CN101218916A - Mix pesticide preparation of tubatoxin and antibiotic insecticide - Google Patents

Mix pesticide preparation of tubatoxin and antibiotic insecticide Download PDF

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Publication number
CN101218916A
CN101218916A CNA2007100326824A CN200710032682A CN101218916A CN 101218916 A CN101218916 A CN 101218916A CN A2007100326824 A CNA2007100326824 A CN A2007100326824A CN 200710032682 A CN200710032682 A CN 200710032682A CN 101218916 A CN101218916 A CN 101218916A
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rotenone
insecticide
antibiotic
mixed
preparation
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CN100594789C (en
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徐汉虹
江定心
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South China Agricultural University
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South China Agricultural University
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Abstract

The invention discloses a pesticide which is mixed-prepared by taking a rotenone and an antibiotic insecticide as main materials. The invention is prepared by mixing the rotenone with a weight percentage of 0.05 to 70 percent, the antibiotic insecticide with a weight percentage of 0.05 to 70 percent and the rest is accessory ingredient. The invention utilizes the synergistic actions between the rotenone and the antibiotic insecticide to reach the goals of overcoming drug fastness of the pests, enlarging the application range of the medicament and prolonging the persistent period of the medicament.

Description

Rotenone and antibiotic insecticide mixed insecticide preparation
Technical field
The invention belongs to technical field of pesticide, be specifically related to a kind of rotenone and antibiotic insecticide mixed insecticide preparation.
Background technology
The long-term single insecticide that uses a certain type that depends on of people, insect is easy to generate pesticide resistance, causes the dosage of chemical insecticide sharply to increase, and not only increases the weight of peasant's financial burden, contaminated environment, and the natural enemy of a large amount of kill pests, cause the wildness harm of insect.A large amount of mixed insecticides is arranged in the market, but the overwhelming majority is being mixed between the chemical pesticide, these mixtures mostly contain organophosphorus insecticides, and are bigger to people and animals' toxicity, easily cause the person poultry poisoning, and long-term the use, and insect also can develop immunity to drugs.
Rotenone is a kind of from the compound in plant derris root or the grey green soy bean blade, has good insecticidal activity, all effective to most of pest, consumption is low, and very fast degraded in environment does not injure natural enemy and other non-target organism, be a kind of outstanding biological insecticides, its shortcoming is that the performance drug effect is slower, instability, and the processing formulation is less.Antibiotic insecticide generally all is efficient or super-high-efficient insecticide, but some is to the high poison of people and animals, and some insecticidal spectrum is narrower.Because of a little rationally being mixed with rotenone and antibiotic insecticide can reach the purpose of mutual supplement with each other's advantages.
At present be mixed kind also seldom about rotenone and antibiotic insecticide.The applicant seeks rotenone and some antibiotic insecticides reasonably are mixed, and expectation obtains to overcome pest resistance to insecticide, enlarges insecticidal spectrum, reduces consumption, has the rotenone mixed insecticide of multiple formulation to fill up the art technology blank.
Summary of the invention
The objective of the invention is to fill up the art technology blank, a kind of rotenone and antibiotic insecticide mixed insecticide preparation of Environmental Safety is provided.By rationally being mixed between rotenone and the antibiotic insecticide, enlarge the insecticidal spectrum of medicament.Utilize rotenone to suppress the electronics transfer function of biological respiratory chain, delay the pesticide resistance of antibiotic insecticide, increase drug effect, reduce consumption, alleviate pollution environment.
Technical scheme of the present invention provides a kind of rotenone and antibiotic insecticide mixed insecticide preparation, by rotenone by weight 0.05~70%, antibiotic insecticide by weight 0.05~70% and the additive mixture of surplus form.
Described rotenone can be former medicine, contain one or more of the plant extract of rotenone or rotenone preparation, uses when multiple, and total usage amount can not be greater than the maximum of deal.
Described antibiotic insecticide is allosamidin, doractin (doramectin), emamectin (emamectin), according to general rhzomorph (eprinomectin), ivermectin (ivermectin), more visit among rhzomorph (milbemectin) or the selamectin one or more, use when multiple, total usage amount can not be greater than the maximum of shared weight proportion.
