy to be popularized.
specific embodiments
Below by specific examples, the present invention is described in detail.
The Water-based thermal insulation coating that a kind of wear-resisting weather-proof is good, be made up of the raw material of following weight part (kilogram): water-soluble epoxy resin 31, elastic caoutchouc powder 5,2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 2, water-based fluorocarbon resin 33, ceramic microsphere 3, cruel sour aluminum fiber 3, pearlstone 2, biocide mildewcide 1, pure acrylic acid Resin emulsion 13, carboxymethyl cellulose 1, dimethyl silicone oil 0.3, Siloxane-Oxyalkylene Copolymers 0.4, polyvinylmethyl ethers 0.6, cetyl trimethylammonium bromide 2, dipropylene 3, heat-insulating slurry 8, deionized water 16;
Described heat-insulating slurry is made up of the raw material of following weight part (kilogram): nano ceramic fibers 6, aluminous cement 24, quartz sand mine tailing 23, wilkinite 4, pearlstone 7, polyvinyl alcohol 3, aluminum phosphate 4, rock wool fibers 6, silicon powder 3, polyoxyethylenated alcohol sodium sulfate 1, lauryl methacrylate(LMA) 13, Silane coupling agent KH550 1.3, ethanol 26, distilled water 35, preparation method is that lauryl methacrylate(LMA) is added in ethanol and fully dissolves by (1), add quartz sand mine tailing again, wilkinite, pearlstone and silicon powder carry out pre-dispersed in 0.3-0.6 hour to stir under 400-600 rev/min, add Silane coupling agent KH550 again to stir and to be added in sand mill that to carry out grinding to form slurry for subsequent use after 15-25 minute, (2) by nano ceramic fibers, rock wool fibers, polyoxyethylenated alcohol sodium sulfate and distilled water mix and blend, high speed shear pulp body, (3) step (1) product is mixed with step (2) product, add all the other remaining components, stir 2-3 hour with the speed of 300-500 rev/min and get final product.
The Water-based thermal insulation coating that a kind of wear-resisting weather-proof of the present invention is good, be made up of following concrete steps:
(1) under the rotating speed of 1000-2000 rev/min, disperse 20-30 minute to obtain the material of fineness at 20-30um deionized water, ceramic microsphere, cruel sour aluminum fiber, pearlstone, then add heat-insulating slurry continuation stirring 20-30 minute;
(2) water-soluble epoxy resin, elastic caoutchouc powder, water-based fluorocarbon resin, pure acrylic acid Resin emulsion, polyvinylmethyl ethers, dipropylene are added to mixing and stirring in Scattered Kettle and are heated to 40-60 ° of C, then the slurry added in carboxymethyl cellulose and step (1) is to continue under the rotating speed of 300-500 rev/min to stir 30-50 minute;
(3) in the reaction system of step (2), add all the other surplus materialss, be added to grinding distribution in sand mill after stirring even, filter and package.
Coating appearance of the present invention is normal, without precipitation, without caking, water tolerance experiment (160H): without exception, alkaline resistance test (72H): without exception, abrasion resistance is tested: pass through for 10000 times, film is without breakage, and artificial ageing resistance is tested: 2000 hours non-foaming, do not peel off, flawless, chalk rating≤1 grade, variable color grade≤1 grade, contamination resistance experiment (5 circulations)≤30%, heat insulation temperature difference experiment >=8 ° of C, wear resistance experiment (750g/500 turns, mg): 14.2.
