CN111094603B - Corrosion-resistant alloy - Google Patents
Corrosion-resistant alloy Download PDFInfo
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- CN111094603B CN111094603B CN201780092598.3A CN201780092598A CN111094603B CN 111094603 B CN111094603 B CN 111094603B CN 201780092598 A CN201780092598 A CN 201780092598A CN 111094603 B CN111094603 B CN 111094603B
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- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 61
- 239000000956 alloy Substances 0.000 title claims abstract description 61
- 230000007797 corrosion Effects 0.000 title claims description 23
- 238000005260 corrosion Methods 0.000 title claims description 23
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 14
- 239000011651 chromium Substances 0.000 claims abstract description 14
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 13
- 239000010955 niobium Substances 0.000 claims abstract description 13
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 13
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 12
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 12
- 239000011733 molybdenum Substances 0.000 claims abstract description 12
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052742 iron Inorganic materials 0.000 claims abstract description 10
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000010936 titanium Substances 0.000 claims abstract description 8
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 8
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000012535 impurity Substances 0.000 claims abstract description 5
- 239000011777 magnesium Substances 0.000 claims abstract description 5
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 4
- 239000011574 phosphorus Substances 0.000 claims abstract description 4
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 4
- 239000010703 silicon Substances 0.000 claims abstract description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052748 manganese Inorganic materials 0.000 abstract description 2
- 239000011572 manganese Substances 0.000 abstract description 2
- 238000005272 metallurgy Methods 0.000 abstract description 2
- 230000001590 oxidative effect Effects 0.000 abstract description 2
- 239000005864 Sulphur Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 229910007932 ZrCl4 Inorganic materials 0.000 description 6
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 6
- 238000005336 cracking Methods 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 229910003865 HfCl4 Inorganic materials 0.000 description 4
- 230000002411 adverse Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- PDPJQWYGJJBYLF-UHFFFAOYSA-J hafnium tetrachloride Chemical compound Cl[Hf](Cl)(Cl)Cl PDPJQWYGJJBYLF-UHFFFAOYSA-J 0.000 description 3
- 150000001247 metal acetylides Chemical class 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- -1 chromium carbides Chemical class 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 150000002362 hafnium Chemical class 0.000 description 2
- 229910000765 intermetallic Inorganic materials 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000011179 visual inspection Methods 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229910001182 Mo alloy Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 229910000449 hafnium oxide Inorganic materials 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
- C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
- C22C19/055—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 20% but less than 30%
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/10—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Powder Metallurgy (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention relates to metallurgy, intended for nickel-based alloys used in aggressive oxidizing environments. The nickel-base alloy of the present invention comprises: carbon up to 0.006 wt.%, silicon up to 0.1 wt.%, manganese up to 1.0 wt.%, chromium up to 22.8-24.0 wt.%, iron up to 0.75 wt.%, molybdenum up to 12.0-14.0 wt.%, niobium up to 0.01-0.03 wt.%, titanium up to 0.01-0.06 wt.%, aluminum up to 0.1-0.2 wt.%, magnesium up to 0.005-0.01 wt.%, phosphorus up to 0.015 wt.%, sulphur up to 0.012 wt.%, the remainder being nickel and unavoidable impurities.
Description
The invention relates to metallurgy, intended for nickel-based alloys used in aggressive oxidizing environments.
The known corrosion-resistant alloy Nicrofer 6616hMo alloy C-4 (No. 2.4610), the weight percentage: 14.5-17.5 Cr, 14.0-17.0M o, less than or equal to 3.0Fe, less than or equal to 0.009C, less than or equal to 1.0Mn, less than or equal to 0.05Si, less than or equal to 2.0Co, less than or equal to 0.7Ti, less than or equal to 0.020P, less than or equal to 0.010S, nickel and other inevitable impurities (handbook "corrosion-resistant, heat-resistant and high-strength steel and alloy", M., Prometey alloy, 2008, pages 304-306).
The alloy is useful for making devices that operate in a variety of chemical environments, both at room temperature and at elevated temperatures. In particular for flue gas desulfurization; an etching bath and an acid recovery device; an apparatus for producing acetic acid and agrochemicals.
