CN111087840A - Deck dressing and manufacturing method thereof - Google Patents
Deck dressing and manufacturing method thereof Download PDFInfo
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- CN111087840A CN111087840A CN201911230309.9A CN201911230309A CN111087840A CN 111087840 A CN111087840 A CN 111087840A CN 201911230309 A CN201911230309 A CN 201911230309A CN 111087840 A CN111087840 A CN 111087840A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D147/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/329—Phosphorus containing acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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Abstract
The invention discloses a deck dressing and a manufacturing method thereof, belonging to the technical field of deck dressings and comprising the following raw materials in parts by weight: 25-30 parts of a coagulant and 15-20 parts of a filling aggregate, wherein the filling aggregate consists of 85% of quartz sand and 15% of ceramic sand, and also comprises 20-30 parts of an antifreezing butylbenzene mixed emulsion and 20-25 parts of an antirust agent; the anti-freezing styrene-butadiene emulsion comprises the following raw materials in parts by weight: 15-20 parts of butadiene, 10-15 parts of styrene emulsion, 10-20 parts of sodium nitrite, 20-30 parts of calcium chloride, 15-20 parts of calcium nitrite, 6-8 parts of urea and 6-10 parts of ethylene glycol; the antirust agent comprises the following raw materials in parts by weight: 6-9 parts of sodium hexametaphosphate, 15-18 parts of phosphoric acid, 9-14 parts of amine-soluble quaternary ammonium copper, 7-10 parts of nano silicon dioxide, 4-8 parts of sodium sulfonate, 7-10 parts of sodium nitrite, 20-25 parts of water-soluble antirust additive, 9-16 parts of antibacterial reinforcing agent, 8-12 parts of degreasing agent and 26-30 parts of deionized water, so that the antirust and antifreezing agent has excellent antirust and antifreezing effects, the service life is effectively prolonged, the other properties are remarkably improved, and the preparation method is scientific and reasonable.
Description
Technical Field
The invention relates to the technical field of deck dressings, in particular to a deck dressing and a manufacturing method thereof.
Background
In the ship repairing and manufacturing process, fireproof deck dressing is laid on a ship steel deck, the existing deck dressing is processed by taking portland cement as a main raw material, taking ceramic sand as an aggregate and taking a flame retardant and chloroprene latex as an adhesive, and due to the characteristics of the dressing, the forming surface roughness of the dressing is large during laying, and the unevenness easily exceeds a specified range.
The adopted compensation measures can be as follows: the surface of the formed dressing is coated with a layer of dressing as a dressing for ships, different types of dressings must be used according to different requirements, the A-60 class deck dressing is the dressing laid at the position with particularly high fireproof requirements of the ship vital department, the surface of the existing deck dressing is easy to be corroded, so that the interior of the existing deck dressing is corroded, the service life of the existing deck dressing is greatly reduced, and meanwhile, the performance of the existing deck dressing is not very remarkable, the anti-freezing performance of the existing deck dressing is not very remarkable, and the dressing for ships is not easy to be used in the environment,
Disclosure of Invention
1. Technical problem to be solved
Aiming at the problems in the prior art, the invention aims to provide a deck dressing and a manufacturing method thereof, which have excellent antirust and antifreezing effects, effectively prolong the service life, remarkably increase the other properties and have scientific and reasonable preparation method.
2. Technical scheme
In order to solve the problems, the invention adopts the following technical scheme:
the deck covering material comprises the following raw materials in parts by weight: 25-30 parts of a coagulant and 15-20 parts of a filling aggregate, wherein the filling aggregate is composed of 85% of quartz sand and 15% of ceramic sand, and is characterized by also comprising 20-30 parts of an anti-freezing butylbenzene mixed emulsion and 20-25 parts of an antirust agent;
the anti-freezing styrene-butadiene emulsion comprises the following raw materials in parts by weight: 15-20 parts of butadiene, 10-15 parts of styrene emulsion, 10-20 parts of sodium nitrite, 20-30 parts of calcium chloride, 15-20 parts of calcium nitrite, 6-8 parts of urea and 6-10 parts of ethylene glycol;
the antirust agent comprises the following raw materials in parts by weight: 6-9 parts of sodium hexametaphosphate, 15-18 parts of phosphoric acid, 9-14 parts of amine-soluble quaternary ammonium copper, 7-10 parts of nano silicon dioxide, 4-8 parts of sodium sulfonate, 7-10 parts of sodium nitrite, 20-25 parts of water-soluble antirust additive, 9-16 parts of antibacterial reinforcing agent, 8-12 parts of degreasing agent and 26-30 parts of deionized water.
