CN111249872A - Two-section type circulating fluidized bed desulfurization system and desulfurization process - Google Patents

Two-section type circulating fluidized bed desulfurization system and desulfurization process Download PDF

Info

Publication number
CN111249872A
CN111249872A CN202010092924.4A CN202010092924A CN111249872A CN 111249872 A CN111249872 A CN 111249872A CN 202010092924 A CN202010092924 A CN 202010092924A CN 111249872 A CN111249872 A CN 111249872A
Authority
CN
China
Prior art keywords
tower
ascending
flue gas
bag
desulfurization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010092924.4A
Other languages
Chinese (zh)
Inventor
马鸿良
杨超玉
潘峰
杨春振
高秀丽
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Shenhua Shanda Energy and Environment Co Ltd
Original Assignee
Shandong Shenhua Shanda Energy and Environment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shandong Shenhua Shanda Energy and Environment Co Ltd filed Critical Shandong Shenhua Shanda Energy and Environment Co Ltd
Priority to CN202010092924.4A priority Critical patent/CN111249872A/en
Publication of CN111249872A publication Critical patent/CN111249872A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/02Particle separators, e.g. dust precipitators, having hollow filters made of flexible material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/02Particle separators, e.g. dust precipitators, having hollow filters made of flexible material
    • B01D46/04Cleaning filters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/507Sulfur oxides by treating the gases with other liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/508Sulfur oxides by treating the gases with solids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/06Arrangements of devices for treating smoke or fumes of coolers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28CHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA COME INTO DIRECT CONTACT WITHOUT CHEMICAL INTERACTION
    • F28C3/00Other direct-contact heat-exchange apparatus
    • F28C3/06Other direct-contact heat-exchange apparatus the heat-exchange media being a liquid and a gas or vapour
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention belongs to the field of flue gas treatment, and provides a two-section type circulating fluidized bed desulfurization system and a desulfurization process in order to solve the problems of high arrangement elevation of a desulfurization system, large and complex support structure amount and large running resistance of a desulfurization tower. The desulfurization system comprises a desulfurization tower and a desulfurizer bin; the desulfurizing tower comprises an ascending tower and a descending tower, and the top of the ascending tower is communicated with the top of the descending tower; the desulfurizing agent bin is communicated with the Venturi section connected with the bottom of the ascending tower and the top of the descending tower respectively and is used for adding a desulfurizing agent into the desulfurizing tower from the Venturi section of the ascending tower and the top of the descending tower respectively.

