CN111267412A - Environment-friendly high-adhesiveness packaging box outer film and manufacturing method thereof - Google Patents

Environment-friendly high-adhesiveness packaging box outer film and manufacturing method thereof Download PDF

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Publication number
CN111267412A
CN111267412A CN202010218299.3A CN202010218299A CN111267412A CN 111267412 A CN111267412 A CN 111267412A CN 202010218299 A CN202010218299 A CN 202010218299A CN 111267412 A CN111267412 A CN 111267412A
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China
Prior art keywords
film
packaging box
environment
friendly high
adhesiveness
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CN202010218299.3A
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Chinese (zh)
Inventor
柯志纯
陈宏源
柯建南
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Jinjiang Zhonghui Printing Packaging Co ltd
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Jinjiang Zhonghui Printing Packaging Co ltd
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Priority to CN202010218299.3A priority Critical patent/CN111267412A/en
Publication of CN111267412A publication Critical patent/CN111267412A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284Application of adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/14Printing or colouring
    • B32B38/145Printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/16Drying; Softening; Cleaning
    • B32B38/164Drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65HHANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H35/00Delivering articles from cutting or line-perforating machines; Article or web delivery apparatus incorporating cutting or line-perforating devices, e.g. adhesive tape dispensers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • B32B2250/242All polymers belonging to those covered by group B32B27/32

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  • Wrappers (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses an environment-friendly high-adhesiveness packaging box outer film and a manufacturing method thereof, and belongs to the technical field of BOPP outer films. This outer pad pasting of environment-friendly high adhesion packing carton includes from interior to exterior in proper order: the composite printing ink comprises an inner-layer pearly-luster BOPP film, an ink layer printed on the back of a matte BOPP film and the matte BOPP film, wherein the matte BOPP film is compounded with the inner-layer pearly-luster BOPP film through an adhesive, and the ink layer is formed by printing steaming-resistant ink. The outer film prepared by the invention is very suitable for being used as an outer film for food packaging, no decolorization and migration phenomena occur in the use process, and when the outer film is used as an outer film for a plastic packaging box, the outer film can be fused with the plastic packaging box into a whole, and the adhesion is excellent.

Description

Environment-friendly high-adhesiveness packaging box outer film and manufacturing method thereof
Technical Field
The invention belongs to the technical field of BOPP (biaxially-oriented polypropylene) external films, and particularly relates to an environment-friendly high-adhesion packaging box external film and a manufacturing method thereof.
Background
In recent years, the application of plastic films in packaging materials is rising year by year, and BOPP films, i.e. biaxially oriented polypropylene films, are widely applied in flexible packaging materials. Usually, before the surface of the BOPP film is printed or glued, the surface of the BOPP film needs to be subjected to corona treatment, so that a good printing effect can be achieved.
Traditional packing carton outer pad pasting is detachable with packing carton body, and the both ends of outer pad pasting pass through the gluing agent and adhere on the box body surface, can tear the pad pasting from the packing carton easily through external force, and this kind of outer pad pasting exists following not enough: firstly, the film is not suitable for being used as an external film of a high-end packaging box, and the aesthetic property needs to be improved; secondly, the environmental protection is not satisfactory, and the phenomena of decolorization and migration can occur in the using process.
Therefore, the research on the environment-friendly high-adhesion packaging box outer pasting film is very important.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide an environment-friendly high-adhesion packaging box outer film and a manufacturing method thereof.
The invention adopts the following technical scheme:
the invention provides an environment-friendly high-adhesiveness packaging box outer film, which sequentially comprises the following components from inside to outside: the composite printing ink comprises an inner-layer pearly-luster BOPP film, an ink layer printed on the back of a matte BOPP film and the matte BOPP film, wherein the matte BOPP film is compounded with the inner-layer pearly-luster BOPP film through an adhesive, and the ink layer is formed by printing steaming-resistant ink.
Still further, the retort resistant ink is an in-print retort resistant ink.
Furthermore, the steam-resistant ink needs to be diluted before printing, and the solvents used for dilution are n-propyl acetate, isopropyl acetate and n-butyl acetate according to the ratio of 5: 3: 2 by volume ratio.