The active insecticidal components of described antibiotic insecticide can be former medicine and/or preparation.
As preferred versions more of the present invention, described rotenone and antibiotic insecticide mixed insecticide preparation are by rotenone by weight 0.5~50%, antibiotic insecticide allosamidin by weight 1~50% or doractin by weight 1~60% emamectin by weight 1~45% or according to general rhzomorph by weight 1~40% ivermectin by weight 1~40% or more visit rhzomorph by weight 1~55% or selamectin by weight 1~55% and the additive mixture of surplus form.
The invention has the beneficial effects as follows:
1. after rotenone and antibiotic insecticide are mixed, can widen the scope of application of medicament, prolong the lasting period.
2. after rotenone and aforementioned antibiotic insecticide were mixed, drug effect obviously improved, and dosage reduces, and has reduced use cost, alleviates the pollution to environment.
3. after rotenone and aforementioned antibiotic insecticide were mixed, mixture had obvious synergistic effect, delays the pesticide resistance of insect, and the resistance management of insect is had important effect.
4. because the compatibility and the reasonable mixture ratio of required each material of this insecticides of preparation can obviously alleviate the toxic action to various pest natural enemies, little to the infringement of ecotope, help protecting the person poultry safety.
Embodiment
In order to understand essence of an invention better, describe the technology contents of invention in detail below in conjunction with specific embodiment.
The preparation of embodiment 1:2.5% rotenone+emamectin missible oil, each composition weight proportioning is:
Rotenone is 0.05%;
Emamectin is 2.45%;
Surfactant: the dodecyl phenol polyethenoxy ether is 15%;
Cosolvent: methyl alcohol is 15%;
Anti-photodissociation agent: castor oil is 1%;
Stabilizing agent: epoxidized soybean oil is 17%;
Penetrating agent: Laurocapram is 12%;
Organic solvent: dimethylbenzene is mended to 100%;
Each component is put into modulation kettle mixes well and promptly gets product.
Embodiment 2:3% rotenone+according to the preparation of general rhzomorph missible oil, each composition weight proportioning is:
Rotenone is 0.3%;
According to general rhzomorph is 2.7%;
Surfactant: the dodecyl phenol polyethenoxy ether is 15%;
Cosolvent: methyl alcohol is 15%;
Anti-photodissociation agent: castor oil is 1%;
Stabilizing agent: epoxidized soybean oil is 17%;
Penetrating agent: Laurocapram is 12%;
Organic solvent: dimethylbenzene is mended to 100%;
Each component is put into modulation kettle mixes well and promptly gets product.
The preparation of embodiment 3:3% rotenone+emamectin missible oil, each composition weight proportioning is:
Rotenone is 2.95%;
Emamectin is 0.05%;
Surfactant: the dodecyl phenol polyethenoxy ether is 15%;
Cosolvent: methyl alcohol is 15%;
Anti-photodissociation agent: castor oil is 1%;
Stabilizing agent: epoxidized soybean oil is 17%;
Penetrating agent: Laurocapram is 12%;
Organic solvent: dimethylbenzene is mended to 100%;
Each component is put into modulation kettle mixes well and promptly gets product.
The preparation of embodiment 4:70.5% rotenone+ivermectin wetting powder, each composition weight proportioning is:
Rotenone is 70%;
Ivermectin is 0.5%;
Wetting agent: bay alcohol radical sodium sulphate is 10%;
Dispersant: alkylsulfonate is 10%;
Carrier: kaolin is mended to 100%;
With each component drying, cooling, mixing, the levigate product that promptly gets.
The preparation of embodiment 5:70.5% rotenone+emamectin wetting powder, each composition weight proportioning is:
Rotenone is 0.5%;
Emamectin is 70%;
Wetting agent: bay alcohol radical sodium sulphate is 10%;
Dispersant: alkylsulfonate is 10%;
Carrier: kaolin is mended to 100%;
With each component drying, cooling, mixing, the levigate product that promptly gets.
The preparation of embodiment 6:10% rotenone+emamectin wetting powder, each composition weight proportioning is:
Rotenone is 0.5%;
Emamectin is 9.5%;
Wetting agent: bay alcohol radical sodium sulphate is 25%;
Dispersant: alkylsulfonate is 22%;
Carrier: kaolin is mended to 100%;
With each component drying, cooling, mixing, the levigate product that promptly gets.
