CN111109280A - Efficient compound pesticide composition containing phenthoate and application thereof - Google Patents

Efficient compound pesticide composition containing phenthoate and application thereof Download PDF

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Publication number
CN111109280A
CN111109280A CN201911390653.4A CN201911390653A CN111109280A CN 111109280 A CN111109280 A CN 111109280A CN 201911390653 A CN201911390653 A CN 201911390653A CN 111109280 A CN111109280 A CN 111109280A
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Prior art keywords
pesticide composition
pesticide
composition containing
percent
agent
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CN201911390653.4A
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Chinese (zh)
Inventor
肖建中
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Jiangsu Tenglong Biological Pharmaceutical Co Ltd
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Jiangsu Tenglong Biological Pharmaceutical Co Ltd
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Priority to CN201911390653.4A priority Critical patent/CN111109280A/en
Publication of CN111109280A publication Critical patent/CN111109280A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/12Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals

Abstract

The invention discloses a high-efficiency compound pesticide composition containing phenthoate, which comprises the following components in percentage by mass: rice is rich and scattered: 10-20%, dimethoate: 10-12%, indoxacarb: 10-15%, solvent: 5-10%, dispersant: 0.5-1%, stabilizer: 1-2%, wetting agent: 1-2%, adhesive: 0.8-1.2%, emulsifier: 2-4%, pH regulator: 1-3%, penetrant: 0.5-1%, defoamer: 1-2%, vector: 5-7 percent of deionized water, and the balance of the deionized water, wherein the sum of the components is 100 percent; the pesticide composition overcomes the defects of a single active component pesticide, has good prevention and treatment effects, and reduces the application dosage.