Still further, the inner pearlescent BOPP film and the matte BOPP film should satisfy: longitudinal tensile strength ofLess than 90N/mm2Transverse tensile strength of not less than 190N/mm2The elongation at break in the machine direction is not less than 140% and the elongation at break in the transverse direction is not less than 40%.
The invention also provides a manufacturing method of the environment-friendly high-adhesiveness packaging box outer pasting film, which comprises the following steps:
step one, preparing printing ink: printing the film on the back of a matte BOPP film, and drying;
step two, compounding: continuously coating an adhesive on the back surface of the printed matte BOPP film, compounding the adhesive to the surface of the pearlescent BOPP film, and pre-drying to obtain a composite film;
step three, drying: and drying the composite film, standing to naturally cool the composite film, slitting and die cutting to obtain the environment-friendly high-adhesiveness packaging box outer pasting film.
Further, the temperature of the drying in the first step is 45-55 ℃.
Furthermore, the adhesive in the second step needs to be diluted by ethyl acetate before coating, and the dry coating amount of the adhesive is 3-4mg/m2
Further, the pre-baking in the second step is divided into four sections, which are specifically as follows: the first-stage temperature is 45-55 ℃, the second-stage temperature is 50-60 ℃, the third-stage temperature is 55-65 ℃, the fourth-stage temperature is 60-70 ℃, the drying speed is 90-110m/min, and the drying time is 6-10 s.
Furthermore, the temperature for drying in the third step is 50 ℃, and the drying time is 36 h.
The invention also provides application of the environment-friendly high-adhesiveness packaging box outer pasting film in a food packaging box, which comprises the following steps: and cutting the outer pasting film to a corresponding size, and pasting the outer pasting film to the outer surface of the food packaging box, wherein the temperature during pasting is 180-185 ℃, and the food packaging box is a PP box body.
Compared with the prior art, the invention has the following beneficial effects:
firstly, the method comprises the following steps: according to the invention, the boiling-resistant ink is diluted and blended, so that during printing, the matte BOPP film is not required to be subjected to corona treatment, a good printing effect can be obtained, and no decolorization phenomenon occurs in the subsequent use process;
secondly, the method comprises the following steps: the outer film prepared by the invention is very suitable for being used as an outer film for food packaging, no decolorization and migration phenomena occur in the use process, and when the outer film is used as an outer film for a plastic packaging box, the outer film can be fused with the plastic packaging box into a whole, the adhesion is excellent, and the high-quality appearance can be endowed to the packaging box.
Detailed Description
The present invention is described in further detail below by way of specific embodiments, but those skilled in the art will appreciate that the following examples are only illustrative of the present invention and should not be construed as limiting the scope of the present invention.
The inner printing boiling-resistant ink used by the invention is TLET series ink of Guangdong Tianlong ink GmbH, and comprises TLET436 original red, TLET210 white, TLET321 original yellow, TLET188 black, TLET551 original blue, TLET864 permanent violet, TLET724 orange and TLET642 color green respectively.
Example 1
The outer pad pasting of environment-friendly high adhesion packing carton includes from interior to exterior in proper order: the matt BOPP film is compounded with the matt BOPP film through an adhesive, wherein the ink layer is formed by printing inner-printed cooking-resistant ink, and the inner-layer pearlescent BOPP film and the matt BOPP film meet the following requirements: longitudinal tensile strength not less than 90N/mm2Transverse tensile strength of not less than 190N/mm2The elongation at break in the machine direction is not less than 140% and the elongation at break in the transverse direction is not less than 40%.
The manufacturing method of the environment-friendly high-adhesion packaging box outer pasting film comprises the following steps:
step one, preparing printing ink: mixing ink according to the color required by the pattern, diluting the inner printing steaming-resistant ink before printing, wherein the used solvents for dilution are n-propyl acetate, isopropyl acetate and n-butyl acetate according to the ratio of 5: 3: 2, printing the diluted inner printing steaming-resistant ink to the back of the matte BOPP film, and drying at 50 ℃;
step two, compounding: matte BOPP film after printingCoating adhesive on the back surface, compounding the adhesive on the surface of the pearly-luster BOPP film, and pre-drying the film, wherein the pre-drying is divided into four sections, and the method comprises the following steps: the first-stage temperature is 50 ℃, the second-stage temperature is 55 ℃, the third-stage temperature is 60 ℃, the fourth-stage temperature is 65 ℃, the drying speed is 100m/min, the drying time is 8s, and the composite film is obtained after pre-drying, wherein the adhesive needs to be diluted by ethyl acetate before coating, and the dry coating amount of the adhesive is 3.5mg/m2
Step three, drying: and drying the composite film at 50 ℃ for 36h, standing to naturally cool the composite film, slitting and die cutting to obtain the environment-friendly high-adhesion packaging box outer pasting film.
