CN111286981A - Environment-friendly textile finishing agent and preparation method and application thereof - Google Patents
Environment-friendly textile finishing agent and preparation method and application thereof Download PDFInfo
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/09—Cellulose ethers
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Abstract
The invention discloses an environment-friendly textile finishing agent, which comprises the following raw materials in parts by weight: 6-10 parts of propolis, 4-8 parts of chitosan, 5-10 parts of sodium carboxymethylcellulose, 5-8 parts of amino silicone oil, 1-4 parts of dandelion extract, 2-3 parts of honeysuckle extract, 1-3 parts of glycyrrhiza alcohol extract, 0.5-1 part of winter jasmine acetone extract, 1-3 parts of mint essential oil, 2-4 parts of catalyst, 8-12 parts of softener, 10-15 parts of ethanol and 80-120 parts of water; the invention also discloses a preparation method and application of the environment-friendly finishing agent. According to the invention, the natural plant extract is dissolved in the propolis and the chitosan, so that the activity of antibacterial components in the natural plant extract is effectively increased, and the antibacterial effect of the propolis is achieved, so that the prepared finishing agent has strong antibacterial property and crease resistance, and simultaneously has the effect of ultraviolet resistance, thereby protecting the skin.
Description
Technical Field
The invention belongs to the technical field of fabric finishing agents, and particularly relates to an environment-friendly finishing agent for textiles and a preparation method and application thereof.
Background
For a long time, human health is threatened by environmental pollution and bacterial infection; the research on the antibacterial agent in various countries in the world is more important, and the research on the antibacterial fabric finishing liquid (finishing agent) becomes a hot spot in the textile and printing and dyeing industries.
As is well known, the existing textile mainly comprises natural components such as cotton, real silk, fibrilia and the like, but the natural components such as the cotton, the real silk, the fibrilia and the like have poor antibacterial performance, and the breeding of bacteria can not only destroy the beauty and the practicability of the textile, but also seriously damage the human body and threaten the health of human beings, so that the antibacterial treatment of the textile is necessary; in recent years, since chlorofluorocarbons such as freon are emitted in large quantities in human production and living activities, the ozone layer is increasingly destroyed, and the damage of ultraviolet rays to the human body is becoming more serious. The fabric can shield a part of ultraviolet rays for human bodies, so that ultraviolet-proof treatment on the textiles is also necessary, and therefore, research on finishing agents with strong antibacterial property and ultraviolet-proof effect is one of the main problems overcome by research and development personnel at the present stage.
Disclosure of Invention
In view of the above, the invention mainly aims to provide an environment-friendly finishing agent for textiles, which solves the problems of poor antibacterial effect and poor ultraviolet-proof effect of the finishing agent prepared by the prior art; the invention also provides a preparation method and application of the environment-friendly antibacterial finishing agent.
In order to achieve the purpose, the technical scheme of the invention is realized as follows: an environment-friendly finishing agent for textiles comprises the following raw materials in parts by weight: 6-10 parts of propolis, 4-8 parts of chitosan, 5-10 parts of sodium carboxymethylcellulose, 5-8 parts of amino silicone oil, 1-4 parts of dandelion extract, 2-3 parts of honeysuckle extract, 1-3 parts of glycyrrhiza alcohol extract, 0.5-1 part of winter jasmine acetone extract, 1-3 parts of mint essential oil, 2-4 parts of catalyst, 8-12 parts of softener, 10-15 parts of ethanol and 80-120 parts of water.
Preferably, the finishing agent comprises the following raw materials in parts by weight: 8 parts of propolis, 6 parts of chitosan, 7 parts of sodium carboxymethylcellulose, 6.5 parts of amino silicone oil, 2 parts of dandelion extract, 2.5 parts of honeysuckle extract, 2 parts of liquorice alcohol extract, 0.8 part of winter jasmine acetone extract, 2 parts of mint essential oil, 3 parts of catalyst, 10 parts of softener, 12 parts of ethanol and 100 parts of water.
Preferably, the catalyst is a mixture of ammonium sulfate, magnesium chloride and tartaric acid, wherein the weight ratio of ammonium sulfate, magnesium chloride and tartaric acid is 1: (1-3): (0.5 to 1).