The preparation of embodiment 7:30% rotenone+allosamidin oil-suspending agent, each composition weight proportioning is:
Rotenone is 10%;
Allosamidin is 20%;
Dispersant: sodium lignin sulfonate is 10%;
Tackifier: bentonite is 3%;
Stabilizing agent: xanthan gum is 2%;
Defoamer: organic silicone is 5%;
Solvent: castor-oil plant oil subsidy to 100%;
Each component put into send into homogeneous blender mixing after the sand milling still grinds and promptly get product.
The preparation of embodiment 8:20% rotenone+allosamidin microemulsion, each composition weight proportioning is:
Rotenone is 8%;
Allosamidin is 12%;
Emulsifier: alkyl benzene sulfonate calcium salt is 20%;
Stabilizing agent: cresyl glycidyl ether is 13%;
Solvent: butanone is 20%;
Antifreezing agent: sorbierite is 3%;
Deionized water is mended to 100%.
Mixture is stirred in agitator, and the heating phase inversion promptly gets product.
The preparation of embodiment 9:18% rotenone+selamectin microemulsion, each composition weight proportioning is:
Rotenone is 8%;
Selamectin is 10%;
Emulsifier: alkyl benzene sulfonate calcium salt is 20%;
Stabilizing agent: cresyl glycidyl ether is 13%;
Solvent: butanone is 20%;
Antifreezing agent: sorbierite is 3%;
Deionized water is mended to 100%.
Mixture is stirred in agitator, and the heating phase inversion promptly gets product.
The preparation of embodiment 10:25% rotenone+doractin water-dispersible granules, each composition weight proportioning is:
Rotenone is 5%;
Doractin is 20%;
Wetting agent: sodium lignin sulfonate is 10%;
Binding agent: polyvinyl acetate is 9%;
Disintegrant: urea is 15%;
Carrier: atlapulgite is mended to 100%;
Mixture is carried out granulation after the ultra-fine grinding, drying, screening promptly get product.
Embodiment 11:30% rotenone+more visit the preparation of rhzomorph water-dispersible granules, each composition weight proportioning is:
Rotenone is 10%;
More visiing rhzomorph is 20%;
Wetting agent: sodium lignin sulfonate is 10%;
Binding agent: polyvinyl acetate is 9%;
Disintegrant: urea is 10%;
Carrier: atlapulgite is mended to 100%;
Mixture is carried out granulation after the ultra-fine grinding, drying, screening promptly get product.
Embodiment 12: the preparation of 30% rotenone+doractin microcapsule formulations, and each composition weight proportioning is:
Rotenone is 7%;
Doractin is 23%;
Dispersant: polyvinyl alcohol is 10%;
Cyst material: gelatin is mended to 100%.
Each component was mixed high-speed stirred 2 hours, saltout and isolate polymer, the formation micro-capsule of heating, freeze drying promptly gets product again.
The foregoing description 1~12 mixed insecticide preparation sees Table 1 according to the conventional virulence experiment in laboratory and single agent agricultural chemicals comparing result.
Each Mixed Pharmacy of table 1 is to diamond-back moth Toxicity Determination result
Medicament Extension rate Lethality
2.5% rotenone emulsifiable solution 1000 32.6%
5% emamectin suspending agent 1500 56.4%
5% according to general rhzomorph suspending agent 1500 67.5%
5% ivermectin suspending agent 1500 56.3%
The 5%allosamidin suspending agent 1500 62.7%
The 5%selamectin suspending agent 1500 53.6%
5% doractin suspending agent 1500 61.8%
5% more visits the rhzomorph suspending agent 1500 53.8%
0.05% rotenone+2.45% emamectin missible oil 3000 80.3%
0.3% rotenone+2.7% is according to general rhzomorph missible oil 3000 83.4%
2.95% rotenone+0.05% emamectin missible oil 3000 84.1%
70% rotenone+0.5% ivermectin wetting powder 10000 100%
0.5% rotenone+70% emamectin wetting powder 10000 100%
0.5% rotenone+9.5% emamectin wetting powder 5000 93.4%
10% rotenone+20%allosamidin oil-suspending agent 8000 93.5%
8% rotenone+12%allosamidin microemulsion 6000 92.4%
8% rotenone+10%selamectin microemulsion 6000 94.6%
5% rotenone+20% doractin water-dispersible granules 8000 92.7%
10% rotenone+20% is more visitd the rhzomorph water-dispersible granules 8000 94.7%
7% rotenone+23% doractin microcapsule formulations 8000 97.1%
Rotenone and the antibiotic insecticide synergy screening experiment that is mixed: single agent and mixture are made into the soup post processing diamond-back moth of variable concentrations, compare with clear water.Calculate the LC50 and the co-toxicity coefficient of medicament.Near 100 expression summation actions,, represent antagonisms as co-toxicity coefficient less than 100 greater than 100 expression synergistic effects.Result of the test sees Table 2.
