CN111268989A - Mud carving material and preparation method thereof - Google Patents
Mud carving material and preparation method thereof Download PDFInfo
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- CN111268989A CN111268989A CN202010098027.4A CN202010098027A CN111268989A CN 111268989 A CN111268989 A CN 111268989A CN 202010098027 A CN202010098027 A CN 202010098027A CN 111268989 A CN111268989 A CN 111268989A
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- mud
- chlorogenic acid
- rosin
- silane
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
- C04B28/145—Calcium sulfate hemi-hydrate with a specific crystal form
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00956—Uses not provided for elsewhere in C04B2111/00 for making sculptures or artistic casts
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a mud carving material which is prepared from the following components in parts by weight: 20-30 parts of calcium carbonate, 15-20 parts of liquid paraffin, 8-12 parts of glycerol, 40-60 parts of mud main material, 3-6 parts of vitamin glue, 3-5 parts of semi-hydrated gypsum and 8-12 parts of vinyl tri (dimethylsiloxane) silane/isocyano ethyl methacrylate/rosin modified chlorogenic acid copolymer. The invention also discloses a preparation method of the mud carving material. The clay sculpture material disclosed by the invention has better comprehensive performance, better water resistance and mechanical property, more excellent performance stability and longer plasticity retention time, and the sculptured clay sculpture is firm, beautiful and durable; the method overcomes the complex process that the clay sculpture material needs to be fired at high temperature in the cave, can achieve the effect of hardening and molding the clay through a common flame spray gun, and has higher economic value and social value.
Description
Technical Field
The invention relates to the technical field of building materials, in particular to a mud carving material and a preparation method thereof.
Background
The art is originated from life, and is higher than life, and the art and the life are interdependent and mutually promoted. The nature and the life provide fertile soil for the art, and the art expresses the nature and the life in a full-hearted manner and makes the life richer and more colorful. The sculpture is one of the artistic embodiment forms in life, is an ornamental and memorial object which is carved and molded for beautifying the environment or for commemorative significance, has certain meanings, symbols or figures, not only has the characteristics of hard texture, wear resistance and extremely heavy weight sense of natural stone, but also has the texture and strong plasticity and expression which are shown by the sculpture, can show various artistic styles to the greatest extent, and shows natural decorative effect and artistic connotation in the building and decorative space, which are incomparable with other decorative materials. According to different manufacturing raw materials, sculptures on the market comprise wood carving, stone carving, gypsum carving, copper carving and clay carving. The sculpture has the lowest price, the sculpture which is commonly used in indoor decoration and furniture decoration is clay sculpture, and the artistic expression effect and the performance stability of the sculpture depend on the performance of clay sculpture materials. Therefore, it is very important to develop a mud carving material with excellent comprehensive performance.
The traditional mud carving material comprises clay, quartz, mica, hematite and the like, most sculptures need to be hardened at high temperature after finishing, and the traditional mud carving material consumes time and energy and is high in cost. Some sculpture muds capable of self-hardening at normal temperature exist, but most sculpture muds have short hardening time and short plastic property maintaining time, and are not beneficial to creators to modify. Sculpture mud with long hardening time is also provided, for example, Chinese patent 'a self-hardening sculpture mud and a preparation method thereof' (publication No. CN102887696B) discloses a self-hardening sculpture mud, the sculpture mud has long hardening time, the maximum hardening time is 72 hours, but the sculpture mud uses glutinous rice flour as a binding material, so that the mildew and rot phenomenon is easy to generate, and the glutinous rice flour is easy to agglomerate and is not easy to stir and disperse; the sculpture mud has easy surface cracking in the hardening process.
Currently, the current practice is. The clay carving material with clay as component appears in the market, the clay is a synthetic material manufactured artificially, is mainly prepared by melting waste rubber, wax, vegetable oil or engine oil, talcum powder, calcium carbonate, toner, water and other materials, has the characteristics of strong viscosity and difficult dry cracking, is greatly influenced by temperature, has high price and small quantity, and has complex manufacturing process, so that ordinary sculptures are commonly used as small manuscripts or small-sized works.
