CN111303745A - Woodenware paint and preparation method thereof - Google Patents
Woodenware paint and preparation method thereof Download PDFInfo
- Publication number
- CN111303745A CN111303745A CN202010204174.5A CN202010204174A CN111303745A CN 111303745 A CN111303745 A CN 111303745A CN 202010204174 A CN202010204174 A CN 202010204174A CN 111303745 A CN111303745 A CN 111303745A
- Authority
- CN
- China
- Prior art keywords
- parts
- paint
- chitosan
- mixture
- acrylate copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a woodenware paint and a preparation method thereof, and relates to the technical field of paints. The technical key points are as follows: the wood paint comprises the following components in parts by weight: polyurethane: 50-60 parts; acrylic resin: 30-40 parts; linseed alkyd resin: 15-20 parts of a solvent; acrylate copolymer emulsion: 10-15 parts; and (3) chitosan: 5-10 parts; kaolin: 1-3 parts; diatomite: 0.5-1 part; activated carbon: 3-5 parts; talc powder: 1-3 parts; emulsifier: 0.5-2 parts; defoaming agent: 0.5-1 part; film-forming auxiliary agent: 0.5-2 parts; grinding aid: 1-5 parts; thickening agent: 0.1-0.5 part, and the paint prepared by adopting the formula has the advantages of good durability and good continuous sterilization performance.
Description
Technical Field
The invention relates to the technical field of paint, in particular to woodware paint and a preparation method thereof.
Background
Paints are very widely used in our lives: such as furniture, props, buildings, home decorations, handicrafts, etc., are painted. The novel decorative material has the protection and decoration functions of bright color, exquisite hand feeling, fashion, beauty and the like, and also has the special functions of firmness, durability, moisture resistance, high temperature resistance, corrosion resistance and the like.
The Chinese patent with the publication number of CN100387666C discloses a nano-silver antibacterial water-based wood lacquer and a preparation method thereof, wherein the nano-silver antibacterial water-based wood lacquer comprises water-based resin, a delustering agent, a wetting agent, a flatting agent, a defoaming agent, a thickening agent, a hand feeling agent, a film forming auxiliary agent, water and a nano-silver antibacterial agent. Although the water-based wood paint can achieve the effects of sterilization and insect prevention, silver ions have thermodynamic instability, and silver oxide is reduced into black simple substance silver through ultraviolet catalysis, so that the antibacterial property of the paint is reduced due to color change, and the attractiveness of the paint is influenced.
Therefore, a new solution is needed to solve the above problems.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide the woodware paint which has the advantage of good continuous sterilization effect.
The second purpose of the invention is to provide a preparation method of the woodware paint, which has the advantages of simple operation and suitability for large-scale production and use.
In order to achieve the first purpose, the invention provides the following technical scheme:
the wood paint comprises the following components in parts by weight:
polyurethane: 50-60 parts;
acrylic resin: 30-40 parts;
linseed alkyd resin: 15-20 parts of a solvent;
acrylate copolymer emulsion: 10-15 parts;
and (3) chitosan: 5-10 parts;
kaolin: 1-3 parts;
diatomite: 0.5-1 part;
activated carbon: 3-5 parts;
talc powder: 1-3 parts;
emulsifier: 0.5-2 parts;
defoaming agent: 0.5-1 part;
film-forming auxiliary agent: 0.5-2 parts;
grinding aid: 1-5 parts;
thickening agent: 0.1 to 0.5 portion.