Table 2 rotenone and allosamidin are mixed to diamond-back moth synergy screening test result
The medicament proportioning LC 50(μg/ml) 95% confidence limit Co-toxicity coefficient
Rotenone 39.86 24.71-64.29 0
allosamidin 2.46 1.86-3.27 0
Rotenone: allosamidin (1: 100) 2.26 1.49-3.43 110.05
Rotenone: allosamidin (1: 50) 1.86 1.36-2.54 134.94
Rotenone: allosamidin (100: 1) 34.28 21.28-55.22 101.08
Rotenone: allosamidin (50: 1) 24.04 15.94-36.27 127.76
Rotenone: allosamidin (1: 1) 2.75 1.95-3.86 168.89
Rotenone: allosamidin (1: 4) 2.21 1.63-2.99 137.32
Rotenone: allosamidin (1: 10) 2.11 1.39-3.18 127.90
Rotenone: allosamidin (1: 30) 2.31 1.75-3.06 109.94
Table 3 rotenone and doractin are mixed to diamond-back moth synergy screening test result
The medicament proportioning LC 50(μg/ml) 95% confidence limit Co-toxicity coefficient
Rotenone 39.86 24.71-64.29 0
Doractin 4.87 3.59-6.59 0
Rotenone: doractin (1: 100) 5.04 3.25-7.81 102.44
Rotenone: doractin (1: 50) 3.99 2.93-5.45 123.93
Rotenone: doractin (100: 1) 32.33 20.75-50.38 115.09
Rotenone: doractin (50: 1) 24.68 17.69-34.43 141.56
Rotenone: doractin (1: 1) 7.19 5.34-9.69 120.55
Rotenone: doractin (1: 4) 4.32 3.18-5.86 136.73
Rotenone: doractin (1: 10) 4.37 2.90-6.57 121.13
Rotenone: doractin (1: 30) 4.60 3.43-6.18 108.81
Table 4 rotenone and emamectin are mixed to diamond-back moth synergy screening test result
The medicament proportioning LC 50(μg/ml) 95% confidence limit Co-toxicity coefficient
Rotenone 39.86 24.71-64.29 0
Emamectin 4.63 3.40-6.30 0
Rotenone: emamectin (1: 100) 4.29 2.99-6.16 108.73
Rotenone: emamectin (1: 50) 4.38 3.23-5.94 107.46
Rotenone: emamectin (100: 1) 34.12 22.86-50.93 108.62
Rotenone: emamectin (50: 1) 28.64 19.44-42.18 121.09
Rotenone: emamectin (1: 1) 6.05 4.40-8.33 137.02
Rotenone: emamectin (1: 4) 3.43 2.49-4.71 163.91
Rotenone: emamectin (1: 10) 3.79 2.56-5.60 132.84
Rotenone: emamectin (1: 30) 4.50 3.19-6.34 105.92
Table 5 rotenone be mixed to diamond-back moth synergy screening test result according to general rhzomorph
The medicament proportioning LC 50(μg/ml) 95% confidence limit Co-toxicity coefficient
Rotenone 39.86 24.71-64.29 0
According to general rhzomorph 5.76 3.99-8.31 0
Rotenone: according to general rhzomorph (1: 100) 4.57 3.15-6.64 127.08
Rotenone: according to general rhzomorph (1: 50) 3.95 2.87-5.43 148.42
Rotenone: according to general rhzomorph (100: 1) 32.33 20.75-50.38 116.46
Rotenone: according to general rhzomorph (50: 1) 25.38 18.08-35.62 140.71
Rotenone: according to general rhzomorph (1: 1) 5.50 3.91-7.73 183.19
Rotenone: according to general rhzomorph (1: 4) 4.71 3.51-6.32 147.69
Rotenone: according to general rhzomorph (1: 10) 3.64 2.72-4.87 171.82
Rotenone: according to general rhzomorph (1: 30) 4.31 3.30-5.64 137.36
