CN111206421A - Preparation method of ecological environment-friendly mosquito-proof rayon yarn with mosquito-proof slow-release function - Google Patents

Preparation method of ecological environment-friendly mosquito-proof rayon yarn with mosquito-proof slow-release function Download PDF

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Publication number
CN111206421A
CN111206421A CN202010127290.1A CN202010127290A CN111206421A CN 111206421 A CN111206421 A CN 111206421A CN 202010127290 A CN202010127290 A CN 202010127290A CN 111206421 A CN111206421 A CN 111206421A
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mosquito
rayon
proof
slow
loose
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CN202010127290.1A
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Inventor
张小丽
孙佳琪
蒋恒冰
丁雨倩
曹娟
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Nantong Xiaoxiang Environmental Protection Technology Co ltd
Nantong University
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Nantong Xiaoxiang Environmental Protection Technology Co ltd
Nantong University
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/06Inorganic compounds or elements
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/12Processes in which the treating agent is incorporated in microcapsules
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Catching Or Destruction (AREA)

Abstract

The invention discloses a preparation method of an ecological environment-friendly mosquito-proof rayon yarn with a mosquito-proof slow-release function, which comprises the following steps: A. removing impurities, loosening and opening the loose rayon; B. pretreating the loose rayon; C. performing ultrasonic finishing on the rayon loose fiber anti-mosquito extract microcapsule; D. blending cotton; E. and (3) carding, combing, drafting, twisting and winding the blended rayon loose fibers according to a spinning principle to obtain the high-quality rayon knitted high-count yarn. The invention carries out ultrasonic alkali-oxygen one-bath pretreatment on the rayon loose fibers, then carries out natural anti-mosquito active ingredient microcapsule finishing with different functions to obtain the rayon loose fibers with different odor types and anti-mosquito functions, and then carries out mixed fiber blending of a plurality of fibers according to the required anti-mosquito functions with different odor types to finally obtain the high-quality ecological slow-release anti-mosquito rayon knitted high count yarn, so that the knitted high count yarn has the functions of ecological anti-mosquito, slow-release effect and the like, and is suitable for high-end anti-mosquito knitted clothes of infants and special crowds.