When the environment-friendly high-adhesiveness packaging box outer film disclosed by the invention is attached to a PP food packaging box, the specific steps are as follows: cutting the outer pasting film to a corresponding size, and pasting the outer pasting film to the outer surface of the food packaging box, wherein the temperature during pasting is 180 ℃.
Example 2
The outer pad pasting of environment-friendly high adhesion packing carton includes from interior to exterior in proper order: the matt BOPP film is compounded with the matt BOPP film through an adhesive, wherein the ink layer is formed by printing inner-printed cooking-resistant ink, and the inner-layer pearlescent BOPP film and the matt BOPP film meet the following requirements: longitudinal tensile strength not less than 90N/mm2Transverse tensile strength of not less than 190N/mm2The elongation at break in the machine direction is not less than 140% and the elongation at break in the transverse direction is not less than 40%.
The manufacturing method of the environment-friendly high-adhesion packaging box outer pasting film comprises the following steps:
step one, preparing printing ink: mixing ink according to the color required by the pattern, diluting the inner printing steaming-resistant ink before printing, wherein the used solvents for dilution are n-propyl acetate, isopropyl acetate and n-butyl acetate according to the ratio of 5: 3: 2, printing the diluted inner printing steaming-resistant ink to the back of the matte BOPP film, and drying at 45 ℃;
step two, compounding: continuously coating adhesive on the back of the printed matte BOPP filmCompounding the pearl BOPP film on the surface of a pearl BOPP film, and pre-drying the pearl BOPP film, wherein the pre-drying is divided into four sections, and the four sections are as follows: the first-stage temperature is 45 ℃, the second-stage temperature is 50 ℃, the third-stage temperature is 55 ℃, the fourth-stage temperature is 60 ℃, the drying speed is 90m/min, the drying time is 10s, and the composite film is obtained after pre-drying, wherein the adhesive needs to be diluted by ethyl acetate before coating, and the dry coating amount of the adhesive is 3mg/m2
Step three, drying: and drying the composite film at 50 ℃ for 36h, standing to naturally cool the composite film, slitting and die cutting to obtain the environment-friendly high-adhesion packaging box outer pasting film.
When the environment-friendly high-adhesiveness packaging box outer film disclosed by the invention is attached to a PP food packaging box, the specific steps are as follows: cutting the outer pasting film to a corresponding size, and pasting the outer pasting film to the outer surface of the food packaging box, wherein the temperature during pasting is 180-185 ℃.
Example 3
The outer pad pasting of environment-friendly high adhesion packing carton includes from interior to exterior in proper order: the matt BOPP film is compounded with the matt BOPP film through an adhesive, wherein the ink layer is formed by printing inner-printed cooking-resistant ink, and the inner-layer pearlescent BOPP film and the matt BOPP film meet the following requirements: longitudinal tensile strength not less than 90N/mm2Transverse tensile strength of not less than 190N/mm2The elongation at break in the machine direction is not less than 140% and the elongation at break in the transverse direction is not less than 40%.
The manufacturing method of the environment-friendly high-adhesion packaging box outer pasting film comprises the following steps:
step one, preparing printing ink: mixing ink according to the color required by the pattern, diluting the inner printing steaming-resistant ink before printing, wherein the used solvents for dilution are n-propyl acetate, isopropyl acetate and n-butyl acetate according to the ratio of 5: 3: 2, printing the diluted inner printing steaming-resistant ink to the back of the matte BOPP film, and drying at 55 ℃;
step two, compounding: continuously coating adhesive on the back of the printed matte BOPP film, and compounding the adhesive to the pearly lusterAnd (3) pre-drying the surface of the BOPP film, wherein the pre-drying is divided into four sections, and the method comprises the following steps: the first-stage temperature is 55 ℃, the second-stage temperature is 60 ℃, the third-stage temperature is 65 ℃, the fourth-stage temperature is 70 ℃, the drying speed is 110m/min, the drying time is 6s, and the composite film is obtained after pre-drying, wherein the adhesive needs to be diluted by ethyl acetate before coating, and the dry coating amount of the adhesive is 4mg/m2
Step three, drying: and drying the composite film at 50 ℃ for 36h, standing to naturally cool the composite film, slitting and die cutting to obtain the environment-friendly high-adhesion packaging box outer pasting film.