As a preferable scheme of the invention, the feed comprises the following raw materials in parts by weight: 25 parts of a coagulant and 15 parts of a filling aggregate, wherein the filling aggregate consists of 85% of quartz sand and 15% of ceramic sand, 20 parts of an antifreezing butylbenzene mixed emulsion and 20 parts of an antirust agent.
As a preferable scheme of the invention, the feed comprises the following raw materials in parts by weight: 27 parts of a coagulant and 17 parts of a filling aggregate, wherein the filling aggregate consists of 85% of quartz sand and 15% of ceramic sand, 25 parts of an antifreezing butylbenzene mixed emulsion and 23 parts of an antirust agent.
As a preferable scheme of the invention, the feed comprises the following raw materials in parts by weight: 30 parts of a coagulant and 20 parts of a filling aggregate, wherein the filling aggregate consists of 85% of quartz sand and 15% of ceramic sand, 30 parts of an antifreezing butylbenzene mixed emulsion and 25 parts of an antirust agent.
As a preferable scheme of the invention, the antifreezing styrene-butadiene emulsion comprises the following raw materials in parts by weight: 15 parts of butadiene, 10 parts of styrene emulsion, 10 parts of sodium nitrite, 20 parts of calcium chloride, 15 parts of calcium nitrite, 6 parts of urea and 6 parts of ethylene glycol;
the antirust agent comprises the following raw materials in parts by weight: 6 parts of sodium hexametaphosphate, 15 parts of phosphoric acid, 9 parts of amine-soluble quaternary ammonium copper, 7 parts of nano silicon dioxide, 4 parts of sulfonic acid, 7 parts of sodium nitrite, 20 parts of water-soluble antirust additive, 9 parts of antibacterial reinforcing agent, 8 parts of degreasing agent and 26 parts of deionized water.
As a preferable scheme of the invention, the antifreezing styrene-butadiene emulsion comprises the following raw materials in parts by weight: 17 parts of butadiene, 13 parts of styrene emulsion, 15 parts of sodium nitrite, 25 parts of calcium chloride, 17 parts of calcium nitrite, 7 parts of urea and 8 parts of ethylene glycol;
the antirust agent comprises the following raw materials in parts by weight: 7 parts of sodium hexametaphosphate, 16 parts of phosphoric acid, 12 parts of amine-soluble quaternary ammonium copper, 8 parts of nano silicon dioxide, 6 parts of sodium sulfonate, 8 parts of sodium nitrite, 22 parts of water-soluble antirust additive, 14 parts of antibacterial reinforcing agent, 10 parts of degreasing agent and 28 parts of deionized water.
As a preferable scheme of the invention, the antifreezing styrene-butadiene emulsion comprises the following raw materials in parts by weight: 20 parts of butadiene, 15 parts of styrene emulsion, 20 parts of sodium nitrite, 30 parts of calcium chloride, 20 parts of calcium nitrite, 8 parts of urea and 10 parts of ethylene glycol;
the antirust agent comprises the following raw materials in parts by weight: 9 parts of sodium hexametaphosphate, 118 parts of phosphoric acid, 14 parts of amine-soluble quaternary ammonium copper, 10 parts of nano silicon dioxide, 8 parts of sodium sulfonate, 10 parts of sodium nitrite, 25 parts of water-soluble antirust additive, 16 parts of antibacterial reinforcing agent, 12 parts of degreasing agent and 30 parts of deionized water.