Preferably, the softener is an esterquat softener.
The other technical scheme of the invention is realized as follows: a preparation method of a textile environment-friendly finishing agent comprises the following steps:
step 1, respectively weighing the following components in parts by weight: 6-10 parts of propolis, 4-8 parts of chitosan, 5-10 parts of sodium carboxymethylcellulose, 5-8 parts of amino silicone oil, 1-4 parts of dandelion extract, 2-3 parts of honeysuckle extract, 1-3 parts of glycyrrhiza alcohol extract, 0.5-1 part of winter jasmine acetone extract, 1-3 parts of mint essential oil, 2-4 parts of catalyst, 8-12 parts of softener, 10-15 parts of ethanol and 80-120 parts of water;
step 2, dispersing the ethanol, the sodium carboxymethyl cellulose and the catalyst in the step 1 into water at the temperature of 30-40 ℃, and fully and uniformly mixing to obtain an initial mixed solution;
step 3, heating the initial mixed solution obtained in the step 2 to 50-60 ℃, sequentially adding the propolis, the chitosan, the amino silicone oil and the softening agent in the step 1, and continuously stirring for 60-120 min to obtain an intermediate mixed solution;
and 4, cooling the intermediate mixture obtained in the step 3 to 30-40 ℃, adding dandelion extract, honeysuckle extract, glycyrol extract, winter jasmine acetone extract and mint essential oil under the condition of continuous stirring, fully and uniformly mixing, and cooling to room temperature to obtain the environment-friendly textile finishing agent.
Preferably, in the step 1, the extraction method of the winter jasmine acetone extract solution comprises the following steps: drying winter jasmine at constant temperature, crushing into powder, adding 60-80 wt% of acetone solution, performing ultrasonic extraction, standing, and taking supernatant to obtain winter jasmine acetone extract; the extraction method of the liquorice alcohol extract comprises the following steps: drying liquorice at constant temperature, crushing into powder, adding 60-70 wt% ethanol solution, heating, extracting, standing, and taking supernatant to obtain the liquorice alcohol extract.
Preferably, when the acetone extracting solution of the winter jasmine is extracted, the leaching temperature is 40-50 ℃, the leaching time is 30-50 min, and the material ratio (g: ml) is 1 (15-25); when the licorice alcohol extract is extracted, the extraction temperature is 50-70 ℃, the extraction time is 30-150 min, and the material ratio (g: ml) is 1 (5-15).
According to another aspect of the invention, the invention provides a use of the textile environment-friendly finishing agent in the antibacterial finishing of textiles.
Preferably, the textile is immersed in the above-mentioned finishing agent, or the textile is immersed in the above-mentioned finishing agent after dilution, impregnated or padded, and then dried.
Preferably, the padding is one padding and one rolling, the rolling residual rate is 75-85%, and the drying temperature is 120-150 ℃.
Compared with the prior art, the propolis composition adopts propolis, chitosan and natural plant extract as raw materials, so that the propolis composition is in compliance with the concept of environmental protection, safe in components and small in harm to human bodies; in addition, the natural plant extract is dissolved in the propolis and the chitosan, so that the activity of antibacterial ingredients in the natural plant extract is effectively increased, and the antibacterial effect of the propolis is achieved, so that the prepared finishing agent has strong antibacterial property and crease resistance, and simultaneously has the effect of ultraviolet resistance, and the skin is protected.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail with reference to the following embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
The molecular weight of the chitosan used in the following examples is less than or equal to 5000.
The embodiment of the invention provides an environment-friendly textile finishing agent, which comprises the following raw materials in parts by weight: 6-10 parts of propolis, 4-8 parts of chitosan, 5-10 parts of sodium carboxymethylcellulose, 5-8 parts of amino silicone oil, 1-4 parts of dandelion extract, 2-3 parts of honeysuckle extract, 1-3 parts of glycyrrhiza alcohol extract, 0.5-1 part of winter jasmine acetone extract, 1-3 parts of mint essential oil, 2-4 parts of catalyst, 8-12 parts of softener, 10-15 parts of ethanol and 80-120 parts of water.