When the environment-friendly high-adhesiveness packaging box outer film disclosed by the invention is attached to a PP food packaging box, the specific steps are as follows: cutting the outer pasting film to a corresponding size, and pasting the outer pasting film to the outer surface of the food packaging box, wherein the temperature during pasting is 180-185 ℃.
In the specific printing, the black ink was diluted to a viscosity of 14. + -.1 s, the gold ink was diluted to a viscosity of 16. + -.1 s, the red ink was diluted to a viscosity of 15. + -.1 s, the violet ink was diluted to a viscosity of 16. + -.1 s, and the viscosity was measured using a # 3 Chuien cup.
The test results of the external film for the environment-friendly high-adhesion packaging box prepared in the embodiment 1 of the invention are shown as follows:
1. sensory requirements
The test method comprises the following steps: GB 4806.7-2016 food safety national standard food contact plastic material and product
TABLE 1 test results
Test items Results Method detection limit Limit value Unit of
Sense organ Meets the standard requirements -- Normal color, no abnormal odor, dirty objects, etc --
Soaking liquid Meets the standard requirements -- The soaking solution obtained by migration test has no organoleptic deterioration such as turbidity, precipitate, and foreign odor --
2. The total migration volume and the test method are as follows: GB 31604.1-2015 & GB 31604.8-2016
Food simulant: 10% ethanol; detection conditions are as follows: 40 ℃, 10d, results are given in the following table:
TABLE 2 test results
Test items Results Method detection limit Limit value Unit of
Total migration volume N.D. 20.0 60 mg/kg
3. Potassium permanganate consumption, test method: GB 31604.2-2016
Food simulant: water; detection conditions are as follows: 60 ℃, 2h, the results are given in the following table:
TABLE 3 test results
Test items Results Method detection limit Limit value Unit of
Consumption of potassium permanganate N.D. 1.0 10 mg/kg
4. Heavy metals (in Pb), test method: GB 31604.9-2016
Food simulant: 4% acetic acid; detection conditions are as follows: 60 ℃, 2h, the results are given in the following table:
TABLE 4 test results
Test items Results Method detection limit Limit value Unit of
Lead (Pb) <1 -- 1 mg/kg
5. Decolorization test, test method: GB 31604.7-2016, with the results given in the following Table:
TABLE 5 test results
Test items Results Method detection limit Limit value Unit of
Rub test-65% ethanol Negative of -- Negative of --
Rub test-vegetable oil Negative of -- Negative of --
Soaking liquid Negative of -- Negative of --
6. Phthalate, test method: GB 31604.30-2016, with the results given in the following Table:
TABLE 6 test results
Test items Results Method detection limit Unit of
Dimethyl phthalate (DMP) N.D. 5 mg/kg
Phthalic acid Diethyl Ester (DEP) N.D. 5 mg/kg
Diisobutyl phthalate (DIBP) N.D. 5 mg/kg
Di-n-butyl phthalate (DBP) N.D. 5 mg/kg
Bis (2-methoxy) ethyl phthalate (DMEP) N.D. 5 mg/kg
Bis (4-methyl-2-pentyl) phthalate (BMPP) N.D. 5 mg/kg
Bis (2-ethoxy) ethyl phthalate (DEEP) N.D. 5 mg/kg
Diamyl phthalate (DPP) N.D. 5 mg/kg
Dihexyl phthalate (DHXP) N.D. 5 mg/kg
Butyl Benzyl Phthalate (BBP) N.D. 5 mg/kg
Bis (2-butoxy) ethyl phthalate (DBEP) N.D. 5 mg/kg
Dicyclohexyl phthalate (DCHP) N.D. 5 mg/kg
Di (2-ethyl) hexyl phthalate (DEHP) N.D. 5 mg/kg
Diphenyl phthalate (DBhP) N.D. 5 mg/kg
Di-n-octyl phthalate (DNOP) N.D. 5 mg/kg
Dinonyl phthalate (DNP) N.D. 5 mg/kg
Diisononyl phthalate (DINP) N.D. 50 mg/kg
Diallyl phthalate (DAP) N.D. 5 mg/kg
Note: n.d. = undetected (less than method detection limit).
mg/kg = ppm = parts per million.