Table 6 rotenone and ivermectin are mixed to diamond-back moth synergy screening test result
The medicament proportioning LC 50(μg/ml) 95% confidence limit Co-toxicity coefficient
Rotenone 39.86 24.71-64.29 0
Ivermectin 11.43 8.51-15.35 0
Rotenone: ivermectin (1: 100) 9.75 6.35-14.96 118.14
Rotenone: ivermectin (1: 50) 8.34 6.21-11.21 138.95
Rotenone: ivermectin (100: 1) 31.05 20.22-47.68 125.28
Rotenone: ivermectin (50: 1) 22.17 16.49-29.82 171.38
Rotenone: ivermectin (1: 1) 10.98 8.32-14.50 161.77
Rotenone: ivermectin (1: 4) 9.72 7.31-12.93 137.19
Rotenone: ivermectin (1: 10) 9.49 6.41-14.05 128.85
Rotenone: ivermectin (1: 30) 9.12 6.71-12.39 128.30
Table 7 rotenone with more visit rhzomorph and be mixed diamond-back moth synergy screening test result
The medicament proportioning LC 50(μg/ml) 95% confidence limit Co-toxicity coefficient
Rotenone 39.86 24.71-64.29 0
More visit rhzomorph 1.39 1.01-1.92 0
Rotenone: more visit rhzomorph (1: 100) 1.22 0.78-1.89 115.47
Rotenone: more visit rhzomorph (1: 50) 1.05 0.76-1.45 134.59
Rotenone: more visit rhzomorph (100: 1) 20.52 15.16-27.78 152.46
Rotenone: more visit rhzomorph (50: 1) 15.11 10.52-21.71 171.01
Rotenone: more visit rhzomorph (1: 1) 1.38 0.95-2.02 194.15
Rotenone: more visit rhzomorph (1: 4) 12.74 0.80-1.53 155.29
Rotenone: more visit rhzomorph (1: 10) 1.15 0.79-1.66 132.70
Rotenone: more visit rhzomorph (1: 30) 1.28 0.94-1.76 111.76
Table 8 rotenone and selamectin are mixed to diamond-back moth synergy screening test result
The medicament proportioning LC 50(μg/ml) 95% confidence limit Co-toxicity coefficient
Rotenone 39.86 24.71-64.29 0
selamectin 1.14 0.85-1.54 0
Rotenone: selamectin (1: 100) 1.10 0.77-1.57 104.69
Rotenone: selamectin (1: 50) 1.03 0.78-1.38 112.71
Rotenone: selamectin (100: 1) 21.69 16.35-28.78 137.59
Rotenone: selamectin (50: 1) 19.78 15.52-25.21 121.06
Rotenone: selamectin (1: 1) 1.45 1.03-2.04 153.33
Rotenone: selamectin (1: 4) 1.02 0.78-1.35 138.65
Rotenone: selamectin (1: 10) 0.88 0.63-1.24 142.11
Rotenone: selamectin (1: 30) 0.92 0.70-1.22 127.66
From table 2-8 as can be seen, rotenone and described antibiotic insecticide are mixed, and co-toxicity coefficient is all greater than 100, show that rotenone and these antibiotic insecticides rationally are mixed and have synergistic effect.
The field effect experiment of embodiment 13 rotenone and antibiotic insecticide mixed insecticide preparation
Test one: 2000 times 2.5% rotenone and emamectin missible oil to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 71.5%, 90.8%, 93.9%, 95.8%; 500 times of 2.5% rotenone emulsifiable solution to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 15.8%, 61.7%, 83.4%, 71.3%; 1000 times of 5% emamectin suspending agent to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 56.1%, 83.2%, 81.3%, 52.6%.