Description

Preparation method of ecological environment-friendly mosquito-proof rayon yarn with mosquito-proof slow-release function
Technical Field
The invention relates to the technical field of rayon fabric preparation, in particular to a preparation method of an ecological environment-friendly mosquito-proof rayon yarn with a mosquito-proof slow-release function.
Background
Mosquito bites cause serious disturbances in human life, and a number of diseases are transmitted by mosquitoes, such as malaria, dengue fever, yellow fever, filariasis, etc., with over 100 million deaths each year from malaria infected with mosquito bites in asia, africa and america. Therefore, the mosquito control work has very important significance.
The research on the anti-mosquito textiles has never been stopped, but at present, the research results in the field are relatively few, and further research is still needed. The use of chemical synthetic pesticides can cause environmental pollution, so that an environment-friendly plant control means becomes a poor choice for people. The natural repellent is mainly plant-derived repellent, mainly comes from roots, stems, leaves, flowers and the like of plants, and is mostly terpenoid esters, alcohols, ketones and the like. Many essential oils have mosquito killing and growth inhibiting effects, and especially citronella essential oil has become a commercial repellent which is especially successful at present. Although the aim of repelling mosquitoes can be achieved by directly finishing the fabric with the citronella essential oil, the lasting and stable mosquito repelling effect is difficult to achieve. The microcapsule technology is a technology in which a trace amount of a substance is coated with a film formed of a natural or synthetic polymer. Up to now, microcapsule technology has gained widespread use, including many fields such as pesticides, textiles, daily chemicals, medicines, paints, foods, and the like.
Disclosure of Invention
The invention aims to provide a preparation method of ecological environment-friendly mosquito-proof cotton yarn with mosquito-proof slow-release function, which aims to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: a preparation method of an ecological environment-friendly mosquito-proof rayon yarn with a mosquito-proof slow-release function comprises the following steps:
A. removing impurities, loosening and opening the loose rayon;
B. pretreating the loose rayon;
C. performing ultrasonic finishing on the rayon loose fiber anti-mosquito extract microcapsule;
D. blending cotton;
E. and (3) carding, combing, drafting, twisting and winding the blended rayon loose fibers according to a spinning principle to prepare the high-quality ecological slow-release mosquito-proof rayon knitted high-count yarn.
Preferably, the pretreatment step in the step B is ultrasonic alkali-oxygen one-bath pretreatment; wherein, the alkali-oxygen one-bath process formula is as follows: the concentration of the alkali liquor is 4.0-6.0g/L, and the concentration of the hydrogen peroxide is 4.0-6.0 g/L; the process conditions are as follows: the ultrasonic wave is applied for 45-60min at 40-60 deg.C.
Preferably, the anti-mosquito effective component extract in the step C comprises a mint extract, a garlic extract or a lavender extract; the formula of the mint microcapsule finishing process comprises the following steps: the adsorption time is 20-60min, the mint microcapsule dosage is 1-5% (omf), the adhesive dosage is 20-60g/L, pH value is 7-9, the adsorption temperature is 20-50 ℃, and the bath ratio is 1:10-1: 40.
Preferably, the garlic microcapsule finishing process formula comprises the following steps: the adsorption time is 30-50min, the garlic microcapsule dosage is 1-6% (omf), the adhesive dosage is 20-50g/L, pH value is 6-8, the adsorption temperature is 30-60 deg.C, and the bath ratio is 1:15-1: 30.
Preferably, the formula of the lavender microcapsule finishing process is as follows: the adsorption time is 30-50min, the lavender microcapsule amount is 2-5% (omf), the adhesive amount is 20-50g/L, pH value is 5-7, the adsorption temperature is 30-60 deg.C, and the bath ratio is 1:10-1: 40.
Preferably, the cotton blending method in the step D comprises: and D, mixing the mint, the garlic and the lavender rayon loose fibers prepared in the step C as raw materials according to the designed mosquito-proof function and the fragrance.
Compared with the prior art, the invention has the beneficial effects that: the preparation method is simple, the rayon loose fibers are subjected to ultrasonic alkali-oxygen one-bath pretreatment, then natural anti-mosquito active ingredient microcapsules with different functions are finished to obtain the rayon loose fibers with different odor types and anti-mosquito functions, then the rayon loose fibers with different odor types are subjected to fiber mixing and blending according to the required anti-mosquito functions with different odor types, and finally the high-quality ecological slow-release anti-mosquito rayon knitted high count yarn is obtained, so that the functions of ecological anti-mosquito, slow-release effects and the like are obtained, and the rayon knitted high count yarn is suitable for high-end anti-mosquito knitted clothing of infants and special crowds.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
the invention provides the following technical scheme: a preparation method of an ecological environment-friendly mosquito-proof rayon yarn with a mosquito-proof slow-release function comprises the following steps:
A. removing impurities, loosening and opening the loose rayon;
B. pretreating the loose rayon;
C. performing ultrasonic finishing on the rayon loose fiber anti-mosquito extract microcapsule;
D. blending cotton;
E. and (3) carding, combing, drafting, twisting and winding the blended rayon loose fibers according to a spinning principle to prepare the high-quality ecological slow-release mosquito-proof rayon knitted high-count yarn.
In this embodiment, the pretreatment step in step B is ultrasonic alkali-oxygen one-bath pretreatment; wherein, the alkali-oxygen one-bath process formula is as follows: the concentration of the alkali liquor is 4.0g/L, and the concentration of the hydrogen peroxide is 4.0 g/L; the process conditions are as follows: the ultrasonic wave is applied for 45min, and the application temperature is 40 ℃.