Claims (2)
1. the Water-based thermal insulation coating that wear-resisting weather-proof is good, it is characterized in that, be made up of the raw material of following weight part: water-soluble epoxy resin 28-35, elastic caoutchouc powder 4-6, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 1-2, water-based fluorocarbon resin 31-35, ceramic microsphere 2-3, cruel sour aluminum fiber 2-3, pearlstone 1-3, biocide mildewcide 1-2, pure acrylic acid Resin emulsion 10-14, carboxymethyl cellulose 1-2, dimethyl silicone oil 0.2-0.4, Siloxane-Oxyalkylene Copolymers 0.3-0.5, polyvinylmethyl ethers 0.5-0.8, cetyl trimethylammonium bromide 1-3, dipropylene 2-4, heat-insulating slurry 7-9, deionized water 14-18,
Described heat-insulating slurry is made up of the raw material of following weight part: nano ceramic fibers 5-7, aluminous cement 20-25, quartz sand mine tailing 20-25, wilkinite 3-5, pearlstone 6-8, polyvinyl alcohol 2-3, aluminum phosphate 4-5, rock wool fibers 5-7, silicon powder 2-4, polyoxyethylenated alcohol sodium sulfate 1-2, lauryl methacrylate(LMA) 12-15, Silane coupling agent KH550 1-2, ethanol 20-30, distilled water 30-40, preparation method is that lauryl methacrylate(LMA) is added in ethanol and fully dissolves by (1), add quartz sand mine tailing again, wilkinite, pearlstone and silicon powder carry out pre-dispersed in 0.3-0.6 hour to stir under 400-600 rev/min, add Silane coupling agent KH550 again to stir and to be added in sand mill that to carry out grinding to form slurry for subsequent use after 15-25 minute, (2) by nano ceramic fibers, rock wool fibers, polyoxyethylenated alcohol sodium sulfate and distilled water mix and blend, high speed shear pulp body, (3) step (1) product is mixed with step (2) product, add all the other remaining components, stir 2-3 hour with the speed of 300-500 rev/min and get final product.
2. the Water-based thermal insulation coating that a kind of wear-resisting weather-proof is good according to claim 1, is characterized in that, is made up of following concrete steps:
(1) under the rotating speed of 1000-2000 rev/min, disperse 20-30 minute to obtain the material of fineness at 20-30um deionized water, ceramic microsphere, cruel sour aluminum fiber, pearlstone, then add heat-insulating slurry continuation stirring 20-30 minute;
(2) water-soluble epoxy resin, elastic caoutchouc powder, water-based fluorocarbon resin, pure acrylic acid Resin emulsion, polyvinylmethyl ethers, dipropylene are added to mixing and stirring in Scattered Kettle and are heated to 40-60 ° of C, then the slurry added in carboxymethyl cellulose and step (1) is to continue under the rotating speed of 300-500 rev/min to stir 30-50 minute;
(3) in the reaction system of step (2), add all the other surplus materialss, be added to grinding distribution in sand mill after stirring even, filter and package.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410590776.3A CN104277671A (en) | 2014-10-29 | 2014-10-29 | Water-based thermal insulating coating with good wear resistance weather resistance and preparation method of water-based thermal insulating coating |
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| CN201410590776.3A CN104277671A (en) | 2014-10-29 | 2014-10-29 | Water-based thermal insulating coating with good wear resistance weather resistance and preparation method of water-based thermal insulating coating |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106189709A (en) * | 2016-08-14 | 2016-12-07 | 安庆市沁之源电器有限公司 | A kind of electric fan antioxidant coating and preparation method thereof |
| CN112552782A (en) * | 2020-11-30 | 2021-03-26 | 长沙理工大学 | Multi-dimensional composite hydrophobic coating and preparation method thereof |
| CN112680064A (en) * | 2020-12-24 | 2021-04-20 | 浩力森涂料（上海）有限公司 | Hollow microsphere fluorocarbon emulsion modified waterborne epoxy resin coating and preparation method thereof |
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2014
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Patent Citations (5)
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| CN101293244A (en) * | 2008-05-27 | 2008-10-29 | 王树成 | Method for preparing acid-fast alkali-proof composite organic protective film on steel surface |
| CN101543814A (en) * | 2009-04-21 | 2009-09-30 | 黑龙江科技学院 | Method for preparing composite organic protective film on surface of steel |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106189709A (en) * | 2016-08-14 | 2016-12-07 | 安庆市沁之源电器有限公司 | A kind of electric fan antioxidant coating and preparation method thereof |
| CN112552782A (en) * | 2020-11-30 | 2021-03-26 | 长沙理工大学 | Multi-dimensional composite hydrophobic coating and preparation method thereof |
| CN112680064A (en) * | 2020-12-24 | 2021-04-20 | 浩力森涂料（上海）有限公司 | Hollow microsphere fluorocarbon emulsion modified waterborne epoxy resin coating and preparation method thereof |
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Application publication date: 20150114 |