CN106349810A - Environment-friendly steam-resisting printing ink - Google Patents

Environment-friendly steam-resisting printing ink Download PDF

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Publication number
CN106349810A
CN106349810A CN201610711051.4A CN201610711051A CN106349810A CN 106349810 A CN106349810 A CN 106349810A CN 201610711051 A CN201610711051 A CN 201610711051A CN 106349810 A CN106349810 A CN 106349810A
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CN
China
Prior art keywords
environment
ink
steaming
resin
resistance
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Pending
Application number
CN201610711051.4A
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Chinese (zh)
Inventor
彭文表
罗丽华
简葵宝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGDONG DEKANG CHEMISTRY INDUSTRY Co Ltd
Original Assignee
GUANGDONG DEKANG CHEMISTRY INDUSTRY Co Ltd
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Priority to CN201610711051.4A priority Critical patent/CN106349810A/en
Publication of CN106349810A publication Critical patent/CN106349810A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses environment-friendly steam-resisting printing ink. The environment-friendly steam-resisting printing ink is prepared from the following ingredients in percentage by weight: 5 to 40 percent of DK163 resin, 5 to 20 percent of ternary vinyl chloride and vinyl acetate copolymer liquid, 5 to 30 percent of pigment, 0.1 to 2 percent of dispersion agent, 0.1 to 3 percent of wax powder, 0.1 to 5 percent of adhesion promoter, 0 to 2 percent of extinction powder, 0 to 2 percent of antistatic agent, 5 to 40 percent of acetic ether, 5 to 20 percent of isopropanol and 1 to 5 percent of propylene glycol methyl ether acetate. According to the environment-friendly steam-resisting printing ink disclosed by the invention, the DK163 resin, the ternary vinyl chloride and vinyl acetate copolymer liquid and the adhesion promoter are selected for carrying out scientific matching, active groups of the DK163 resin, the ternary vinyl chloride and vinyl acetate copolymer liquid and the adhesion promoter can be in cross-linking combination under the catalysis of gentle heating in a drying process after ink printing, the environment-friendly steam-resisting printing ink has very good adhesion and mechanical strength on treated OPP (O-Phenyl Phenol)/PET (Poly Ethylene Terephthalate)/NL and can be steamed for 30 minutes at a high temperature of 121 to 126 DEG C, and a product is environmentally friendly, is steam-resisting and has strong printing adaptability.