The closest analogue of the present invention is KHN65MVU (EP760) alloy, in weight percent: not more than 0.02C, not more than 0.1Si, not more than 1.0Mn, 14.5-16.5 Cr, 15.0-17, 0Mo, 3.0-4.5W, not more than 0.5Fe, not more than 0.012S, not more than 0.015P, nickel and inevitable impurities, the rest (GOST 5632-.
For creating structures (columns, heat exchangers, reactors), chemical, petrochemical industries (production of acetic acid, epoxy, vinyl acetate, melamine, complex organic compounds) and other temperature ranges from-70 to 5000 degrees celsius.
KhN65MVU alloy and its welding joint can be on KCl-AlCl3–ZrCl4The temperature can reach 500 deg.C when used in environment, and the temperature is higher than the specified valueAt the temperature, besides intergranular corrosion and corrosion cracking, the elongation of the alloy is sharply reduced from 48% to 7.3-13% at 550 ℃, the elongation is up to 2.5% at 625 ℃, and embrittlement of metal is shown after deformation.
The problem to which the invention relates is in the chloride plant (KCl-AlCl)3–ZrCl4) In a working environment at temperatures up to 650 c, alloys with high corrosion performance are produced.
The technical result of the invention is an alloy with high plasticity when working in the temperature range of 550 ℃ to 625 ℃ and increased molten chlorides KCl, AlCl at temperatures up to 650 DEG C3+(ZrCl4 HfCl4) Corrosion cracking resistance of (1).
The specific technical result is an alloy containing carbon, silicon, manganese, chromium, molybdenum, phosphorus, sulfur, iron, nickel and unavoidable impurities, which according to the invention additionally contains the following proportions, in weight percent, of the components titanium, aluminum, niobium, magnesium:
in order to obtain stable structural and plastic properties, the contents of chromium, molybdenum and iron are preferably related to the following ratios:
(the ratio of the total mass percent of chromium and molybdenum to the mass percent of iron is not less than 46.4)
In order to obtain a stable structure and high corrosion performance, the contents of niobium and carbon are preferably related by the following ratio:
(the ratio of the mass percent of niobium to the mass percent of carbon is not less than 1.66.
The contents of chromium, molybdenum, iron, niobium and carbon are preferably related to the following ratios:
by comparative analysis with prototypes, we can conclude that the claimed alloy differs from the known alloys in that: the alloy is characterized by comprising the following components, by weight, low carbon content (changed from less than or equal to 0.02% to less than or equal to 0.006%), molybdenum (changed from 15.0-17.0% to 12.0-14.0%), chromium content (changed from 14.5-16.5% to 23.0-24.0%), iron (changed from less than or equal to 0.5% to less than or equal to 0.75%), and elements such as 0.01-0.03% of niobium, 0.01-0.06% of titanium, 0.1-0.2% of aluminum and 0.005-0.01% of magnesium.
Furthermore, in the specific case of the invention, the required element ratios are satisfied:
or
Or
The limitations of the content of alloying elements in the alloys of the present invention were determined by studying the properties of the alloys for the selection of different compositions.
Carbon contents exceeding 0.006% lead to a reduction in the corrosion resistance in zirconium and hafnium salt solutions due to an increase in the carbide formation process (appearance of poor carbide phases) at high temperatures.
The content of chromium is 22.8-24% to ensure the heat resistance required by hafnium and zirconium oxide. When the amount of chromium incorporated is less than 22.8%, the alloy does not have the desired heat resistance, and exceeding 24.0% lowers the heat resistance of the alloy.
The introduction of molybdenum into the nickel alloy can raise the recrystallization temperature of the solid solution, suppress its softening, improve the heat resistance, and improve the plasticity in both short-term and long-term tests.
We select a molybdenum content of 12.0-14.0% to provide the mechanical properties required for short and long term loading and high temperatures. The addition of molybdenum is less than 12.0 percent, and the requirement of mechanical property cannot be met. When the content is more than 14.0%, the plasticity of the alloy is reduced, and thus, the workability of the alloy is deteriorated during metallurgical processing.
The niobium is added in an amount of 0.01 to 0.03% to bond residual carbon and nitrogen to carbides, nitrides and carbonitrides, thereby preventing the formation of chromium carbides and carbonitrides along grain boundaries. Niobium, added in an amount of 6 to 10 times the carbon content of the alloy, eliminates intergranular corrosion of the alloy and protects the weld from damage. When the content of niobium is less than 0.01%, the interaction with the residual carbon is ineffective, and the content of niobium more than 0.03% is disadvantageous in the formation of carbides.