The laboratory soaking mode is single-side soaking, and S/V (area/volume) is 6.0dm2/L。
The result of the migration test is the test result of the first soaking.
The above-mentioned embodiments are merely preferred embodiments for fully illustrating the present invention, and the scope of protection is not limited thereto. The equivalents and modifications of the present invention which may occur to those skilled in the art are within the scope of the present invention as defined by the appended claims.

Claims (10)

1. The outer pad pasting of environment-friendly high adhesion packing carton, its characterized in that includes from interior to exterior in proper order: the composite printing ink comprises an inner-layer pearly-luster BOPP film, an ink layer printed on the back of a matte BOPP film and the matte BOPP film, wherein the matte BOPP film is compounded with the inner-layer pearly-luster BOPP film through an adhesive, and the ink layer is formed by printing steaming-resistant ink.
2. The exterior film for environment-friendly high-adhesion packaging boxes according to claim 1, wherein said boiling-resistant ink is an inner-printed boiling-resistant ink.
3. The environment-friendly high-adhesiveness packaging box outer film according to claim 1, wherein the steam-resistant ink is diluted before printing, and the solvents used for dilution are n-propyl acetate, isopropyl acetate and n-butyl acetate, and the ratio of the solvent to the solvent is 5: 3: 2 by volume ratio.
4. The environment-friendly high-adhesiveness packaging box outer film according to claim 1, wherein the inner pearlescent BOPP film and the matte BOPP film are such that: longitudinal tensile strength not less than 90N/mm2Transverse tensile strength of not less than 190N/mm2The elongation at break in the machine direction is not less than 140% and the elongation at break in the transverse direction is not less than 40%.
5. The method for manufacturing the external adhesive film for the environment-friendly high-adhesiveness packaging box according to claim 1, comprising the steps of:
step one, preparing printing ink: printing the film on the back of a matte BOPP film, and drying;
step two, compounding: continuously coating an adhesive on the back surface of the printed matte BOPP film, compounding the adhesive to the surface of the pearlescent BOPP film, and pre-drying to obtain a composite film;
step three, drying: and drying the composite film, standing to naturally cool the composite film, slitting and die cutting to obtain the environment-friendly high-adhesiveness packaging box outer pasting film.
6. The method for manufacturing the exterior coating film for the environment-friendly high-adhesiveness packaging box according to claim 5, wherein the temperature for drying in the first step is 45-55 ℃.
7. The method for manufacturing the environment-friendly high-adhesiveness packaging box outer film according to claim 5, wherein the adhesive in the second step needs to be diluted with ethyl acetate before coating, and the dry coating amount of the adhesive is 3-4mg/m2
8. The method for manufacturing the external adhesive film of the environment-friendly high-adhesiveness packaging box according to claim 5, wherein the pre-baking in the second step is divided into four sections, specifically as follows: the first-stage temperature is 45-55 ℃, the second-stage temperature is 50-60 ℃, the third-stage temperature is 55-65 ℃, the fourth-stage temperature is 60-70 ℃, the drying speed is 90-110m/min, and the drying time is 6-10 s.
9. The method for manufacturing the environment-friendly high-adhesiveness packaging box outer film according to claim 5, wherein the temperature in the step three is 50 ℃ and the drying time is 36 hours.
10. The use of the exterior coating film for an environmentally friendly high adhesion packaging box according to claim 1 in a food packaging box, characterized by comprising the steps of: and cutting the outer pasting film to a corresponding size, and pasting the outer pasting film to the outer surface of the food packaging box, wherein the temperature during pasting is 180-185 ℃, and the food packaging box is a PP box body.
CN202010218299.3A 2020-03-25 2020-03-25 Environment-friendly high-adhesiveness packaging box outer film and manufacturing method thereof Pending CN111267412A (en)

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