A method of making a deck covering comprising the steps of:
s1, taking 15-20 parts of butadiene, 10-15 parts of styrene emulsion, 10-20 parts of sodium nitrite and 20-30 parts of calcium chloride, putting the butadiene, the styrene emulsion, the sodium nitrite and the calcium chloride into a stirrer, fully stirring for 20min, adding 15-20 parts of calcium nitrite, 6-8 parts of urea and 6-10 parts of ethylene glycol into the stirrer, and mixing and stirring for 15min again to prepare the antifreezing butylbenzene mixed emulsion for later use;
s2, putting the quartz sand and the ceramic sand into a crusher according to the ratio of 17:2, fully crushing, screening particles with the size of 85-90 meshes, putting the particles into a stirrer, and fully stirring for 15 min;
s3, taking 6-9 parts of sodium hexametaphosphate, 15-18 parts of phosphoric acid, 9-14 parts of amine-soluble quaternary ammonium copper, 7-10 parts of nano silicon dioxide, 4-8 parts of sodium sulfonate, 7-10 parts of sodium nitrite, 20-25 parts of water-soluble antirust additive, 9-16 parts of antibacterial reinforcing agent, 8-12 parts of degreasing agent and 26-30 parts of deionized water, putting the mixture into a stirrer, fully stirring for 20min, heating the mixture at 80-85 ℃ in the stirring process, keeping the temperature for 15min after stirring, standing for layering and distilling under reduced pressure to obtain the antirust agent for later use;
s4, taking 20-30 parts of the anti-freezing butylbenzene mixed emulsion, 20-25 parts of antirust agent, 25-30 parts of coagulant, 20-25 parts of antirust agent and 15-20 parts of filling aggregate, putting the mixture into a stirrer, fully stirring for 30min, curing for 10min, and stirring again for 20min to obtain the finished product.
3. Advantageous effects
Compared with the prior art, the invention has the advantages that:
the scheme has excellent antirust and antifreezing effects, effectively prolongs the service life, remarkably increases the other properties, and has scientific and reasonable preparation method.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention. It is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments, and all other embodiments obtained by those skilled in the art without any inventive work are within the scope of the present invention.
Example 1:
the deck covering comprises the following raw materials in parts by weight: 25 parts of a coagulant and 15 parts of a filling aggregate, wherein the filling aggregate consists of 85% of quartz sand and 15% of ceramic sand, 20 parts of an antifreezing butylbenzene mixed emulsion and 20 parts of an antirust agent.
The anti-freezing styrene-butadiene emulsion comprises the following raw materials in parts by weight: 15 parts of butadiene, 10 parts of styrene emulsion, 10 parts of sodium nitrite, 20 parts of calcium chloride, 15 parts of calcium nitrite, 6 parts of urea and 6 parts of ethylene glycol;
the antirust agent comprises the following raw materials in parts by weight: 6 parts of sodium hexametaphosphate, 15 parts of phosphoric acid, 9 parts of amine-soluble quaternary ammonium copper, 7 parts of nano silicon dioxide, 4 parts of sulfonic acid, 7 parts of sodium nitrite, 20 parts of water-soluble antirust additive, 9 parts of antibacterial reinforcing agent, 8 parts of degreasing agent and 26 parts of deionized water.
Example 2:
the deck covering comprises the following raw materials in parts by weight: 25 parts of a coagulant and 15 parts of a filling aggregate, wherein the filling aggregate consists of 85% of quartz sand and 15% of ceramic sand, 20 parts of an antifreezing butylbenzene mixed emulsion and 20 parts of an antirust agent.
The anti-freezing styrene-butadiene emulsion comprises the following raw materials in parts by weight: 17 parts of butadiene, 13 parts of styrene emulsion, 15 parts of sodium nitrite, 25 parts of calcium chloride, 17 parts of calcium nitrite, 7 parts of urea and 8 parts of ethylene glycol;
the antirust agent comprises the following raw materials in parts by weight: 7 parts of sodium hexametaphosphate, 16 parts of phosphoric acid, 12 parts of amine-soluble quaternary ammonium copper, 8 parts of nano silicon dioxide, 6 parts of sodium sulfonate, 8 parts of sodium nitrite, 22 parts of water-soluble antirust additive, 14 parts of antibacterial reinforcing agent, 10 parts of degreasing agent and 28 parts of deionized water.
Example 3:
the deck covering comprises the following raw materials in parts by weight: 25 parts of a coagulant and 15 parts of a filling aggregate, wherein the filling aggregate consists of 85% of quartz sand and 15% of ceramic sand, 20 parts of an antifreezing butylbenzene mixed emulsion and 20 parts of an antirust agent.