Further, the finishing agent comprises the following raw materials in parts by weight: 8 parts of propolis, 6 parts of chitosan, 7 parts of sodium carboxymethylcellulose, 6.5 parts of amino silicone oil, 2 parts of dandelion extract, 2.5 parts of honeysuckle extract, 2 parts of liquorice alcohol extract, 0.8 part of winter jasmine acetone extract, 2 parts of mint essential oil, 3 parts of catalyst, 10 parts of softener, 12 parts of ethanol and 100 parts of water.
Further, the catalyst is a mixture of ammonium sulfate, magnesium chloride and tartaric acid, wherein the weight ratio of the ammonium sulfate to the magnesium chloride to the tartaric acid is 1: (1-3): (0.5 to 1).
Further, the softening agent is an ester quaternary ammonium salt softening agent.
The embodiment of the invention also provides a preparation method of the environment-friendly textile finishing agent, which comprises the following steps:
step 1, respectively weighing the following components in parts by weight: 6-10 parts of propolis, 4-8 parts of chitosan, 5-10 parts of sodium carboxymethylcellulose, 5-8 parts of amino silicone oil, 1-4 parts of dandelion extract, 2-3 parts of honeysuckle extract, 1-3 parts of glycyrrhiza alcohol extract, 0.5-1 part of winter jasmine acetone extract, 1-3 parts of mint essential oil, 2-4 parts of catalyst, 8-12 parts of softener, 10-15 parts of ethanol and 80-120 parts of water;
step 2, dispersing the ethanol, the sodium carboxymethyl cellulose and the catalyst in the step 1 into water at the temperature of 30-40 ℃, and fully and uniformly mixing to obtain an initial mixed solution;
step 3, heating the initial mixed solution obtained in the step 2 to 50-60 ℃, sequentially adding the propolis, the chitosan, the amino silicone oil and the softening agent in the step 1, and continuously stirring for 60-120 min to obtain an intermediate mixed solution;
and 4, cooling the intermediate mixture obtained in the step 3 to 30-40 ℃, adding dandelion extract, honeysuckle extract, glycyrol extract, winter jasmine acetone extract and mint essential oil under the condition of continuous stirring, fully and uniformly mixing, and cooling to room temperature to obtain the environment-friendly textile finishing agent.
In addition, the acetone extract of winter jasmine used in this example was obtained by the following extraction method: drying winter jasmine at constant temperature, crushing into powder, adding 60-80 wt% of acetone solution, performing ultrasonic extraction, standing, and taking supernatant to obtain winter jasmine acetone extract; when the acetone extracting solution of the winter jasmine is extracted, the extracting temperature is 40-50 ℃, the extracting time is 30-50 min, and the material ratio (g: ml) is 1 (15-25).
The used glycyrrhiza alcohol extract is obtained by the following extraction method: drying liquorice at constant temperature, crushing the dried liquorice into powder, adding 60-70 wt% of ethanol solution, heating and extracting, standing and taking supernatant to obtain liquorice alcohol extract; wherein, when the liquorice alcohol extract is extracted, the extraction temperature is 50-70 ℃, the extraction time is 30-150 min, and the material ratio (g: ml) is 1 (5-15).
The embodiment of the invention also provides application of the environment-friendly antibacterial finishing agent in antibacterial finishing of textiles.
The concrete application is as follows: dipping a textile into the finishing agent, or dipping a textile into the diluted finishing agent according to any one of claims 1 to 4, dipping or padding, and then drying.
Further, padding is performed by one-time soaking and one-time rolling, the rolling residual rate is 75-85%, and the drying temperature is 120-150 ℃.
According to the invention, propolis, chitosan and natural plant extract are used as raw materials, so that the environment-friendly concept is conformed, the components are safe, and the harm to human bodies is small; in addition, the natural plant extract is dissolved in the propolis and the chitosan, so that the activity of antibacterial ingredients in the natural plant extract is effectively increased, and the antibacterial effect of the propolis is achieved, so that the prepared finishing agent has strong antibacterial property and crease resistance, and simultaneously has the effect of ultraviolet resistance, and the skin is protected.