Therefore, the clay sculpture material which has good performance stability, long plasticity retention time and low preparation cost and is solid, beautiful and durable in sculpture is developed, meets the market demand, has wide market value and application prospect and has very important significance for promoting the development of the clay sculpture industry.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides a mud carving material and a preparation method thereof, wherein the preparation method is simple and easy to implement, convenient to construct, low in energy consumption, low in preparation cost, high in preparation efficiency and finished product qualification rate, and suitable for continuous industrial production; the prepared mud carving material has better comprehensive performance, better water resistance and mechanical property, more excellent performance stability and longer plasticity retention time, and the carved mud carving is firm, beautiful and durable; the method overcomes the complex process that the clay sculpture material needs to be fired at high temperature in the cave, can achieve the effect of hardening and molding the clay through a common flame spray gun, and has higher economic value and social value.
In order to achieve the purpose, the invention adopts the technical scheme that:
the mud carving material is characterized by comprising the following components in parts by weight: 20-30 parts of calcium carbonate, 15-20 parts of liquid paraffin, 8-12 parts of glycerol, 40-60 parts of mud main material, 3-6 parts of vitamin glue, 3-5 parts of semi-hydrated gypsum and 8-12 parts of vinyl tri (dimethylsiloxane) silane/isocyano ethyl methacrylate/rosin modified chlorogenic acid copolymer.
Further, the main material of the mud is at least one of metakaolin, shale, attapulgite clay, fly ash and sepiolite powder.
Further, the preparation method of the vinyltris (dimethylsiloxy) silane/isocyanoethyl methacrylate/rosin modified chlorogenic acid copolymer comprises the following steps: adding vinyltris (dimethylsiloxy) silane, isocyano ethyl methacrylate, rosin modified chlorogenic acid and an initiator into a high-boiling-point solvent, stirring and polymerizing for 3-5 hours at 70-80 ℃ in a nitrogen atmosphere, and then removing the solvent by rotary evaporation to obtain the vinyltris (dimethylsiloxy) silane/isocyano ethyl methacrylate/rosin modified chlorogenic acid copolymer.
Preferably, the mass ratio of the vinyltri (dimethylsiloxy) silane to the isocyanoethyl methacrylate to the rosin-modified chlorogenic acid to the initiator to the high-boiling point solvent is 1: 2 to (0.03-0.05) to (15-25).
Preferably, the initiator is at least one of azobisisobutyronitrile and azobisisoheptonitrile; the high boiling point solvent is at least one of N, N-dimethylformamide, N-dimethylacetamide and N-methylpyrrolidone.
Further, the preparation method of the rosin modified chlorogenic acid comprises the following steps: dissolving hydrogenated rosin, chlorogenic acid and 2-ethoxy-1-ethoxycarbonyl-1, 2-dihydroquinoline in tetrahydrofuran, stirring and reacting for 6-8 hours at room temperature, and then removing tetrahydrofuran and 2-ethoxy-1-ethoxycarbonyl-1, 2-dihydroquinoline by rotary evaporation to obtain the aroma modified chlorogenic acid.
Preferably, the mass ratio of the hydrogenated rosin to the chlorogenic acid to the 2-ethoxy-1-ethoxycarbonyl-1, 2-dihydroquinoline to the tetrahydrofuran is 1: 1.24: 0.2-0.4: 8-12.
Another object of the present invention is to provide a method for preparing the mud carving material, which is characterized by comprising the following steps: the components are uniformly mixed according to the proportion to obtain a mixture, then the mixture is milled together and sieved by a 200-mesh and 300-mesh sieve to obtain the mud carving material.
Due to the application of the technical scheme, compared with the prior art, the invention has the following advantages: the preparation method of the mud carving material provided by the invention is simple and feasible, convenient to construct, low in energy consumption, low in preparation cost, high in preparation efficiency and finished product qualification rate, and suitable for continuous industrial production; the prepared mud carving material has better comprehensive performance, better water resistance and mechanical property, more excellent performance stability and longer plasticity retention time, and the carved mud carving is firm, beautiful and durable; the method overcomes the complex process that the clay sculpture material needs to be fired at high temperature in the cave, can achieve the effect of hardening and molding the clay through a common flame spray gun, and has higher economic value and social value.
