CN111122006B - Flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor and manufacturing method thereof - Google Patents
Flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor and manufacturing method thereof Download PDFInfo
- Publication number
- CN111122006B CN111122006B CN202010030060.3A CN202010030060A CN111122006B CN 111122006 B CN111122006 B CN 111122006B CN 202010030060 A CN202010030060 A CN 202010030060A CN 111122006 B CN111122006 B CN 111122006B
- Authority
- CN
- China
- Prior art keywords
- optical fiber
- mode
- nano
- fiber
- flower
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 70
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 70
- 239000002086 nanomaterial Substances 0.000 title claims abstract description 37
- 238000004519 manufacturing process Methods 0.000 title abstract description 7
- 239000013307 optical fiber Substances 0.000 claims abstract description 123
- 239000000463 material Substances 0.000 claims abstract description 39
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 22
- 229910052751 metal Inorganic materials 0.000 claims abstract description 22
- 239000002184 metal Substances 0.000 claims abstract description 22
- 239000000835 fiber Substances 0.000 claims description 65
- 238000001035 drying Methods 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 14
- 239000002121 nanofiber Substances 0.000 claims description 13
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 230000004927 fusion Effects 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 11
- 230000008018 melting Effects 0.000 claims description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- 239000000725 suspension Substances 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 238000007664 blowing Methods 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 238000005253 cladding Methods 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 6
- 239000011521 glass Substances 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 6
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 230000010354 integration Effects 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000001132 ultrasonic dispersion Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 210000004705 lumbosacral region Anatomy 0.000 claims 1
- 230000035945 sensitivity Effects 0.000 abstract description 12
- 238000001228 spectrum Methods 0.000 abstract description 9
- 230000008859 change Effects 0.000 abstract description 5
- 230000000694 effects Effects 0.000 description 6
- 238000010586 diagram Methods 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 238000001514 detection method Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
- G01K11/00—Measuring temperature based upon physical or chemical changes not covered by groups G01K3/00, G01K5/00, G01K7/00 or G01K9/00
- G01K11/32—Measuring temperature based upon physical or chemical changes not covered by groups G01K3/00, G01K5/00, G01K7/00 or G01K9/00 using changes in transmittance, scattering or luminescence in optical fibres
Abstract
The invention discloses a flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor and a manufacturing method thereof, and belongs to the field of optical fiber sensing. The temperature sensor comprises an ASE light source, an optical fiber circulator, a temperature sensing head and a spectrometer. The signal light is transmitted to the temperature sensing head by the ASE light source through the optical fiber circulator, the signal light is reflected by the metal aluminum film in the temperature sensing head, passes through the single-mode-tapered multi-mode-single-mode optical fiber structure for the second time, forms strong interference by means of the single-sphere micro-nano structure, is transmitted outwards in a basic mode, and finally is transmitted to the spectrometer by the temperature sensing head through the optical fiber circulator. The sensor has the advantage that the interference spectrum of the sensor is greatly drifted due to the temperature change by means of the prepared flower-shaped ZnO/graphene temperature sensitive material and the strong interference optical fiber structure. The corresponding temperature change can be measured by the amount of drift. The invention combines the sensitive material and the special interference type optical fiber structure, so that the optical fiber temperature sensor successfully realizes the superior performances of high sensitivity, strong stability and low cost.
Description
Technical Field
The invention belongs to the technical field of optical fiber sensors, and particularly relates to a flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor and a manufacturing method thereof.
Background
Temperature measurement is spread in all corners of people's life, and optical fiber temperature sensors are widely used as the last-generation ones in the category of temperature sensors by virtue of the advantages of small size, high temperature resistance, corrosion resistance and strong electromagnetic interference resistance. However, with the development and progress of production and life, the sensitive performance of the sensor is required to be higher and higher.
The improvement on the optical fiber structure can well improve the sensitivity of the sensor. In recent years, an optical fiber sensor formed by combining a sensitive material as a sensing medium and an optical fiber structure has been developed in the aspects of sensitivity, stability and the like. Such fiber optic sensors are becoming increasingly popular with many advantages, as are temperature sensing. Therefore, the optical fiber temperature sensor is combined with a special optical fiber structure with a strong interference effect, and is made of a sensitive material with better selectivity, so that the temperature sensitivity of the optical fiber temperature sensor is improved, and the optical fiber temperature sensor has great significance in better solving the temperature detection problem in different severe environments.