Description

Efficient compound pesticide composition containing phenthoate and application thereof
Technical Field
The invention relates to a pesticide, in particular to a high-efficiency compound pesticide composition containing phenthoate and application thereof, belonging to the field of agricultural chemicals.
Background
Daofengsan, also known as Yier san, Aier san, methyl ethyl phosphate, chemical name O, O-dimethyl-3- (ethyl benzyl) phosphorodithioate. The pesticide is a non-systemic organophosphorus pesticide, has the advantages of medium toxicity, low residue and wide insecticidal spectrum, can protect rice, cotton, vegetables, oil plants, fruit trees and other crops from being damaged by lepidoptera, leafhopper, aphids and soft beetles, and particularly has very remarkable effect on preventing and controlling snout moth's disease such as rice stem borer, tryporyza incertulas and the like and rice planthopper and other rice pests. Meanwhile, the phenthoate is a pesticide variety integrating insecticidal performance and bactericidal performance, has good control effect on rice pests, and simultaneously has certain control effect on rice false smut and sheath blight, so that the phenthoate can be used for replacing high-toxicity pesticides such as methamidophos and the like, and is also a specified replacement product of Ministry of agriculture.
In recent years, with the wide planting of hybrid rice, the mixed occurrence of diseases and pests in the middle and later stages of rice becomes more and more obvious. Insect pests such as rice planthopper, leafhopper and snout moth's larva including Chilo suppressalis, tryporyza incertulas, rice leaf roller and the like are getting more and more serious. The single pesticide has no obvious control effect, and two or more pesticides are mixed to achieve the effect of 'one pesticide and multiple pesticides' in consideration of economic benefit, so that the control effect is greatly improved, and time and labor are saved.
Disclosure of Invention
The invention aims to solve the technical problem that aiming at the defects in the prior art, the invention provides the efficient compound pesticide composition containing phenthoate and the use thereof.
The technical scheme for solving the technical problems is as follows:
the efficient compound pesticide composition containing phenthoate comprises the following components in percentage by mass:
rice is rich and scattered: 10-20%, dimethoate: 10-12%, indoxacarb: 10-15%, solvent: 5-10%, dispersant: 0.5-1%, stabilizer: 1-2%, wetting agent: 1-2%, adhesive: 0.8-1.2%, emulsifier: 2-4%, pH regulator: 1-3%, penetrant: 0.5-1%, defoamer: 1-2%, vector: 5-7 percent of deionized water, and the balance of deionized water, wherein the sum of the above components is 100 percent.
The invention further defines the technical scheme as follows:
in the efficient compound pesticide composition containing phenthoate, the phenthoate is as follows: 20%, dimethoate: 10%, indoxacarb: 13%, solvent: 10%, dispersant: 0.5%, stabilizer: 2%, wetting agent: 1%, adhesive: 1.2%, emulsifier: 3%, pH adjuster: 2%, penetrant: 0.8%, defoamer: 1%, carrier: 7 percent of deionized water, and the balance of deionized water, wherein the sum of the above components is 100 percent.
In the efficient compound pesticide composition containing phenthoate, the phenthoate is as follows: 10%, dimethoate: 12%, indoxacarb: 10%, solvent: 5%, dispersing agent: 1%, stabilizer: 1%, wetting agent: 2%, adhesive: 0.8%, emulsifier: 4%, pH adjuster: 3%, penetrant: 0.5%, defoamer: 2%, carrier: 5 percent, and the balance of deionized water, wherein the sum of the above components is 100 percent.
In the efficient compound pesticide composition containing phenthoate, the phenthoate is as follows: 15%, dimethoate: 11%, indoxacarb: 15%, solvent: 8%, dispersant: 0.8%, stabilizer: 1%, wetting agent: 1%, adhesive: 1% and emulsifier: 1%, pH regulator: 1%, penetrant: 1%, defoaming agent: 2%, carrier: 6 percent, and the balance of deionized water, wherein the sum of the above components is 100 percent.
