CN111297701A - Foam skin cleaning towel and its making process - Google Patents

Foam skin cleaning towel and its making process Download PDF

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Publication number
CN111297701A
CN111297701A CN202010174778.XA CN202010174778A CN111297701A CN 111297701 A CN111297701 A CN 111297701A CN 202010174778 A CN202010174778 A CN 202010174778A CN 111297701 A CN111297701 A CN 111297701A
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China
Prior art keywords
ammonium
aqueous solution
foam skin
face
towel
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CN202010174778.XA
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Chinese (zh)
Inventor
乔丽丽
邹亮忠
徐智轩
董兆庆
韩春玲
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Shanghai Shuimo Baby Products Co Ltd
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Shanghai Shuimo Baby Products Co Ltd
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Priority to CN202010174778.XA priority Critical patent/CN111297701A/en
Publication of CN111297701A publication Critical patent/CN111297701A/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0208Tissues; Wipes; Patches
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005Antimicrobial preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/596Mixtures of surface active compounds

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention relates to a foam skin cleaning towel and a manufacturing process thereof, belonging to the technical field of skin care products. The foam skin cleaning towel is non-woven fabric loaded with a face cleaning agent, and the face cleaning agent comprises the following components in percentage by weight: 5-15% of lauryl alcohol ether ammonium sulfate aqueous solution, 1-10% of lauryl ammonium sulfate aqueous solution, 0.1-5% of cationic ammonium salt, 0.1-5% of carbomer, 1-10% of pearly luster sheet, 0.05-1% of pH regulator, 0.01-0.8% of preservative, 0.001-0.3% of essential oil, 1-10% of cocamidopropyl betaine and the balance of water. The foam skin cleaning towel foam face cleaning wet tissue is convenient to carry and use, good in face cleaning effect, small in skin irritation, free of complex water washing process, and capable of achieving face washing, face cleaning and drying in one step only by wiping.