In this embodiment, the mosquito-repellent active ingredient extract in step C includes a mint extract and a garlic extract; the formula of the mint microcapsule finishing process comprises the following steps: the adsorption time is 30min, the mint microcapsule dosage is 3% (omf), the adhesive dosage is 40g/L, pH value is 8, the adsorption temperature is 30 ℃, and the bath ratio is 1: 10.
The garlic microcapsule finishing process formula comprises: the adsorption time is 30min, the usage amount of the garlic microcapsule is 1% (omf), the usage amount of the adhesive is 20g/L, pH value is 8, the adsorption temperature is 30 ℃, and the bath ratio is 1: 15.
In this embodiment, the cotton blending method in step D includes: and D, mixing the mint and garlic rayon loose fibers prepared in the step C as raw materials according to the designed mosquito-proof functionality and the fragrance.
Example two:
a preparation method of an ecological environment-friendly mosquito-proof rayon yarn with a mosquito-proof slow-release function comprises the following steps:
A. removing impurities, loosening and opening the loose rayon;
B. pretreating the loose rayon;
C. performing ultrasonic finishing on the rayon loose fiber anti-mosquito extract microcapsule;
D. blending cotton;
E. and (3) carding, combing, drafting, twisting and winding the blended rayon loose fibers according to a spinning principle to prepare the high-quality ecological slow-release mosquito-proof rayon knitted high-count yarn.
In this embodiment, the pretreatment step in step B is ultrasonic alkali-oxygen one-bath pretreatment; wherein, the alkali-oxygen one-bath process formula is as follows: the concentration of the alkali liquor is 5g/L, and the concentration of the hydrogen peroxide is 5 g/L; the process conditions are as follows: the ultrasonic wave is applied for 50min, and the temperature is 50 ℃.
In this embodiment, the mosquito-repellent active ingredient extract in step C includes a mint extract; the formula of the mint microcapsule finishing process comprises the following steps: the adsorption time is 60min, the mint microcapsule dosage is 5% (omf), the adhesive dosage is 60g/L, pH value is 7-9, the adsorption temperature is 50 ℃, and the bath ratio is 1: 40.
The formula of the lavender microcapsule finishing process comprises the following steps: the adsorption time is 50min, the lavender microcapsule dosage is 3% (omf), the adhesive dosage is 50g/L, pH value is 7, the adsorption temperature is 400 ℃, and the bath ratio is 1: 40.
In this embodiment, the cotton blending method in step D includes: and D, mixing the mint and the lavender rayon loose fibers prepared in the step C as raw materials according to the designed mosquito-proof functionality and the fragrance.
Example three:
a preparation method of an ecological environment-friendly mosquito-proof rayon yarn with a mosquito-proof slow-release function comprises the following steps:
A. removing impurities, loosening and opening the loose rayon;
B. pretreating the loose rayon;
C. performing ultrasonic finishing on the rayon loose fiber anti-mosquito extract microcapsule;
D. blending cotton;
E. and (3) carding, combing, drafting, twisting and winding the blended rayon loose fibers according to a spinning principle to prepare the high-quality ecological slow-release mosquito-proof rayon knitted high-count yarn.
In this embodiment, the pretreatment step in step B is ultrasonic alkali-oxygen one-bath pretreatment; wherein, the alkali-oxygen one-bath process formula is as follows: the concentration of the alkali liquor is 6.0g/L, and the concentration of the hydrogen peroxide is 6.0 g/L; the process conditions are as follows: the ultrasonic wave is applied for 45min, and the application temperature is 40 ℃.
In this embodiment, the extract of the mosquito-repellent active ingredient in step C includes a mint extract, a garlic extract or a lavender extract; the formula of the mint microcapsule finishing process comprises the following steps: the adsorption time is 50min, the mint microcapsule dosage is 4% (omf), the adhesive dosage is 50g/L, pH value is 8, the adsorption temperature is 40 ℃, and the bath ratio is 1: 10.
In the embodiment, the formula of the garlic microcapsule finishing process is as follows: the adsorption time is 40min, the usage amount of the garlic microcapsule is 2% (omf), the usage amount of the adhesive is 40g/L, pH value is 8, the adsorption temperature is 50 ℃, and the bath ratio is 1: 15.
In the embodiment, the formula of the lavender microcapsule finishing process is as follows: the adsorption time is 35min, the lavender microcapsule dosage is 4% (omf), the adhesive dosage is 35g/L, pH value is 6, the adsorption temperature is 40 ℃, and the bath ratio is 1: 20.
In this embodiment, the cotton blending method in step D includes: and D, mixing the mint, the garlic and the lavender rayon loose fibers prepared in the step C as raw materials according to the designed mosquito-proof function and the fragrance.
The product obtained by adopting the embodiments of the invention is used for performance test, and the test effect is as follows:
mosquito-proof performance
Repellent effect of mosquito-proof fabric on aedes albopictus
Figure BDA0002394783810000051
The repelling rate of the fabric to aedes albopictus after the microcapsule finishing is 98%, the fabric has a strong repelling effect, and the grade of mosquito prevention is A.
In conclusion, the preparation method is simple, the rayon loose fibers are subjected to ultrasonic alkali-oxygen one-bath pretreatment, then natural anti-mosquito active ingredient microcapsules with different functions are finished to obtain the rayon loose fibers with different odor types and anti-mosquito functions, and then the rayon loose fibers are mixed and spliced with various fibers according to the required anti-mosquito functions with different odor types to finally obtain the high-quality ecological slow-release anti-mosquito rayon knitted high-count yarn, so that the knitted high-count yarn has the functions of ecological anti-mosquito, slow-release effects and the like, and is suitable for high-end anti-mosquito knitted clothing of infants and special crowds.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (6)