In the efficient compound pesticide composition containing phenthoate, the carrier is one or a mixture of more of kaolin, bentonite, activated clay, sepiolite, white carbon black, diatomite, light calcium carbonate, talcum powder, plaster, chalk soil, pottery clay, montmorillonite and clay; the defoaming agent comprises an organosiloxane; the penetrating agent is organic silicon; the pH regulator comprises one or more of hydrochloric acid, phosphoric acid, acetic acid, sodium hydroxide, ammonia water, triethanolamine, sodium benzoate, etc.; polyethylene glycol as a binder; the wetting agent is sodium dodecyl sulfate and alkyl naphthalene sulfonate; the stabilizer is catechol or epoxidized soybean oil; the dispersant is sodium lignosulfonate or polycarboxylate; the solvent comprises one or more of toluene, xylene, cyclohexanone, dimethyl sulfoxide, sec-butyl acetate, aromatic solvent oil, methyl oleate, vegetable oil and the like.
In the efficient compound pesticide composition containing phenthoate, the emulsifier is a mixture of calcium dodecyl sulfonate, alkylphenol formaldehyde resin polyoxyethylene ether, aryl phenol polyoxyethylene ether phosphate, sec-butyl acetate and 120# solvent oil, and the mass ratio of the calcium dodecyl sulfonate is as follows: alkylphenol formaldehyde resin polyoxyethylene ether: aryl phenol polyoxyethylene ether phosphate ester: sec-butyl acetate: 120# mineral spirits =2:1:1:3: 5.
The emulsifier used in the invention is a compound emulsifier, which can improve the advantages and avoid the disadvantages, and avoid the disadvantages caused by single emulsifier, and can be used for processing various different missible oil products, thereby reducing or avoiding the use of harmful organic solvents such as toluene, xylene and the like in the traditional missible oil, reducing the pollution to the environment, and promoting the development of the missible oil; compared with a single emulsifier, the composite emulsifier has a remarkable synergistic effect.
In the efficient compound pesticide composition containing phenthoate, the preparation of the pesticide composition is as follows:
the pesticide composition is prepared by uniformly mixing the phenthoate, the dimethoate and the indoxacarb, then adding a solvent, a dispersing agent, a stabilizing agent, a wetting agent, an adhesive, an emulsifying agent, a pH regulator, a penetrating agent, a defoaming agent, a carrier and deionized water, uniformly mixing, and grinding.
The invention also relates to the use of the efficient compound pesticide composition containing phenthoate, and the pesticide composition is used for agricultural pests, and is specifically used as follows:
(1) selecting the pesticide composition according to the condition of insect pests, fully dissolving the pesticide composition with water, uniformly stirring, and preparing pesticide liquid;
(2) putting pesticide liquid into a pesticide liquid tank, simultaneously opening switches of the pesticide liquid tank and an irrigation system water tank, and spraying pesticide while irrigating;
(3) and (5) after spraying for 5-7d, fertilizing.
The invention has the beneficial effects that:
the pesticide composition ensures the stability of the insecticidal active ingredient and the stability of the composition by adding various auxiliary agents, is convenient to store and transport, has long shelf life, reduces the surface tension, improves the permeability, improves the knockdown speed and enhances the pesticide effect by adding the auxiliary agents.
The invention strictly controls the amount of each component, has reasonable proportion, enhances the quick action and reduces the use cost of the pesticide.
After the phenthoate, the dimethoate and the indoxacarb are compounded, the obvious synergistic effect on homoptera pests such as rice planthopper and the like is obtained, namely the quick-acting property of the pesticide is obvious, the lasting period is prolonged, the dosage and the obvious synergistic effect of pesticide application insects are reduced, namely the quick-acting property of the pesticide is obvious, the lasting period is prolonged, the dosage, the pesticide application frequency and the pesticide application cost are reduced, the pollution and the residue are low, and the generation of the drug resistance of the pests is delayed.