Disclosure of Invention
Aiming at the defects and improvement needs of the prior art, the invention provides a flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor and a manufacturing method thereof, and aims to combine a sensitive material preparation method, fuse a novel composite sensitive material with a special optical fiber structure with a strong interference effect, and prepare an optical fiber temperature sensor with high sensitivity, strong stability and low cost by means of the temperature-sensitive performance of the flower-shaped ZnO/graphene material, so that the temperature detection problem in severe environments is better solved.
In order to achieve the purpose, the invention adopts the following technical scheme:
the flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized by comprising an ASE light source (1), an optical fiber circulator (2), a temperature sensing head (3) and a spectrometer (4).
The temperature sensing head (3) comprises a first single mode fiber (3-1), a multimode single sphere micro-nano fiber (3-2), a flower-shaped ZnO/graphene sensitive material (3-3), a second single mode fiber (3-4) and a metal aluminum film (3-5).
The temperature sensing head (3) takes a multimode single-sphere micro-nano optical fiber (3-2) as a temperature sensitive area, the multimode single-sphere micro-nano optical fiber (3-2) coats a temperature sensitive flower-shaped ZnO/graphene sensitive material (3-3), and is connected with a single mode fiber I (3-1) and a single mode fiber II (3-4) in an optical fiber fusion connection mode;
in the temperature sensing head (3), one end of a second single-mode fiber (3-4) is connected with the multimode single-sphere micro-nano fiber (3-2) in a melting mode, and the other end of the second single-mode fiber is coated with a metal aluminum film (3-5).
The multimode single-sphere micro-nano optical fiber (3-2) takes a multimode optical fiber as a main body, the multimode micro-nano optical fiber is firstly prepared, and then the multimode micro-nano optical fiber is burnt at the tapered part of the multimode micro-nano optical fiber by utilizing a method of melting and tapering by oxyhydrogen flame and then reversely adjusting a clamp, so that the structure is formed.
The ASE light source (1) is connected with the optical fiber circulator (2) through a single-mode optical fiber, the optical fiber circulator (2) is connected with the temperature sensing head (3) through the single-mode optical fiber, the optical fiber circulator (2) is connected with the spectrometer (4) through the single-mode optical fiber, and the single-mode optical fiber is connected with each device in an optical fiber fusion connection mode.
The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized in that the output center wavelength of the ASE light source (1) is 1550nm, and the frequency bandwidth is 60 nm.
The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized in that a flower-shaped ZnO/graphene sensitive material (3-3) in the temperature sensing head (3) is a temperature composite sensitive material.
The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized in that a method for combining the multimode single-sphere micro-nano optical fiber (3-2) in the temperature sensing head (3) and the flower-shaped ZnO/graphene sensitive material (3-3) is a dripping method.
The preparation method of the flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized by comprising the following steps:
s1: preparing a multimode single-sphere micro-nano optical fiber (3-2), namely performing melt tapering on the multimode optical fiber with the length of 8cm and the fiber core diameter of 62.5 microns by using oxyhydrogen flame, and then performing treatment by using a method of reversely adjusting an optical fiber clamp in a heating state of the oxyhydrogen flame to prepare the multimode single-sphere micro-nano optical fiber (3-2);
s2: preparing a flower-shaped ZnO/graphene sensitive material (3-3), namely placing 15.0mg of graphene powder into 40mL of deionized water for ultrasonic dispersion for 2 hours, mixing the dispersed graphene solution with 3.5g of zinc nitrate, 4.8g of citric acid and 100mL of deionized water, stirring for 1.5 hours at the temperature of 75 ℃, placing the mixture into a constant-temperature drying box at the temperature of 90 ℃ for 1.5-2 hours, dripping 1.5mol/L of sodium hydroxide solution into the mixed solution, adjusting the pH value of the suspension to be 9.5, transferring the suspension into a reaction kettle, placing the reaction kettle into a constant-temperature drying box at the temperature of 125 ℃ for 15-16 hours, taking out the suspension, naturally cooling, washing a product with the deionized water for 4-5 times, and centrifuging for 15 minutes at 5000rmp/min to obtain a flower-shaped ZnO/graphene aqueous solution;
s3: preparing a single mode-tapering multi-mode-single mode fiber structure, intercepting two single mode fibers with the length of 5cm as a first single mode fiber (3-1) and a second single mode fiber (3-4), and connecting the first single mode fiber (3-1), the multi-mode single-sphere micro-nano fiber (3-2) and the second single mode fiber (3-4) in a fiber fusion connection mode to form the single mode-tapering multi-mode-single mode fiber structure;
s4: cladding of the metal aluminum film (3-5), namely truncating the end, which is not welded, of the second single-mode fiber (3-4) in the single-mode-tapered multi-mode-single-mode fiber structure, and cladding the metal aluminum film (2) with better reflection performance on the end;
s5: and (3) integrating a temperature sensing head (3), fixing a single-mode-tapered multi-mode-single-mode optical fiber structure which is manufactured but is not coated with a material in a dripping mode on a glass substrate, cleaning the glass substrate by using alcohol and deionized water to remove residual impurities, dripping flower-shaped ZnO/graphene aqueous solution along the surface of the multi-mode single-sphere micro-nano optical fiber (3-2), and putting the sensing head into a constant-temperature electrothermal blowing drying box for drying treatment to enable the sensitive material to be tightly combined with the multi-mode single-sphere micro-nano optical fiber (3-2) to form the temperature sensing head (3).