Description

Foam skin cleaning towel and its making process
Technical Field
The invention belongs to the technical field of skin care products, and particularly relates to a foam skin cleaning towel and a manufacturing process thereof.
Background
The skin cleaning product is used for cleaning skin dirt, dissolving sweat, oil-soluble cosmetics and the like remained on the surface of the skin by a surfactant and the like, and carrying away oily components and residues by aqueous components. Currently, skin cleaning is generally carried out by firstly cleaning with water, and then further cleaning with a facial cleanser, wherein the facial cleanser can clean the face and then wash off the facial cleanser with water.
When the skin is cleaned, water is needed for cleaning, but in some occasions, the water is inconvenient to wash. The invention patent with application publication number CN106806168A discloses a no-clean facial wipe, which is a non-woven fabric soaked with a no-clean facial cleanser, and the no-clean facial cleanser comprises the following components of 10-18% of sodium dodecyl sulfate, 12-16% of cetyl alcohol, 10-15% of glycerin, 6-10% of stearyl alcohol, 0.8-1.2% of vitamin E, 1-3% of pH buffering agent, 0.6-0.8% of defoaming agent and the balance of deionized water. The no-clean facial cleaning wet tissue is soaked in the no-clean facial cleaning agent, wherein sodium dodecyl sulfate, stearyl alcohol and the like in the no-clean facial cleaning agent have certain irritation to skin, and the no-clean facial cleaning wet tissue obtained by soaking also has certain irritation to skin.
Disclosure of Invention
The first purpose of the invention is to provide a foam skin cleaning towel which has better skin cleaning effect and less irritation to the skin.
The second purpose of the invention is to provide a manufacturing process of the foam skin cleaning towel.
In order to achieve the above purpose, the invention adopts the technical scheme that: the foam skin cleaning towel is a non-woven fabric loaded with a face cleaning agent, and the face cleaning agent comprises the following components in percentage by weight: 5-15% of lauryl alcohol ether ammonium sulfate aqueous solution, 1-10% of lauryl ammonium sulfate aqueous solution, 0.1-5% of cationic ammonium salt, 0.1-5% of carbomer, 1-10% of pearly luster sheet, 0.05-1% of pH regulator, 0.01-0.8% of preservative, 0.001-0.3% of essential oil, 1-10% of cocamidopropyl betaine and the balance of water.
Further, the cationic polyammonium salt is a dimethyl diallyl ammonium chloride-acrylamide copolymer.
Further, the pH regulator is citric acid.
Further, the preservative is nipagin ester or isothiazolinone.
Further, the mass fraction of the ammonium lauryl alcohol ether sulfate in the aqueous solution of the ammonium lauryl alcohol ether sulfate is 70%.
Further, the mass fraction of ammonium lauryl sulfate in the ammonium lauryl sulfate aqueous solution is 70%.
The preparation method of the foam skin cleaning towel comprises the following steps:
1) mixing the lauryl alcohol ether ammonium sulfate aqueous solution, the lauryl ammonium sulfate aqueous solution, the cationic ammonium salt, carbomer, the pearly luster sheet, the pH regulator, the preservative, the essential oil, the cocamidopropyl betaine and water according to the formula ratio to prepare the face cleaning agent;
2) the non-woven fabric is arranged in the cleanser for soaking or the cleanser is atomized and sprayed on the non-woven fabric.
Further, before the non-woven fabric is soaked in the face cleaning agent or the face cleaning agent is atomized and sprayed on the non-woven fabric, the non-woven fabric is cut into square blocks of 20 x 20 cm.
Further, the non-woven fabric is soaked in the cleanser for 1-2 h.
Further, the face cleaning agent is atomized and sprayed on the non-woven fabric, and then dried by using a drying oven at the temperature of 50-70 ℃ for 0.1-10 min.
The invention has the beneficial effects that:
the foam face cleaning wet tissue contains the dodecyl alcohol ether ammonium sulfate foam which is rich and fine, has strong detergency and good biodegradability, has good hard water resistance, moderate degreasing force, mild performance and better face cleaning effect. Ammonium lauryl sulfate is a low-irritation anionic surfactant and has excellent detergency. The cationic surfactant has effects of eliminating static electricity and conditioning skin. Carbomer is a stable emulsifier, and can be used as auxiliary for cleaning face with ammonium lauryl sulfate and ammonium lauryl sulfate. The cocoamidopropyl betaine has excellent solubility and compatibility, good foaming and thickening effects, low irritation and bactericidal properties, good hard water resistance, antistatic property and biodegradability, and good compatibility with ammonium lauryl ether sulfate and ammonium lauryl sulfate. The foam face cleaning wet tissue is convenient to carry and use, good in face cleaning effect and small in irritation to skin, does not need a complex water washing process, and can be used for washing, cleaning and drying the face at one time only by wiping.
Drawings
FIG. 1(A) is an image of the skin before cleansing;
FIG. 1(B) is an image of the skin after being wiped with a foam skin cleansing pad;