Description

Two-section type circulating fluidized bed desulfurization system and desulfurization process
Technical Field
The invention belongs to the field of flue gas treatment, and particularly relates to a two-section type circulating fluidized bed desulfurization system and a desulfurization process.
Background
The statements in this section merely provide background information related to the present disclosure and may not necessarily constitute prior art.
The semidry desulfurization process of the circulating fluidized bed is one of the main flue gas desulfurization and dust removal processes at present, and is a main way for realizing ultralow emission of flue gas. The main equipment of the process is a circulating fluidized bed desulfurization tower and a dust remover, and the working principle is that flue gas flows through a Venturi tube of the circulating fluidized bed desulfurization tower, a desulfurizing agent and externally circulating desulfurization ash are fluidized and sent into the desulfurization tower, and desulfurization semi-dry type washing reaction is carried out. And large-particle desulfurization ash in the high ash-containing flue gas flows back into the desulfurization tower at the top of the desulfurization tower to form an internal circulation mode of the desulfurization ash. The desulfurized fly ash separated from the flue gas by the dust remover after passing through the desulfurizing tower is returned to the Venturi tube of the desulfurizing tower by the conveying device of the fly ash circulating system, so that an external circulating mode of the desulfurized fly ash is formed, namely the desulfurized fly ash of the external circulating mode. The flue gas firstly enters a desulfurizing tower, is subjected to desulfurization reaction in the desulfurizing tower, and is discharged after being dedusted by a bag-type deduster.
At present, the form of a circulating fluidized bed desulfurizing tower is mostly an ascending empty tower structure, namely, the lower part of the tower is a flue gas inlet, the upper part of the tower is a flue gas outlet, the flow velocity of flue gas in the tower is generally designed to be about 5 m/s, and the retention time of the flue gas in the tower is 5-6 s. The ascending tower has the advantages that in the process that the desulfurization ash in the tower flows upwards along with the flue gas, the desulfurization ash falls back into the tower from the top part of the tower due to gravity to form internal circulation of the desulfurization ash, so that the ash concentration in the tower is increased; however, the inventor finds that the upward hollow tower structure has the defects that the reaction section of the tower body is higher, usually reaching 30 meters, so that the arrangement elevation of the whole system is increased, the support structure is large and complex, and the running resistance of the desulfurizing tower is large.
Disclosure of Invention
In order to solve the above problems, a first aspect of the present invention provides a two-stage circulating fluidized bed desulfurization system, which utilizes the advantage of high concentration of materials in an ascending tower and the advantage of high contact probability between fresh materials and sulfur dioxide in a descending tower, reduces the height of the tower and improves the overall utilization rate of the desulfurizing agent under the condition of ensuring the same residence time of flue gas.
In order to achieve the purpose, the invention adopts the following technical scheme:
a two-section type circulating fluidized bed desulfurization system comprises a desulfurization tower and a desulfurizer bin;
the desulfurizing tower comprises an ascending tower and a descending tower, and the top of the ascending tower is communicated with the top of the descending tower; the flue gas enters the ascending tower from the bottom of the ascending tower, flows upwards along the ascending tower, enters the top of the descending tower from the top of the ascending tower and is finally discharged from the bottom of the descending tower;
the desulfurizing agent bin is communicated with the top of the venturi section and the top of the descending tower of the ascending tower respectively and is used for adding a desulfurizing agent into the desulfurizing tower from the top of the venturi section and the top of the descending tower of the ascending tower respectively; the flue gas reacts with a desulfurizer in the desulfurizing tower to generate desulfurized ash, and part of the desulfurized ash carried by the flue gas reflows into the ascending tower from the top of the ascending tower due to gravity and inertia sedimentation to become internally-circulated desulfurized ash; and the other part of the desulfurized ash is discharged from the bottom of the descending tower along with the flue gas.
In one embodiment, the bottom of the downer is also connected to a dust separator.
As an embodiment, the dust remover is a bag-type dust remover.
As an implementation mode, the desulfurizing agent is discharged from the bottom of the descending tower along with the flue gas and enters the bag-type dust remover, the desulfurizing agent is captured by the bag-type dust remover, a desulfurizing ash filter cake section is formed on the surface of a filter bag, and the flue gas flowing through the bag-type dust remover is continuously desulfurized.
The filter cake has the advantages that the filter cake has a better desulfurization effect when smoke passes through due to higher content of the fresh desulfurizer, and the desulfurization effect of the whole two-section type circulating fluidized bed desulfurization system is improved.
As an implementation mode, the desulfurization ash discharged from the bottom of the descending tower along with the flue gas enters a bag-type dust remover, and the desulfurization ash is filtered by the bag-type dust remover and then is returned to the Venturi section of the ascending tower.
As an implementation mode, the position of the desulfurization ash returned to the venturi section of the ascending tower after being filtered by the bag-type dust collector is set as a first position; the position of the desulfurizer added into the Venturi section of the ascending tower is set as a second position; the first position is the same height as the second position.
As an implementation mode, an atomization device is further arranged at the bottom of the ascending tower and above the venturi section, and the atomization device is used for atomizing humidifying water so as to reduce the temperature of the flue gas.
Wherein, the position of the atomizing device is higher than the circulating material tower inlet point of the ascending tower and the position of the Venturi section of the desulfurizing agent added into the ascending tower. Therefore, the humidifying water can be quickly adsorbed to the high-concentration desulfurized fly ash in the area after being sprayed, the requirement of desulfurization reaction is ensured, and the phenomenon that the desulfurized fly ash is adhered to the wall and is hardened due to the fact that the water is sprayed to the tower wall is reduced.
In order to solve the above problems, a second aspect of the present invention provides a two-stage circulating fluidized bed desulfurization process, which utilizes the advantage of high material concentration in the ascending tower and the advantage of high contact probability between the fresh material and sulfur dioxide in the descending tower, reduces the tower height and improves the overall utilization rate of the desulfurizing agent under the condition of ensuring the same residence time of the flue gas.
In order to achieve the purpose, the invention adopts the following technical scheme:
a two-stage type circulating fluidized bed desulfurization process comprises the following steps:
adding the desulfurizer in the desulfurizer bin into the desulfurizing tower from the top of the venturi section and the top of the descending tower of the ascending tower respectively;
the flue gas enters the desulfurizing tower from the bottom of the ascending tower for a vulcanization reaction, flows upwards along the ascending tower, enters the top of the descending tower from the top of the ascending tower and is finally discharged from the bottom of the descending tower;
in the process of the vulcanization reaction, the flue gas reacts with a desulfurizer to generate desulfurized ash, and part of the desulfurized ash carried by the flue gas reflows into the ascending tower from the top of the ascending tower due to gravity and inertia sedimentation to become internally-circulated desulfurized ash; and the other part of the desulfurized ash is discharged from the bottom of the descending tower along with the flue gas.
As an implementation mode, the desulfurization ash discharged from the bottom of the descending tower along with the flue gas enters a bag-type dust remover, and is filtered by the bag-type dust remover and then returned to the Venturi section of the ascending tower.
As an implementation mode, the desulfurizing agent is discharged from the bottom of the descending tower along with the flue gas and enters the bag-type dust remover, the desulfurizing agent is captured by the bag-type dust remover, a desulfurizing ash filter cake section is formed on the surface of a filter bag, and the flue gas flowing through the bag-type dust remover is continuously desulfurized.
The invention has the beneficial effects that:
(1) the desulfurizing tower is designed in two sections, and the height of the desulfurizing tower is reduced under the condition of ensuring the same retention time of flue gas, so that the overall elevation of a desulfurizing and dedusting system is reduced, and the desulfurizing tower is favorable for a tower body structure and a civil engineering supporting structure;
(2) the desulfurizer is added into the desulfurizing tower in two stages, namely from the Venturi section of the ascending tower and the top of the descending tower, so that the overall utilization rate of the desulfurizer is improved; the principle is as follows: because the flow process of the flue gas in the desulfurizing tower is that the flue gas flows upwards along the ascending tower, enters the top of the descending tower from the top of the ascending tower and is finally discharged from the bottom of the descending tower, new desulfurizing agents are respectively added into the flue gas entering the ascending tower and the descending tower, the phenomenon that the desulfurizing agents are less and less along with the flowing of the flue gas, the whole vulcanization reaction effect is influenced can be avoided, and the overall utilization rate of the desulfurizing agents is further improved.
(3) In the ascending tower, the internal circulation characteristic of the desulfurization ash is utilized, the concentration of the desulfurization ash in the tower is high, the large turbulent contact between sulfur dioxide in the flue gas and the desulfurization ash is ensured, and the utilization rate of effective components in the circulating material is improved; wherein, the circulating material is desulfurized ash, the desulfurized ash carried by the flue gas enters the tower again after passing through the dust remover, the process is circulated repeatedly, and the part of desulfurized ash is called as circulating material;
(4) in the descending tower, because part of the desulfurization ash sinks in the ascending tower, the concentration of the desulfurization ash is lower, and part of the desulfurizing agent is supplemented from the top, so that the contact reaction of the fresh desulfurizing agent in the descending tower and sulfur dioxide in the flue gas is improved, and the desulfurization efficiency is further improved;
(5) the desulfurizing agent which is not completely reacted in the descending tower can be captured by the bag-type dust collector, and a desulfurizing ash filter cake is formed on the surface of the filter bag, so that the filter cake has a better desulfurizing effect when the flue gas passes through due to higher desulfurizing agent content;
(6) the ascending tower has high concentration of the desulfurized ash in the tower, and the resistance of the tower body is large, and the resistance of the ascending tower is reduced because the height of the ascending tower is reduced, so that the smoke resistance of the whole desulfurization and dust removal system is reduced.
Drawings
The accompanying drawings, which are incorporated in and constitute a part of this specification, are included to provide a further understanding of the invention, and are incorporated in and constitute a part of this specification, illustrate exemplary embodiments of the invention and together with the description serve to explain the invention and not to limit the invention.
FIG. 1 is a schematic structural diagram of a two-stage circulating fluidized bed desulfurization system according to an embodiment of the present invention;
fig. 2 is a typical layout of a two-stage circulating fluidized bed desulfurization system in accordance with an embodiment of the present invention.
Wherein, 1 is an ascending tower, 2 is a descending tower, 3 is a bag-type dust remover, and 4 is a desulfurizer bin.
Detailed Description
The invention is further described with reference to the following figures and examples.
It is to be understood that the following detailed description is exemplary and is intended to provide further explanation of the invention as claimed. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.
It is noted that the terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of exemplary embodiments according to the invention. As used herein, the singular forms "a", "an" and "the" are intended to include the plural forms as well, and it should be understood that when the terms "comprises" and/or "comprising" are used in this specification, they specify the presence of stated features, steps, operations, devices, components, and/or combinations thereof, unless the context clearly indicates otherwise.
In the present invention, terms such as "upper", "lower", "left", "right", "front", "rear", "vertical", "horizontal", "side", "bottom", and the like indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings, and are only terms of relationships determined for convenience of describing structural relationships of the parts or elements of the present invention, and are not intended to refer to any parts or elements of the present invention, and are not to be construed as limiting the present invention.
In the present invention, terms such as "fixedly connected", "connected", and the like are to be understood in a broad sense, and mean either a fixed connection or an integrally connected or detachable connection; may be directly connected or indirectly connected through an intermediate. The specific meanings of the above terms in the present invention can be determined according to specific situations by persons skilled in the relevant scientific or technical field, and are not to be construed as limiting the present invention.
As shown in fig. 1 and fig. 2, the two-stage circulating fluidized bed desulfurization system of the present embodiment includes a desulfurization tower and a desulfurizing agent bin; the desulfurizing tower comprises an ascending tower 1 and a descending tower 2, and the top of the ascending tower 1 is communicated with the top of the descending tower 2; the flue gas enters the ascending tower from the bottom of the ascending tower, flows upwards along the ascending tower, enters the top of the descending tower from the top of the ascending tower and is finally discharged from the bottom of the descending tower;
