CN111101681A - High-wear-resistance scratch-resistant carbon nano heat-conducting composite floor - Google Patents
High-wear-resistance scratch-resistant carbon nano heat-conducting composite floor Download PDFInfo
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- CN111101681A CN111101681A CN202010006707.9A CN202010006707A CN111101681A CN 111101681 A CN111101681 A CN 111101681A CN 202010006707 A CN202010006707 A CN 202010006707A CN 111101681 A CN111101681 A CN 111101681A
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/382—Boron-containing compounds and nitrogen
- C08K2003/385—Binary compounds of nitrogen with boron
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/02—Specially adapted covering, lining or flooring elements not otherwise provided for for accommodating service installations or utility lines, e.g. heating conduits, electrical lines, lighting devices or service outlets
- E04F2290/023—Specially adapted covering, lining or flooring elements not otherwise provided for for accommodating service installations or utility lines, e.g. heating conduits, electrical lines, lighting devices or service outlets for heating
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- Organic Chemistry (AREA)
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- Structural Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
The invention belongs to the technical field of floors, and particularly relates to a high-wear-resistance scratch-resistant carbon nano heat-conducting composite floor which comprises a main support layer formed by a composite material, wherein the main support layer is of a strip-shaped plate structure, six surfaces outside the strip-shaped plate structure are uniformly provided with a carbon nano heat-conducting composite layer, five surfaces outside the carbon nano heat-conducting composite layer except the bottom surface are uniformly provided with an external wrapping layer formed by the composite material, the defects of the prior art are overcome, the main support layer wrapped inside is formed by carbon nano and polyvinyl chloride resin and other materials, then, the external wrapping layers are arranged on five surfaces outside the carbon nano heat-conducting composite layer, the bottom of the external wrapping layer is open, the heat energy is more favorably contacted with the carbon nano heat-conducting composite layer, then the heat energy is transmitted to other parts, finally, the heat is emitted out through the external wrapping layer, the, energy conservation and environmental protection, and wide application range.
Description
Technical Field
The invention belongs to the technical field of floors, and particularly relates to a high-wear-resistance scratch-resistant carbon nano heat-conducting composite floor.
Background
Floor, i.e. the surface layer of the floor or floor of a house. Made of wood or other material. There are many classifications of floors, classified by structure: solid wood floors, laminate wood floors, three-layer solid wood laminate floors, bamboo and wood floors, anti-corrosion floors, cork floors, and the most popular multilayer solid wood laminate floors; classified by use are: household, commercial, antistatic floors, outdoor floors, floors dedicated to stage dancing, floors dedicated to sports stadiums, floors dedicated to track and field, etc.; the environmental protection grades are classified as follows: e0 grade floor, E1 grade floor, F4 grade floor, JAS star standard F4 star floor, and the like.
The existing floor has a common characteristic that the heat conduction is slow, so that the heat conduction is slow in occasions where floor heating is needed to be installed, and a large amount of heat energy is wasted.
Disclosure of Invention
The invention aims to provide a high-wear-resistance scratch-resistant carbon nano heat-conducting composite floor, which overcomes the defects of the prior art, a main supporting layer wrapped inside is formed by utilizing materials such as carbon nano and polyvinyl chloride resin, then, external wrapping layers are arranged on five surfaces outside a carbon nano heat-conducting composite layer, the bottom of each external wrapping layer is open, so that heat energy is more favorably contacted with the carbon nano heat-conducting composite layer, the heat energy is transmitted to other parts, and finally, the heat energy is emitted out through the external wrapping layers without passing through the main supporting layer, the heat conduction speed is greatly improved, the effect is energy-saving and environment-friendly, the application range is wide, and meanwhile, the external wrapping layer formed by composite materials keeps the high-wear-resistance scratch-.
In order to solve the problems, the technical scheme adopted by the invention is as follows:
the utility model provides a high wear-resisting resistant carbon nanometer heat conduction laminate flooring of scraping, includes the main tributary supporting layer that combined material constitutes, the main tributary supporting layer is the bar plate structure, six outside even carbon nanometer heat conduction composite beds that are equipped with of bar plate structure, the outside other five even outside parcel layers that are equipped with by combined material that remove the bottom surface of carbon nanometer heat conduction composite bed.