By adopting the technical scheme, the woodware paint generally adopts a mode of adding the silver ion antibacterial agent to achieve the antibacterial purpose, but silver ions are easily reduced into simple substance silver in the using process, so that the antibacterial performance is reduced, and the appearance is changed from black silver oxide to white simple substance silver. According to the invention, a certain amount of acrylate copolymer emulsion is added into the formula, methacryloyloxyethyl trimethyl ammonium chloride is taken as a functional monomer and is copolymerized with methyl methacrylate, butyl acrylate and acrylic acid to obtain the acrylate copolymer emulsion, the methacryloyloxyethyl trimethyl ammonium chloride has extremely high bactericidal property, the acrylate copolymer emulsion obtained by grafting the methacrylate copolymer emulsion has excellent continuous antibacterial property, and the acrylate copolymer emulsion also has good mechanical property and thermal stability. Chitosan is a natural biological high molecular polymer and is the only natural polymer with positrons in the known natural joe at present, cations in the chitosan can be combined with anions dissociated from bacterial cell walls and adsorbed on the surfaces of the cell walls to form a protective layer to prevent the supply of bacterial nutrients, meanwhile, the introduction of the cations can destroy the charge balance on the surfaces of cells to cause the rupture of cell membranes and influence the propagation and movement of the cells, and meanwhile, the chitosan can also enter the interior to disturb the normal physiological activity of the cells to block the transformation process of genetic factors from DNA to RNA, so that the bacteria cannot be propagated, and the aim of disinfection and sterilization is finally achieved, and the sterilization rate can reach more than 99%. By adding the chitosan, the defect that the acrylate copolymer emulsion has poor bactericidal effect in the early stage can be overcome, and the chitosan and the acrylate copolymer emulsion can be used together to ensure that the woodware paint has higher bactericidal rate and better antibacterial property in the early, middle and later stages, and the coating cannot be influenced at all.
Polyurethane and acrylic resin are main film-forming agents, linseed oil alkyd resin is alkyd resin prepared from polybasic acid and linseed oil, the invention adopts the thousand nature oleic acid resin to be added into the formula, and the prepared paint film has higher hardness, better gloss and gloss retention; the kaolin has good dispersity and viscosity, can improve the adsorbability of paint, and the diatomite and the activated carbon can exert better adsorbability by compounding and using the diatomite and the activated carbon, and can adsorb pungent odor and harmful substances such as toluene, so that the peculiar smell of a paint film is reduced, and the addition of the talcum powder can improve the surface smoothness of the paint film and endow the paint film with good leveling property and hand feeling.
The film-forming assistant can enable the emulsion or the dispersed particles to form a uniform and compact film after water is volatilized, and can improve the film-forming property under the low-temperature condition; the grinding aid can improve the smoothness of the surface of the woodware, and avoid the temperature rise during mechanical polishing to cause the softening of a coating film and stand on sand paper or paste the sand wheel; the thickening agent can increase the viscosity of the paint liquid and improve the thickness of a wet film of one-time coating.
More preferably, the solid content of the acrylate copolymer emulsion is 33-36%.
By adopting the technical scheme, when the solid content of the emulsion is 33-36%, the emulsion has the optimal storage stability and the best antibacterial effect.
More preferably, the emulsifier is one or more of castor oil polyoxyethylene ether, polyglycerol fatty acid ester and lauryl glucoside.
By adopting the technical scheme, the emulsifier is added, so that the dispersing effect on other various fillers can be achieved, and the fillers and other components are better dispersed in the system.
More preferably, the defoaming agent is polydimethylsiloxane.
By adopting the technical scheme, the polydimethylsiloxane is a hydrophobic organic silicon material, is green and environment-friendly, has no toxicity, low viscosity, good volatility and better defoaming effect, can inhibit bubbles generated in the wood paint in the production process, enables the generated bubbles to escape from the liquid level and break the bubbles, and ensures that the wood paint can be uniformly coated on a wood substrate when in use.
More preferably, the film-forming assistant adopts dipropylene glycol butyl ether and/or diethylene glycol butyl ether; the grinding aid adopts zinc stearate grinding aid; the thickening agent is a polyurethane thickening agent.
By adopting the technical scheme, the dipropylene glycol butyl ether and the diethylene glycol butyl ether have the advantages of high boiling point, excellent environmental protection performance, good miscibility, low volatility, easy absorption by latex particles, excellent continuous coating absorption, good solubility to grease in wood, and greatly improved wettability to wood, thereby improving the transparency and adhesive force of the wood paint; the zinc stearate grinding aid is formed into slurry by dispersing zinc stearate and water, can be the same as wood paint and can be well dispersed in the wood paint, and the effect of the grinding aid can be improved; the polyurethane thickener can improve stable viscosity, is not influenced by pH, and has excellent fluidity and glossiness.