Example 1
The environment-friendly finishing agent for the textiles provided by the embodiment comprises the following raw materials in parts by weight: 6 parts of propolis, 8 parts of chitosan, 5 parts of sodium carboxymethylcellulose, 8 parts of amino silicone oil, 1 part of dandelion extract, 3 parts of honeysuckle extract, 1 part of liquorice alcohol extract, 0.5 part of winter jasmine acetone extract and 1 part of mint essential oil, wherein the weight ratio of the components is 1: 2: 4 parts of catalyst consisting of 0.8 part of ammonium sulfate, magnesium chloride and tartaric acid, 8 parts of softening agent (preferably fatty acid triethanol quaternary ammonium sodium), 15 parts of ethanol and 80 parts of water;
the environment-friendly antibacterial finishing agent is prepared by the following method:
step 1, respectively weighing the following components in parts by weight: 6 parts of propolis, 8 parts of chitosan, 5 parts of sodium carboxymethylcellulose, 8 parts of amino silicone oil, 1 part of dandelion extract, 3 parts of honeysuckle extract, 1 part of liquorice alcohol extract, 1 part of winter jasmine acetone extract, 1 part of mint essential oil and a mixture of the components in parts by weight of 1: 1: 4 parts of catalyst consisting of 0.5 part of ammonium sulfate, magnesium chloride and tartaric acid, 8 parts of softening agent (preferably fatty acid triethanol quaternary ammonium sodium), 15 parts of ethanol and 80 parts of water for later use;
step 2, dispersing the ethanol, the sodium carboxymethyl cellulose and the catalyst in the step 1 into water at the temperature of 30 ℃, and fully and uniformly mixing to obtain an initial mixed solution;
step 3, heating the initial mixed solution obtained in the step 2 to 50 ℃, sequentially adding the propolis, the chitosan, the amino silicone oil and the softening agent obtained in the step 1, and continuously stirring for 90min to obtain an intermediate mixed solution;
and 4, cooling the intermediate mixture obtained in the step 3 to 30 ℃, adding dandelion extract, honeysuckle extract, glycyrol extract, winter jasmine acetone extract and mint essential oil under the condition of continuous stirring, fully and uniformly mixing, and cooling to room temperature to obtain the environment-friendly textile finishing agent.
Example 2
The environment-friendly finishing agent for textiles provided by the embodiment comprises the following raw materials in parts by weight: 8 parts of propolis, 6 parts of chitosan, 8 parts of sodium carboxymethylcellulose, 6 parts of amino silicone oil, 2 parts of dandelion extract, 1 part of honeysuckle extract, 2 parts of liquorice alcohol extract, 0.8 part of winter jasmine acetone extract and 2 parts of mint essential oil, wherein the weight ratio of the components is 1: 2: 0.8 of catalyst consisting of ammonium sulfate, magnesium chloride and tartaric acid, 10 parts of softening agent (preferably fatty acid triethanol quaternary ammonium sodium), 12 parts of ethanol and 100 parts of water.
The environment-friendly antibacterial finishing agent is prepared by the following method:
step 1, respectively weighing the following components in parts by weight: 8 parts of propolis, 6 parts of chitosan, 8 parts of sodium carboxymethylcellulose, 6 parts of amino silicone oil, 2 parts of dandelion extract, 1 part of honeysuckle extract, 2 parts of liquorice alcohol extract, 0.8 part of winter jasmine acetone extract and 2 parts of mint essential oil, wherein the weight ratio of the components is 1: 2: 0.8 part of catalyst consisting of ammonium sulfate, magnesium chloride and tartaric acid, 3 parts of softening agent (preferably fatty acid triethanol quaternary ammonium sodium), 12 parts of ethanol and 100 parts of water for later use;
step 2, dispersing the ethanol, the sodium carboxymethyl cellulose and the catalyst in the step 1 into water at the temperature of 30 ℃, and fully and uniformly mixing to obtain an initial mixed solution;
step 3, heating the initial mixed solution obtained in the step 2 to 50 ℃, sequentially adding the propolis, the chitosan, the amino silicone oil and the softening agent obtained in the step 1, and continuously stirring for 90min to obtain an intermediate mixed solution; and 4, cooling the intermediate mixture obtained in the step 3 to 30 ℃, adding dandelion extract, honeysuckle extract, glycyrol extract, winter jasmine acetone extract and mint essential oil under the condition of continuous stirring, fully and uniformly mixing, and cooling to room temperature to obtain the environment-friendly textile finishing agent.