The anti-freezing styrene-butadiene emulsion comprises the following raw materials in parts by weight: 20 parts of butadiene, 15 parts of styrene emulsion, 20 parts of sodium nitrite, 30 parts of calcium chloride, 20 parts of calcium nitrite, 8 parts of urea and 10 parts of ethylene glycol;
the antirust agent comprises the following raw materials in parts by weight: 9 parts of sodium hexametaphosphate, 118 parts of phosphoric acid, 14 parts of amine-soluble quaternary ammonium copper, 10 parts of nano silicon dioxide, 8 parts of sodium sulfonate, 10 parts of sodium nitrite, 25 parts of water-soluble antirust additive, 16 parts of antibacterial reinforcing agent, 12 parts of degreasing agent and 30 parts of deionized water.
Example 4:
the deck covering comprises the following raw materials in parts by weight: 27 parts of a coagulant and 17 parts of a filling aggregate, wherein the filling aggregate consists of 85% of quartz sand and 15% of ceramic sand, 25 parts of an antifreezing butylbenzene mixed emulsion and 23 parts of an antirust agent.
The anti-freezing styrene-butadiene emulsion comprises the following raw materials in parts by weight: 15 parts of butadiene, 10 parts of styrene emulsion, 10 parts of sodium nitrite, 20 parts of calcium chloride, 15 parts of calcium nitrite, 6 parts of urea and 6 parts of ethylene glycol;
the antirust agent comprises the following raw materials in parts by weight: 6 parts of sodium hexametaphosphate, 15 parts of phosphoric acid, 9 parts of amine-soluble quaternary ammonium copper, 7 parts of nano silicon dioxide, 4 parts of sulfonic acid, 7 parts of sodium nitrite, 20 parts of water-soluble antirust additive, 9 parts of antibacterial reinforcing agent, 8 parts of degreasing agent and 26 parts of deionized water.
Example 5:
the deck covering comprises the following raw materials in parts by weight: 27 parts of a coagulant and 17 parts of a filling aggregate, wherein the filling aggregate consists of 85% of quartz sand and 15% of ceramic sand, 25 parts of an antifreezing butylbenzene mixed emulsion and 23 parts of an antirust agent.
The anti-freezing styrene-butadiene emulsion comprises the following raw materials in parts by weight: 17 parts of butadiene, 13 parts of styrene emulsion, 15 parts of sodium nitrite, 25 parts of calcium chloride, 17 parts of calcium nitrite, 7 parts of urea and 8 parts of ethylene glycol;
the antirust agent comprises the following raw materials in parts by weight: 7 parts of sodium hexametaphosphate, 16 parts of phosphoric acid, 12 parts of amine-soluble quaternary ammonium copper, 8 parts of nano silicon dioxide, 6 parts of sodium sulfonate, 8 parts of sodium nitrite, 22 parts of water-soluble antirust additive, 14 parts of antibacterial reinforcing agent, 10 parts of degreasing agent and 28 parts of deionized water.
Example 6:
the deck covering comprises the following raw materials in parts by weight: 27 parts of a coagulant and 17 parts of a filling aggregate, wherein the filling aggregate consists of 85% of quartz sand and 15% of ceramic sand, 25 parts of an antifreezing butylbenzene mixed emulsion and 23 parts of an antirust agent.
The anti-freezing styrene-butadiene emulsion comprises the following raw materials in parts by weight: 20 parts of butadiene, 15 parts of styrene emulsion, 20 parts of sodium nitrite, 30 parts of calcium chloride, 20 parts of calcium nitrite, 8 parts of urea and 10 parts of ethylene glycol;
the antirust agent comprises the following raw materials in parts by weight: 9 parts of sodium hexametaphosphate, 118 parts of phosphoric acid, 14 parts of amine-soluble quaternary ammonium copper, 10 parts of nano silicon dioxide, 8 parts of sodium sulfonate, 10 parts of sodium nitrite, 25 parts of water-soluble antirust additive, 16 parts of antibacterial reinforcing agent, 12 parts of degreasing agent and 30 parts of deionized water.
Example 7:
the deck covering comprises the following raw materials in parts by weight: 30 parts of a coagulant and 20 parts of a filling aggregate, wherein the filling aggregate consists of 85% of quartz sand and 15% of ceramic sand, 30 parts of an antifreezing butylbenzene mixed emulsion and 25 parts of an antirust agent.
