CN111280187A - Compound traditional Chinese medicine disinfectant and preparation method thereof - Google Patents
Compound traditional Chinese medicine disinfectant and preparation method thereof Download PDFInfo
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/10—Apiaceae or Umbelliferae [Carrot family], e.g. parsley, caraway, dill, lovage, fennel or snakebed
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/12—Asteraceae or Compositae [Aster or Sunflower family], e.g. daisy, pyrethrum, artichoke, lettuce, sunflower, wormwood or tarragon
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/32—Ranunculaceae [Buttercup family], e.g. hepatica, hydrastis or goldenseal
Abstract
A compound traditional Chinese medicine disinfectant and a preparation method thereof belong to the technical field of disinfection and sterilization agents, and aim at providing a broad-spectrum antibacterial compound traditional Chinese medicine disinfectant. The composition is prepared from the following components in parts by weight: 21-28 parts of dandelion, 15-22 parts of folium artemisiae argyi, 3-7 parts of coptis chinensis, 8-13 parts of houttuynia cordata, 3-7 parts of honeysuckle, 7-13 parts of radix isatidis, 4-10 parts of radix bupleuri and 450-500 parts of 95-degree edible alcohol, and after the 7 traditional Chinese medicinal materials are combined, an ethanol extraction method is adopted to prepare a compound traditional Chinese medicine disinfectant product with the alcohol content of 75%. The disinfectant has good sterilization and disinfection effects, wide antimicrobial spectrum and lasting drug effect, can be applied to spraying, disinfection and disinfection in public places and crowded places such as families, hospitals, offices, hotels and the like, and can also play a role in preventing and applying the disinfection of various paroxysmal viral infectious diseases.
Description
Technical Field
The invention relates to a compound traditional Chinese medicine disinfectant and a preparation method thereof in the technical field of disinfection and sterilization agents.
Background
With the continuous development and technological progress of disinfection and sterilization products, the technical requirements on disinfection and sterilization agents, particularly compound traditional Chinese medicine disinfection solutions, are higher and higher, plant-derived antibacterial disinfection substances contained in Chinese herbal medicine plants widely exist in the nature, and the traditional Chinese medicine disinfection solution has the characteristics of small side effect, strong comprehensive disinfection function, good effect and the like compared with a chemical disinfection product, so that the traditional Chinese medicine disinfection solution is widely developed and widely applied. In the known technology, the existing traditional Chinese medicine disinfectant is a compound traditional Chinese medicine disinfectant prepared by matching traditional Chinese medicinal materials such as dandelion, coptis chinensis, honeysuckle, houttuynia cordata and the like, and the efficacy and the sterilization and disinfection effects are different due to different component contents and preparation methods of the compatibility of the traditional Chinese medicinal materials. Therefore, the new compound traditional Chinese medicine disinfectant with high efficiency and good sterilization and disinfection effect is further improved and researched, and is very necessary for promoting the continuous development and application of the sterilization and disinfection agent.
Disclosure of Invention
Aiming at the technical problems, the invention aims to provide a novel compound traditional Chinese medicine disinfectant with broad-spectrum antibacterial property, which is prepared by selecting and matching antibacterial and disinfectant traditional Chinese medicinal materials and extracting the effective components of the antibacterial and disinfectant traditional Chinese medicinal materials, has the advantages of effective sterilization and disinfection, no toxic or side effect, no anaphylactic reaction, no irritation to human skin, wide antibacterial spectrum and convenient use.
The technical scheme adopted by the invention for solving the problems is as follows:
a compound traditional Chinese medicine disinfectant is prepared from the following components in parts by weight: 21-28 parts of dandelion, 15-22 parts of folium artemisiae argyi, 3-7 parts of coptis chinensis, 8-13 parts of houttuynia cordata, 3-7 parts of honeysuckle, 7-13 parts of radix isatidis, 4-10 parts of radix bupleuri and 450-500 parts of 95-degree edible alcohol, and after the 7 traditional Chinese medicinal materials are combined, an ethanol extraction method is adopted to prepare a compound traditional Chinese medicine disinfectant product with the alcohol content of 75%.
The compound traditional Chinese medicine disinfectant is further optimized, and comprises the following components in parts by weight: 24-27 parts of dandelion, 18-21 parts of folium artemisiae argyi, 4-5 parts of coptis chinensis, 9-11 parts of houttuynia cordata, 3-5 parts of honeysuckle, 8-10 parts of radix isatidis, 5-8 parts of radix bupleuri and 460-480 parts of 95-degree edible alcohol, and after the 7 traditional Chinese medicinal materials are combined, an ethanol extraction method is adopted to prepare a compound traditional Chinese medicine disinfectant product with the alcohol content of 75%.