Detailed Description
The invention relates to a mud carving material which is characterized by comprising the following components in parts by weight: 20-30 parts of calcium carbonate, 15-20 parts of liquid paraffin, 8-12 parts of glycerol, 40-60 parts of mud main material, 3-6 parts of vitamin glue, 3-5 parts of semi-hydrated gypsum and 8-12 parts of vinyl tri (dimethylsiloxane) silane/isocyano ethyl methacrylate/rosin modified chlorogenic acid copolymer.
Further, the main material of the mud is at least one of metakaolin, shale, attapulgite clay, fly ash and sepiolite powder.
Further, the preparation method of the vinyltris (dimethylsiloxy) silane/isocyanoethyl methacrylate/rosin modified chlorogenic acid copolymer comprises the following steps: adding vinyltris (dimethylsiloxy) silane, isocyano ethyl methacrylate, rosin modified chlorogenic acid and an initiator into a high-boiling-point solvent, stirring and polymerizing for 3-5 hours at 70-80 ℃ in a nitrogen atmosphere, and then removing the solvent by rotary evaporation to obtain a vinyltris (dimethylsiloxy) silane/isocyano ethyl methacrylate/rosin modified chlorogenic acid copolymer; the mass ratio of the vinyl tri (dimethylsiloxy) silane to the isocyano ethyl methacrylate to the rosin modified chlorogenic acid to the initiator to the high-boiling point solvent is 1: 2 to (0.03-0.05) to (15-25); the initiator is at least one of azobisisobutyronitrile and azobisisoheptonitrile; the high boiling point solvent is at least one of N, N-dimethylformamide, N-dimethylacetamide and N-methylpyrrolidone.
Further, the preparation method of the rosin modified chlorogenic acid comprises the following steps: dissolving hydrogenated rosin, chlorogenic acid and 2-ethoxy-1-ethoxycarbonyl-1, 2-dihydroquinoline in tetrahydrofuran, stirring and reacting for 6-8 hours at room temperature, and then removing tetrahydrofuran and 2-ethoxy-1-ethoxycarbonyl-1, 2-dihydroquinoline by rotary evaporation to obtain aroma modified chlorogenic acid; the mass ratio of the hydrogenated rosin to the chlorogenic acid to the 2-ethoxy-1-ethoxycarbonyl-1, 2-dihydroquinoline to the tetrahydrofuran is 1: 1.24: 0.2-0.4: 8-12.
Another object of the present invention is to provide a method for preparing the mud carving material, which is characterized by comprising the following steps: the components are uniformly mixed according to the proportion to obtain a mixture, then the mixture is milled together and sieved by a 200-mesh and 300-mesh sieve to obtain the mud carving material.
Due to the application of the technical scheme, compared with the prior art, the invention has the following advantages: the preparation method of the mud carving material provided by the invention is simple and feasible, convenient to construct, low in energy consumption, low in preparation cost, high in preparation efficiency and finished product qualification rate, and suitable for continuous industrial production; the prepared mud carving material has better comprehensive performance, better water resistance and mechanical property, more excellent performance stability and longer plasticity retention time, and the carved mud carving is firm, beautiful and durable; the method overcomes the complex process that the clay sculpture material needs to be fired at high temperature in the cave, can achieve the effect of hardening and molding the clay through a common flame spray gun, and has higher economic value and social value.
The invention will be further described with reference to specific examples, but the scope of the invention is not limited thereto.
Example 1
Embodiment 1 provides a clay carving material, which is characterized by comprising the following components in parts by weight: 20 parts of calcium carbonate, 15 parts of liquid paraffin, 8 parts of glycerol, 40 parts of metakaolin, 3 parts of vitamin glue, 3 parts of semi-hydrated gypsum and 8 parts of vinyl tri (dimethylsiloxane) silane/isocyano ethyl methacrylate/rosin modified chlorogenic acid copolymer.