In order to achieve the second purpose, the invention provides the following technical scheme:
the preparation method of the woodware paint is characterized by comprising the following steps:
s1, uniformly mixing kaolin, diatomite, activated carbon, talcum powder and grinding aid, putting into a grinding machine, and grinding for 1.5-2h at the rotating speed of 150-;
s2, mixing polyurethane, acrylic resin, linseed oil alkyd resin and acrylate copolymer emulsion, controlling the temperature to be 35-55 ℃, and stirring for 15-30min at the rotating speed of 1000-1200r/min to obtain a mixture B;
s3, adding an emulsifier, a film-forming aid and a thickener into the mixture A, controlling the temperature to be 25-35 ℃, and stirring for 10-15min at the rotating speed of 200-300r/min to obtain a mixture C;
s4, mixing the mixture A, the mixture C, the defoaming agent and the chitosan solution prepared from chitosan, heating to 55-70 ℃, and stirring at the rotating speed of 100-150r/min for 10-15min to obtain the wood paint.
By adopting the technical scheme, the woodware paint prepared by the preparation method has better mechanical property and better continuous antibacterial property, and the preparation method does not relate to more complicated method conditions, is simple to operate and is suitable for large-scale production and use.
More preferably, the chitosan solution is obtained by dissolving chitosan in an acetic acid solution with the mass fraction of 1%.
By adopting the technical scheme, the chitosan is prepared into the chitosan solution, and the chitosan solution can be better dispersed in a paint system so as to fully exert the antibacterial performance of the paint system.
In summary, compared with the prior art, the invention has the following beneficial effects:
(1) according to the invention, the acrylate copolymer emulsion is added into a formula system, and is obtained by copolymerization grafting with methacryloyloxyethyl trimethyl ammonium chloride with bactericidal property as a monomer, the obtained paint has a continuous bactericidal effect, and chitosan is compounded, so that the defect of poor bactericidal effect in the early and middle stages of the paint can be overcome by the chitosan, and the acrylate copolymer emulsion and the chitosan can be used together, so that the woodware paint can be ensured to have higher bactericidal rate and better antibacterial property in the early, middle and later stages, and the coating cannot be influenced;
(2) according to the invention, kaolin, diatomite and active carbon are added into the formula system, and the bactericide is combined, so that the waste generated by microorganisms in the paint can be adsorbed, the pungent smell of the paint and the peculiar smell brought by the microorganisms are reduced, and the paint also has certain adsorbability on harmful substances such as toluene, thereby reducing the peculiar smell of a paint film;
(3) the invention also provides a preparation method of the wood paint, the wood paint prepared by the preparation method has better mechanical property and better continuous antibacterial property, and the preparation method does not relate to more complicated method conditions, is simple to operate and is suitable for large-scale production and use.
Drawings
Fig. 1 is a flow chart of a preparation process of the wood paint in embodiment 1 of the present invention.
Detailed Description
The invention is described in detail below with reference to the figures and examples.
Example 1: the woodenware paint comprises the following components in parts by weight as shown in Table 1, and is prepared by the following steps:
s1, uniformly mixing kaolin, diatomite, activated carbon, talcum powder and grinding aid, putting into a grinding machine, and grinding for 2 hours at a rotating speed of 150r/min to obtain a mixture A;
s2, mixing polyurethane, acrylic resin, linseed oil alkyd resin and acrylate copolymer emulsion, controlling the temperature to be 35 ℃, and stirring for 30min at the rotating speed of 1000r/min to obtain a mixture B;
s3, adding an emulsifier, a film-forming aid and a thickener into the mixture A, controlling the temperature to be 25 ℃, and stirring for 10min at the rotating speed of 300r/min to obtain a mixture C;
and S4, mixing the mixture A, the mixture C, a defoaming agent and a chitosan solution prepared from chitosan, heating to 55 ℃, and stirring at the rotating speed of 100r/min for 15min to obtain the wood paint.
In this example, the solid content of the acrylate copolymer emulsion was 33%; the emulsifier adopts castor oil polyoxyethylene ether; the defoaming agent adopts polydimethylsiloxane; the film-forming assistant adopts dipropylene glycol butyl ether; the grinding aid adopts zinc stearate grinding aid with solid content of 42%; the thickener is PUR62 produced by German Mingling company; the chitosan solution is obtained by dissolving chitosan in 1% acetic acid solution by mass, and the weight ratio of chitosan to acetic acid is 1: 100.