The pesticide prepared by combining the effective components of different pesticides is an effective and quick way for developing and researching new pesticides at present. When mixed, different varieties of pesticides typically exhibit three types of action: additive action, synergistic action and antagonistic action. The invention combines the three effective components, improves the control effect by 20-25 percent compared with single paddy rice, obviously improves the actual control effect, reduces the using amount of pesticide, greatly delays the generation of pest drug resistance and is an important means for comprehensive control.
Detailed Description
Example 1
The embodiment provides a high-efficiency compound pesticide composition containing phenthoate, which comprises the following components in percentage by mass:
rice is rich and scattered: 20%, dimethoate: 10%, indoxacarb: 13%, solvent: 10%, dispersant: 0.5%, stabilizer: 2%, wetting agent: 1%, adhesive: 1.2%, emulsifier: 3%, pH adjuster: 2%, penetrant: 0.8%, defoamer: 1%, carrier: 7 percent of deionized water, and the balance of deionized water, wherein the sum of the above components is 100 percent.
In this embodiment, the carrier is a mixture of white carbon black and diatomite; the defoaming agent comprises an organosiloxane; the penetrating agent is organic silicon; the pH regulator comprises hydrochloric acid; polyethylene glycol as a binder; the wetting agent is sodium dodecyl sulfate; the stabilizer is catechol; the dispersant is sodium lignosulfonate; the solvent comprises dimethyl sulfoxide.
In this embodiment, the emulsifier is a mixture of calcium dodecyl sulfonate, alkylphenol formaldehyde resin polyoxyethylene ether, aryl phenol polyoxyethylene ether phosphate, sec-butyl acetate, and 120# solvent oil, and the mass ratio of the calcium dodecyl sulfonate: alkylphenol formaldehyde resin polyoxyethylene ether: aryl phenol polyoxyethylene ether phosphate ester: sec-butyl acetate: 120# mineral spirits =2:1:1:3: 5.
In this example, the pesticide composition was prepared as follows:
the pesticide composition is prepared by uniformly mixing the phenthoate, the dimethoate and the indoxacarb, then adding a solvent, a dispersing agent, a stabilizing agent, a wetting agent, an adhesive, an emulsifying agent, a pH regulator, a penetrating agent, a defoaming agent, a carrier and deionized water, uniformly mixing, and grinding.
In the application of the efficient compound pesticide composition containing phenthoate, the pesticide composition is used for agricultural pests, and the specific application is as follows:
(1) selecting the pesticide composition according to the condition of insect pests, fully dissolving the pesticide composition with water, uniformly stirring, and preparing pesticide liquid;
(2) putting pesticide liquid into a pesticide liquid tank, simultaneously opening switches of the pesticide liquid tank and an irrigation system water tank, and spraying pesticide while irrigating;
(3) and (5) after spraying for 5d, fertilizing.
Example 2
The embodiment provides a high-efficiency compound pesticide composition containing phenthoate, which comprises the following components in percentage by mass:
rice is rich and scattered: 10%, dimethoate: 12%, indoxacarb: 10%, solvent: 5%, dispersing agent: 1%, stabilizer: 1%, wetting agent: 2%, adhesive: 0.8%, emulsifier: 4%, pH adjuster: 3%, penetrant: 0.5%, defoamer: 2%, carrier: 5 percent, and the balance of deionized water, wherein the sum of the above components is 100 percent.
In this example, the carrier is bentonite; the defoaming agent comprises an organosiloxane; the penetrating agent is organic silicon; the pH regulator comprises phosphoric acid; polyethylene glycol as a binder; the wetting agent is alkyl naphthalene sulfonate; the stabilizer is epoxidized soybean oil; the dispersant is polycarboxylate; the solvent comprises sec-butyl acetate.
In this embodiment, the emulsifier is a mixture of calcium dodecyl sulfonate, alkylphenol formaldehyde resin polyoxyethylene ether, aryl phenol polyoxyethylene ether phosphate, sec-butyl acetate, and 120# solvent oil, and the mass ratio of the calcium dodecyl sulfonate: alkylphenol formaldehyde resin polyoxyethylene ether: aryl phenol polyoxyethylene ether phosphate ester: sec-butyl acetate: 120# mineral spirits =2:1:1:3: 5.