FIG. 2(C) is a photograph of the skin after 15min after the foam skin cleaning towel is wiped;
FIG. 2(D) is a photograph of the skin after washing and exposure for 1 hour.
Detailed Description
The following will further describe the present invention in conjunction with examples.
Example 1
The foam skin-cleaning towel of the embodiment is a non-woven fabric loaded with a face-cleaning agent, and the face-cleaning agent comprises the following components in percentage by weight: 10% of lauryl alcohol ether ammonium sulfate aqueous solution, 5% of lauryl ammonium sulfate aqueous solution, 0.5% of dimethyl diallyl ammonium chloride-acrylamide copolymer, 0.6% of carbomer, 4% of pearlescent piece, 0.8% of citric acid, 0.5% of octyl paraben, 0.5% of essential oil, 5% of cocamidopropyl betaine and the balance of water. The mass fraction of the ammonium lauryl alcohol ether sulfate in the ammonium lauryl alcohol ether sulfate aqueous solution is 70 percent. The mass fraction of ammonium dodecyl sulfate in the ammonium dodecyl sulfate aqueous solution is 70%.
The manufacturing process of the foam skin cleaning towel comprises the following steps:
1) mixing the lauryl alcohol ether ammonium sulfate aqueous solution, the lauryl ammonium sulfate aqueous solution, the cationic ammonium salt, carbomer, the pearly luster sheet, the pH regulator, the preservative, the essential oil, the cocamidopropyl betaine and water according to the formula ratio to prepare the face cleaning agent;
2) the nonwoven fabric was cut into square pieces having a size of 20X 20 cm. And (3) soaking the cut non-woven fabric in a face cleaning agent for 1 hour to obtain the face cleaning agent.
Example 2
The foam skin-cleaning towel of the embodiment is a non-woven fabric loaded with a face-cleaning agent, and the face-cleaning agent comprises the following components in percentage by weight: 10% of ammonium lauryl alcohol ether sulfate aqueous solution, 5% of ammonium lauryl sulfate aqueous solution, 0.5% of dimethyl diallyl ammonium chloride-acrylamide copolymer, 0.6% of carbomer, 4% of pearlescent piece, 1% of citric acid, 0.8% of isothiazolinone, 0.2% of essential oil, 8% of cocamidopropyl betaine and the balance of water. The mass fraction of the ammonium lauryl alcohol ether sulfate in the ammonium lauryl alcohol ether sulfate aqueous solution is 70 percent. The mass fraction of ammonium dodecyl sulfate in the ammonium dodecyl sulfate aqueous solution is 70%.
The manufacturing process of the foam skin cleaning towel comprises the following steps:
1) mixing the lauryl alcohol ether ammonium sulfate aqueous solution, the lauryl ammonium sulfate aqueous solution, the cationic ammonium salt, carbomer, the pearly luster sheet, the pH regulator, the preservative, the essential oil, the cocamidopropyl betaine and water according to the formula ratio to prepare the face cleaning agent;
2) the nonwoven fabric was cut into square pieces having a size of 20X 20 cm. Atomizing the cleanser, spraying onto non-woven fabric, and drying in a drying oven at 50 deg.C for 10 min. The atomization process is pump pressurization atomization.
Example 3
The foam skin-cleaning towel of the embodiment is a non-woven fabric loaded with a face-cleaning agent, and the face-cleaning agent comprises the following components in percentage by weight: 5% of ammonium lauryl alcohol ether sulfate aqueous solution, 3% of ammonium lauryl sulfate aqueous solution, 0.1% of dimethyl diallyl ammonium chloride-acrylamide copolymer, 3% of carbomer, 1% of pearlescent sheet, 0.01% of citric acid, 0.01% of isothiazolinone, 0.3% of essential oil, 1% of cocamidopropyl betaine and the balance of water. The mass fraction of the ammonium lauryl alcohol ether sulfate in the ammonium lauryl alcohol ether sulfate aqueous solution is 70 percent. The mass fraction of ammonium dodecyl sulfate in the ammonium dodecyl sulfate aqueous solution is 70%.
The manufacturing process of the foam skin cleaning towel comprises the following steps:
1) mixing the lauryl alcohol ether ammonium sulfate aqueous solution, the lauryl ammonium sulfate aqueous solution, the cationic ammonium salt, carbomer, the pearly luster sheet, the pH regulator, the preservative, the essential oil, the cocamidopropyl betaine and water according to the formula ratio to prepare the face cleaning agent;
2) the nonwoven fabric was cut into square pieces having a size of 20X 20 cm. And (3) soaking the cut non-woven fabric in a face cleaning agent for 2 hours to obtain the face cleaning agent.
Example 4
The foam skin-cleaning towel of the embodiment is a non-woven fabric loaded with a face-cleaning agent, and the face-cleaning agent comprises the following components in percentage by weight: 8% of ammonium lauryl alcohol ether sulfate aqueous solution, 1% of ammonium lauryl sulfate aqueous solution, 5% of dimethyl diallyl ammonium chloride-acrylamide copolymer, 2% of carbomer, 5% of pearlescent flake, 0.5% of citric acid, 0.3% of isothiazolinone, 0.001% of essential oil, 3% of cocamidopropyl betaine and the balance of water. The mass fraction of the ammonium lauryl alcohol ether sulfate in the ammonium lauryl alcohol ether sulfate aqueous solution is 70 percent. The mass fraction of ammonium dodecyl sulfate in the ammonium dodecyl sulfate aqueous solution is 70%.