the desulfurizer bin 3 is respectively communicated with the venturi section connected with the bottom of the ascending tower 1 and the top of the descending tower 2 and is used for adding a desulfurizer into the desulfurizing tower from the venturi section of the ascending tower and the top of the descending tower; the flue gas reacts with a desulfurizer in the desulfurizing tower to generate desulfurized ash, and part of the desulfurized ash carried by the flue gas reflows into the ascending tower from the top of the ascending tower due to gravity and inertia sedimentation to become internally-circulated desulfurized ash; and the other part of the desulfurized ash is discharged from the bottom of the descending tower along with the flue gas.
In the embodiment, the desulfurizing tower is designed in two sections, and the height of the desulfurizing tower is reduced under the condition of ensuring the same retention time of flue gas, so that the integral elevation of a desulfurizing and dedusting system is reduced, and the desulfurizing tower is favorable for a tower body structure and a civil engineering supporting structure;
in the embodiment, the desulfurizing agent is respectively added into the desulfurizing tower from the top of the venturi section of the ascending tower and the top of the descending tower, so that the overall utilization rate of the desulfurizing agent is improved;
in the ascending tower, the internal circulation characteristic of the desulfurization ash is utilized, the concentration of the desulfurization ash in the tower is high, the large turbulent contact between sulfur dioxide in the flue gas and the desulfurization ash is ensured, and the utilization rate of effective components in the circulating material is improved;
in the descending tower, because part of the desulfurization ash sinks in the ascending tower, the concentration of the desulfurization ash is lower, and part of the desulfurizing agent is supplemented from the top, so that the contact reaction of the fresh desulfurizing agent in the descending tower and sulfur dioxide in the flue gas is improved, and the desulfurization efficiency is further improved;
as shown in fig. 1 and 2, the bottom of the downer is also connected to a dust separator. As an embodiment, the dust remover is a bag dust remover 4.
As a specific implementation mode, the desulfurizing agent is discharged from the bottom of the descending tower along with the flue gas and enters the bag-type dust remover, the desulfurizing agent is captured by the bag-type dust remover, a desulfurizing ash filter cake section is formed on the surface of a filter bag, and the flue gas flowing through the bag-type dust remover is continuously desulfurized.
The filter cake has the advantages that the filter cake has a better desulfurization effect when smoke passes through due to higher content of the fresh desulfurizer, and the desulfurization effect of the whole two-section type circulating fluidized bed desulfurization system is improved.
As an implementation mode, the desulfurization ash discharged from the bottom of the descending tower along with the flue gas enters a bag-type dust remover, and the desulfurization ash is filtered by the bag-type dust remover and then is returned to the Venturi section of the ascending tower.
Wherein, the structure of the bag-type dust collector is the existing structure, and the technical personnel in the field can specifically select the model of the bag-type dust collector according to the actual situation.
As an implementation mode, the position of the venturi section which is filtered by the bag-type dust collector and then returned to the ascending tower is set as a first position; the position of the desulfurizer added into the Venturi section of the ascending tower is set as a second position; the first position is the same height as the second position.
As an implementation mode, an atomization device is further arranged at the bottom of the ascending tower and above the venturi section, and the atomization device is used for atomizing humidifying water so as to reduce the temperature of the flue gas.
The structure of the atomization device is the existing structure, and the description is not repeated here.
Specifically, reaction humidifying water enters the desulfurization system from the lower part of the ascending tower, and the water spraying position is above the material adding point of the ascending tower. The humidifying water is added in an atomized form, and is evaporated by the flue gas after being added, or is attached to the desulfurization ash, or is reacted, the flue gas discharged out of the desulfurization tower is still dry flue gas, and the desulfurization ash is in a dry state.
Wherein, the position of the atomizing device is higher than the circulating material tower inlet point of the ascending tower and the position of the Venturi section of the desulfurizing agent added into the ascending tower. Therefore, the humidifying water can be quickly adsorbed to the high-concentration desulfurized fly ash in the area after being sprayed, the requirement of desulfurization reaction is ensured, and the phenomenon that the desulfurized fly ash is adhered to the wall and is hardened due to the fact that the water is sprayed to the tower wall is reduced.
Example two
The embodiment provides a two-stage type circulating fluidized bed desulfurization process, which comprises the following steps:
adding the desulfurizer in the desulfurizer bin into the desulfurizing tower from the top of the venturi section and the top of the descending tower of the ascending tower respectively;
the flue gas enters the desulfurizing tower from the bottom of the ascending tower for a vulcanization reaction, flows upwards along the ascending tower, enters the top of the descending tower from the top of the ascending tower and is finally discharged from the bottom of the descending tower;
in the process of the vulcanization reaction, the flue gas reacts with a desulfurizer to generate desulfurized ash, and part of the desulfurized ash carried by the flue gas reflows into the ascending tower from the top of the ascending tower due to gravity and inertia sedimentation to become internally-circulated desulfurized ash; and the other part of the desulfurized ash is discharged from the bottom of the descending tower along with the flue gas.
The embodiment utilizes the advantage of high material concentration in the ascending tower, and utilizes the advantage of high contact probability of the fresh materials and sulfur dioxide in the tower, thereby reducing the height of the tower, improving the overall utilization rate of the desulfurizer, ensuring the desulfurization efficiency and reducing the calcium-sulfur ratio under the condition of ensuring the same retention time of flue gas.
As an implementation mode, the desulfurization ash discharged from the bottom of the descending tower along with the flue gas enters a bag-type dust remover, and the desulfurization ash is filtered by the bag-type dust remover and then is returned to the Venturi section of the ascending tower.
As a specific implementation mode, the desulfurizing agent is discharged from the bottom of the descending tower along with the flue gas and enters the bag-type dust remover, the desulfurizing agent is captured by the bag-type dust remover, a desulfurizing ash filter cake section is formed on the surface of a filter bag, and the flue gas flowing through the bag-type dust remover is continuously desulfurized. Therefore, the effective material proportion of the filter cake on the surface of the bag-type dust collector is increased, the desulfurization efficiency is ensured, and the calcium-sulfur ratio is reduced.
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (10)