Further, the carbon nano heat-conducting composite layer comprises, by weight, 100 parts of polyvinyl chloride resin, 25-30 parts of nano carbon-coated boron nitride composite powder, 1-5 parts of a heat stabilizer, 1-5 parts of a flame retardant, 5-8 parts of an antifoaming agent, 2-5 parts of a dispersant, 1-5 parts of an anti-aging agent, 2-3 parts of a thickener, 5-10 parts of a plasticizer, 5-8 parts of a pigment and 1.5-2 parts of a leveling agent.
Further, the carbon nano heat-conducting composite layer comprises, by weight, 100 parts of polyvinyl chloride resin, 25 parts of nano carbon-coated boron nitride composite powder, 3 parts of a heat stabilizer, 3 parts of a flame retardant, 7 parts of a defoaming agent, 3 parts of a dispersing agent, 2 parts of an anti-aging agent, 2.3 parts of a thickening agent, 7 parts of a plasticizer, 6.5 parts of a pigment and 1.5 parts of a leveling agent.
Further, the preparation method of the carbon nano heat-conducting composite layer comprises the following steps: firstly, after polyvinyl chloride resin, nano carbon-coated boron nitride composite powder, a heat stabilizer, a flame retardant, an antifoaming agent, a dispersing agent, an anti-aging agent and a leveling agent are installed in a weight ratio, the mixture is uniformly stirred and heated to 200 ℃, the mixture is continuously stirred for 20 minutes, then a thickening agent, a plasticizer, a pigment and the antifoaming agent are added, the mixture is continuously stirred for 10 minutes and then is static, and the mixture is uniformly smeared or sprayed on the outer surface of a main support layer by using a smearing or spraying device.
Further, the preparation method of the nano carbon coated boron nitride composite powder comprises the following steps: adding a nano carbon material raw material into a nitric acid solution with the concentration of 2-8M, refluxing for 1-24h at the temperature of 140 ℃, filtering, washing a filter to be neutral to obtain the carboxylated nano carbon material, dispersing the carboxylated nano carbon material in water, gradually adding amino functionalized boron nitride powder under the condition of high-speed stirring, mixing and stirring for 10min-2h, filtering, and drying a filter in vacuum at the temperature of 60-100 ℃ to obtain the nano carbon coated boron nitride composite powder.
Compared with the prior art, the invention has the following beneficial effects:
1. utilize materials such as carbon nanometer and polyvinyl chloride resin to constitute the main supporting layer of the inside parcel, then set up outside parcel layer at five outside faces of carbon nanometer heat conduction composite bed, outside parcel layer bottom is open and more does benefit to heat energy and carbon nanometer heat conduction composite bed and contacts, then transmits other positions, gives out through outside parcel layer at last, need not pass through the main supporting layer, great improvement heat-conducting speed the effect, energy-concerving and environment-protective, application scope is wide.
2. The carbon nano heat-conducting composite layer not only has ultrahigh heat conductivity, but also has radiation rate close to a theoretical black body, so that the infrared radiation heat dissipation function of the carbon nano heat-conducting composite layer is enhanced, the current floor heating heat dissipation mode is expected to be changed, and the heat exchange capacity is greatly improved.
3. The outer coating of the composite material retains its high abrasion and scratch resistance properties.
Drawings
Fig. 1 is a schematic structural diagram of a high-wear-resistant scratch-resistant carbon nano heat-conducting composite floor.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example one
As shown in the figures, the high-wear-resistance scratch-resistance carbon nano heat-conducting composite floor provided by the invention comprises a main support layer 1 made of a composite material, wherein the main support layer is of a strip-shaped plate structure, six surfaces outside the strip-shaped plate structure are uniformly provided with carbon nano heat-conducting composite layers 2, and the other five surfaces outside the carbon nano heat-conducting composite layers except the bottom surface are uniformly provided with outer wrapping layers 3 made of the composite material.
Example two
The carbon nano heat-conducting composite layer comprises, by weight, 100 parts of polyvinyl chloride resin, 25-30 parts of nano carbon-coated boron nitride composite powder, 1-5 parts of a heat stabilizer, 1-5 parts of a flame retardant, 5-8 parts of an antifoaming agent, 2-5 parts of a dispersant, 1-5 parts of an anti-aging agent, 2-3 parts of a thickener, 5-10 parts of a plasticizer, 5-8 parts of a pigment and 1.5-2 parts of a leveling agent.