Examples 2 to 6: the wood paint is different from the wood paint in the embodiment 1 in that the components and the corresponding parts by weight are shown in the table 1.
TABLE 1 Components and parts by weight of examples 1-6
Example 7: a woodenware paint is different from that in the embodiment 1 in that in the step S3, castor oil polyoxyethylene ether and polyglycerol fatty acid ester in a weight ratio of 1:1 are adopted as an emulsifier.
Example 8: a woodenware paint is different from that in the embodiment 1 in that in the step S3, castor oil polyoxyethylene ether, polyglycerol fatty acid ester and lauric glucoside are adopted as emulsifying agents in a weight ratio of 1:1: 0.6.
Example 9: a woodenware paint is different from that of the example 1 in that in the step S3, dipropylene glycol butyl ether and diethylene glycol butyl ether with the weight ratio of 1:0.6 are adopted as film forming aids.
Example 10: a woodware paint is different from that in the embodiment 1 in the process conditions, and comprises the following specific steps:
s1, uniformly mixing kaolin, diatomite, activated carbon, talcum powder and grinding aid, putting into a grinding machine, and grinding for 1.5 hours at a rotating speed of 200r/min to obtain a mixture A;
s2, mixing polyurethane, acrylic resin, linseed oil alkyd resin and acrylate copolymer emulsion, controlling the temperature to be 55 ℃, and stirring for 15min at the rotating speed of 1200r/min to obtain a mixture B;
s3, adding an emulsifier, a film-forming aid and a thickener into the mixture A, controlling the temperature to be 35 ℃, and stirring for 15min at the rotating speed of 200r/min to obtain a mixture C;
and S4, mixing the mixture A, the mixture C, a defoaming agent and a chitosan solution prepared from chitosan, heating to 75 ℃, and stirring at the rotating speed of 150r/min for 10min to obtain the wood paint.
Comparative example 1: the difference from example 1 is that no chitosan was added to the paint formulation system.
Comparative example 2: the difference from example 1 is that hydrogen peroxide is added to the formulation instead of chitosan.
Comparative example 3: the difference from example 1 is that no acrylate copolymer emulsion was added to the paint formulation system.
Comparative example 4: the difference from example 1 is that the chitosan and acrylate copolymer emulsion is not added to the formulation system.
Performance test antibacterial performance and antibacterial durability performance test
According to the detection of national standard GB/T1866-2008 'antibacterial coating (paint film) antibacterial property determination method and antibacterial effect', bacteria are quantitatively inoculated on a sample plate to be detected, the bacteria are uniformly contacted with the sample plate by a film pasting method, after a certain period of culture, the viable bacteria in the sample plate are detected, and the antibacterial rate of the sample plate is obtained. The antibacterial rate and the lasting antibacterial rate are obtained according to GB/T21866-2009, and the antibacterial rate of the paint is measured at 30 days and 60 days, and the results are shown in the following table 2.
As can be seen from the test data in table 2, in examples 1 to 10, the chitosan and acrylate copolymer emulsion used in combination has better antibacterial property and lasting antibacterial property, the early antibacterial rate reaches more than 99.2%, and the lasting antibacterial rate also reaches more than 98.3%; in example 1, since chitosan is not added, the acrylate copolymer emulsion cannot exert all antibacterial performance in the early stage, so that the early-stage antibacterial rate is slightly low, and the acrylate copolymer emulsion gradually exerts the antibacterial performance along with the prolonging of time; comparative example 2 adopts hydrogen peroxide to replace chitosan, although hydrogen peroxide has stronger oxidizability, the antibacterial performance of the compound of the hydrogen peroxide and the acrylate copolymer emulsion is still inferior to the antibacterial performance of the compound of the chitosan and the acrylate copolymer emulsion; in comparative example 3, since the acrylate copolymer emulsion is not added, although the paint still has a certain antibacterial rate in the early stage, the antibacterial performance is gradually reduced with the time, and the lasting antibacterial performance is poor.
Table 2 results of performance testing
The above description is only a preferred embodiment of the present invention, and the protection scope of the present invention is not limited to the above embodiments, and all technical solutions belonging to the idea of the present invention belong to the protection scope of the present invention. It should be noted that modifications and embellishments within the scope of the invention may occur to those skilled in the art without departing from the principle of the invention, and are considered to be within the scope of the invention.