The compound traditional Chinese medicine disinfectant has the advantages that the preparation method comprises the following steps:
weighing the Chinese medicinal materials of dandelion, folium artemisiae argyi, coptis chinensis, houttuynia cordata, honeysuckle, radix isatidis and radix bupleuri, crushing, adding into a stirring and leaching tank, adding 95-degree edible alcohol according to the weight ratio of the Chinese medicinal materials into the stirring and leaching tank, starting the stirring and leaching tank to stir and soak for 12-13 hours, starting shearing, refluxing and stirring for 3.5-4 hours, then adding into a settling tank to perform static precipitation for 8-9 hours, extracting supernatant for the first time, performing low-temperature static precipitation on the residual liquid medicine in an environment of minus 5 ℃ for 6-7 hours, extracting the supernatant for the second time, taking out the Chinese medicinal residues in the settling tank, removing the Chinese medicinal liquid through a centrifuge, uniformly mixing the supernatant collected twice and the centrifugally removed Chinese medicinal liquid, filtering, and preparing the compound Chinese medicinal disinfectant product with the alcohol content of 75% by using purified water.
The compound traditional Chinese medicine disinfectant is prepared by combining pharmacology and medicinal properties according to the traditional Chinese medicine theory and performing formula compatibility according to the principle that monarch, minister, assistant and guide supplement and complement each other, and preferably selecting and selecting traditional Chinese medicinal materials. The technical scheme of the invention is given, and the pharmacology and drug properties and the disinfection principle of the raw materials of the compound disinfectant are also explained:
dandelion: sweet in nature, slightly bitter and cold, and contains taraxasterol, taraxasterin, caffeic acid, choline, inulin, etc.; according to records in compendium of materia medica, dandelion can clear away heat and toxic materials, digest food, eliminate swelling, clear away heat and toxic materials, relieve swelling and dissipate stagnation; the dandelion is commonly used as an anti-inflammatory agent, and has certain bactericidal effects on staphylococcus aureus resistant strains, hemolytic streptococcus, diplococcus pneumoniae, meningococcus, diphtheria bacillus, pseudomonas aeruginosa, proteus, typhoid bacillus, dysentery bacillus and the like.
Folium artemisiae argyi: bitter, pungent and warm in nature and flavor, recorded in compendium of materia Medica: folium artemisiae argyi is used as a medicine, is warm in nature, bitter in taste, non-toxic, purely positive in nature, and capable of dredging twelve meridians, has the effects of restoring yang, regulating qi and blood, dispelling dampness and cold, stopping bleeding, preventing miscarriage and the like, and pharmacological research of modern medicine shows that the folium artemisiae argyi is a broad-spectrum antibacterial and antiviral medicine, has the effects of inhibiting and killing various bacteria and viruses, has a certain effect of preventing and treating respiratory diseases, and has a unique sterilization function.
Coptis chinensis: is bitter and cold in nature and has the effects of clearing heat, eliminating dampness, purging fire and removing toxicity; mainly contains berberine, coptisine, methyl coptisine, jateorhizine, phellodendron lactone and the function of pathogenic microorganisms of coptis, and domestic and foreign researches report that the Chinese medicinal composition has stronger antibacterial action on staphylococcus, streptococcus, pneumococcus, vibrio cholerae, carbon plague bacillus and disease bacillus, and has better antibacterial function on staphylococcus aureus than penicillin.
The houttuynia cordata decoction mainly contains volatile oil, houttuynin, α -pinene, camphene, myrcene, d-limonene, methyl n-nonyl ketone, decanal, decanoic acid and other effective components, and has obvious inhibiting effect on staphylococcus aureus, staphylococcus albus, influenza bacillus, candida albicans, colibacillus, pneumococcus and trichophyton.
Honeysuckle flower: the honeysuckle flower health-care tea is sweet in taste and cold in nature, has the effects of clearing away heat and toxic materials and dispelling wind and heat, mainly contains chlorogenic acid and a plurality of other components such as flavone, iridoid glycoside, saponin and the like, and is a main component of the honeysuckle flower with an antibacterial effect.
