CN111081791A - Solar photovoltaic module - Google Patents

Solar photovoltaic module Download PDF

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Publication number
CN111081791A
CN111081791A CN201811224277.7A CN201811224277A CN111081791A CN 111081791 A CN111081791 A CN 111081791A CN 201811224277 A CN201811224277 A CN 201811224277A CN 111081791 A CN111081791 A CN 111081791A
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temperature
photovoltaic module
coating
transparent heat
solar photovoltaic
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CN201811224277.7A
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张世臣
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Liaoning Sun New Energy Technology Co ltd
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Liaoning Sun New Energy Technology Co ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0216Coatings
    • H01L31/02161Coatings for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/02167Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/69Particle size larger than 1000 nm
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/052Cooling means directly associated or integrated with the PV cell, e.g. integrated Peltier elements for active cooling or heat sinks directly associated with the PV cells
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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Abstract

A solar photovoltaic module comprises a cell solar cell main body packaged between toughened glass and a back plate, and is characterized in that the upper surface of the toughened glass is coated with a transparent heat-insulating and temperature-reducing coating; the thickness of the transparent heat-insulation and temperature-reduction coating is 10-30 mu m, and the transparent heat-insulation and temperature-reduction coating comprises the following components in parts by weight: 50-60% of thermoplastic acrylic resin, 5-10% of micron powder, 5-10% of nano barium sulfate, 5-10% of ceramic powder, 5-10% of vacuum glass microspheres, 1-2% of siloxane coupling agent, 0.2-1% of polytetrafluoroethylene wax, 0.1-0.5% of organic silicon defoamer, 5-10% of mixture of xylene and butyl acetate and 1-5% of coating additive. The invention effectively reduces the temperature of the solar photovoltaic module, thereby effectively improving the photoelectric conversion efficiency; the invention has simple structure, more economic preparation mode, easy batch production and high conversion efficiency.