The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized in that oxyhydrogen flame melting tapering is carried out in the step S1, a oxyhydrogen flame tapering machine is adopted to carry out melting tapering for 12.4mm, a multimode micro-nano optical fiber with the lumbar vertebra diameter of 6.92 mu m is formed, a clamp is adjusted back for 1mm, the multimode micro-nano optical fiber is burnt in the lumbar vertebra region through oxyhydrogen flame to melt spheres, and a multimode single-sphere micro-nano optical fiber (3-2) is formed, wherein the diameter of the single sphere is 13.1 mu m.
The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized in that in the step S4 of coating the metal aluminum film (3-5), the length of the second single-mode optical fiber (3-4) after being truncated is 3 cm.
The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized in that in the step S4 of coating the metal aluminum film (3-5), the thickness range of the metal aluminum film (2) is 80-200 mu m.
The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized in that in the integration of the temperature sensing head (3) in the step S5, the temperature of the constant-temperature electrothermal blowing drying oven is set to be 45 ℃, and the heating time is 5 hours.
The beneficial effects of the invention are as follows:
the invention combines the preparation method of the sensitive material, fuses the novel composite sensitive material with a special optical fiber structure with a strong interference effect, and prepares the optical fiber temperature sensor with high sensitivity, strong stability and low cost by means of the temperature-sensitive performance of the flower-shaped ZnO/graphene material. The method has important significance for better solving the temperature detection problem in severe environments.
Drawings
FIG. 1 is a schematic structural diagram of a flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor of the invention;
FIG. 2 is a block diagram of a temperature sensing head;
FIG. 3 is a drift diagram of an interference spectrum of the flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor at different temperatures;
FIG. 4 is a plot of a data fit of an interference spectrum in a temperature experiment;
FIG. 5 is a block flow diagram of a method of fabricating a temperature sensing head;
FIG. 6 is an SEM image of flower-like ZnO/graphene prepared by the invention.
Detailed Description
The following description will further describe the specific embodiments of the present invention with reference to the accompanying drawings.
Referring to fig. 1, the flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor according to the embodiment is characterized by comprising an ASE light source (1), an optical fiber circulator (2), a temperature sensing head (3) and a spectrometer (4).
Referring to fig. 2, the temperature sensing head (3) comprises a first single mode fiber (3-1), a multimode single sphere micro-nano fiber (3-2), a flower-shaped ZnO/graphene sensitive material (3-3), a second single mode fiber (3-4) and a metal aluminum film (3-5).
The temperature sensing head (3) takes a multimode single-sphere micro-nano optical fiber (3-2) as a temperature sensitive area, the multimode single-sphere micro-nano optical fiber (3-2) coats a temperature sensitive flower-shaped ZnO/graphene sensitive material (3-3), and is connected with a single mode fiber I (3-1) and a single mode fiber II (3-4) in an optical fiber fusion connection mode;
in the temperature sensing head (3), one end of a second single-mode fiber (3-4) is connected with the multimode single-sphere micro-nano fiber (3-2) in a melting mode, and the other end of the second single-mode fiber is coated with a metal aluminum film (3-5).