Radix isatidis: is cold in nature and bitter in taste, mainly contains organic acid and ester compounds thereof, alkaloid compounds, sinapside compounds, flavonoid compounds, anthraquinone compounds, sterol compounds, amino acid compounds, sulfur-containing compounds and other chemical components, has broad-spectrum antibacterial effect, and also has the effects of killing viruses and inhibiting viruses.
Bupleurum root: slightly cold in nature and bitter in taste, and mainly contains saikosaponin, sterol, volatile oil (such as bupleuri radix alcohol and eugenol), fatty acid (such as oleic acid, linoleic acid, palmitic acid and stearic acid), polysaccharide, etc.; has obvious heat-clearing effect on fever caused by typhoid bacillus, colon bacillus, saccharomycetes and the like, can inhibit tubercle bacillus, influenza bacillus and vaccinia virus, and can kill plasmodium.
In order to prove the pharmacodynamic properties of the compound traditional Chinese medicine disinfectant product, the compound traditional Chinese medicine disinfectant is subjected to disinfection and sterilization efficacy tests, onset time tests, efficacy stability tests, drug resistance tests, allergy tests and other efficacy tests.
Experiments prove that after 7 preferable Chinese medicinal materials are compatible, the compound traditional Chinese medicine disinfectant prepared by an ethanol extraction method can supplement each other, and comprehensively has broad-spectrum antibacterial, antiviral and virus-killing effects on staphylococcus aureus, hemolytic streptococcus, diplococcus pneumoniae, escherichia coli, shigella dysenteriae and the like.
When the compound traditional Chinese medicine disinfectant is used, the compound traditional Chinese medicine disinfectant product is filled in a spray bottle or a container of 100-2000 ml or a disinfectant spraying apparatus according to design requirements and actual requirements, and is sprayed by aiming at a target object and a space.
The invention adopts the technical scheme. The test and trial results show that the disinfectant has the advantages of good sterilization and disinfection effect, wide antimicrobial spectrum, lasting drug effect, capability of inhibiting virus and bacteria for a long time, no toxic or side effect, no anaphylactic reaction, no irritation to human skin, convenience in use and the like, can be applied to spraying, disinfecting and sterilizing in public places and crowds such as families, hospitals, offices, hotels and the like, and can play a role in preventing and applying to disinfecting various sudden virus infectious diseases.
Additional features and advantages of the invention will be set forth in the description which follows, and in part will be obvious from the description, or may be learned by practice of the invention. The objectives and other advantages of the invention will be realized and attained by the structure particularly pointed out in the written description and claims hereof.
Detailed Description
The technical solution of the present invention is further described in detail with reference to the following examples.
Example 1:
preparing materials and weighing according to the weight ratio of the formula: 1.3kg of dandelion, 1.0kg of folium artemisiae argyi, 2.3kg of coptis, 4.8kg of houttuynia cordata, 2.1kg of honeysuckle, 4.5kg of radix isatidis, 3.5kg of radix bupleuri and 235kg of 95-degree edible alcohol.
The preparation method of the compound traditional Chinese medicine disinfectant comprises the following steps:
weighing the Chinese medicinal materials of dandelion, folium artemisiae argyi, coptis chinensis, houttuynia cordata, honeysuckle, radix isatidis and radix bupleuri, crushing, adding the crushed materials into a stirring and leaching tank, adding 235kg of edible alcohol with the temperature of 95 ℃ according to the weight ratio of the Chinese medicinal materials into the stirring and leaching tank, starting stirring and soaking the stirring and leaching tank for 12 hours, then starting shearing, refluxing and stirring for 3.5 hours, then putting the stirred and leaching tank into a settling tank for standing and settling for 8 hours, extracting supernatant for the first time, carrying out low-temperature standing and settling on the residual liquid medicine in an environment with the temperature of minus 5 ℃ for 6 hours, extracting the supernatant for the second time, taking out the Chinese medicine residues in the stirring and leaching tank, removing the Chinese medicine liquid through a centrifugal machine, uniformly mixing the supernatant collected for the two times and the centrifuged Chinese medicine liquid, filtering, and preparing the compound Chinese medicine disinfectant (I) with the alcohol content.
Example 2:
preparing materials and weighing according to the weight ratio of the formula: 2.6kg of dandelion, 2.0kg of folium artemisiae argyi, 4.5kg of coptis chinensis, 1.0kg of houttuynia cordata, 4.5kg of honeysuckle, 1.2kg of isatis root, 5.6kg of radix bupleuri and 50kg of 95-degree edible alcohol.