In this example, the pesticide composition was prepared as follows:
the pesticide composition is prepared by uniformly mixing the phenthoate, the dimethoate and the indoxacarb, then adding a solvent, a dispersing agent, a stabilizing agent, a wetting agent, an adhesive, an emulsifying agent, a pH regulator, a penetrating agent, a defoaming agent, a carrier and deionized water, uniformly mixing, and grinding.
In the application of the efficient compound pesticide composition containing phenthoate, the pesticide composition is used for agricultural pests, and the specific application is as follows:
(1) selecting the pesticide composition according to the condition of insect pests, fully dissolving the pesticide composition with water, uniformly stirring, and preparing pesticide liquid;
(2) putting pesticide liquid into a pesticide liquid tank, simultaneously opening switches of the pesticide liquid tank and an irrigation system water tank, and spraying pesticide while irrigating;
(3) and (5) after spraying for 7d, fertilizing.
Example 3
The embodiment provides a high-efficiency compound pesticide composition containing phenthoate, which comprises the following components in percentage by mass:
rice is rich and scattered: 15%, dimethoate: 11%, indoxacarb: 15%, solvent: 8%, dispersant: 0.8%, stabilizer: 1%, wetting agent: 1%, adhesive: 1% and emulsifier: 1%, pH regulator: 1%, penetrant: 1%, defoaming agent: 2%, carrier: 6 percent, and the balance of deionized water, wherein the sum of the above components is 100 percent.
In this embodiment, the carrier is diatomite or montmorillonite; the defoaming agent comprises an organosiloxane; the penetrating agent is organic silicon; the pH regulator comprises acetic acid; polyethylene glycol as a binder; the wetting agent is sodium dodecyl sulfate; the stabilizer is catechol; the dispersant is sodium lignosulfonate; the solvent comprises vegetable oil.
In this embodiment, the emulsifier is a mixture of calcium dodecyl sulfonate, alkylphenol formaldehyde resin polyoxyethylene ether, aryl phenol polyoxyethylene ether phosphate, sec-butyl acetate, and 120# solvent oil, and the mass ratio of the calcium dodecyl sulfonate: alkylphenol formaldehyde resin polyoxyethylene ether: aryl phenol polyoxyethylene ether phosphate ester: sec-butyl acetate: 120# mineral spirits =2:1:1:3: 5.
In this example, the pesticide composition was prepared as follows:
the pesticide composition is prepared by uniformly mixing the phenthoate, the dimethoate and the indoxacarb, then adding a solvent, a dispersing agent, a stabilizing agent, a wetting agent, an adhesive, an emulsifying agent, a pH regulator, a penetrating agent, a defoaming agent, a carrier and deionized water, uniformly mixing, and grinding.
In the application of the efficient compound pesticide composition containing phenthoate, the pesticide composition is used for agricultural pests, and the specific application is as follows:
(1) selecting the pesticide composition according to the condition of insect pests, fully dissolving the pesticide composition with water, uniformly stirring, and preparing pesticide liquid;
(2) putting pesticide liquid into a pesticide liquid tank, simultaneously opening switches of the pesticide liquid tank and an irrigation system water tank, and spraying pesticide while irrigating;
(3) and (5) after spraying for 6d, fertilizing.
The pesticide composition prepared by the invention has better quick-acting property and durability of the pesticide effect; compared with the common medicament, the same or better medicament effect can be achieved by reducing the medicament application amount; compared with a single medicament, the pesticide has better effect and less dosage, is beneficial to delaying the drug resistance of pests and reduces the harm to the environment and human beings; emulsion in water is used to replace missible oil, so that the harm to the environment is reduced.
In addition to the above embodiments, the present invention may have other embodiments. All technical solutions formed by adopting equivalent substitutions or equivalent transformations fall within the protection scope of the claims of the present invention.