Further, the preparation method of the vinyltris (dimethylsiloxy) silane/isocyanoethyl methacrylate/rosin modified chlorogenic acid copolymer comprises the following steps: 100g of vinyltris (dimethylsiloxy) silane, 100g of isocyanoethyl methacrylate, 200g of rosin-modified chlorogenic acid and 3g of azobisisobutyronitrile are added into 1500g of N, N-dimethylformamide, stirred and polymerized for 4 hours at 75 ℃ in a nitrogen atmosphere, and then the solvent is removed by rotary evaporation to obtain the vinyltris (dimethylsiloxy) silane/isocyanoethyl methacrylate/rosin-modified chlorogenic acid copolymer.
The preparation method of the rosin modified chlorogenic acid comprises the following steps: dissolving 100g of hydrogenated rosin, 124g of chlorogenic acid and 20g of 2-ethoxy-1-ethoxycarbonyl-1, 2-dihydroquinoline in 800g of tetrahydrofuran, stirring and reacting for 6 hours at room temperature, and then removing the tetrahydrofuran and the 2-ethoxy-1-ethoxycarbonyl-1, 2-dihydroquinoline by rotary evaporation to obtain the aroma modified chlorogenic acid.
The preparation method of the mud carving material is characterized by comprising the following steps of: the components are uniformly mixed according to a proportion to obtain a mixture, then the mixture is milled together and sieved by a 200-mesh sieve to obtain the mud carving material.
Example 2
Embodiment 2 provides a mud carving material, which has a formulation and a preparation method substantially the same as those of embodiment 1, except that the mud carving material comprises the following components in parts by weight: 23 parts of calcium carbonate, 17 parts of liquid paraffin, 9 parts of glycerol, 45 parts of shale, 4 parts of vitamin glue, 3.5 parts of semi-hydrated gypsum and 9 parts of vinyl tri (dimethylsiloxane) silane/isocyano ethyl methacrylate/rosin modified chlorogenic acid copolymer.
Example 3
Embodiment 3 provides a mud carving material, which has a formula and a preparation method substantially the same as those of embodiment 1, except that the mud carving material is prepared from the following raw materials in parts by weight: 25 parts of calcium carbonate, 18 parts of liquid paraffin, 10 parts of glycerol, 50 parts of attapulgite clay, 4.5 parts of vitamin glue, 4 parts of semi-hydrated gypsum and 10 parts of vinyl tri (dimethylsiloxane) silane/isocyano ethyl methacrylate/rosin modified chlorogenic acid copolymer.
Example 4
Embodiment 4 provides a mud carving material, which has a formula and a preparation method substantially the same as those of embodiment 1, except that the mud carving material is prepared from the following raw materials in parts by weight: 28 parts of calcium carbonate, 19 parts of liquid paraffin, 11 parts of glycerol, 58 parts of mud main material, 5.5 parts of vitamin glue, 4.8 parts of semi-hydrated gypsum and 11 parts of vinyl tri (dimethylsiloxane) silane/isocyano ethyl methacrylate/rosin modified chlorogenic acid copolymer; the main material of the mud is sepiolite powder and fly ash which are mixed according to the mass ratio of 3: 5.
Example 5
Embodiment 5 provides a mud carving material, which has a formula and a preparation method substantially the same as those of embodiment 1, except that the mud carving material is prepared from the following raw materials in parts by weight: 30 parts of calcium carbonate, 20 parts of liquid paraffin, 12 parts of glycerol, 60 parts of sepiolite powder, 6 parts of vitamin glue, 5 parts of semi-hydrated gypsum and 12 parts of vinyl tri (dimethylsiloxane) silane/isocyano ethyl methacrylate/rosin modified chlorogenic acid copolymer.
Comparative example 1
Comparative example 1 provides a clay-engraving material whose formulation and preparation method are substantially the same as those of example 1, except that calcium carbonate and glycerin are not added.