Description

Solar photovoltaic module
Technical Field
The invention relates to a solar photovoltaic module, in particular to a solar photovoltaic module with heat insulation and cooling functions, and belongs to the technical field of solar cells.
Background
The solar photovoltaic power generation system (photovoltaic for short) is a system which utilizes the photovoltaic effect to directly convert solar energy into electric energy, the main component of photoelectric conversion is a crystalline silicon photovoltaic cell, when sunlight irradiates the crystalline silicon photovoltaic cell, the crystalline silicon photovoltaic cell can convert the solar energy into electric energy to generate current. At present, photovoltaic module mainly includes glass layer, front rubber film, a plurality of battery pieces, back glue film and the photovoltaic backplate that the interval array was arranged, glass layer, front rubber film, a plurality of battery pieces, back glue film and photovoltaic backplate glue in proper order, in order to improve photovoltaic module's generating efficiency, need reduce the reflection of subassembly surface sunlight to increase the irradiance of subassembly, improve solar cell's photoelectric conversion efficiency.
In the prior art, chinese patent CN203690323U discloses a hollow water cavity manner for cooling a photovoltaic module, which has a complex structure, high cost and water consumption. Chinese patent CN201621010862.3 discloses a metal heat dissipation base for reducing the temperature of a junction box on the back of a photovoltaic module, which is also complex in structure and high in cost.
The preparation methods of the two patents are relatively complex and have high cost. Therefore, in order to overcome the defects of the prior art, a new technical scheme needs to be provided.
Disclosure of Invention
The invention provides a solar photovoltaic module with heat insulation and cooling functions, and aims to provide a novel solar photovoltaic module which radiates heat to the space so as to achieve cooling and help improve photoelectric conversion efficiency; and the structure is simple, the preparation mode is more economical, and the batch production is easy.
In order to achieve the purpose, the solar photovoltaic module with the heat insulation and cooling functions comprises a cell solar cell main body packaged between tempered glass and a back plate, and is characterized in that a transparent heat insulation and cooling coating is coated on the upper surface of the tempered glass; the thickness of the transparent heat-insulation and temperature-reduction coating is 10-30 mu m, and the transparent heat-insulation and temperature-reduction coating comprises the following components in parts by weight:
50-60% of thermoplastic acrylic resin, 5-10% of micron powder, 5-10% of nano barium sulfate, 5-10% of ceramic powder, 5-10% of vacuum glass microspheres, 1-2% of siloxane coupling agent, 0.2-1% of polytetrafluoroethylene wax, 0.1-0.5% of organic silicon defoamer, 5-10% of mixture of xylene and butyl acetate and 1-5% of coating additive
Wherein the micro powder comprises titanium dioxide (TiO)2) And silicon dioxide (SiO)2) Any one or the combination of two of the above, wherein the particle size of the micron powder is 10-30 μm.
Based on the technical scheme, the preferred weight percentage of the mixture of the dimethylbenzene and the butyl acetate is 50 percent to 50 percent.
Based on the technical scheme, preferably, the coating auxiliary agent is at least one of a dispersing agent, a leveling agent, a film forming auxiliary agent and a thickening agent.
Based on the technical scheme, preferably, the transparent heat-insulation and temperature-reduction coating is coated on the upper surface of the toughened glass by spraying and brushing, and is cured for 0.5-1 h at the temperature of 100-200 ℃.
The preparation method of the transparent heat-insulation cooling coating comprises the following steps: firstly, preparing the raw materials into a coating by a mechanical blending method according to a formula, then coating a transparent coating containing micron particles on solar photovoltaic front glass by adopting a spraying and brushing method, and curing for 0.5-1 h at the temperature of 100-200 ℃ to form the solar photovoltaic module. Wherein the thickness of the transparent heat insulation and cooling coating is 10-30 μm.
Advantageous effects
According to the technical scheme, the transparent heat insulation and cooling coating is coated on the upper surface of the toughened glass, heat of the photovoltaic module is conducted to the transparent heat insulation and cooling coating on the premise that light transmittance is not affected, and then the transparent heat insulation and cooling coating emits the heat to the outer space through infrared radiation, so that the temperature of the solar photovoltaic module is effectively reduced, and the photoelectric conversion efficiency is effectively improved; the invention has simple structure, more economic preparation mode, easy batch production and high conversion efficiency.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to the structures shown in the drawings without creative efforts.
FIG. 1 is a schematic structural diagram of an embodiment of the present invention;
1 is a back film; 2 is a battery piece; 3 is toughened glass; and 4, a transparent heat-insulating and cooling coating.
The implementation, functional features and advantages of the objects of the present invention will be further explained with reference to the accompanying drawings.
Detailed Description
The invention provides a solar photovoltaic module with heat insulation and cooling functions.
In an embodiment of the present invention, as shown in FIG. 1; the solar photovoltaic module with the heat insulation and temperature reduction functions comprises a back film 1, a battery piece 2, tempered glass 3 and a transparent heat insulation and temperature reduction coating 4; the thickness of the transparent heat-insulation and temperature-reduction coating 4 is 10-30 mu m, and the components and parts by weight of the transparent heat-insulation and temperature-reduction coating 4 are as follows:
55% of thermoplastic acrylic resin, 8% of micron powder, 8% of nano barium sulfate, 8% of ceramic powder, 7% of vacuum glass beads, 2% of siloxane coupling agent, 0.5% of polytetrafluoroethylene wax, 0.3% of organic silicon defoamer, 8% of mixture of xylene and butyl acetate, 3% of coating additive, and 50% of each station of xylene and butyl acetate in the mixture of xylene and butyl acetate. Wherein the micrometer powder is titanium dioxide (TiO)2) The particle size of the micron powder is 10-30 microns, and the coating additive is a dispersing agent.
And (3) coating the transparent heat-insulating and temperature-reducing coating 4 on the upper surface of the toughened glass 3 by a spraying method, and curing at the temperature of 100-200 ℃ for 0.5-1 h.
The solar photovoltaic module with the heat insulation and temperature reduction functions has the advantages that the photoelectric conversion efficiency is remarkably improved, the solar photovoltaic module is subjected to sunshine with the energy density of 800W/m2 under the condition that the air temperature is 300K (about 27 ℃), and the surface temperature of an unmeasured solar cell is increased to 342.3K (about 69 ℃). The power generation performance of the outdoor type solar cell is mostly rated at a temperature of 25 ℃. Moreover, the crystalline silicon solar cell has poor tolerance to temperature rise, and the output power decreases by 0.45% for every 1K rise in temperature. At a surface temperature of 69 c, the temperature rises by about 42K from the nominal condition, resulting in a drop in output power of about 19%. In the case of a solar cell with a 20% conversion efficiency rating, the conversion efficiency actually exhibited under this condition is only about 16%. The invention can control the temperature rise amplitude under 800W/m2 sunshine at 17.6K. In this case, the surface temperature of the solar cell is only about 52 ℃, and the output power is reduced by only about 11%. The solar cell having the above conversion efficiency of 20% actually operates at a conversion efficiency of about 18%.
Meanwhile, the existing photovoltaic module is cooled by using other materials or combination forms on the back surface, and the structure is complex. The invention adopts a mode of cooling from the front side of the photovoltaic module and has strong infrared heat insulation and cooling functions. Therefore, the combination form of the present invention is original.
The above description is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention, and all modifications and equivalents of the present invention, which are made by the contents of the present specification and the accompanying drawings, or directly/indirectly applied to other related technical fields, are included in the scope of the present invention.