Example 3
The environment-friendly finishing agent for textiles provided by the embodiment comprises the following raw materials in parts by weight: 10 parts of propolis, 4 parts of chitosan, 10 parts of sodium carboxymethylcellulose, 5 parts of amino silicone oil, 4 parts of dandelion extract, 2 parts of honeysuckle extract, 3 parts of liquorice alcohol extract, 0.5 part of winter jasmine acetone extract and 3 parts of mint essential oil, wherein the weight ratio of the components is 1: 2: 0.8 part of catalyst consisting of ammonium sulfate, magnesium chloride and tartaric acid, 12 parts of softening agent (preferably fatty acid triethanol quaternary ammonium sodium), 10 parts of ethanol and 120 parts of water.
The environment-friendly antibacterial finishing agent is prepared by the following method:
step 1, respectively weighing the following components in parts by weight: 10 parts of propolis, 4 parts of chitosan, 10 parts of sodium carboxymethylcellulose, 5 parts of amino silicone oil, 4 parts of dandelion extract, 2 parts of honeysuckle extract, 3 parts of liquorice alcohol extract, 0.5 part of winter jasmine acetone extract and 3 parts of mint essential oil, wherein the weight ratio of the components is 1: 2: 0.8 part of catalyst consisting of ammonium sulfate, magnesium chloride and tartaric acid, 2 parts of softening agent (preferably fatty acid triethanol quaternary ammonium sodium), 10 parts of ethanol and 120 parts of water for later use;
step 2, dispersing the ethanol, the sodium carboxymethyl cellulose and the catalyst in the step 1 into water at the temperature of 30 ℃, and fully and uniformly mixing to obtain an initial mixed solution;
step 3, heating the initial mixed solution obtained in the step 2 to 50 ℃, sequentially adding the propolis, the chitosan, the amino silicone oil and the softening agent obtained in the step 1, and continuously stirring for 90min to obtain an intermediate mixed solution;
and 4, cooling the intermediate mixture obtained in the step 3 to 30 ℃, adding dandelion extract, honeysuckle extract, glycyrol extract, winter jasmine acetone extract and mint essential oil under the condition of continuous stirring, fully and uniformly mixing, and cooling to room temperature to obtain the environment-friendly textile finishing agent.
Comparative example 1
The finishing agent comprises the following raw materials in parts by weight: 6 parts of chitosan, 8 parts of sodium carboxymethylcellulose, 6 parts of amino silicone oil, 2 parts of dandelion extract, 1 part of honeysuckle extract, 2 parts of liquorice alcohol extract, 0.8 part of winter jasmine acetone extract, 2 parts of mint essential oil and a mixture of the components in parts by weight of 1: 2: 0.8 of catalyst consisting of ammonium sulfate, magnesium chloride and tartaric acid, 10 parts of softening agent (preferably fatty acid triethanol quaternary ammonium sodium), 12 parts of ethanol and 100 parts of water.
The environment-friendly antibacterial finishing agent is prepared by the following method:
step 1, respectively weighing the following components in parts by weight: 6 parts of chitosan, 8 parts of sodium carboxymethylcellulose, 6 parts of amino silicone oil, 2 parts of dandelion extract, 1 part of honeysuckle extract, 2 parts of liquorice alcohol extract, 0.8 part of winter jasmine acetone extract, 2 parts of mint essential oil and a mixture of the components in parts by weight of 1: 2: 0.8 part of catalyst consisting of ammonium sulfate, magnesium chloride and tartaric acid, 3 parts of softening agent (preferably fatty acid triethanol quaternary ammonium sodium), 12 parts of ethanol and 100 parts of water for later use;
step 2, dispersing the ethanol, the sodium carboxymethyl cellulose and the catalyst in the step 1 into water at the temperature of 30 ℃, and fully and uniformly mixing to obtain an initial mixed solution;
step 3, heating the initial mixed solution obtained in the step 2 to 50 ℃, sequentially adding 6 parts of chitosan, amino silicone oil and a softening agent in the step 1, and continuously stirring for 90min to obtain an intermediate mixed solution;
and 4, cooling the intermediate mixture obtained in the step 3 to 30 ℃, adding dandelion extract, honeysuckle extract, glycyrol extract, winter jasmine acetone extract and mint essential oil under the condition of continuous stirring, fully and uniformly mixing, and cooling to room temperature to obtain the environment-friendly textile finishing agent.