Description

A kind of environment-friendly type printing-ink of resistance to steaming and decocting
Technical field
The present invention relates to a kind of environment-friendly type printing-ink of resistance to steaming and decocting
Background technology
The resistance to anti-boiling ink in market easily produces color bleeding migration after experience high temperature steaming now, and composite bed is easily shelled From phenomenon.Cause product unqualified.Because being now loaded with packing material, cause economic loss quite serious.High temperature bleeding is moved Move, the compound appearance main cause peeled off is that ink vehicle high temperature strength is good long caused.Present invention is generally directed to market is resistance to The problem that anti-boiling ink exists, in ink vehicle key breakthrough, develops the high temperature printing-ink of resistance to steaming and decocting of excellent performance, with Adapt to the needs in market.
Content of the invention
The purpose of the present invention is: provides a kind of environment-friendly type printing-ink of resistance to steaming and decocting, it has splendid intensity, boiling resistance And printing adaptability.
The present invention be achieved in that a kind of environment-friendly type printing-ink of resistance to steaming and decocting it is characterised in that: its formula composition weight Amount percentage ratio is:
A kind of described environment-friendly type printing-ink of resistance to steaming and decocting, it is characterized in that its preparation method as follows:
Dk163 resin, ternary chlorine vinegar resin liquid, isopropanol, propylene glycol methyl ether acetate are pressed the 50% of formula ratio and put into Pot in, open stirring, pigment, dispersant and wax powder put into pot in, stirring 15 minutes, with sand mill material be dispersed to fineness≤ 10 microns;
Then remaining all material put into pot in, stir (about 20-30 minute) regulate viscosity and form and aspect, warp Detection is qualified to use 120 mesh gauzes to filter, and is packaged into finished product.
Described dk163 resin, is our company's patent of invention " a kind of environment-friendly type link stuff of resistance to anti-boiling ink and its preparation side The product (patent No.: zl201310251490.8) of method ", this resin is substantially the pu resin of modified environment-friendly type, by weighing as follows The raw material of amount degree is prepared from;Polyether polyol 16-30%;Polyhydroxy resin 0-16%, diisocyanate 1- 25%, chain extender 0.5-5%, solvent 40-75%, this Environment-friendlysteaming/boiling-resinkant steaming/boiling-resinkant inkant vehicle, it is obtained by following technical process: PEPA and polyhydroxy resin, open stirring, add diisocyanate, control temperature to be reacted in 50-160 DEG C of interval Nco content≤8% to system, adds chain extender to control temperature 110-120 DEG C to react 1 hour, is then cooled to 80 DEG C, plus Enter solvent dilution, that is, obtain the environment-friendly type link stuff of resistance to anti-boiling ink (dk163 resin).
A kind of described environment-friendly type printing-ink of resistance to steaming and decocting, it is characterized in that described ternary chlorine vinegar resin liquid is ternary Vinyl chloride-vinyl acetate resin content is 20% solution, and ternary chlorine vinegar resin is that Japanese bracelet deep pool chemistry is produced, model t5hx trihydroxylic chlorine Vinegar resin.
Described pigment is red, yellow, blue, white, black, one kind therein;
A kind of described environment-friendly type printing-ink of resistance to steaming and decocting, it is characterized in that the described environment-friendly type printing-ink of resistance to steaming and decocting, Its fineness≤10 micron, can be in 121-126 DEG C of steaming and decocting 30 minutes, for the packaging for foodstuff printing of the resistance to steaming and decocting of high temperature.
A kind of described environment-friendly type printing-ink of resistance to steaming and decocting, it is characterized in that the ink through printing, at 50-80 DEG C Temperature range, described adhesion promoter and dk163 resin, ternary chlorine vinegar resin and stock can crosslinked chelate each other, carry High mechanical properties and adhesive force, improve ink intensity and boiling resistance energy.
Ternary chlorine vinegar resin is that Japanese bracelet deep pool chemistry is produced, model: t5hx trihydroxylic vinyl chloride-vinyl acetate resin.
Described adhesion promoter is that splendidness Chemical Co., Ltd. of Zhongshan city produces;Model: fcmap801 adhesive force promotes Agent;
24000 dispersants that described dispersant is produced for U.S. Lu Borun;
Described wax powder is Clariant chemical industry (Switzerland) company limited product, model: 3620 waxes;
Described antistatic additive is that SANYO GS chemical conversion industry Co., Ltd. produces, model: ae-2 antistatic additive.
A kind of environment-friendly type printing-ink of resistance to steaming and decocting, with our company's patent of invention product dk163 resin for main link stuff, with Ternary chlorine vinegar resin and additive compatibility, it has splendid intensity, boiling resistance and printing adaptability.
Specific embodiment:
With reference to embodiment, the invention will be further described.
Embodiment 1
A kind of environment-friendly type printing-ink of resistance to steaming and decocting, hundred parts by weight are obtained by following components than meter:
Described pigment is primary color red.
Dk163 resin, ternary chlorine vinegar resin liquid, isopropanol, propylene glycol methyl ether acetate are pressed the 50% of formula ratio and put into Pot in, open stirring, pigment, dispersant and wax powder put into pot in, stirring 15 minutes, with sand mill material be dispersed to fineness≤ 10 microns;