EXAMPLE III
The carbon nano heat-conducting composite layer comprises, by weight, 100 parts of polyvinyl chloride resin, 25 parts of nano carbon-coated boron nitride composite powder, 3 parts of a heat stabilizer, 3 parts of a flame retardant, 7 parts of an antifoaming agent, 3 parts of a dispersant, 2 parts of an anti-aging agent, 2.3 parts of a thickener, 7 parts of a plasticizer, 6.5 parts of a pigment and 1.5 parts of a leveling agent.
Example four
The preparation method of the carbon nano heat-conducting composite layer comprises the following steps: firstly, after polyvinyl chloride resin, nano carbon-coated boron nitride composite powder, a heat stabilizer, a flame retardant, an antifoaming agent, a dispersing agent, an anti-aging agent and a leveling agent are installed in a weight ratio, the mixture is uniformly stirred and heated to 200 ℃, the mixture is continuously stirred for 20 minutes, then a thickening agent, a plasticizer, a pigment and the antifoaming agent are added, the mixture is continuously stirred for 10 minutes and then is static, and the mixture is uniformly smeared or sprayed on the outer surface of a main support layer by using a smearing or spraying device.
EXAMPLE five
The preparation method of the nanometer carbon coated boron nitride composite powder comprises the following steps: adding a nano carbon material raw material into a nitric acid solution with the concentration of 2-8M, refluxing for 1-24h at the temperature of 140 ℃, filtering, washing a filter to be neutral to obtain the carboxylated nano carbon material, dispersing the carboxylated nano carbon material in water, gradually adding amino functionalized boron nitride powder under the condition of high-speed stirring, mixing and stirring for 10min-2h, filtering, and drying a filter in vacuum at the temperature of 60-100 ℃ to obtain the nano carbon coated boron nitride composite powder.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Claims (5)
1. The utility model provides a high wear-resisting resistant carbon nanometer heat conduction laminate flooring that scrapes which characterized in that: the main tributary supporting layer that constitutes including combined material, the main tributary supporting layer is the strip shaped plate structure, six outside even carbon nanometer heat conduction composite beds that are equipped with of strip shaped plate structure, the outside other five even outside parcel layers that are equipped with that constitute by combined material that remove the bottom surface of carbon nanometer heat conduction composite bed.
2. The carbon nano heat-conducting composite floor with high wear resistance and scratch resistance as claimed in claim 1, wherein: the carbon nano heat-conducting composite layer comprises, by weight, 100 parts of polyvinyl chloride resin, 25-30 parts of nano carbon-coated boron nitride composite powder, 1-5 parts of a heat stabilizer, 1-5 parts of a flame retardant, 5-8 parts of an antifoaming agent, 2-5 parts of a dispersant, 1-5 parts of an anti-aging agent, 2-3 parts of a thickener, 5-10 parts of a plasticizer, 5-8 parts of a pigment and 1.5-2 parts of a leveling agent.
3. The carbon nano heat-conducting composite floor with high wear resistance and scratch resistance as claimed in claim 1, wherein: the carbon nano heat-conducting composite layer comprises, by weight, 100 parts of polyvinyl chloride resin, 25 parts of nano carbon-coated boron nitride composite powder, 3 parts of a heat stabilizer, 3 parts of a flame retardant, 7 parts of an antifoaming agent, 3 parts of a dispersant, 2 parts of an anti-aging agent, 2.3 parts of a thickener, 7 parts of a plasticizer, 6.5 parts of a pigment and 1.5 parts of a leveling agent.
4. The high-wear-resistance scratch-resistant carbon nano heat-conducting composite floor as claimed in claim 2 or 3, wherein: the preparation method of the carbon nano heat-conducting composite layer comprises the following steps: firstly, after polyvinyl chloride resin, nano carbon-coated boron nitride composite powder, a heat stabilizer, a flame retardant, an antifoaming agent, a dispersing agent, an anti-aging agent and a leveling agent are installed in a weight ratio, the mixture is uniformly stirred and heated to 200 ℃, the mixture is continuously stirred for 20 minutes, then a thickening agent, a plasticizer, a pigment and the antifoaming agent are added, the mixture is continuously stirred for 10 minutes and then is static, and the mixture is uniformly smeared or sprayed on the outer surface of a main support layer by using a smearing or spraying device.