Comparative example 2
The finishing agent comprises the following raw materials in parts by weight: 8 parts of propolis, 8 parts of sodium carboxymethylcellulose, 6 parts of amino silicone oil, 2 parts of dandelion extract, 1 part of honeysuckle extract, 2 parts of liquorice alcohol extract, 0.8 part of winter jasmine acetone extract, 2 parts of mint essential oil and a mixture of the components in parts by weight of 1: 2: 0.8 of catalyst consisting of ammonium sulfate, magnesium chloride and tartaric acid, 10 parts of softening agent (preferably fatty acid triethanol quaternary ammonium sodium), 12 parts of ethanol and 100 parts of water.
The environment-friendly antibacterial finishing agent is prepared by the following method:
step 1, respectively weighing the following components in parts by weight: 8 parts of propolis, 8 parts of sodium carboxymethylcellulose, 6 parts of amino silicone oil, 2 parts of dandelion extract, 1 part of honeysuckle extract, 2 parts of liquorice alcohol extract, 0.8 part of winter jasmine acetone extract, 2 parts of mint essential oil and a mixture of the components in parts by weight of 1: 2: 0.8 part of catalyst consisting of ammonium sulfate, magnesium chloride and tartaric acid, 3 parts of softening agent (preferably fatty acid triethanol quaternary ammonium sodium), 12 parts of ethanol and 100 parts of water for later use;
step 2, dispersing the ethanol, the sodium carboxymethyl cellulose and the catalyst in the step 1 into water at the temperature of 30 ℃, and fully and uniformly mixing to obtain an initial mixed solution;
step 3, heating the initial mixed solution obtained in the step 2 to 50 ℃, sequentially adding the propolis, the amino silicone oil and the softening agent obtained in the step 1, and continuously stirring for 90min to obtain an intermediate mixed solution;
and 4, cooling the intermediate mixture obtained in the step 3 to 30 ℃, adding dandelion extract, honeysuckle extract, glycyrol extract, winter jasmine acetone extract and mint essential oil under the condition of continuous stirring, fully and uniformly mixing, and cooling to room temperature to obtain the environment-friendly textile finishing agent.
Comparative example 3
The finishing agent comprises the following raw materials in parts by weight: 8 parts of propolis, 6 parts of chitosan, 8 parts of sodium carboxymethylcellulose and 6 parts of amino silicone oil, wherein the weight ratio of propolis to chitosan is 1: 2: 0.8 of catalyst consisting of ammonium sulfate, magnesium chloride and tartaric acid, 10 parts of softening agent (preferably fatty acid triethanol quaternary ammonium sodium), 12 parts of ethanol and 100 parts of water.
The environment-friendly antibacterial finishing agent is prepared by the following method:
step 1, respectively weighing the following components in parts by weight: 8 parts of propolis, 6 parts of chitosan, 8 parts of sodium carboxymethylcellulose and 6 parts of amino silicone oil, wherein the weight ratio of propolis to chitosan is 1: 2: 0.8 part of catalyst consisting of ammonium sulfate, magnesium chloride and tartaric acid, 3 parts of softening agent (preferably fatty acid triethanol quaternary ammonium sodium), 12 parts of ethanol and 100 parts of water for later use;
step 2, dispersing the ethanol, the sodium carboxymethyl cellulose and the catalyst in the step 1 into water at the temperature of 30 ℃, and fully and uniformly mixing to obtain an initial mixed solution;
step 3, heating the initial mixed solution obtained in the step 2 to 50 ℃, sequentially adding the propolis, the chitosan, the amino silicone oil and the softening agent obtained in the step 1, and continuously stirring for 90min to obtain an intermediate mixed solution;
and 4, cooling the intermediate mixture obtained in the step 3 to 30 ℃, adding mint essential oil under the condition of continuous stirring, fully and uniformly mixing, and cooling to room temperature to obtain the environment-friendly textile finishing agent.