The preparation method of the compound traditional Chinese medicine disinfectant comprises the following steps:
the preparation method comprises the following steps of crushing the raw materials, weighing the raw materials, adding the crushed raw materials into a stirring and leaching tank, adding 95-degree edible alcohol into the stirring and leaching tank, starting the stirring and leaching tank to stir and soak for 12 hours, then starting shearing, refluxing and stirring for 4.5 hours, then putting the stirred and leaching tank into a settling tank to perform static settling for 8 hours, extracting supernatant for the first time, performing low-temperature static settling on the residual liquid medicine at minus 5 ℃ for 6.5 hours, extracting the supernatant for the second time, taking out traditional Chinese medicine residues in the stirring and leaching tank, removing traditional Chinese medicine liquid through a centrifugal machine, uniformly mixing the supernatant collected for the two times and the traditional Chinese medicine liquid removed through centrifugation, filtering, and preparing the compound traditional Chinese medicine disinfectant (II) with the alcohol content of 75% by using purified water.
Example 3:
preparing materials and weighing according to the weight of the formula: 260kg of dandelion, 190kg of folium artemisiae argyi, 46kg of coptis, 97kg of houttuynia cordata, 45kg of honeysuckle, 95kg of isatis root, 65kg of radix bupleuri and 4700kg of 95-degree edible alcohol.
The preparation method of the compound traditional Chinese medicine disinfectant comprises the following steps:
weighing the Chinese medicinal materials of dandelion, folium artemisiae argyi, coptis chinensis, houttuynia cordata, honeysuckle, radix isatidis and radix bupleuri, crushing, adding the crushed materials into a stirring and leaching tank, adding 95-degree edible alcohol according to the weight ratio of the Chinese medicinal materials into the stirring and leaching tank, starting the stirring and leaching tank to stir and soak for 13 hours, then starting shearing, refluxing and stirring for 3.5 hours, then putting the stirred and leaching tank into a settling tank for standing and precipitating for 9 hours, extracting supernatant for the first time, carrying out low-temperature static precipitation on the residual liquid medicine in an environment at minus 5 ℃ for 6.5 hours, extracting the supernatant for the second time, taking out the traditional Chinese medicine residues in the stirring and leaching tank, removing the traditional Chinese medicine liquid through a centrifugal machine, uniformly mixing the supernatant collected for the two times and the centrifuged traditional Chinese medicine liquid, filtering, and preparing the compound traditional Chinese medicine disinfectant (III) with the alcohol content of 75%.
Example 4:
preparing materials and weighing according to the weight ratio of the formula: 25kg of dandelion, 20kg of folium artemisiae argyi, 5kg of coptis chinensis, 10kg of houttuynia cordata, 4kg of honeysuckle, 10kg of isatis root, 6kg of radix bupleuri and 480kg of 95-degree edible alcohol, wherein the total amount of the materials is 560 kg.
The preparation method of the compound traditional Chinese medicine disinfectant comprises the following steps:
the preparation method comprises the following steps of (1) weighing the prepared materials: the method comprises the steps of crushing dandelion, folium artemisiae argyi, coptis chinensis, houttuynia cordata, honeysuckle, radix isatidis and radix bupleuri, adding the crushed dandelion, folium artemisiae argyi, coptis chinensis, houttuynia cordata, honeysuckle, radix isatidis and radix bupleuri into a stirring and leaching tank, adding 95-DEG edible alcohol into the stirring and leaching tank, starting stirring and soaking for 12 hours by starting the stirring and leaching tank, then starting shearing, refluxing and stirring for 4 hours, then putting the stirred and leaching tank into a settling tank for standing and settling for 8 hours, extracting supernatant for the first time, carrying out low-temperature standing and settling for 6 hours in an environment at minus 5 ℃ on the residual liquid medicine, extracting supernatant for the second time, taking out the traditional Chinese medicine residues in the stirring and leaching tank, removing traditional Chinese medicine liquid by a centrifuge, uniformly mixing the supernatant collected for the two times and the centrifugally removed traditional Chinese.
Example 5:
preparing materials and weighing according to the weight of the formula: 120kg of dandelion, 100kg of folium artemisiae argyi, 25kg of coptis, 47kg of houttuynia cordata, 25kg of honeysuckle, 45kg of isatis root, 35kg of radix bupleuri and 2400kg of 95-degree edible alcohol.
