CN111073534A - Cloth with traceless removable adhesive coating and production method thereof - Google Patents
Cloth with traceless removable adhesive coating and production method thereof Download PDFInfo
- Publication number
- CN111073534A CN111073534A CN201911415509.1A CN201911415509A CN111073534A CN 111073534 A CN111073534 A CN 111073534A CN 201911415509 A CN201911415509 A CN 201911415509A CN 111073534 A CN111073534 A CN 111073534A
- Authority
- CN
- China
- Prior art keywords
- cloth
- component
- removable adhesive
- adhesive coating
- traceless
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/21—Paper; Textile fabrics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4808—Mixtures of two or more polyetherdiols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4825—Polyethers containing two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/20—Presence of organic materials
- C09J2400/26—Presence of textile or fabric
- C09J2400/263—Presence of textile or fabric in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention belongs to the technical field of adhesive tapes, and particularly relates to a cloth with a traceless removable adhesive coating, which comprises a cloth base layer and the traceless removable adhesive coating arranged on the surface of the cloth base layer, wherein the traceless removable adhesive coating is a polyurethane elastomer coating and comprises the following components: a component A and a component B; the mass ratio of the component A to the component B is 100: 25-30; the cloth with the traceless removable adhesive coating comprises a cloth base layer and the traceless removable adhesive coating arranged on the surface of the cloth base layer, wherein the traceless removable adhesive coating is a polyurethane elastomer coating, has viscosity, is used for being adhered with other objects, and has the advantages of easy removal, no residue after removal and reusability after washing; the cloth with the traceless removable adhesive coating can be widely applied to mouse pads, table pads, anti-collision stickers and the like. The invention also provides a production method of the cloth with the traceless removable adhesive coating, and the production method is simple in process and suitable for large-scale production.
Description
Technical Field
The invention belongs to the technical field of adhesive tapes, and particularly relates to a cloth with a traceless removable adhesive coating and a production method thereof.
Background
The adhesive plaster is a common object in daily life. The conventional adhesive plaster uses paper, cloth, rubber or plastic film as a base material, and then the base material is coated with an adhesive substance to obtain the adhesive plaster. However, these tapes have disadvantages in that the tape is inconvenient to remove after being pasted, has adhesive residue after being removed, and cannot be reused.
Therefore, it is desirable to provide a cloth with a traceless removable adhesive coating and a method for producing the same to overcome the deficiencies of the prior art.
Disclosure of Invention
The invention aims to provide cloth with a traceless removable adhesive coating and a production method thereof, and aims to solve the technical problem that adhesive residues exist after an adhesive tape in the prior art is removed.
In order to achieve the above purpose, the cloth with the traceless removable adhesive coating provided by the embodiment of the invention comprises a cloth base layer and the traceless removable adhesive coating arranged on the surface of the cloth base layer, wherein the traceless removable adhesive coating is a polyurethane elastomer coating and comprises the following components: a component A and a component B; the mass ratio of the component A to the component B is 100: 25-30; the viscosity of the traceless removable adhesive coating is adjusted by the mass ratio of the A component and the B component;
the component A comprises the following components in parts by weight: 30-50 parts by weight of diphenylmethane diisocyanate, 1-10 parts by weight of polymethylene polyphenyl polyisocyanate and 45-65 parts by weight of polyether polyol; the diphenylmethane diisocyanate has a symmetrical structure, and the polyurethane elastomer coating prepared by the diphenylmethane diisocyanate has better thermal stability and tensile strength; polymethylene polyphenyl polyisocyanates contain a certain amount of higher functionality isocyanate which functions to increase the degree of crosslinking of the A component;
the component B comprises the following components in parts by weight: 95-98 parts by weight of polypropylene oxide ether polyol, 0.5-1 part by weight of zinc catalyst, 2-3 parts by weight of heat-resistant modifier and 1-2 parts by weight of anti-yellowing agent. The zinc catalyst has the advantages of low toxicity, safety and environmental protection.