1. A two-section type circulating fluidized bed desulfurization system is characterized by comprising a desulfurization tower and a desulfurizer bin;
the desulfurizing tower comprises an ascending tower and a descending tower, and the top of the ascending tower is communicated with the top of the descending tower; the flue gas enters the ascending tower from the bottom of the ascending tower, flows upwards along the ascending tower, enters the top of the descending tower from the top of the ascending tower and is finally discharged from the bottom of the descending tower;
the desulfurizing agent bin is communicated with the top of the venturi section and the top of the descending tower of the ascending tower respectively and is used for adding a desulfurizing agent into the desulfurizing tower from the top of the venturi section and the top of the descending tower of the ascending tower respectively; the flue gas reacts with a desulfurizer in the desulfurizing tower to generate desulfurized ash, and part of the desulfurized ash carried by the flue gas reflows into the ascending tower from the top of the ascending tower due to gravity and inertia sedimentation to become internally-circulated desulfurized ash; and the other part of the desulfurized ash is discharged from the bottom of the descending tower along with the flue gas.
2. The two-stage circulating fluidized bed desulfurization system according to claim 1, wherein the bottom of the lower column is further connected to a dust remover.
3. The two-stage circulating fluidized bed desulfurization system of claim 2, wherein the dust remover is a bag-type dust remover.
4. The two-stage circulating fluidized bed desulfurization system of claim 3, wherein the desulfurization ash discharged from the bottom of the lower column along with the flue gas enters the bag-type dust collector, is filtered by the bag-type dust collector, and is returned to the venturi section of the upper column.
5. The two-stage circulating fluidized bed desulfurization system of claim 4, wherein the position at which the desulfurization ash is returned to the venturi section of the ascending tower after being filtered by the bag-type dust collector is set as a first position; the position of the desulfurizer added into the Venturi section of the ascending tower is set as a second position; the first position is the same height as the second position.
6. The two-stage circulating fluidized bed desulfurization system of claim 3, wherein the desulfurizing agent is discharged from the bottom of the descending tower with the flue gas and enters the bag-type dust collector, and is collected by the bag-type dust collector to form a cake of desulfurized ash on the surface of the filter bag, and the flue gas flowing through the bag-type dust collector is further desulfurized.
7. The two-stage circulating fluidized bed desulfurization system according to claim 1, wherein an atomization device is further disposed at the bottom of the ascending tower above the venturi section, and the atomization device is used for atomizing the humidified water to reduce the temperature of the flue gas.
8. A desulfurization process of the two-stage circulating fluidized bed desulfurization system of any one of claims 1 to 7, comprising:
adding the desulfurizer in the desulfurizer bin into the desulfurizing tower from the top of the venturi section and the top of the descending tower of the ascending tower respectively;
the flue gas enters the desulfurizing tower from the bottom of the ascending tower for a vulcanization reaction, flows upwards along the ascending tower, enters the top of the descending tower from the top of the ascending tower and is finally discharged from the bottom of the descending tower;
in the process of the vulcanization reaction, the flue gas reacts with a desulfurizer to generate desulfurized ash, and part of the desulfurized ash carried by the flue gas reflows into the ascending tower from the top of the ascending tower due to gravity and inertia sedimentation to become internally-circulated desulfurized ash; and the other part of the desulfurized ash is discharged from the bottom of the descending tower along with the flue gas.
9. The desulfurization process of the two-stage circulating fluidized bed desulfurization system according to claim 8, wherein the desulfurization ash discharged from the bottom of the lower column along with the flue gas enters the bag-type dust collector, is filtered by the bag-type dust collector, and is returned to the venturi section of the upper column.
10. The desulfurization process of the two-stage circulating fluidized bed desulfurization system according to claim 8, wherein the desulfurizing agent is discharged from the bottom of the lower column along with the flue gas into the bag-type dust collector, and is collected by the bag-type dust collector to form a desulfurization ash cake section on the surface of the filter bag, thereby continuously desulfurizing the flue gas flowing through the bag-type dust collector.
CN202010092924.4A 2020-02-14 2020-02-14 Two-section type circulating fluidized bed desulfurization system and desulfurization process Pending CN111249872A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010092924.4A CN111249872A (en) 2020-02-14 2020-02-14 Two-section type circulating fluidized bed desulfurization system and desulfurization process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010092924.4A CN111249872A (en) 2020-02-14 2020-02-14 Two-section type circulating fluidized bed desulfurization system and desulfurization process