Claims (7)
1. The woodware paint is characterized by comprising the following components in parts by weight:
polyurethane: 50-60 parts;
acrylic resin: 30-40 parts;
linseed alkyd resin: 15-20 parts of a solvent;
acrylate copolymer emulsion: 10-15 parts;
and (3) chitosan: 5-10 parts;
kaolin: 1-3 parts;
diatomite: 0.5-1 part;
activated carbon: 3-5 parts;
talc powder: 1-3 parts;
emulsifier: 0.5-2 parts;
defoaming agent: 0.5-1 part;
film-forming auxiliary agent: 0.5-2 parts;
grinding aid: 1-5 parts;
thickening agent: 0.1 to 0.5 portion.
2. The wood paint of claim 1, wherein the acrylate copolymer emulsion has a solid content of 33-36%.
3. The wood paint according to claim 1, wherein the emulsifier is one or more selected from the group consisting of castor oil polyoxyethylene ether, polyglycerin fatty acid ester and lauryl glucoside.
4. The wood paint of claim 1, wherein the defoamer is polydimethylsiloxane.
5. The wood paint according to claim 1, wherein the film forming aid is dipropylene glycol butyl ether and/or diethylene glycol butyl ether; the grinding aid adopts zinc stearate grinding aid; the thickening agent is a polyurethane thickening agent.
6. The method for preparing the woodenware paint according to any one of claims 1 to 5, characterized by comprising the following steps:
s1, uniformly mixing kaolin, diatomite, activated carbon, talcum powder and grinding aid, putting into a grinding machine, and grinding for 1.5-2h at the rotating speed of 150-;
s2, mixing polyurethane, acrylic resin, linseed oil alkyd resin and acrylate copolymer emulsion, controlling the temperature to be 35-55 ℃, and stirring for 15-30min at the rotating speed of 1000-1200r/min to obtain a mixture B;
s3, adding an emulsifier, a film-forming aid and a thickener into the mixture A, controlling the temperature to be 25-35 ℃, and stirring for 10-15min at the rotating speed of 200-300r/min to obtain a mixture C;
s4, mixing the mixture A, the mixture C, the defoaming agent and the chitosan solution prepared from chitosan, heating to 55-70 ℃, and stirring at the rotating speed of 100-150r/min for 10-15min to obtain the wood paint.
7. The method for preparing the wood paint according to claim 6, wherein the chitosan solution is obtained by dissolving chitosan in an acetic acid solution with a mass fraction of 1%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010204174.5A CN111303745A (en) | 2020-03-21 | 2020-03-21 | Woodenware paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010204174.5A CN111303745A (en) | 2020-03-21 | 2020-03-21 | Woodenware paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111303745A true CN111303745A (en) | 2020-06-19 |
Family
ID=71153506
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010204174.5A Pending CN111303745A (en) | 2020-03-21 | 2020-03-21 | Woodenware paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111303745A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112876963A (en) * | 2021-01-15 | 2021-06-01 | 湖州和悦新材料科技股份有限公司 | Water-based spray coating floor paint and preparation method thereof |
| CN113072848A (en) * | 2021-03-26 | 2021-07-06 | 台州市万胜涂料有限公司 | Water-based woodware anti-expansion bar seal primer and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101760113A (en) * | 2009-11-30 | 2010-06-30 | 北方涂料工业研究设计院 | Method for preparing long-lasting anti-static and anti-corrosive paint without solvent |
| CN103992429A (en) * | 2014-05-17 | 2014-08-20 | 北京化工大学 | Cationic copolymer emulsion for waterborne wood coating and preparation method thereof |
| CN105567030A (en) * | 2015-12-26 | 2016-05-11 | 北京金之桥科技发展有限公司 | Waterborne carpentry paint |
| CN105647362A (en) * | 2016-04-12 | 2016-06-08 | 湖州新奥克化工有限公司 | High-durability high-efficiency nano antimicrobial water-based wood paint and preparation method thereof |
| CN106609074A (en) * | 2015-10-24 | 2017-05-03 | 洪其祥 | Multifunctional waterborne wood diatom ooze paint |
| CN107689200A (en) * | 2017-08-31 | 2018-02-13 | 苏州龙行洲实业有限公司 | A kind of Portable, environmental protective antibacterial Display Rack |
-