When the silicon content exceeds 0.1%, the workability of the alloy is adversely affected and the alloy is embrittled due to the increase in the content of the silicate.
An increase in the manganese content beyond 1.0% leads to the appearance of eutectic melting, which leads to the destruction of the steel ingot during the press working, to a reduction in the heat resistance of the alloy, and also to a reduction in the local corrosion resistance.
Nickel is stable in hydrochloric acid even at the boiling point. However, the corrosion of nickel and nickel chromium of molybdenum alloys is exacerbated in the presence of chloride, fe (iii) ions and other oxidants, and the iron content is limited to no more than 0.75%.
The addition of 0.01-0.06% titanium improves the corrosion resistance of the zirconium and hafnium salt melts, allowing residual carbon to combine with carbides to form Ni in sufficient quantities3The Ti-type intermetallic compound has a positive influence on the heat resistance of the alloy at the working temperature of 500-700 ℃. When the titanium content is less than 0.01%, the corrosion resistance requirement is not satisfied, and when the titanium content exceeds 0.06%, the workability of the alloy is lowered and a poor phase is formed due to the reactivity of titanium.
0.1-0.2% and 0.005-0.01% of aluminum and magnesium to remove residual oxygen, and, for aluminum, Ni is formed3An Al-type intermetallic compound, which has a positive influence on the heat resistance of the alloy. When the amount of these elements incorporated is less than the indicated amount, the necessary removal of residual oxygen cannot be achieved. If the content of these elements is exceeded, a large amount of non-metallic inclusions are formed.
When the sulfur content exceeds 0.012% and the phosphorus content exceeds 0.015%, coarse non-metallic inclusions are formed, adversely affecting the plasticity of the alloy.
In that
Under the conditions, when the ratio is reduced below 46.4, the alloy structure becomes unstable (sigma phase is released), which adversely affects the plastic properties and corrosion resistance of the alloy.
In that
Under the condition, when the ratio is less than 1.66, the corrosion resistance of the alloy is lowered.
The proportions of the elements in the proposed alloys are found experimentally and are optimal as they allow you to obtain the claimed combined technical result. The alloy performance is deteriorated and unstable without violating the element proportion, and the composite effect is not achieved.
Examples of the invention.
And smelting the alloy ingot in a vacuum induction furnace. According to GOST 14019-. In chloride melt KCl, AlCl3+(ZrCl4 HfCl4) In the process of carrying out the industrial test of corrosion cracking resistance of the alloy
Table 1 shows the chemical composition of the alloy ingots with various composition selections as well as the prototype alloys. Table 2 shows the results of the determination of the plastic properties of the alloys shown in Table 1 according to GOST 14019-2003 bending at an angle of 90 degrees. Table 3 shows the alloy shown in table 1 in the presence of molten chloride KCl,AlCl3+(ZrCl4HfCl4) Industrial test results of resistance to corrosion cracking at T650 c for 100 hours.
From tables 1, 2 it can be seen that the alloys satisfying the required composition (alloys 1, 2), having plasticity properties at 550 ℃ and 625 ℃ higher than those of the prototype alloy, and alloy 3 not satisfying the required composition, having plasticity properties lower than those of alloys 1, 2, resulted in cracking according to the GOST 14019-.
As can be seen from table 3, the alloys (alloys 1, 2) satisfying the required composition have a lower corrosion rate than the prototype alloy, and no cracks were found by visual inspection. Alloy 3, which is an undesirable composition, has a corrosion rate that exceeds that of alloys 1 and 2 (but is lower than that of the prototype alloy) and visual inspection reveals cracks in the sample.