The raw material ratios of the above examples 1 to 3 and comparative examples 1 to 3 are shown in Table 1.
To verify the antibacterial properties of the finishes obtained in the above examples and comparative examples, the following experiments were carried out:
the cotton fabrics are subjected to three-dipping and three-rolling in the environment-friendly antibacterial finishing agent prepared in the above examples 1-3 and comparative examples 1-3, the rolling retention rate is 65%, the treatment time is 30min each time, the dipping temperature is 60 ℃, the finished cotton fabrics are pre-dried at 100 ℃ for 3min, then the cotton fabrics are baked at 120 ℃ for 5min, and then the index determination is carried out.
And (3) evaluating the antibacterial performance of the textile according to GB/T20944.3-2008: performing antibacterial performance by a vibration method; the tear strength was tested on an Elmendorf tear Strength apparatus according to ASTM D5587-2003 Standard test method for measuring tear Strength of Fabric by trapezoidal Process; the ultraviolet resistance of the fabric is tested according to the AS.NZS4399 standard, and the specific test results are shown in the following table 2:
TABLE 2 results of the measurement of bacteriostatic properties
TABLE 3 anti-wrinkle Effect test results
TABLE 4 ultraviolet protection Performance test
As can be seen from the data in tables 1, 2 and 3, the antibacterial property and the crease resistance of the finishing agent obtained by the invention are far better than those of the finishing agent obtained by the comparative example; in addition, as can be seen from the data in table 4, the UPF value of the fabric treated by the finishing agent obtained in the present invention can reach 22.2, which indicates that the fabric treated by the finishing agent obtained in the present invention has a good ultraviolet protection function.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any changes or substitutions that can be easily conceived by those skilled in the art within the technical scope of the present invention are included in the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the claims.
Claims (10)
1. The environment-friendly textile finishing agent is characterized by comprising the following raw materials in parts by weight: 6-10 parts of propolis, 4-8 parts of chitosan, 5-10 parts of sodium carboxymethylcellulose, 5-8 parts of amino silicone oil, 1-4 parts of dandelion extract, 2-3 parts of honeysuckle extract, 1-3 parts of glycyrrhiza alcohol extract, 0.5-1 part of winter jasmine acetone extract, 1-3 parts of mint essential oil, 2-4 parts of catalyst, 8-12 parts of softener, 10-15 parts of ethanol and 80-120 parts of water.
2. The environment-friendly textile finishing agent as claimed in claim 1, characterized in that the finishing agent comprises the following raw materials in parts by weight: 8 parts of propolis, 6 parts of chitosan, 7 parts of sodium carboxymethylcellulose, 6.5 parts of amino silicone oil, 2 parts of dandelion extract, 2.5 parts of honeysuckle extract, 2 parts of liquorice alcohol extract, 0.8 part of winter jasmine acetone extract, 2 parts of mint essential oil, 3 parts of catalyst, 10 parts of softener, 12 parts of ethanol and 100 parts of water.
3. An environment-friendly textile finishing agent as claimed in claim 1 or 2, wherein the catalyst is a mixture of ammonium sulfate, magnesium chloride and tartaric acid, wherein the weight ratio of the ammonium sulfate, the magnesium chloride and the tartaric acid is 1: (1-3): (0.5 to 1).
4. An environment-friendly textile finishing agent as claimed in claim 1 or 2, wherein the softening agent is an esterquat softening agent.