Comparative example 2
Comparative example 2 provides a clay engraving material whose formulation and preparation method are substantially the same as those of example 1, except that no vitamin glue or liquid paraffin is added.
Comparative example 3
Comparative example 3 provides a clay engraving material having substantially the same formulation and preparation method as in example 1, except that vinyltris (dimethylsiloxy) silane/isocyanoethyl methacrylate/rosin-modified chlorogenic acid copolymer and hemihydrate gypsum were not added.
In order to illustrate the technical effects of the embodiments of the present invention, the related properties of the mud carving materials of the examples are tested with reference to national standards, the test results are shown in table 1, and the test method is as follows: and (3) respectively adding water into the carving materials in each example, wherein the mass of the added water is 20% of the total mass of the components, stirring the materials until the materials are in a dough-like plastic state, and then completing the integral carving four days after the initial forming. Wrapping with plastic film, drying in the shade for one month, and performing color modification and colorless waterproof treatment. And (5) carrying out shade drying and maintenance for one month, soaking the carving in water again after three months, and weighing the weight change before and after soaking.
TABLE 1
| Item | Change in quality after one month | Change in quality after three months |
| Unit of | ％ | ％ |
| Example 1 | 0.20 | 0 |
| Example 2 | 0.17 | 0 |
| Example 3 | 0.14 | 0 |
| Example 4 | 0.10 | 0 |
| Example 5 | 0.07 | 0 |
| Comparative example 1 | 0.60 | 0.32 |
| Comparative example 2 | 0.65 | 0.48 |
| Comparative example 3 | 0.62 | 0.45 |
As can be seen from Table 1, the engravings made from the mud engraving material of examples 1-5 had a low water absorption and were not easily deformed; this is a result of the synergistic effect of the components.
The above embodiments are merely illustrative of the technical ideas and features of the present invention, and the purpose thereof is to enable those skilled in the art to understand the contents of the present invention and implement the present invention, and not to limit the protection scope of the present invention. All equivalent changes and modifications made according to the spirit of the present invention should be covered within the protection scope of the present invention.
Claims (8)
1. The mud carving material is characterized by comprising the following components in parts by weight: 20-30 parts of calcium carbonate, 15-20 parts of liquid paraffin, 8-12 parts of glycerol, 40-60 parts of mud main material, 3-6 parts of vitamin glue, 3-5 parts of semi-hydrated gypsum and 8-12 parts of vinyl tri (dimethylsiloxane) silane/isocyano ethyl methacrylate/rosin modified chlorogenic acid copolymer.
2. The mud carving material as claimed in claim 1, wherein the main mud material is at least one of metakaolin, shale, attapulgite clay, fly ash and sepiolite powder.
3. The mud engraving material of claim 1, wherein the preparation method of the vinyltris (dimethylsiloxy) silane/isocyanoethyl methacrylate/rosin-modified chlorogenic acid copolymer comprises the following steps: adding vinyltris (dimethylsiloxy) silane, isocyano ethyl methacrylate, rosin modified chlorogenic acid and an initiator into a high-boiling-point solvent, stirring and polymerizing for 3-5 hours at 70-80 ℃ in a nitrogen atmosphere, and then removing the solvent by rotary evaporation to obtain the vinyltris (dimethylsiloxy) silane/isocyano ethyl methacrylate/rosin modified chlorogenic acid copolymer.
4. The clay engraving material according to claim 3, wherein the mass ratio of the vinyltris (dimethylsiloxy) silane to the isocyanoethyl methacrylate to the rosin-modified chlorogenic acid to the initiator to the high-boiling solvent is 1: 2 to (0.03-0.05) to (15-25).
5. The mud carving material of claim 3, wherein the initiator is at least one of azobisisobutyronitrile, azobisisoheptonitrile; the high boiling point solvent is at least one of N, N-dimethylformamide, N-dimethylacetamide and N-methylpyrrolidone.