The multimode single-sphere micro-nano optical fiber (3-2) takes a multimode optical fiber as a main body, the multimode micro-nano optical fiber is firstly prepared, and then the multimode micro-nano optical fiber is burnt at the tapered part of the multimode micro-nano optical fiber by utilizing a method of melting and tapering by oxyhydrogen flame and then reversely adjusting a clamp, so that the structure is formed;
the ASE light source (1) is connected with the optical fiber circulator (2) through a single-mode optical fiber, the optical fiber circulator (2) is connected with the temperature sensing head (3) through the single-mode optical fiber, the optical fiber circulator (2) is connected with the spectrometer (4) through the single-mode optical fiber, and the single-mode optical fiber is connected with each device in an optical fiber fusion connection mode.
The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized in that the output center wavelength of the ASE light source (1) is 1550nm, and the frequency bandwidth is 60 nm.
The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized in that a flower-shaped ZnO/graphene sensitive material (3-3) in the temperature sensing head (3) is a temperature composite sensitive material.
The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized in that a method for combining the multimode single-sphere micro-nano optical fiber (3-2) in the temperature sensing head (3) and the flower-shaped ZnO/graphene sensitive material (3-3) is a dripping method.
The preparation method of the flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized by comprising the following steps:
s1: preparing a multimode single-sphere micro-nano optical fiber (3-2), namely performing melt tapering on the multimode optical fiber with the length of 8cm and the fiber core diameter of 62.5 microns by using oxyhydrogen flame, and then performing treatment by using a method of reversely adjusting an optical fiber clamp in a heating state of the oxyhydrogen flame to prepare the multimode single-sphere micro-nano optical fiber (3-2);
s2: preparing a flower-shaped ZnO/graphene sensitive material (3-3), namely placing 15.0mg of graphene powder into 40mL of deionized water for ultrasonic dispersion for 2 hours, mixing the dispersed graphene solution with 3.5g of zinc nitrate, 4.8g of citric acid and 100mL of deionized water, stirring for 1.5 hours at the temperature of 75 ℃, placing the mixture into a constant-temperature drying box at the temperature of 90 ℃ for 1.5-2 hours, dripping 1.5mol/L of sodium hydroxide solution into the mixed solution, adjusting the pH value of the suspension to be 9.5, transferring the suspension into a reaction kettle, placing the reaction kettle into a constant-temperature drying box at the temperature of 125 ℃ for 15-16 hours, taking out the suspension, naturally cooling, washing a product with the deionized water for 4-5 times, and centrifuging for 15 minutes at 5000rmp/min to obtain a flower-shaped ZnO/graphene aqueous solution;
s3: preparing a single mode-tapering multi-mode-single mode fiber structure, intercepting two single mode fibers with the length of 5cm as a first single mode fiber (3-1) and a second single mode fiber (3-4), and connecting the first single mode fiber (3-1), the multi-mode single-sphere micro-nano fiber (3-2) and the second single mode fiber (3-4) in a fiber fusion connection mode to form the single mode-tapering multi-mode-single mode fiber structure;
s4: cladding of the metal aluminum film (3-5), namely truncating the end, which is not welded, of the second single-mode fiber (3-4) in the single-mode-tapered multi-mode-single-mode fiber structure, and cladding the metal aluminum film (2) with better reflection performance on the end;
s5: and (3) integrating a temperature sensing head (3), fixing a single-mode-tapered multi-mode-single-mode optical fiber structure which is manufactured but is not coated with a material in a dripping mode on a glass substrate, cleaning the glass substrate by using alcohol and deionized water to remove residual impurities, dripping flower-shaped ZnO/graphene aqueous solution along the surface of the multi-mode single-sphere micro-nano optical fiber (3-2), and putting the sensing head into a constant-temperature electrothermal blowing drying box for drying treatment to enable the sensitive material to be tightly combined with the multi-mode single-sphere micro-nano optical fiber (3-2) to form the temperature sensing head (3).
The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized in that oxyhydrogen flame melting tapering is carried out in the step S1, a oxyhydrogen flame tapering machine is adopted to carry out melting tapering for 12.4mm, a multimode micro-nano optical fiber with the lumbar vertebra diameter of 6.92 mu m is formed, a clamp is adjusted back for 1mm, the multimode micro-nano optical fiber is burnt in the lumbar vertebra region through oxyhydrogen flame to melt spheres, and a multimode single-sphere micro-nano optical fiber (3-2) is formed, wherein the diameter of the single sphere is 13.1 mu m.