Publications (1)

Publication Number Publication Date
CN111249872A true CN111249872A (en) 2020-06-09

Family

ID=70954474

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010092924.4A Pending CN111249872A (en) 2020-02-14 2020-02-14 Two-section type circulating fluidized bed desulfurization system and desulfurization process

Country Status (1)

Country Link
CN (1) CN111249872A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111804131A (en) * 2020-07-30 2020-10-23 威海市正大环保设备股份有限公司 Two-stage desulfurization technology with downstream ash curtain
CN112221325A (en) * 2020-10-20 2021-01-15 威海市正大环保设备股份有限公司 Circulating double-feeding dry desulfurization method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2358979Y (en) * 1999-03-09 2000-01-19 山东工业大学 Venturi fluidized bed suspension dry desulfurization device for flue gas
CN101053763A (en) * 2007-03-09 2007-10-17 福建鑫泽环保设备工程有限公司 Circulating suspension state dried method desulfurizing technology and special purpose desulfurizing tower thereof
KR20110029412A (en) * 2009-09-15 2011-03-23 주식회사 태영이엠씨 Desulfurization system and desulfurization method
CN207237697U (en) * 2017-08-31 2018-04-17 大连碧海环保设备有限公司 Without fluid bed dry desulfurizing tower
CN109847554A (en) * 2019-01-28 2019-06-07 淮阴工学院 Middle high-sulfur flue gas compound desulfurizing process