The manufacturing process of the foam skin cleaning towel comprises the following steps:
1) mixing the lauryl alcohol ether ammonium sulfate aqueous solution, the lauryl ammonium sulfate aqueous solution, the cationic ammonium salt, carbomer, the pearly luster sheet, the pH regulator, the preservative, the essential oil, the cocamidopropyl betaine and water according to the formula ratio to prepare the face cleaning agent;
2) the nonwoven fabric was cut into square pieces having a size of 20X 20 cm. Atomizing the cleanser, spraying onto non-woven fabric, and drying in a drying oven at 70 deg.C for 0.1 min. The atomization process is pump pressurization atomization.
Example 5
The foam skin-cleaning towel of the embodiment is a non-woven fabric loaded with a face-cleaning agent, and the face-cleaning agent comprises the following components in percentage by weight: 15% of ammonium lauryl alcohol ether sulfate aqueous solution, 8% of ammonium lauryl sulfate aqueous solution, 3% of dimethyl diallyl ammonium chloride-acrylamide copolymer, 0.1% of carbomer, 8% of pearlescent piece, 0.1% of citric acid, 0.2% of octyl paraben, 0.01% of essential oil, 10% of cocoamidopropyl betaine and the balance of water. The mass fraction of the ammonium lauryl alcohol ether sulfate in the ammonium lauryl alcohol ether sulfate aqueous solution is 70 percent. The mass fraction of ammonium dodecyl sulfate in the ammonium dodecyl sulfate aqueous solution is 70%.
The manufacturing process of the foam skin cleaning towel comprises the following steps:
1) mixing the lauryl alcohol ether ammonium sulfate aqueous solution, the lauryl ammonium sulfate aqueous solution, the cationic ammonium salt, carbomer, the pearly luster sheet, the pH regulator, the preservative, the essential oil, the cocamidopropyl betaine and water according to the formula ratio to prepare the face cleaning agent;
2) the nonwoven fabric was cut into square pieces having a size of 20X 20 cm. Atomizing the cleanser, spraying onto non-woven fabric, and drying in a drying oven at 60 deg.C for 5 min. The atomization process is pump pressurization atomization.
Example 6
The foam skin-cleaning towel of the embodiment is a non-woven fabric loaded with a face-cleaning agent, and the face-cleaning agent comprises the following components in percentage by weight: 9% of ammonium lauryl alcohol ether sulfate aqueous solution, 10% of ammonium lauryl sulfate aqueous solution, 1% of dimethyl diallyl ammonium chloride-acrylamide copolymer, 5% of carbomer, 10% of pearlescent flake, 0.8% of citric acid, 0.1% of octyl paraben, 0.015% of essential oil, 6% of cocamidopropyl betaine and the balance of water. The mass fraction of the ammonium lauryl alcohol ether sulfate in the ammonium lauryl alcohol ether sulfate aqueous solution is 70 percent. The mass fraction of ammonium dodecyl sulfate in the ammonium dodecyl sulfate aqueous solution is 70%.
The manufacturing process of the foam skin cleaning towel comprises the following steps:
1) mixing the lauryl alcohol ether ammonium sulfate aqueous solution, the lauryl ammonium sulfate aqueous solution, the cationic ammonium salt, carbomer, the pearly luster sheet, the pH regulator, the preservative, the essential oil, the cocamidopropyl betaine and water according to the formula ratio to prepare the face cleaning agent;
2) the nonwoven fabric was cut into square pieces having a size of 20X 20 cm. And (3) soaking the cut non-woven fabric in a face cleaning agent for 1 hour to obtain the face cleaning agent.
Test examples
1. Determination of soil-Release ability
The test method comprises the following steps:
(1) the skin is divided into regions of about 6cm area on face2. The skin image was recorded with a dermatoscope polarized light mode.
(2) The foam skin cleansing sheet of example 1 was gently wiped 3 times, folding the foam skin cleansing sheet once per wiping, then wiping the other side, and recording the skin image after cleaning in a skin mirror polarized light mode and comparing it with the skin image before cleaning, as shown in fig. 1(a) and 1 (B).
(3) After 15min, the skin was washed clean, exposed to room temperature air for 1h in a calm state, and the skin image at this time was recorded in a skin mirror polarized light mode and compared with the skin image before cleaning, as shown in fig. 2(C) and 2 (D).
As can be seen from fig. 1 and 2, the foam skin cleaning towel can rapidly remove various dirt on the surface of the skin. After being washed clean, the pH value of the skin can be kept normal, the skin barrier is less damaged, and the image of local flora is smaller. The skin is glossy and smooth after use and is not dry.
2. Degreasing, dispersing, foaming, tightening, easy-to-rinse test
The subjects consisted of 13, including 8 females and 5 males, aged between 20-40 years, all with intermediate dry skin.
The subjects were all tested using the products of examples 1-6. The subjects were scored for defatting, dispersibility, foamability, tautness, and ease of rinsing, with a full score of 5, and the results of the test were obtained by averaging the scores of 13 subjects, and are shown in table 1.
TABLE 1 results of tests on degreasing, dispersing, foaming, tightening, and easy-rinsing degrees of examples 1-6
Figure BDA0002410427670000051