5. The preparation method of the textile environment-friendly finishing agent is characterized by comprising the following steps:
step 1, respectively weighing the following components in parts by weight: 6-10 parts of propolis, 4-8 parts of chitosan, 5-10 parts of sodium carboxymethylcellulose, 5-8 parts of amino silicone oil, 1-4 parts of dandelion extract, 2-3 parts of honeysuckle extract, 1-3 parts of glycyrrhiza alcohol extract, 0.5-1 part of winter jasmine acetone extract, 1-3 parts of mint essential oil, 2-4 parts of catalyst, 8-12 parts of softener, 10-15 parts of ethanol and 80-120 parts of water;
step 2, dispersing the ethanol, the sodium carboxymethyl cellulose and the catalyst in the step 1 into water at the temperature of 30-40 ℃, and fully and uniformly mixing to obtain an initial mixed solution;
step 3, heating the initial mixed solution obtained in the step 2 to 50-60 ℃, sequentially adding the propolis, the chitosan, the amino silicone oil and the softening agent in the step 1, and continuously stirring for 60-120 min to obtain an intermediate mixed solution;
and 4, cooling the intermediate mixture obtained in the step 3 to 30-40 ℃, adding dandelion extract, honeysuckle extract, glycyrol extract, winter jasmine acetone extract and mint essential oil under the condition of continuous stirring, fully and uniformly mixing, and cooling to room temperature to obtain the environment-friendly textile finishing agent.
6. The preparation method of the textile environment-friendly finishing agent according to claim 5, wherein in the step 1, the extraction method of the winter jasmine acetone extracting solution is as follows: drying winter jasmine at constant temperature, crushing into powder, adding 60-80 wt% of acetone solution, performing ultrasonic extraction, standing, and taking supernatant to obtain winter jasmine acetone extract; the extraction method of the liquorice alcohol extract comprises the following steps: drying liquorice at constant temperature, crushing into powder, adding 60-70 wt% ethanol solution, heating, extracting, standing, and taking supernatant to obtain the liquorice alcohol extract.
7. The preparation method of the textile environment-friendly finishing agent according to claim 5, characterized in that when the acetone extract of the winter jasmine is extracted, the leaching temperature is 40-50 ℃, the leaching time is 30-50 min, and the material ratio (g: ml) is 1 (15-25); when the licorice alcohol extract is extracted, the extraction temperature is 50-70 ℃, the extraction time is 30-150 min, and the material ratio (g: ml) is 1 (5-15).
8. Use of the textile environmental protection finishing agent according to any one of claims 1 to 4 in the antibacterial finishing of textiles.
9. Use according to claim 8, characterized in that the textile is dipped into the finish according to any one of claims 1 to 3 or the textile is dipped into the diluted finish according to any one of claims 1 to 4, impregnated or padded and then dried.
10. The use according to claim 9, wherein the padding is a padding and rolling, the rolling residual rate is 75-85%, and the drying temperature is 120-150 ℃.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106758218A (en) * | 2015-11-19 | 2017-05-31 | 张发民 | Special antibacterial finishing agent of textile and preparation method thereof |
| CN108035146A (en) * | 2018-01-05 | 2018-05-15 | 苏州经贸职业技术学院 | A kind of Environment Compatible Textiles finishing agent and preparation method thereof |
| CN108677530A (en) * | 2018-05-15 | 2018-10-19 | 张彦 | antibacterial finishing agent and its preparation method and application |
| CN109972267A (en) * | 2019-04-12 | 2019-07-05 | 江苏布拉芙纺织科技有限公司 | A kind of preparation method of long-lasting antibacterial textile fabric |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106758218A (en) * | 2015-11-19 | 2017-05-31 | 张发民 | Special antibacterial finishing agent of textile and preparation method thereof |
| CN108035146A (en) * | 2018-01-05 | 2018-05-15 | 苏州经贸职业技术学院 | A kind of Environment Compatible Textiles finishing agent and preparation method thereof |
| CN108677530A (en) * | 2018-05-15 | 2018-10-19 | 张彦 | antibacterial finishing agent and its preparation method and application |
| CN109972267A (en) * | 2019-04-12 | 2019-07-05 | 江苏布拉芙纺织科技有限公司 | A kind of preparation method of long-lasting antibacterial textile fabric |
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Application publication date: 20200616 |