Claims (4)

1. A solar photovoltaic module comprises a cell solar cell main body packaged between toughened glass and a back plate, and is characterized in that the upper surface of the toughened glass is coated with a transparent heat-insulating and temperature-reducing coating; the thickness of the transparent heat-insulation and temperature-reduction coating is 10-30 mu m, and the transparent heat-insulation and temperature-reduction coating comprises the following components in parts by weight:
50-60% of thermoplastic acrylic resin, 5-10% of micron powder, 5-10% of nano barium sulfate, 5-10% of ceramic powder, 5-10% of vacuum glass microspheres, 1-2% of siloxane coupling agent, 0.2-1% of polytetrafluoroethylene wax, 0.1-0.5% of organic silicon defoamer, 5-10% of mixture of xylene and butyl acetate and 1-5% of coating additive;
wherein the micron powder bodyIncluding titanium dioxide (TiO)2) And silicon dioxide (SiO)2) Any one or the combination of two of the above, wherein the particle size of the micron powder is 10-30 μm.
2. The solar photovoltaic module of claim 1, wherein the weight percentage of the mixture of xylene and butyl acetate is 50% to 50%.
3. The solar photovoltaic module of claim 1, wherein the coating additive is at least one of a dispersant, a leveling agent, a film forming additive, or a thickener.
4. The solar photovoltaic module as claimed in any one of claims 1 to 3, wherein the transparent heat insulation and temperature reduction coating is coated on the upper surface of the tempered glass by spraying and brushing, and is cured at a temperature of 100 to 200 ℃ for 0.5 to 1 hour.
CN201811224277.7A 2018-10-19 2018-10-19 Solar photovoltaic module Pending CN111081791A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113527961A (en) * 2021-07-15 2021-10-22 南通强生光电科技有限公司 Preparation and application of coating for enhancing output power of solar power generation panel
CN116925617A (en) * 2022-03-30 2023-10-24 广东晶天新能源电力有限公司 Super heat-dissipation light-absorption coating for solar module

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113527961A (en) * 2021-07-15 2021-10-22 南通强生光电科技有限公司 Preparation and application of coating for enhancing output power of solar power generation panel
CN116925617A (en) * 2022-03-30 2023-10-24 广东晶天新能源电力有限公司 Super heat-dissipation light-absorption coating for solar module

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Application publication date: 20200428