The anti-freezing styrene-butadiene emulsion comprises the following raw materials in parts by weight: 15 parts of butadiene, 10 parts of styrene emulsion, 10 parts of sodium nitrite, 20 parts of calcium chloride, 15 parts of calcium nitrite, 6 parts of urea and 6 parts of ethylene glycol;
the antirust agent comprises the following raw materials in parts by weight: 6 parts of sodium hexametaphosphate, 15 parts of phosphoric acid, 9 parts of amine-soluble quaternary ammonium copper, 7 parts of nano silicon dioxide, 4 parts of sulfonic acid, 7 parts of sodium nitrite, 20 parts of water-soluble antirust additive, 9 parts of antibacterial reinforcing agent, 8 parts of degreasing agent and 26 parts of deionized water.
Example 8:
the deck covering comprises the following raw materials in parts by weight: 30 parts of a coagulant and 20 parts of a filling aggregate, wherein the filling aggregate consists of 85% of quartz sand and 15% of ceramic sand, 30 parts of an antifreezing butylbenzene mixed emulsion and 25 parts of an antirust agent.
The anti-freezing styrene-butadiene emulsion comprises the following raw materials in parts by weight: 17 parts of butadiene, 13 parts of styrene emulsion, 15 parts of sodium nitrite, 25 parts of calcium chloride, 17 parts of calcium nitrite, 7 parts of urea and 8 parts of ethylene glycol;
the antirust agent comprises the following raw materials in parts by weight: 7 parts of sodium hexametaphosphate, 16 parts of phosphoric acid, 12 parts of amine-soluble quaternary ammonium copper, 8 parts of nano silicon dioxide, 6 parts of sodium sulfonate, 8 parts of sodium nitrite, 22 parts of water-soluble antirust additive, 14 parts of antibacterial reinforcing agent, 10 parts of degreasing agent and 28 parts of deionized water.
Example 9:
the deck covering comprises the following raw materials in parts by weight: 30 parts of a coagulant and 20 parts of a filling aggregate, wherein the filling aggregate consists of 85% of quartz sand and 15% of ceramic sand, 30 parts of an antifreezing butylbenzene mixed emulsion and 25 parts of an antirust agent.
The anti-freezing styrene-butadiene emulsion comprises the following raw materials in parts by weight: 20 parts of butadiene, 15 parts of styrene emulsion, 20 parts of sodium nitrite, 30 parts of calcium chloride, 20 parts of calcium nitrite, 8 parts of urea and 10 parts of ethylene glycol;
the antirust agent comprises the following raw materials in parts by weight: 9 parts of sodium hexametaphosphate, 118 parts of phosphoric acid, 14 parts of amine-soluble quaternary ammonium copper, 10 parts of nano silicon dioxide, 8 parts of sodium sulfonate, 10 parts of sodium nitrite, 25 parts of water-soluble antirust additive, 16 parts of antibacterial reinforcing agent, 12 parts of degreasing agent and 30 parts of deionized water.
A method of making a deck covering comprising the steps of:
s1, putting butadiene, styrene emulsion, sodium nitrite and calcium chloride into a stirrer, stirring for 20min sufficiently, adding calcium nitrite, urea and ethylene glycol into the stirrer, and stirring for 15min again to obtain the anti-freezing butylbenzene mixed emulsion for later use;
s2, putting the quartz sand and the ceramic sand into a crusher according to the ratio of 17:2, fully crushing, screening particles with the size of 85-90 meshes, putting the particles into a stirrer, and fully stirring for 15 min;
s3, placing sodium hexametaphosphate, phosphoric acid, amine-soluble quaternary ammonium copper, nano silicon dioxide, sodium sulfonate, sodium nitrite, a water-soluble antirust additive, an antibacterial reinforcing agent, an oil removing agent and deionized water into a stirrer, fully stirring for 20min, heating the mixture at 80-85 ℃ in the stirring process, keeping the temperature for 15min after stirring, standing for layering, and distilling under reduced pressure to obtain the antirust agent for later use;
and S4, putting the antifreezing butylbenzene mixed emulsion, the antirust agent, the coagulant, the antirust agent and the filling aggregate into a stirrer, fully stirring for 30min, curing for 10min, and stirring again for 20min to obtain the finished product.