1. A preparation method of an ecological environment-friendly mosquito-proof rayon yarn with a mosquito-proof slow-release function is characterized by comprising the following steps: the method comprises the following steps:
A. removing impurities, loosening and opening the loose rayon;
B. pretreating the loose rayon;
C. performing ultrasonic finishing on the rayon loose fiber anti-mosquito extract microcapsule;
D. blending cotton;
E. and (3) carding, combing, drafting, twisting and winding the blended rayon loose fibers according to a spinning principle to prepare the high-quality ecological slow-release mosquito-proof rayon knitted high-count yarn.
2. The preparation method of the ecological environment-friendly mosquito-proof rayon yarn with the mosquito-proof slow-release function according to claim 1, which is characterized by comprising the following steps of: the pretreatment step in the step B is ultrasonic alkali-oxygen one-bath pretreatment; wherein, the alkali-oxygen one-bath process formula is as follows: the concentration of the alkali liquor is 4.0-6.0g/L, and the concentration of the hydrogen peroxide is 4.0-6.0 g/L; the process conditions are as follows: the ultrasonic wave is applied for 45-60min at 40-60 deg.C.
3. The preparation method of the ecological environment-friendly mosquito-proof rayon yarn with the mosquito-proof slow-release function according to claim 1, which is characterized by comprising the following steps of: the anti-mosquito active ingredient extract in the step C comprises a mint extract, a garlic extract or a lavender extract; the formula of the mint microcapsule finishing process comprises the following steps: the adsorption time is 20-60min, the mint microcapsule dosage is 1-5% (omf), the adhesive dosage is 20-60g/L, pH value is 7-9, the adsorption temperature is 20-50 ℃, and the bath ratio is 1:10-1: 40.
4. The preparation method of the ecological environment-friendly mosquito-proof rayon yarn with the mosquito-proof slow-release function according to claim 3, which is characterized by comprising the following steps of: the garlic microcapsule finishing process formula comprises the following steps: the adsorption time is 30-50min, the garlic microcapsule dosage is 1-6% (omf), the adhesive dosage is 20-50g/L, pH value is 6-8, the adsorption temperature is 30-60 deg.C, and the bath ratio is 1:15-1: 30.
5. The preparation method of the ecological environment-friendly mosquito-proof rayon yarn with the mosquito-proof slow-release function according to claim 3, which is characterized by comprising the following steps of: the formula of the lavender microcapsule finishing process comprises: the adsorption time is 30-50min, the lavender microcapsule amount is 2-5% (omf), the adhesive amount is 20-50g/L, pH value is 5-7, the adsorption temperature is 30-60 deg.C, and the bath ratio is 1:10-1: 40.
6. The preparation method of the ecological environment-friendly mosquito-proof rayon yarn with the mosquito-proof slow-release function according to claim 1, which is characterized by comprising the following steps of: the cotton blending method in the step D comprises the following steps: and D, mixing the mint, the garlic and the lavender rayon loose fibers prepared in the step C as raw materials according to the designed mosquito-proof function and the fragrance.
CN202010127290.1A 2020-02-28 2020-02-28 Preparation method of ecological environment-friendly mosquito-proof rayon yarn with mosquito-proof slow-release function Pending CN111206421A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113047053A (en) * 2021-04-22 2021-06-29 南通欣颐家纺有限公司 Preparation method of plant-derived slow-release anti-mosquito polyester fabric

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101021023A (en) * 2007-03-20 2007-08-22 浙江华孚色纺有限公司 Mosquito preventing fiber dyed yarn and its production process
CN104480724A (en) * 2014-12-05 2015-04-01 南通大学 Functional natural plant mosquito repelling ecological home textile product
CN107419527A (en) * 2017-06-23 2017-12-01 宁波高新区达康工业科技有限公司 A kind of mosquito-proof refrigerant fabric for infant-wear

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101021023A (en) * 2007-03-20 2007-08-22 浙江华孚色纺有限公司 Mosquito preventing fiber dyed yarn and its production process
CN104480724A (en) * 2014-12-05 2015-04-01 南通大学 Functional natural plant mosquito repelling ecological home textile product
CN107419527A (en) * 2017-06-23 2017-12-01 宁波高新区达康工业科技有限公司 A kind of mosquito-proof refrigerant fabric for infant-wear

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113047053A (en) * 2021-04-22 2021-06-29 南通欣颐家纺有限公司 Preparation method of plant-derived slow-release anti-mosquito polyester fabric

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