Then dk163 resin and ternary chlorine vinegar resin liquid, isopropanol, the 40% of propylene glycol methyl ether acetate total amount, face Material, dispersant, wax powder, adhesion promoter, flatting silica and antistatic additive put in pot, and 20-30 minute is stirred in stirring, with remaining Remaining isopropanol, propylene glycol methyl ether acetate regulate viscosity and form and aspect, after testing qualified use 120 mesh gauzes filter, be packaged into Finished product.
Isopropanol during the described environment-friendly type printing-ink of resistance to steaming and decocting dilution, its nontoxic taste is little, is environment-friendly type solvent.
Using isopropanol as diluent when being used.
Dk163 resin used, the preparation method of its composition comprises the steps: polyether polyol 16-30%, polyhydroxy tree Fat 0-16%, diisocyanate 1-25%, chain extender 0.5-5%, solvent 40-75%.PEPA and hydroxy resin are two In the presence of isocyanates, react nco content≤8% to system between 50-160 DEG C, add chain extender control temperature in 110-120 DEG C is reacted 1 hour, is then cooled to 80 DEG C, adds solvent dilution, filters through 120 mesh gauzes, obtains final product dk163 resin (Environment-friendlysteaming/boiling-resinkant steaming/boiling-resinkant inkant vehicle).
Embodiment 2
A kind of environment-friendly type printing-ink of resistance to steaming and decocting, the percentage by weight of its composition is:
Described pigment is Rutile type titanium dioxide.
Dk163 resin, ternary chlorine vinegar resin liquid, isopropanol, propylene glycol methyl ether acetate are pressed the 50% of formula ratio and put into Pot in, open stirring, pigment, dispersant and wax powder put into pot in, stirring 25 minutes, with sand mill material be dispersed to fineness≤ 10 microns;
Then dk163 resin and ternary chlorine vinegar resin liquid, isopropanol, the 40% of propylene glycol methyl ether acetate total amount, face Material, dispersant, wax powder, adhesion promoter, flatting silica and antistatic additive put in pot, and 20-30 minute is stirred in stirring, with remaining Remaining isopropanol, propylene glycol methyl ether acetate regulate viscosity and form and aspect, after testing qualified use 120 mesh gauzes filter, be packaged into Finished product.
Ink through printing, in 50-80 DEG C of temperature range, described adhesion promoter and dk163 resin, ternary chlorine vinegar Resin and stock each other can crosslinked integration, improve mechanical strength and adhesive force, raising ink intensity and boiling resistance energy.
The described environment-friendly type printing-ink of resistance to steaming and decocting, isopropanol during dilution, its taste is little, is environment-friendly type solvent.
Described dk163 resin is it is characterized in that its composition and preparation method comprise the steps: the liquor-saturated 16- of polyether polyols 30%, polyhydroxy resin 0-16%, diisocyanate 1-25%, chain extender 0.5-5%, solvent 40-75%, polyether polyol and Hydroxy resin, in the presence of diisocyanate, reacted nco content≤8% to system before 50-160 DEG C, added chain extension Agent controls temperature to react 1 hour in 110-120 DEG C, is then cooled to 80 DEG C, adds solvent dilution, filters through 120 mesh gauzes, that is, Obtain dk163 resin (Environment-friendlysteaming/boiling-resinkant steaming/boiling-resinkant inkant vehicle).
Embodiment 3
A kind of environment-friendly type printing-ink of resistance to steaming and decocting, the percentage by weight of its composition is:
Dk163 resin, ternary chlorine vinegar resin liquid, isopropanol, propylene glycol methyl ether acetate are pressed the 50% of formula ratio and put into Pot in, open stirring, pigment, dispersant and wax powder put into pot in, stirring 15 minutes, with sand mill material be dispersed to fineness≤ 10 microns;
Then dk163 resin and ternary chlorine vinegar resin liquid, isopropanol, the 40% of propylene glycol methyl ether acetate total amount, face Material, dispersant, wax powder, adhesion promoter, flatting silica and antistatic additive put in pot, and 20-30 minute is stirred in stirring, with remaining Remaining isopropanol, propylene glycol methyl ether acetate regulate viscosity and form and aspect, after testing qualified use 120 mesh gauzes filter, be packaged into Finished product.
Described pigment is transparent yellow.
Embodiment 4
A kind of environment-friendly type printing-ink of resistance to steaming and decocting, the percentage by weight of its composition is:
Dk163 resin, ternary chlorine vinegar resin liquid, isopropanol, propylene glycol methyl ether acetate are pressed the 50% of formula ratio and put into Pot in, open stirring, pigment, dispersant and wax powder put into pot in, stirring 15 minutes, with sand mill material be dispersed to fineness≤ 10 microns;
Then dk163 resin and ternary chlorine vinegar resin liquid, isopropanol, the 40% of propylene glycol methyl ether acetate total amount, face Material, dispersant, wax powder, adhesion promoter, flatting silica and antistatic additive put in pot, and 20-30 minute is stirred in stirring, with remaining Remaining isopropanol, propylene glycol methyl ether acetate regulate viscosity and form and aspect, after testing qualified use 120 mesh gauzes filter, be packaged into Finished product.
Described pigment is phthalocyanine blue.
Above-described is only the mode of priority of the present invention it is noted that for those of ordinary skill in the art For, without departing from the principles of the present invention, some improvement and modification also can be made, this is also considered as the protection model of the present invention Enclose.