The performance indexes of the deck dressing are as follows:
the density is less than or equal to 1600kg/m3;
The bending resistance is more than or equal to 15 Mpa;
the compression resistance is more than or equal to 30 Mpa;
water absorption is less than or equal to 15 percent;
oil absorption is less than or equal to 10 percent;
fluidity: 35cm-45 cm;
the water and freeze resistance tests were performed for examples 1 to 9:
soaking the deck dressing prepared in the examples 1 to 9 in clear water for 30min, wherein no rust is found within 150 days;
the deck covering prepared in example 1 to example 9 was placed in an environment at-20 ℃ without cracking within 60 days.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered as the technical scope of the present invention, and equivalents and modifications thereof according to the technical solution and the modified concept of the present invention are included in the scope of the present invention.
Claims (8)
1. The deck covering comprises the following raw materials in parts by weight: 25-30 parts of a coagulant and 15-20 parts of a filling aggregate, wherein the filling aggregate is composed of 85% of quartz sand and 15% of ceramic sand, and is characterized by also comprising 20-30 parts of an anti-freezing butylbenzene mixed emulsion and 20-25 parts of an antirust agent;
the anti-freezing styrene-butadiene emulsion comprises the following raw materials in parts by weight: 15-20 parts of butadiene, 10-15 parts of styrene emulsion, 10-20 parts of sodium nitrite, 20-30 parts of calcium chloride, 15-20 parts of calcium nitrite, 6-8 parts of urea and 6-10 parts of ethylene glycol;
the antirust agent comprises the following raw materials in parts by weight: 6-9 parts of sodium hexametaphosphate, 15-18 parts of phosphoric acid, 9-14 parts of amine-soluble quaternary ammonium copper, 7-10 parts of nano silicon dioxide, 4-8 parts of sodium sulfonate, 7-10 parts of sodium nitrite, 20-25 parts of water-soluble antirust additive, 9-16 parts of antibacterial reinforcing agent, 8-12 parts of degreasing agent and 26-30 parts of deionized water.
2. The deck covering of claim 1, comprising the following raw materials in parts by weight: 25 parts of a coagulant and 15 parts of a filling aggregate, wherein the filling aggregate consists of 85% of quartz sand and 15% of ceramic sand, 20 parts of an antifreezing butylbenzene mixed emulsion and 20 parts of an antirust agent.
3. The deck covering of claim 1, comprising the following raw materials in parts by weight: 27 parts of a coagulant and 17 parts of a filling aggregate, wherein the filling aggregate consists of 85% of quartz sand and 15% of ceramic sand, 25 parts of an antifreezing butylbenzene mixed emulsion and 23 parts of an antirust agent.
4. The deck covering of claim 1, comprising the following raw materials in parts by weight: 30 parts of a coagulant and 20 parts of a filling aggregate, wherein the filling aggregate consists of 85% of quartz sand and 15% of ceramic sand, 30 parts of an antifreezing butylbenzene mixed emulsion and 25 parts of an antirust agent.
5. The deck covering as claimed in any one of claims 1 to 4, wherein the antifreeze styrene-butadiene emulsion comprises the following raw materials in parts by weight: 15 parts of butadiene, 10 parts of styrene emulsion, 10 parts of sodium nitrite, 20 parts of calcium chloride, 15 parts of calcium nitrite, 6 parts of urea and 6 parts of ethylene glycol;
the antirust agent comprises the following raw materials in parts by weight: 6 parts of sodium hexametaphosphate, 15 parts of phosphoric acid, 9 parts of amine-soluble quaternary ammonium copper, 7 parts of nano silicon dioxide, 4 parts of sulfonic acid, 7 parts of sodium nitrite, 20 parts of water-soluble antirust additive, 9 parts of antibacterial reinforcing agent, 8 parts of degreasing agent and 26 parts of deionized water.