The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized in that in the step S4 of coating the metal aluminum film (3-5), the length of the second single-mode optical fiber (3-4) after being truncated is 3 cm.
The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized in that in the step S4 of coating the metal aluminum film (3-5), the thickness range of the metal aluminum film (2) is 80-200 mu m.
The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized in that in the integration of the temperature sensing head (3) in the step S5, the temperature of the constant-temperature electrothermal blowing drying oven is set to be 45 ℃, and the heating time is 5 hours.
The working principle is as follows:
flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor:
the working process is as follows: signal light is transmitted to a temperature sensing head (3) from an ASE light source (1) along a single mode fiber through a fiber circulator (2), in the temperature sensing head (3), the signal light is transmitted to a multimode single sphere micro-nano fiber (3-2) through a first single mode fiber (3-1), then transmitted to a second single mode fiber (3-3) through the multimode single sphere micro-nano fiber (3-2), reflected at a metal aluminum film (3-5) through the second single mode fiber (3-3), and then sequentially passes through the second single mode fiber (3-3), the multimode single sphere micro-nano fiber (3-2) and the first single mode fiber (3-1), and finally transmitted to a spectrometer (4) from the temperature sensing head (3) through the fiber circulator (2).
In the process of signal light transmission, the diameter of the fiber core of the multimode fiber is far larger than that of the common single-mode fiber, the fiber core of the multimode fiber can accommodate various light wave modes, and multimode interference effect can occur in different modes in the transmission process. In addition, the surface evanescent field of the multimode single-sphere micro-nano optical fiber after tapering and ball melting treatment is enhanced, the interaction between light and the external environment is increased when the light is transmitted in the multimode single-sphere micro-nano optical fiber, and particularly the interference effect in a single sphere is better. When signal light passes through the temperature sensing head (3), a series of mutually independent eigen modes are excited when the signal light is transmitted to the multimode single-sphere micro-nano optical fiber (3-2) through the first single-mode optical fiber (3-1), each mode interferes in the optical fiber, energy is redistributed, and when the signal light is transmitted to the second single-mode optical fiber (3-3) through the multimode single-sphere micro-nano optical fiber (3-2), optical coupling is formed and the signal light is transmitted in a fundamental mode. When the signal light reaches the metal aluminum film (3-5), the signal light is reflected and passes through the optical fiber structure formed by combining the second single-mode optical fiber (3-3), the multi-mode single-sphere micro-nano optical fiber (3-2) and the first single-mode optical fiber (3-1) again to form secondary interference, and finally the signal light is transmitted to the circulator from the first single-mode optical fiber (3-1) in a basic mode.
The difference in refractive index between the different modes is Δ n, the phase difference can be expressed as:
considering the inter-mode dispersion, the wavelength shift and external index relationship can be expressed as:
the dispersion factor is:
therefore, the sensitivity of the temperature sensor depends on the difference in effective refractive index and the dispersion factor between the modes. The invention adopts the multimode single-sphere micro-nano optical fiber (3-2), which has stronger sensitivity to the change of the external refractive index due to stronger evanescent field and smaller dispersion factor. In addition, the flower-like ZnO/graphene sensitive material (3-3) selected and prepared by the invention is very sensitive to temperature, and the structure of the material can be changed to a great extent by changing the temperature, so that the refractive index of the material is changed. The multimode single-sphere micro-nano optical fiber (3-2) is compounded with the flower-shaped ZnO/graphene sensitive material (3-3), and the single mode-tapered multimode-single mode and the metal aluminum film (3-5) are combined to enable the signal light to form secondary interference, so that the temperature sensitivity of the temperature sensing head (3) is greatly enhanced, and the temperature sensor has high sensitivity and stability.