Claims (10)

1. The foam skin cleaning towel is characterized by being non-woven fabric loaded with a face cleaning agent, wherein the face cleaning agent comprises the following components in percentage by weight: 5-15% of lauryl alcohol ether ammonium sulfate aqueous solution, 1-10% of lauryl ammonium sulfate aqueous solution, 0.1-5% of cationic ammonium salt, 0.1-5% of carbomer, 1-10% of pearly luster sheet, 0.05-1% of pH regulator, 0.01-0.8% of preservative, 0.001-0.3% of essential oil, 1-10% of cocamidopropyl betaine and the balance of water.
2. The foam skin cleansing towel of claim 1, wherein said cationic polyammonium salt is a dimethyl diallyl ammonium chloride-acrylamide copolymer.
3. The foam skin cleansing towel of claim 1, wherein said pH adjusting agent is citric acid.
4. The foam skin cleansing wipe of claim 1 wherein said preservative is a paraben or an isothiazolinone.
5. The foam skin cleansing towel of claim 1, wherein the mass fraction of ammonium lauryl alcohol ether sulfate in the aqueous solution of ammonium lauryl alcohol ether sulfate is 70%.
6. The foam skin cleansing wipe as set forth in claim 1 wherein the aqueous solution of ammonium lauryl sulfate has a mass fraction of ammonium lauryl sulfate of 70%.
7. A process for making a foam skin cleansing wipe as claimed in claim 1, comprising the steps of:
1) mixing the lauryl alcohol ether ammonium sulfate aqueous solution, the lauryl ammonium sulfate aqueous solution, the cationic ammonium salt, carbomer, the pearly luster sheet, the pH regulator, the preservative, the essential oil, the cocamidopropyl betaine and water according to the formula ratio to prepare the face cleaning agent;
2) the non-woven fabric is arranged in the cleanser for soaking or the cleanser is atomized and sprayed on the non-woven fabric.
8. The process for preparing a foam skin cleansing towel according to claim 7, wherein the non-woven fabric is cut into square pieces before being soaked in the cleansing agent or the cleansing agent is atomized and sprayed on the non-woven fabric.
9. The process of making a foam skin cleansing wipe according to claim 7 or 8 wherein said nonwoven fabric arrangement is soaked in a cleanser for a soaking time of 1 to 2 hours.
10. The process for preparing the foam skin-cleaning towel according to claim 1, wherein the face-cleaning agent is atomized and sprayed on the non-woven fabric and then dried by using a drying oven, wherein the drying temperature is 50-70 ℃, and the drying time is 0.1-10 min.
CN202010174778.XA 2020-03-13 2020-03-13 Foam skin cleaning towel and its making process Pending CN111297701A (en)

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WO2019066522A1 (en) * 2017-09-29 2019-04-04 주식회사 아모레퍼시픽 Cosmetic hair or scalp composition for increasing hair volume

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Application publication date: 20200619