Test two: 5000 times 20% rotenone and allosamidin microemulsion to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 67.9%, 88.8%, 94.2%, 92.3%; 500 times of 2.5% rotenone emulsifiable solution to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 15.8%, 61.7%, 83.4%, 71.3%; 1000 times of 5%allosamidin suspending agents to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 43.3%, 57.5%, 68.8%, 53.1%.
Test three: 6000 times 25% rotenone and doractin water-dispersible granules to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 72.5%, 89.0%, 95.3%, 93.8%; 500 times of 2.5% rotenone emulsifiable solution to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 15.8%, 61.7%, 83.4%, 71.3%; 1000 times of 5% doractin suspending agent to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 53.6%, 61.1%, 71.9%, 50.3%.
Test four: 8000 times 70.5% rotenone and ivermectin wetting powder to the Spodoptera litura larvae medication after the 1st, 3,7,14 day preventive effect be respectively 77.4%, 89.6%, 98.3%, 93.4%; 500 times of 2.5% rotenone emulsifiable solution to the Spodoptera litura larvae medication after the 1st, 3,7,14 day preventive effect be respectively 25.3%, 51.4%, 73.2%, 61.38%; 1000 times of 5% ivermectin suspending agent to the Spodoptera litura larvae medication after the 1st, 3,7,14 day preventive effect be respectively 43.9%, 65.1%, 78.8%, 60.1%.
Contrast with former agricultural chemicals from the above-mentioned test of pesticide effectiveness explanation agricultural chemicals that the present invention was mixed, the control of insect is had remarkable synergistic effect and control efficiency.

Claims (5)

1. rotenone and antibiotic insecticide mixed insecticide preparation, it is characterized in that by rotenone by weight 0.05~70%, antibiotic insecticide by weight 0.05~70% and the additive mixture of surplus form.
2. according to described rotenone of claim 1 and antibiotic insecticide mixed insecticide preparation, it is characterized in that described rotenone can be former medicine, contain one or more of the plant extract of rotenone or rotenone preparation.
3. according to described rotenone of claim 1 and antibiotic insecticide mixed insecticide preparation, it is characterized in that described antibiotic insecticide is allosamidin, doractin, emamectin or according to general rhzomorph, ivermectin, more visit among rhzomorph or the selamectin one or more.
4. according to described rotenone of claim 3 and antibiotic insecticide mixed insecticide preparation, it is characterized in that described antibiotic insecticide can be former medicine and/or preparation.
5. according to described rotenone of claim 1 and antibiotic insecticide mixed insecticide preparation, it is characterized in that by rotenone by weight 0.5~50%, antibiotic insecticide allosamidin by weight 1~50% or doractin by weight 1~60% emamectin by weight 1~45% or according to general rhzomorph by weight 1~40% ivermectin by weight 1~40% or more visit rhzomorph by weight 1~55% or selamectin by weight 1~55% and the additive mixture of surplus form.
CN200710032682A 2007-12-18 2007-12-18 Mix pesticide preparation of tubatoxin and antibiotic insecticide Expired - Fee Related CN100594789C (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102484991A (en) * 2010-12-02 2012-06-06 华南农业大学 Synergic farm pesticide composition of ivermectin and tea saponin
CN104082316A (en) * 2014-06-25 2014-10-08 广州市秀田生物工程有限公司 Pesticide composition and preparation method thereof
CN104996437A (en) * 2015-06-08 2015-10-28 诺农(北京)国际生物技术有限公司 Doramectin and plant source pesticide combination

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102484991A (en) * 2010-12-02 2012-06-06 华南农业大学 Synergic farm pesticide composition of ivermectin and tea saponin
CN102484991B (en) * 2010-12-02 2014-11-12 华南农业大学 Synergic farm pesticide composition of ivermectin and tea saponin
CN104082316A (en) * 2014-06-25 2014-10-08 广州市秀田生物工程有限公司 Pesticide composition and preparation method thereof
CN104996437A (en) * 2015-06-08 2015-10-28 诺农(北京)国际生物技术有限公司 Doramectin and plant source pesticide combination

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