6. The mud carving material as set forth in claim 3, wherein said method for preparing rosin-modified chlorogenic acid comprises the steps of: dissolving hydrogenated rosin, chlorogenic acid and 2-ethoxy-1-ethoxycarbonyl-1, 2-dihydroquinoline in tetrahydrofuran, stirring and reacting for 6-8 hours at room temperature, and then removing tetrahydrofuran and 2-ethoxy-1-ethoxycarbonyl-1, 2-dihydroquinoline by rotary evaporation to obtain the aroma modified chlorogenic acid.
7. The mud carving material as claimed in claim 6, wherein the mass ratio of the hydrogenated rosin, the chlorogenic acid, the 2-ethoxy-1-ethoxycarbonyl-1, 2-dihydroquinoline and the tetrahydrofuran is 1: 1.24 (0.2-0.4) to (8-12).
8. The mud-engraved material of any one of claims 1-7, wherein said method of making said mud-engraved material comprises the steps of: the components are uniformly mixed according to the proportion to obtain a mixture, then the mixture is milled together and sieved by a 200-mesh and 300-mesh sieve to obtain the mud carving material.
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1463284A (en) * | 2001-03-16 | 2003-12-24 | 山室敏之 | Lightweight clay and mfg. method thereof |
| CN101348361A (en) * | 2007-07-17 | 2009-01-21 | 张文瑞 | Color handwork sculptures mud for student and manufacturing method thereof |
| ES2311304T3 (en) * | 1998-08-14 | 2009-02-01 | Seagull Decor Co., Ltd. | METHOD FOR THE PRODUCTION OF A CERAMIC ORNAMENT COVERED DENSELY WITH DIMINARY EDGES AND CORNERS. |
| CN103408707A (en) * | 2013-08-08 | 2013-11-27 | 中科院广州化学有限公司 | Amphiphilic crosslinkable fluorosilicon resin, water-borne coating and super-amphiphobic coating prepared through water-borne coating |
| CN105859235A (en) * | 2016-03-30 | 2016-08-17 | 广西盈益环保建材科技股份有限公司 | Clay sculpture material and preparation method thereof |
| CN106396541A (en) * | 2016-08-30 | 2017-02-15 | 派丽(上海)管理有限公司 | Lightweight spray carving mortar |
| CN106420411A (en) * | 2016-09-28 | 2017-02-22 | 济南大学 | Preparation method of long-acting rosin type natural botanical mosquito repellent liquid |
| CN109970425A (en) * | 2019-05-08 | 2019-07-05 | 深圳职业技术学院 | A kind of artistic sculpture lightweight mud and preparation method thereof |
-
2020
- 2020-02-17 CN CN202010098027.4A patent/CN111268989B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2311304T3 (en) * | 1998-08-14 | 2009-02-01 | Seagull Decor Co., Ltd. | METHOD FOR THE PRODUCTION OF A CERAMIC ORNAMENT COVERED DENSELY WITH DIMINARY EDGES AND CORNERS. |
| CN1463284A (en) * | 2001-03-16 | 2003-12-24 | 山室敏之 | Lightweight clay and mfg. method thereof |
| CN101348361A (en) * | 2007-07-17 | 2009-01-21 | 张文瑞 | Color handwork sculptures mud for student and manufacturing method thereof |
| CN103408707A (en) * | 2013-08-08 | 2013-11-27 | 中科院广州化学有限公司 | Amphiphilic crosslinkable fluorosilicon resin, water-borne coating and super-amphiphobic coating prepared through water-borne coating |
| CN105859235A (en) * | 2016-03-30 | 2016-08-17 | 广西盈益环保建材科技股份有限公司 | Clay sculpture material and preparation method thereof |
| CN106396541A (en) * | 2016-08-30 | 2017-02-15 | 派丽(上海)管理有限公司 | Lightweight spray carving mortar |
| CN106420411A (en) * | 2016-09-28 | 2017-02-22 | 济南大学 | Preparation method of long-acting rosin type natural botanical mosquito repellent liquid |
| CN109970425A (en) * | 2019-05-08 | 2019-07-05 | 深圳职业技术学院 | A kind of artistic sculpture lightweight mud and preparation method thereof |
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