Claims (8)

1. The efficient compound pesticide composition containing phenthoate is characterized by comprising the following components in percentage by mass:
rice is rich and scattered: 10-20%, dimethoate: 10-12%, indoxacarb: 10-15%, solvent: 5-10%, dispersant: 0.5-1%, stabilizer: 1-2%, wetting agent: 1-2%, adhesive: 0.8-1.2%, emulsifier: 2-4%, pH regulator: 1-3%, penetrant: 0.5-1%, defoamer: 1-2%, vector: 5-7 percent of deionized water, and the balance of deionized water, wherein the sum of the above components is 100 percent.
2. The efficient compound pesticide composition containing phenthoate as claimed in claim 1, which is characterized in that: rice is rich and scattered: 20%, dimethoate: 10%, indoxacarb: 13%, solvent: 10%, dispersant: 0.5%, stabilizer: 2%, wetting agent: 1%, adhesive: 1.2%, emulsifier: 3%, pH adjuster: 2%, penetrant: 0.8%, defoamer: 1%, carrier: 7 percent of deionized water, and the balance of deionized water, wherein the sum of the above components is 100 percent.
3. The efficient compound pesticide composition containing phenthoate as claimed in claim 1, which is characterized in that: rice is rich and scattered: 10%, dimethoate: 12%, indoxacarb: 10%, solvent: 5%, dispersing agent: 1%, stabilizer: 1%, wetting agent: 2%, adhesive: 0.8%, emulsifier: 4%, pH adjuster: 3%, penetrant: 0.5%, defoamer: 2%, carrier: 5 percent, and the balance of deionized water, wherein the sum of the above components is 100 percent.
4. The efficient compound pesticide composition containing phenthoate as claimed in claim 1, which is characterized in that: rice is rich and scattered: 15%, dimethoate: 11%, indoxacarb: 15%, solvent: 8%, dispersant: 0.8%, stabilizer: 1%, wetting agent: 1%, adhesive: 1% and emulsifier: 1%, pH regulator: 1%, penetrant: 1%, defoaming agent: 2%, carrier: 6 percent, and the balance of deionized water, wherein the sum of the above components is 100 percent.
5. The highly effective built pesticide composition containing phenthoate as claimed in any one of claims 1 to 4, which is characterized in that: the carrier is one or a mixture of more of kaolin, bentonite, activated clay, sepiolite, white carbon black, diatomite, light calcium carbonate, talcum powder, calcined gypsum, chalk soil, argil, montmorillonite and clay; the defoaming agent comprises organic siloxane; the penetrating agent is organic silicon; the pH regulator comprises one or more of hydrochloric acid, phosphoric acid, acetic acid, sodium hydroxide, ammonia water, triethanolamine, sodium benzoate and the like; the adhesive is polyethylene glycol; the wetting agent is sodium dodecyl sulfate and alkyl naphthalene sulfonate; the stabilizer is catechol or epoxidized soybean oil; the dispersant is sodium lignosulphonate or polycarboxylate; the solvent comprises one or more of toluene, xylene, cyclohexanone, dimethyl sulfoxide, sec-butyl acetate, aromatic solvent oil, methyl oleate, vegetable oil and the like.
6. The efficient compound pesticide composition containing phenthoate as claimed in any one of claims 1 to 4, wherein the emulsifier is a mixture of calcium dodecyl sulfonate, alkylphenol formaldehyde resin polyoxyethylene ether, aryl phenol polyoxyethylene ether phosphate, sec-butyl acetate and 120# solvent oil, and the mass ratio of the calcium dodecyl sulfonate: alkylphenol formaldehyde resin polyoxyethylene ether: aryl phenol polyoxyethylene ether phosphate ester: sec-butyl acetate: 120# mineral spirits =2:1:1:3: 5.
7. The highly effective built pesticide composition containing phenthoate as claimed in any one of claims 1 to 4, which is characterized in that: the pesticide composition is prepared by the following steps:
the pesticide composition is prepared by uniformly mixing the phenthoate, the dimethoate and the indoxacarb, then adding a solvent, a dispersing agent, a stabilizing agent, a wetting agent, an adhesive, an emulsifying agent, a pH regulator, a penetrating agent, a defoaming agent, a carrier and deionized water, uniformly mixing, and grinding.
8. The use of the highly effective compounded pesticide composition containing phenthoate as claimed in any one of claims 1 to 4, is characterized in that the pesticide composition is used for agricultural pests, and the following are used specifically:
(1) selecting the pesticide composition according to the condition of insect pests, fully dissolving the pesticide composition with water, uniformly stirring, and preparing pesticide liquid;
(2) putting pesticide liquid into a pesticide liquid tank, simultaneously opening switches of the pesticide liquid tank and an irrigation system water tank, and spraying pesticide while irrigating;
(3) and (5) after spraying for 5-7d, fertilizing.
CN201911390653.4A 2019-12-30 2019-12-30 Efficient compound pesticide composition containing phenthoate and application thereof Pending CN111109280A (en)

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CN201911390653.4A CN111109280A (en) 2019-12-30 2019-12-30 Efficient compound pesticide composition containing phenthoate and application thereof

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Application Number Priority Date Filing Date Title
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102626110A (en) * 2012-03-20 2012-08-08 永农生物科学有限公司 Indoxacarb-containing complex pesticide composition
CN107950564A (en) * 2017-10-26 2018-04-24 江苏腾龙生物药业有限公司 A kind of composite insecticide and its preparation process containing phenthoate dimephenthoate cidial and dimethoate emulsifiable concentrate

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102626110A (en) * 2012-03-20 2012-08-08 永农生物科学有限公司 Indoxacarb-containing complex pesticide composition
CN107950564A (en) * 2017-10-26 2018-04-24 江苏腾龙生物药业有限公司 A kind of composite insecticide and its preparation process containing phenthoate dimephenthoate cidial and dimethoate emulsifiable concentrate

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Application publication date: 20200508