The effect of the invention is demonstrated by the following examples:
the temperature sensing head (3) of the flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is placed in a constant-temperature drying oven for heating test, when the temperature rises, the effective refractive index of the optical fiber of the sensing part, which is the combination of the multimode single-sphere micro-nano optical fiber (3-2) and the flower-shaped ZnO/graphene sensitive material (3-3), will change accordingly, and the interference spectrum will have obvious and regular drift along with the rise of the temperature. FIG. 3 is a graph showing the drift of the interference spectrum of the temperature sensor at different temperatures, wherein the directions of arrows indicate the temperatures of the curves from the top to the bottom, respectively, at 32 deg.C, 34 deg.C, 36 deg.C, 38 deg.C, 40 deg.C, 42 deg.C, 44 deg.C, 46 deg.C, and 48 deg.C. Fig. 4 is a data fitting graph of interference spectrum in temperature experiment, and the selected data points are peaks and peaks of interference spectrum at different temperatures within the dotted line frame in fig. 3, where the slope is 0.13867 and the goodness of fit is 0.99048.
As can be seen from fig. 4, the interference spectrum of the temperature sensor shifts with a significant regularity as the temperature increases. In addition, the sensitivity of the sensor to the temperature can be obtained by processing the data of the interference spectrum drift amount and the temperature change in the temperature experiment, and the sensitivity can reach 138.67 pm/DEG C.
Claims (9)
1. The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor is characterized by comprising an ASE light source (1), an optical fiber circulator (2), a temperature sensing head (3) and a spectrometer (4);
the temperature sensing head (3) comprises a first single mode fiber (3-1), a multimode single sphere micro-nano fiber (3-2), a flower-shaped ZnO/graphene sensitive material (3-3), a second single mode fiber (3-4) and a metal aluminum film (3-5);
the temperature sensing head (3) takes a multimode single-sphere micro-nano optical fiber (3-2) as a temperature sensitive area, the multimode single-sphere micro-nano optical fiber (3-2) coats a temperature sensitive flower-shaped ZnO/graphene sensitive material (3-3), and is connected with a single mode fiber I (3-1) and a single mode fiber II (3-4) in an optical fiber fusion connection mode;
in the temperature sensing head (3), one end of a second single-mode fiber (3-4) is connected with the multimode single-sphere micro-nano fiber (3-2) in a melting way, and the other end of the second single-mode fiber is coated with a metal aluminum film (3-5);
the multimode single-sphere micro-nano optical fiber (3-2) takes a multimode optical fiber as a main body, the multimode micro-nano optical fiber is firstly prepared, and then the multimode micro-nano optical fiber is burnt at the tapered part of the multimode micro-nano optical fiber by utilizing a method of melting and tapering by oxyhydrogen flame and then reversely adjusting a clamp, so that the structure is formed;
the ASE light source (1) is connected with the optical fiber circulator (2) through a single-mode optical fiber, the optical fiber circulator (2) is connected with the temperature sensing head (3) through the single-mode optical fiber, the optical fiber circulator (2) is connected with the spectrometer (4) through the single-mode optical fiber, and the single-mode optical fiber is connected with each device in an optical fiber fusion connection mode.
2. The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor according to claim 1, wherein the output center wavelength of the ASE light source (1) is 1550nm, and the frequency bandwidth is 60 nm.
3. The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor according to claim 1, wherein the flower-shaped ZnO/graphene sensitive material (3-3) in the temperature sensing head (3) is a temperature composite sensitive material.
4. The flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor according to claim 1, wherein a method adopted by combining the multimode single-sphere micro-nano fiber (3-2) in the temperature sensing head (3) with the flower-shaped ZnO/graphene sensitive material (3-3) is a dropping coating method.