6. The deck covering as claimed in any one of claims 1 to 4, wherein the antifreeze styrene-butadiene emulsion comprises the following raw materials in parts by weight: 17 parts of butadiene, 13 parts of styrene emulsion, 15 parts of sodium nitrite, 25 parts of calcium chloride, 17 parts of calcium nitrite, 7 parts of urea and 8 parts of ethylene glycol;
the antirust agent comprises the following raw materials in parts by weight: 7 parts of sodium hexametaphosphate, 16 parts of phosphoric acid, 12 parts of amine-soluble quaternary ammonium copper, 8 parts of nano silicon dioxide, 6 parts of sodium sulfonate, 8 parts of sodium nitrite, 22 parts of water-soluble antirust additive, 14 parts of antibacterial reinforcing agent, 10 parts of degreasing agent and 28 parts of deionized water.
7. The deck covering as claimed in any one of claims 1 to 4, wherein the antifreeze styrene-butadiene emulsion comprises the following raw materials in parts by weight: 20 parts of butadiene, 15 parts of styrene emulsion, 20 parts of sodium nitrite, 30 parts of calcium chloride, 20 parts of calcium nitrite, 8 parts of urea and 10 parts of ethylene glycol;
the antirust agent comprises the following raw materials in parts by weight: 9 parts of sodium hexametaphosphate, 118 parts of phosphoric acid, 14 parts of amine-soluble quaternary ammonium copper, 10 parts of nano silicon dioxide, 8 parts of sodium sulfonate, 10 parts of sodium nitrite, 25 parts of water-soluble antirust additive, 16 parts of antibacterial reinforcing agent, 12 parts of degreasing agent and 30 parts of deionized water.
8. A method of making a deck covering as claimed in claim 1, comprising the steps of:
s1, taking 15-20 parts of butadiene, 10-15 parts of styrene emulsion, 10-20 parts of sodium nitrite and 20-30 parts of calcium chloride, putting the butadiene, the styrene emulsion, the sodium nitrite and the calcium chloride into a stirrer, fully stirring for 20min, adding 15-20 parts of calcium nitrite, 6-8 parts of urea and 6-10 parts of ethylene glycol into the stirrer, and mixing and stirring for 15min again to prepare the antifreezing butylbenzene mixed emulsion for later use;
s2, putting the quartz sand and the ceramic sand into a crusher according to the ratio of 17:2, fully crushing, screening particles with the size of 85-90 meshes, putting the particles into a stirrer, and fully stirring for 15 min;
s3, taking 6-9 parts of sodium hexametaphosphate, 15-18 parts of phosphoric acid, 9-14 parts of amine-soluble quaternary ammonium copper, 7-10 parts of nano silicon dioxide, 4-8 parts of sodium sulfonate, 7-10 parts of sodium nitrite, 20-25 parts of water-soluble antirust additive, 9-16 parts of antibacterial reinforcing agent, 8-12 parts of degreasing agent and 26-30 parts of deionized water, putting the materials into a stirrer, fully stirring for 20min, heating the materials at 80-85 ℃ in the stirring process, keeping the temperature for 15min after stirring, standing, layering and distilling under reduced pressure to obtain the antirust agent for later use;
s4, taking 20-30 parts of the anti-freezing butylbenzene mixed emulsion, 20-25 parts of antirust agent, 25-30 parts of coagulant, 20-25 parts of antirust agent and 15-20 parts of filling aggregate, putting the mixture into a stirrer, fully stirring for 30min, curing for 10min, and stirring again for 20min to obtain the finished product.
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Cited By (1)
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CN116514430A (en) * | 2023-05-26 | 2023-08-01 | 重庆交通大学 | Modification method of bamboo aggregate and application of composition |
Citations (2)
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CN101648804A (en) * | 2009-08-26 | 2010-02-17 | 太仓市兰燕甲板敷料涂料有限公司 | Deck composition and preparation method thereof |
CN104072074A (en) * | 2014-05-29 | 2014-10-01 | 蚌埠华东石膏有限公司 | Flame-retardant concrete and preparation method thereof |
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CN101648804A (en) * | 2009-08-26 | 2010-02-17 | 太仓市兰燕甲板敷料涂料有限公司 | Deck composition and preparation method thereof |
CN104072074A (en) * | 2014-05-29 | 2014-10-01 | 蚌埠华东石膏有限公司 | Flame-retardant concrete and preparation method thereof |
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CN116514430A (en) * | 2023-05-26 | 2023-08-01 | 重庆交通大学 | Modification method of bamboo aggregate and application of composition |
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