The preparation method of the compound traditional Chinese medicine disinfectant comprises the following steps:
weighing the Chinese medicinal materials of dandelion, folium artemisiae argyi, coptis chinensis, houttuynia cordata, honeysuckle, radix isatidis and radix bupleuri, crushing, adding the crushed Chinese medicinal materials into a stirring and leaching tank, adding 95-degree edible alcohol according to the weight ratio of the Chinese medicinal materials into the stirring and leaching tank, starting the stirring and leaching tank to stir and soak for 12.5 hours, then starting shearing, refluxing and stirring for 3.5 hours, then putting the stirred and leaching tank into a settling tank for standing and settling for 9 hours, extracting supernatant for the first time, carrying out low-temperature standing and settling on the residual liquid medicine in an environment at minus 5 ℃ for 7 hours, extracting the supernatant for the second time, taking out the Chinese medicine residues in the stirring and leaching tank, removing the Chinese medicine liquid through a centrifugal machine, uniformly mixing the supernatant collected for the two times and the centrifuged Chinese medicine liquid, filtering, and preparing the compound Chinese medicine disinfectant with the alcohol content of 75%.
The above is only one example, and on the basis of this, the person skilled in the art adds components and parts without inventive effort. Other technical characteristics and technical solutions derived from the improvements are all within the scope of the present invention.
Claims (3)
1. The compound traditional Chinese medicine disinfectant is characterized by comprising the following components in parts by weight: 21-28 parts of dandelion, 15-22 parts of folium artemisiae argyi, 3-7 parts of coptis chinensis, 8-13 parts of houttuynia cordata, 3-7 parts of honeysuckle, 7-13 parts of radix isatidis, 4-10 parts of radix bupleuri and 450-500 parts of 95-degree edible alcohol, and after the 7 traditional Chinese medicinal materials are combined, an ethanol extraction method is adopted to prepare a compound traditional Chinese medicine disinfectant product with the alcohol content of 75%.
2. The compound traditional Chinese medicine disinfectant as claimed in claim 1, wherein the traditional Chinese medicine disinfectant is prepared from the following components in parts by weight: 24-27 parts of dandelion, 18-21 parts of folium artemisiae argyi, 4-5 parts of coptis chinensis, 9-11 parts of houttuynia cordata, 3-5 parts of honeysuckle, 8-10 parts of radix isatidis, 5-8 parts of radix bupleuri and 460-480 parts of 95-degree edible alcohol, and after the 7 traditional Chinese medicinal materials are combined, an ethanol extraction method is adopted to prepare a compound traditional Chinese medicine disinfectant product with the alcohol content of 75%.
3. The compound traditional Chinese medicine disinfectant as claimed in claim 1, wherein the preparation method of the compound traditional Chinese medicine disinfectant comprises the following steps: weighing the Chinese medicinal materials of dandelion, folium artemisiae argyi, coptis chinensis, houttuynia cordata, honeysuckle, radix isatidis and radix bupleuri, crushing, adding the crushed materials into a stirring and leaching tank, adding 95-degree edible alcohol in a weight ratio of the Chinese medicinal materials into the stirring and leaching tank, starting the stirring and leaching tank to stir and soak for 12-13 hours, then starting shearing, refluxing and stirring for 3.5-4 hours, then putting the stirred and leaching tank into a settling tank for standing and settling for 8-9 hours, extracting supernatant for the first time, carrying out low-temperature standing and settling on the residual liquid medicine in an environment at minus 5 ℃ for 6-7 hours, extracting the supernatant for the second time, taking out the Chinese medicine residues in the stirring and leaching tank, removing the liquid medicine through a centrifugal machine, uniformly mixing the supernatant collected for the two times and the centrifugally removed liquid medicine, filtering, and preparing the compound Chinese medicine disinfectant product with the alcohol content of 75%.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104488986A (en) * | 2014-12-26 | 2015-04-08 | 孔祥华 | Traditional Chinese medicine sterilizing liquid for clinical laboratory |
| CN106577863A (en) * | 2016-11-30 | 2017-04-26 | 广西大学 | Traditional Chinese medicine disinfectant and preparation method thereof |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104488986A (en) * | 2014-12-26 | 2015-04-08 | 孔祥华 | Traditional Chinese medicine sterilizing liquid for clinical laboratory |
| CN106577863A (en) * | 2016-11-30 | 2017-04-26 | 广西大学 | Traditional Chinese medicine disinfectant and preparation method thereof |
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Application publication date: 20200616 |