5. The preparation method of the flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor according to claim 1, which is characterized by comprising the following steps:
s1: preparing a multimode single-sphere micro-nano optical fiber (3-2), namely performing melt tapering on the multimode optical fiber with the length of 8cm and the fiber core diameter of 62.5 microns by using oxyhydrogen flame, and then performing treatment by using a method of reversely adjusting an optical fiber clamp in a heating state of the oxyhydrogen flame to prepare the multimode single-sphere micro-nano optical fiber (3-2);
s2: preparing a flower-shaped ZnO/graphene sensitive material (3-3), namely placing 15.0mg of graphene powder into 40mL of deionized water for ultrasonic dispersion for 2 hours, mixing the dispersed graphene solution with 3.5g of zinc nitrate, 4.8g of citric acid and 100mL of deionized water, stirring for 1.5 hours at the temperature of 75 ℃, placing the mixture into a constant-temperature drying box at the temperature of 90 ℃ for 1.5-2 hours, dripping 1.5mol/L of sodium hydroxide solution into the mixed solution, adjusting the pH value of the suspension to be 9.5, transferring the suspension into a reaction kettle, placing the reaction kettle into a constant-temperature drying box at the temperature of 125 ℃ for 15-16 hours, taking out the suspension, naturally cooling, washing a product with the deionized water for 4-5 times, and centrifuging for 15 minutes at 5000rmp/min to obtain a flower-shaped ZnO/graphene aqueous solution;
s3: preparing a single mode-tapering multi-mode-single mode fiber structure, intercepting two single mode fibers with the length of 5cm as a first single mode fiber (3-1) and a second single mode fiber (3-4), and connecting the first single mode fiber (3-1), the multi-mode single-sphere micro-nano fiber (3-2) and the second single mode fiber (3-4) in a fiber fusion connection mode to form the single mode-tapering multi-mode-single mode fiber structure;
s4: cladding of the metal aluminum film (3-5), namely truncating the end, which is not welded, of the second single-mode fiber (3-4) in the single-mode-tapered multi-mode-single-mode fiber structure, and cladding the metal aluminum film (2) with better reflection performance on the end;
s5: and (3) integrating a temperature sensing head (3), fixing a single-mode-tapered multi-mode-single-mode optical fiber structure which is manufactured but is not coated with a material in a dripping mode on a glass substrate, cleaning the glass substrate by using alcohol and deionized water to remove residual impurities, dripping flower-shaped ZnO/graphene aqueous solution along the surface of the multi-mode single-sphere micro-nano optical fiber (3-2), and putting the sensing head into a constant-temperature electrothermal blowing drying box for drying treatment to enable the sensitive material to be tightly combined with the multi-mode single-sphere micro-nano optical fiber (3-2) to form the temperature sensing head (3).
6. The preparation method of the flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor according to claim 5, wherein oxyhydrogen flame is used for fusion tapering in step S1, a oxyhydrogen flame tapering machine is used for fusion tapering by 12.4mm to form the multimode micro-nano optical fiber with the lumbar diameter of 6.92 microns, a clamp is adjusted back by 1mm, the multimode micro-nano optical fiber is burned and melted in the lumbar region by oxyhydrogen flame to form the multimode single-sphere micro-nano optical fiber (3-2), and the diameter of the single sphere is 13.1 microns.
7. The preparation method of the flower-like ZnO/graphene single-sphere micro-nano structure temperature sensor according to claim 5, wherein in the coating of the metallic aluminum film (3-5) in the step S4, the length of the second single-mode optical fiber (3-4) after being truncated is 3 cm.
8. The preparation method of the flower-like ZnO/graphene single-sphere micro-nano structure temperature sensor according to claim 5, wherein in the coating of the metallic aluminum film (3-5) in the step S4, the thickness of the metallic aluminum film (2) ranges from 80 μm to 200 μm.
9. The preparation method of the flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor according to claim 5, wherein in the integration of the temperature sensing head (3) in the step S5, the temperature of a constant temperature electrothermal blowing drying oven is set to be 45 ℃, and the heating time is 5 hours.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010030060.3A CN111122006B (en) | 2020-01-12 | 2020-01-12 | Flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor and manufacturing method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010030060.3A CN111122006B (en) | 2020-01-12 | 2020-01-12 | Flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor and manufacturing method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN111122006A CN111122006A (en) | 2020-05-08 |
CN111122006B true CN111122006B (en) | 2021-04-30 |
Family
ID=70487974