TABLE 2 results of determination of the plasticity properties by 90 degree bending according to GOST 14019-
TABLE 3-100 hours at T ═ 650 ℃
In chloride melts KCl, AlCl3+(ZrCl4 HfCl4) In
Industrial test results of Corrosion cracking resistant alloys
Claims (4)
1. A corrosion-resistant nickel-based alloy contains carbon, silicon, manganese, chromium, molybdenum, phosphorus, sulfur, iron, nickel and inevitable impurities, and is characterized by further containing titanium, aluminum, niobium and magnesium in the following component proportion by weight percent:
2. an alloy according to claim 1, characterized in that the contents of chromium, molybdenum, iron are related to the following ratios:
3. the alloy of claim 1, wherein the contents of niobium and carbon are related to the following ratios:
4. an alloy according to claim 1, characterized in that the contents of chromium, molybdenum, iron are related to the following ratios:
the specific content of niobium and carbon is as follows:
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2017127607A RU2672647C1 (en) | 2017-08-01 | 2017-08-01 | Corrosive-resistant alloy |
| RU2017127607 | 2017-08-01 | ||
| PCT/RU2017/001014 WO2019027347A1 (en) | 2017-08-01 | 2017-12-29 | Corrosion-resistant alloy |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN111094603A CN111094603A (en) | 2020-05-01 |
| CN111094603B true CN111094603B (en) | 2021-12-07 |
Family
ID=64328060
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201780092598.3A Active CN111094603B (en) | 2017-08-01 | 2017-12-29 | Corrosion-resistant alloy |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20210164075A1 (en) |
| EP (1) | EP3663422A4 (en) |
| JP (1) | JP6974507B2 (en) |
| KR (1) | KR20200060694A (en) |
| CN (1) | CN111094603B (en) |
| CA (1) | CA3093022C (en) |
| EA (1) | EA201992733A1 (en) |
| JO (1) | JOP20190301A1 (en) |
| MY (1) | MY192470A (en) |
| RU (1) | RU2672647C1 (en) |
| WO (1) | WO2019027347A1 (en) |
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2017
- 2017-08-01 RU RU2017127607A patent/RU2672647C1/en active
- 2017-12-29 MY MYPI2019007591A patent/MY192470A/en unknown
- 2017-12-29 CA CA3093022A patent/CA3093022C/en active Active
- 2017-12-29 CN CN201780092598.3A patent/CN111094603B/en active Active
- 2017-12-29 EA EA201992733A patent/EA201992733A1/en unknown
- 2017-12-29 US US16/627,736 patent/US20210164075A1/en not_active Abandoned
- 2017-12-29 EP EP17919968.2A patent/EP3663422A4/en not_active Withdrawn
- 2017-12-29 KR KR1020197038839A patent/KR20200060694A/en not_active Application Discontinuation
- 2017-12-29 WO PCT/RU2017/001014 patent/WO2019027347A1/en unknown
- 2017-12-29 JP JP2019572506A patent/JP6974507B2/en active Active
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2019
- 2019-02-01 JO JOP/2019/0301A patent/JOP20190301A1/en unknown
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| EP0247577A1 (en) * | 1986-05-27 | 1987-12-02 | Carpenter Technology Corporation | Corrosion resistant age hardenable nickel-base alloy |
| JPH0617173A (en) * | 1992-07-03 | 1994-01-25 | Mitsubishi Steel Mfg Co Ltd | Conductive roll for electroplating |
| US5855699A (en) * | 1994-10-03 | 1999-01-05 | Daido Tokushuko Kabushiki Kaisha | Method for manufacturing welded clad steel tube |
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| RU2440876C1 (en) * | 2010-08-23 | 2012-01-27 | Евгений Григорьевич Старченко | Welding wire for welding structural parts from diverse steels |
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Also Published As
| Publication number | Publication date |
|---|---|
| EP3663422A4 (en) | 2021-01-20 |
| BR112019028257A2 (en) | 2020-08-04 |
| WO2019027347A1 (en) | 2019-02-07 |
| US20210164075A1 (en) | 2021-06-03 |
| CN111094603A (en) | 2020-05-01 |
| KR20200060694A (en) | 2020-06-01 |
| MY192470A (en) | 2022-08-22 |
| JP6974507B2 (en) | 2021-12-01 |
| WO2019027347A8 (en) | 2020-09-10 |
| CA3093022C (en) | 2023-08-08 |
| JOP20190301A1 (en) | 2019-12-30 |
| EP3663422A1 (en) | 2020-06-10 |
| RU2672647C1 (en) | 2018-11-16 |
| CA3093022A1 (en) | 2019-02-07 |
| JP2020530064A (en) | 2020-10-15 |
| EA201992733A1 (en) | 2021-04-20 |
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