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2358979Y (en) * 1999-03-09 2000-01-19 山东工业大学 Venturi fluidized bed suspension dry desulfurization device for flue gas
CN101053763A (en) * 2007-03-09 2007-10-17 福建鑫泽环保设备工程有限公司 Circulating suspension state dried method desulfurizing technology and special purpose desulfurizing tower thereof
KR20110029412A (en) * 2009-09-15 2011-03-23 주식회사 태영이엠씨 Desulfurization system and desulfurization method
CN207237697U (en) * 2017-08-31 2018-04-17 大连碧海环保设备有限公司 Without fluid bed dry desulfurizing tower
CN109847554A (en) * 2019-01-28 2019-06-07 淮阴工学院 Middle high-sulfur flue gas compound desulfurizing process

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
岳涛等: "《工业锅炉大气污染控制技术与应用》", 30 November 2016, 中国环境出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111804131A (en) * 2020-07-30 2020-10-23 威海市正大环保设备股份有限公司 Two-stage desulfurization technology with downstream ash curtain
CN111804131B (en) * 2020-07-30 2022-02-15 威海市正大环保设备股份有限公司 Downstream ash curtain two-stage desulfurization method
CN112221325A (en) * 2020-10-20 2021-01-15 威海市正大环保设备股份有限公司 Circulating double-feeding dry desulfurization method

Similar Documents

Publication Publication Date Title
CN105854561B (en) The device and technique that a kind of flue gas desulfurization, dedusting collaboration are administered
CN104107626B (en) Sintering flue gas circulating fluidized bed (CFB) semi-dry combined desulfurization and denitrification device and method
CN103785275B (en) Desulfurization, ash disposal, denitration integrated flue gas clarifier
CN102764584B (en) Efficient wet type electrostatic-precipitation desulfurization process
CN202823151U (en) Multistage spray efficient wet process of flue gas desulfurization and synergistic mercury removal integrated device
CN206414960U (en) Waste gas purification tower with swirling flow plate
CN111249872A (en) Two-section type circulating fluidized bed desulfurization system and desulfurization process
CN205832956U (en) A kind of coke oven low-sulfur tail gas wet method desulfurization reduces soluble dust exhaust system
CN103316576A (en) Desulfurizing and demisting combined tower
CN107913589A (en) A kind of desulfurization of flue gas cleaning discharge and low-temperature denitrifying system and technique
CN201537454U (en) Desulphurization tower for desulphurization through ammonia process
CN205435424U (en) Synchronous SOx/NOx control demercuration system
CN105056729A (en) Dust removal and desulfuration integrated purifier
CN105056671B (en) A kind of wet desulphurization tower desulfurization and dedusting demisting water saving art and its device
CN203777911U (en) Desulfuration, dedusting and denitration integrated flue gas cleaner
CN111888896A (en) Dust removal device and method for lime-gypsum wet desulfurization tower
CN205340543U (en) Coal fired boiler flue gas desulfurization and dust removal device
CN206965506U (en) A kind of desulfurization and dedusting integrated device
CN205886580U (en) DC combination tower electrostatic precipitator integration flue gas processing system
CN1201852C (en) Flue gas desulfurizing and desaltpeterizing down flow bed reactor
CN207187462U (en) A kind of industrial waste-gas purifier of low temperature plasma combined power ripple
CN203355528U (en) Defluorination and desulfuration dust removal device
CN205055798U (en) Modular wet -type flue gas desulfurization dust collector
CN101879405A (en) Dry-wet integrated desulfurizing dust remover
CN205815455U (en) Furnace flue gas desulfurizer

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information

Address after: 250001 5th Floor, Swan Building, 157 Lishan Road, Lixia District, Jinan City, Shandong Province

Applicant after: Guoneng (Shandong) energy environment Co.,Ltd.

Address before: 250001 5th Floor, Swan Building, 157 Lishan Road, Lixia District, Jinan City, Shandong Province

Applicant before: SHANDONG SHENHUA SHANDA ENERGY & ENVIRONMENT Co.,Ltd.

CB02 Change of applicant information
RJ01 Rejection of invention patent application after publication

Application publication date: 20200609

RJ01 Rejection of invention patent application after publication