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202010030060.3A Expired - Fee Related CN111122006B (en) | 2020-01-12 | 2020-01-12 | Flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor and manufacturing method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN111122006B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112577628B (en) * | 2020-12-14 | 2023-01-17 | 武汉理工大学 | High-sensitivity temperature sensor of cascade light reflection device of interferometer with strong evanescent field |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102261966A (en) * | 2011-04-26 | 2011-11-30 | 北京东方锐择科技有限公司 | Fluorescent optical fiber temperature measurement optical system |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100437036C (en) * | 2006-11-16 | 2008-11-26 | 国家纳米技术与工程研究院 | Fibre optic sensor for measuring temperature and refractive index of liquid contemporarily |
WO2012178071A2 (en) * | 2011-06-23 | 2012-12-27 | Brown University | Device and methods for temperature and humidity measurements using a nanocomposite film sensor |
GB2534191A (en) * | 2015-01-16 | 2016-07-20 | Mahle Int Gmbh | Sliding bearing |
CN105561965B (en) * | 2015-12-31 | 2018-04-03 | 宿州学院 | A kind of preparation method of flower-shaped ZnO/ graphenes complex microsphere |
US10774450B2 (en) * | 2016-02-24 | 2020-09-15 | Tingying Zeng | Method to massively manufacture carbon fibers through graphene composites and the use thereof |
CN106745189B (en) * | 2016-11-30 | 2019-01-22 | 浙江理工大学 | A kind of ZnO quantum dot/graphene oxide composite material preparation method for material |
CN207964619U (en) * | 2017-12-08 | 2018-10-12 | 金陵科技学院 | A kind of fibre optical sensor and its detection platform |
CN207540692U (en) * | 2017-12-20 | 2018-06-26 | 广州大学 | Array fibre surveys metal/composite material interlayer temperature and strain device |
CN108254019A (en) * | 2017-12-29 | 2018-07-06 | 潘彦伶 | Highly sensitive environmental quality monitoring system based on graphene |
CN109238506B (en) * | 2018-10-30 | 2023-09-29 | 南通大学 | High-sensitivity temperature sensor and temperature detection system |
CN109827678A (en) * | 2019-03-14 | 2019-05-31 | 哈尔滨工程大学 | A kind of temperature sensor and preparation method thereof that conversion fluorescence is luminous |
CN110132328B (en) * | 2019-04-08 | 2021-05-07 | 东莞理工学院 | Optical fiber sensor based on thermal coupling enhancement effect and preparation method thereof |
-
2020
- 2020-01-12 CN CN202010030060.3A patent/CN111122006B/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102261966A (en) * | 2011-04-26 | 2011-11-30 | 北京东方锐择科技有限公司 | Fluorescent optical fiber temperature measurement optical system |
Also Published As
Publication number | Publication date |
---|---|
CN111122006A (en) | 2020-05-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0722105B1 (en) | Optical fibre with conical lens | |
CN104808287A (en) | Graphene-coated optical microfiber long-period grating and preparation method thereof | |
CN101367608B (en) | Method for manufacturing panda type polarization-preserving fiber | |
US5200024A (en) | Wet chemical etching technique for optical fibers | |
CN111122006B (en) | Flower-shaped ZnO/graphene single-sphere micro-nano structure temperature sensor and manufacturing method thereof | |
US4589725A (en) | Optical-fiber directional coupler using boron oxide as interstitial material | |
CN111505762B (en) | High-precision polarization maintaining optical fiber and preparation method thereof | |
CN110240402A (en) | A kind of saturating deep ultraviolet borosilicate glass of environment-friendly type and preparation method thereof, application | |
CN111122513A (en) | Sheet ZnO/graphene single-sphere micro-nano structure gas sensor and manufacturing method thereof | |
TW576934B (en) | Fabrication of microlensed fiber using doped silicon dioxide | |
CN114019430A (en) | Micro-optical fiber magnetic field sensor based on magnetostrictive material and preparation method | |
CN111121963B (en) | Rod-shaped ZnO/graphene single-sphere micro-nano structure ultraviolet sensor and manufacturing method thereof | |
CN110672135A (en) | Fiber bragg grating ultraviolet sensing method and device capable of compensating temperature | |
CN106597602A (en) | Micro-structure elliptical suspension core polarization maintaining optical fiber and manufacturing method thereof | |
CN108828796A (en) | Temperature-tunable filter based on wick-containing microcavity | |
JPH10218635A (en) | Production of optical fiber | |
CA1240015A (en) | Fiber-optic rotation sensor | |
CN103708721B (en) | A kind of manufacturing installation of polarization-preserving fiber preform and manufacture method | |
CN110217984A (en) | A kind of optical glass and its gas preform, element and instrument | |
CN113307490B (en) | Optical glass with high photoinduced refractive index change, optical fiber prepared from optical glass, and preparation method and application of optical fiber | |
CN106772812A (en) | A kind of single polarization fiber polarizer structure with extinction coat | |
CN1258823C (en) | Method for preparing monodisperse cadium sulfide-silicon dioxide nucleo capsid structure | |
Lv et al. | Fabrication of gradient refractive index ball lenses | |
CN112456789A (en) | Gourd-shaped polarization maintaining optical fiber and preparation method thereof | |
CN113405690B (en) | Temperature sensor based on torsion double-core optical fiber |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20210430 |