5. The high-wear-resistance scratch-resistant carbon nano heat-conducting composite floor as claimed in claim 4, wherein: the preparation method of the nanometer carbon coated boron nitride composite powder comprises the following steps: adding a nano carbon material raw material into a nitric acid solution with the concentration of 2-8M, refluxing for 1-24h at the temperature of 140 ℃, filtering, washing a filter to be neutral to obtain the carboxylated nano carbon material, dispersing the carboxylated nano carbon material in water, gradually adding amino functionalized boron nitride powder under the condition of high-speed stirring, mixing and stirring for 10min-2h, filtering, and drying a filter in vacuum at the temperature of 60-100 ℃ to obtain the nano carbon coated boron nitride composite powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010006707.9A CN111101681A (en) | 2020-01-03 | 2020-01-03 | High-wear-resistance scratch-resistant carbon nano heat-conducting composite floor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010006707.9A CN111101681A (en) | 2020-01-03 | 2020-01-03 | High-wear-resistance scratch-resistant carbon nano heat-conducting composite floor |
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| Publication Number | Publication Date |
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| CN111101681A true CN111101681A (en) | 2020-05-05 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN202010006707.9A Pending CN111101681A (en) | 2020-01-03 | 2020-01-03 | High-wear-resistance scratch-resistant carbon nano heat-conducting composite floor |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104788959A (en) * | 2015-03-31 | 2015-07-22 | 中国科学院化学研究所 | Thermal conductive composite material provided with orientation structure and preparation method of thermal conductive composite material |
| CN104804618A (en) * | 2014-01-24 | 2015-07-29 | 江苏联科纳米科技有限公司 | Aqueous heat dissipation coating and preparation method thereof |
| CN104803369A (en) * | 2014-01-24 | 2015-07-29 | 江苏联科纳米科技有限公司 | Nanometer carbon-coated boron nitride composite powder and its preparation method and use |
| CN105038033A (en) * | 2015-08-21 | 2015-11-11 | 安徽优胜美塑胶有限公司 | PVC (polyvinyl chloride) plastic floor |
| KR20150135619A (en) * | 2014-05-22 | 2015-12-03 | (주)엘지하우시스 | Floor material improved sound insulation and thermal conductivity |
| CN106671501A (en) * | 2017-01-13 | 2017-05-17 | 重庆云天化瀚恩新材料开发有限公司 | Highly heat-resistant graphite film metal composite and preparation method thereof |
| CN109587842A (en) * | 2018-11-08 | 2019-04-05 | 中国科学院山西煤炭化学研究所 | A kind of graphene-based self limiting temperature electric heating slurry and preparation method thereof and the application in electric heating floor system |
-
2020
- 2020-01-03 CN CN202010006707.9A patent/CN111101681A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104804618A (en) * | 2014-01-24 | 2015-07-29 | 江苏联科纳米科技有限公司 | Aqueous heat dissipation coating and preparation method thereof |
| CN104803369A (en) * | 2014-01-24 | 2015-07-29 | 江苏联科纳米科技有限公司 | Nanometer carbon-coated boron nitride composite powder and its preparation method and use |
| KR20150135619A (en) * | 2014-05-22 | 2015-12-03 | (주)엘지하우시스 | Floor material improved sound insulation and thermal conductivity |
| CN104788959A (en) * | 2015-03-31 | 2015-07-22 | 中国科学院化学研究所 | Thermal conductive composite material provided with orientation structure and preparation method of thermal conductive composite material |
| CN105038033A (en) * | 2015-08-21 | 2015-11-11 | 安徽优胜美塑胶有限公司 | PVC (polyvinyl chloride) plastic floor |
| CN106671501A (en) * | 2017-01-13 | 2017-05-17 | 重庆云天化瀚恩新材料开发有限公司 | Highly heat-resistant graphite film metal composite and preparation method thereof |
| CN109587842A (en) * | 2018-11-08 | 2019-04-05 | 中国科学院山西煤炭化学研究所 | A kind of graphene-based self limiting temperature electric heating slurry and preparation method thereof and the application in electric heating floor system |
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