Claims (10)

1. a kind of environment-friendly type printing-ink of resistance to steaming and decocting it is characterised in that: its formula composition percentage by weight be:
2. according to claim 1 a kind of environment-friendly type printing-ink of resistance to steaming and decocting it is characterised in that: its preparation method presses following walking Rapid:
Dk163 resin, ternary chlorine vinegar resin liquid, isopropanol, propylene glycol methyl ether acetate are pressed in 50% input pot of formula ratio, Open stirring, pigment, dispersant and wax powder are put in pot, stirs 15 minutes, with sand mill, material is dispersed to fineness≤10 micro- Rice;
Then remaining all material is put in pot, stir (about 20-30 minute), regulates viscosity and form and aspect, through inspection Survey is qualified to use 120 mesh gauzes to filter, and is packaged into finished product.
3. according to claim 1 a kind of environment-friendly type printing-ink of resistance to steaming and decocting it is characterised in that:
Described dk163 resin is the pu resin of modified environment-friendly type, is prepared from by the raw material of following weight percent content; Polyether polyol 16-30%;Polyhydroxy resin 0-16%, diisocyanate 1-25%, chain extender 0.5-5%, solvent 40- 75%, this Environment-friendlysteaming/boiling-resinkant steaming/boiling-resinkant inkant vehicle, it is obtained by following technical process: PEPA and polyhydroxy resin, open Open stirring, add diisocyanate, control nco content≤8% that temperature is reacted to system in 50-160 DEG C of interval, plus Entering chain extender controls temperature 110-120 DEG C to react 1 hour, is then cooled to 80 DEG C, adds solvent dilution, that is, obtain environment-friendly type The link stuff of resistance to anti-boiling ink.
4. according to claim 1 a kind of environment-friendly type printing-ink of resistance to steaming and decocting it is characterised in that: described ternary chlorine vinegar resin liquid The solution being 20% for ternary chlorine vinegar resin content, i.e. model t5hx trihydroxylic vinyl chloride-vinyl acetate resin.
5. according to claim 1 a kind of environment-friendly type printing-ink of resistance to steaming and decocting it is characterised in that: described pigment be red, yellow, Blue, white, black, one kind therein.
6. according to claim 1 a kind of environment-friendly type printing-ink of resistance to steaming and decocting it is characterised in that: through printing ink, in 50- 80 DEG C of temperature range, described adhesion promoter and dk163 resin, ternary chlorine vinegar resin and stock each other can crosslinked chelas Conjunction, improve mechanical strength and adhesive force, improve ink intensity and boiling resistance energy, and described adhesion promoter is model: Fcmap801 adhesion promoter.
7. according to claim 1 a kind of environment-friendly type printing-ink of resistance to steaming and decocting it is characterised in that: described dispersant be 24000 Dispersant.
8. according to claim 1 a kind of environment-friendly type printing-ink of resistance to steaming and decocting it is characterised in that: described wax powder be 3620 waxes.
9. according to claim 1 a kind of environment-friendly type printing-ink of resistance to steaming and decocting it is characterised in that: described antistatic additive be ae-2 Antistatic additive.
10. according to claim 1 a kind of environment-friendly type printing-ink of resistance to steaming and decocting it is characterised in that: its fineness≤10 micron, can In 121-126 DEG C of steaming and decocting 30 minutes, for the packaging for foodstuff printing of the resistance to steaming and decocting of high temperature.
CN201610711051.4A 2016-08-24 2016-08-24 Environment-friendly steam-resisting printing ink Pending CN106349810A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111087571A (en) * 2019-12-27 2020-05-01 黄山中泽新材料有限公司 Solvent-resistant diluted polyurethane ink binder and preparation method and application thereof
CN111253797A (en) * 2020-03-31 2020-06-09 英科﹒卡乐油墨(苏州)有限公司 OPP water mark alkali-resistant environment-friendly printing ink
CN111267412A (en) * 2020-03-25 2020-06-12 晋江市中辉印刷包装有限公司 Environment-friendly high-adhesiveness packaging box outer film and manufacturing method thereof
CN112694787A (en) * 2020-12-28 2021-04-23 黄山新力油墨科技有限公司 High-scratch-resistance plastic surface printing delustering oil and preparation method thereof
CN114958084A (en) * 2022-07-01 2022-08-30 浙江浦江永进工贸有限公司 Preparation method of low-viscosity high-solid-content anti-fouling composite ink for flexography

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111087571A (en) * 2019-12-27 2020-05-01 黄山中泽新材料有限公司 Solvent-resistant diluted polyurethane ink binder and preparation method and application thereof
CN111267412A (en) * 2020-03-25 2020-06-12 晋江市中辉印刷包装有限公司 Environment-friendly high-adhesiveness packaging box outer film and manufacturing method thereof
CN111253797A (en) * 2020-03-31 2020-06-09 英科﹒卡乐油墨(苏州)有限公司 OPP water mark alkali-resistant environment-friendly printing ink
CN112694787A (en) * 2020-12-28 2021-04-23 黄山新力油墨科技有限公司 High-scratch-resistance plastic surface printing delustering oil and preparation method thereof
CN114958084A (en) * 2022-07-01 2022-08-30 浙江浦江永进工贸有限公司 Preparation method of low-viscosity high-solid-content anti-fouling composite ink for flexography
CN114958084B (en) * 2022-07-01 2023-09-29 浙江浦江永进工贸有限公司 Preparation method of low-viscosity high-solid-content anti-offset composite ink for flexography

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