2020
- 2020-03-21 CN CN202010204174.5A patent/CN111303745A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101760113A (en) * | 2009-11-30 | 2010-06-30 | 北方涂料工业研究设计院 | Method for preparing long-lasting anti-static and anti-corrosive paint without solvent |
| CN103992429A (en) * | 2014-05-17 | 2014-08-20 | 北京化工大学 | Cationic copolymer emulsion for waterborne wood coating and preparation method thereof |
| CN106609074A (en) * | 2015-10-24 | 2017-05-03 | 洪其祥 | Multifunctional waterborne wood diatom ooze paint |
| CN105567030A (en) * | 2015-12-26 | 2016-05-11 | 北京金之桥科技发展有限公司 | Waterborne carpentry paint |
| CN105647362A (en) * | 2016-04-12 | 2016-06-08 | 湖州新奥克化工有限公司 | High-durability high-efficiency nano antimicrobial water-based wood paint and preparation method thereof |
| CN107689200A (en) * | 2017-08-31 | 2018-02-13 | 苏州龙行洲实业有限公司 | A kind of Portable, environmental protective antibacterial Display Rack |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112876963A (en) * | 2021-01-15 | 2021-06-01 | 湖州和悦新材料科技股份有限公司 | Water-based spray coating floor paint and preparation method thereof |
| CN113072848A (en) * | 2021-03-26 | 2021-07-06 | 台州市万胜涂料有限公司 | Water-based woodware anti-expansion bar seal primer and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103897571B (en) | A kind of aqueous double-component woodenware lacquer and uses thereof | |
| CN112063249A (en) | Artistic paint and preparation method thereof | |
| CN111303745A (en) | Woodenware paint and preparation method thereof | |
| CN101812156B (en) | Water-base ambient crosslinking acrylate wood paint resin and preparation method thereof | |
| CN103468066A (en) | Antimicrobial and mildewproof paint and preparation method thereof | |
| CN101717603A (en) | Aqueous dull finishing coat, preparation method and use method thereof | |
| CN105017906B (en) | A kind of colorful sealing wax of water-water and preparation method thereof | |
| CN106147453B (en) | Clear priming paint of a kind of anti-tannic acid of aqueous one-component and preparation method thereof | |
| CN111285959A (en) | Acrylate emulsion with high water-white resistance and preparation method thereof | |
| CN105440925A (en) | Waterborne woodware surface color modifier | |
| CN110713760A (en) | Water-based acrylic floor paint and preparation method thereof | |
| CN106543877A (en) | The modified polyurethane woodwork coating of water polyacrylic acid containing organosilicon and its preparation method and application | |
| CN110256883A (en) | A kind of aqueous UV woodware high-gloss clear finish and preparation method and implementing process | |
| CN112280417A (en) | Water-based wood paint | |
| CN107793844A (en) | A kind of water-based organic pigment mill base and preparation method thereof | |
| US3894976A (en) | Pseudoplastic water base paint containing a novel heteropolysaccharide | |
| CN111548715A (en) | Preparation method and application of high-light-transmission anti-yellowing plastic coating | |
| CN106752540A (en) | A kind of high rigidity, wear-resistant aqueous woodware paint and preparation method thereof | |
| CN113969087A (en) | Nano negative ion interior wall latex paint and preparation method thereof | |
| CN114195930A (en) | Modified potassium silicate styrene-acrylic emulsion and preparation method thereof, and preservative-free and solvent-free aqueous polymer material and preparation method thereof | |
| CN106700886A (en) | Polyurethane internal wall building mildew-proof paint | |
| CN109370353B (en) | Environment-friendly fluorine modified styrene-acrylic emulsion coating used in winter and preparation method thereof | |
| CN108276838A (en) | A kind of colorful ordor removing environmental protection coating material and preparation method thereof | |
| CN111100506A (en) | Mildew-proof environment-friendly water-based color paste suitable for color mixing of automatic color mixer and preparation method thereof | |
| CN107400424A (en) | A kind of environmental protection coating material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200619 |