Preferably, the polyether polyol in the component A is polypropylene oxide polyether polyol with the number average molecular weight of 400-2000 and the functionality of 2 or 3; the content of isocyanic acid radical of the diphenylmethane diisocyanate is 28% -30%; the content of isocyanic acid radical of the polymethylene polyphenyl polyisocyanate is 30-32%.
Preferably, the polypropylene oxide polyether polyol in the component B is the polypropylene oxide polyether polyol with the number average molecular weight of 1000-3000 and the functionality of 2 or 3.
Preferably, the heat-resistant modifier is selected from one or more of carbon fiber, glass fiber, graphene and carbon nanotube.
Preferably, the heat-resistant modifier is carbon fiber with the length of 1-3 mm. The carbon fiber with the length of 1-3 mm is added into the component A, so that the strength of the polyurethane elastomer coating can be obviously improved, and the wear resistance and the thermal stability of the polyurethane elastomer coating are improved.
Preferably, the fabric base layer is made of any one of polyester fabric, PG fabric and nylon fabric. The polyester fabric, the PG fabric and the nylon fabric have the advantages of high strength, good touch and good compounding effect with the traceless removable adhesive coating.
The embodiment of the invention also provides a production method of the cloth with the traceless removable adhesive coating, which comprises the following steps:
1) preparation of the component A: weighing diphenylmethane diisocyanate, polyether polyol and polymethylene polyphenyl polyisocyanate according to the proportion, uniformly stirring, and heating to 70-80 ℃ for 1-1.5 hours; then preserving heat for 2.5-3 hours, and cooling to room temperature to prepare the component A with the content of the isocyanic acid radical of 6-10%; for the active diphenylmethane diisocyanate, when the reaction temperature is 70-80 ℃, the reaction speed is high and the system viscosity is moderate; the generation of bubbles in the curing process is influenced by the isocyanate content of the component A, and when the isocyanate content of the component A is 6-10%, the amount of bubbles is reduced to be within an acceptable range.
2) Preparation of the component B: weighing the polypropylene oxide ether polyol, the zinc catalyst, the heat-resistant modifier and the anti-yellowing agent according to the proportion, and uniformly stirring; vacuum dehydrating at 100-110 ℃ to obtain the component B; vacuum dehydration can reduce moisture and air bubbles in the B component; the purpose of dehydration is to prevent the isocyanate from reacting with water to produce carbon dioxide and thereby cause bubbling.
3) Mixing of two components: the component A and the component B are respectively stored in vacuum by two containers and then are respectively led into the same spray gun according to the mass ratio, and the component A and the component B are stirred and mixed uniformly in the spray gun to obtain a mixture;
4) coating and thermosetting molding: injecting the mixture into a coater by a spray gun; coating the mixture on one side of the cloth substrate by a glue homogenizing roller of the coating machine; conveying the coated semi-finished product into a baking device for drying at the temperature of 90-130 ℃; and (3) performing thermosetting molding on the semi-finished product in a baking device to obtain the cloth with the traceless removable adhesive coating.
Preferably, in the step 4), the other side of the cloth base layer is coated with a protective film. The protective film is used for ensuring that the cloth base material cannot stretch and deform in the transferring process and can be removed when the cloth base material is used after being made into a finished product. The protective film is preferably a PET film.
Preferably, in the step 3), the stirring speed of the spray gun is 2800-3200 rpm.
Preferably, the coating speed of the coating machine is 5-10 m/min.
The technical scheme or the technical schemes in the cloth with the traceless removable adhesive coating and the production method thereof provided by the embodiment of the invention have at least one of the following technical effects:
1. the cloth with the traceless removable adhesive coating comprises a cloth base layer and the traceless removable adhesive coating arranged on the surface of the cloth base layer, wherein the traceless removable adhesive coating is a polyurethane elastomer coating, has viscosity, is used for being adhered with other objects, and has the advantages of easy removal, no residue after removal and reusability after washing; the cloth base layer is exposed when in use, and has the advantages of good touch and skin friendliness; the cloth with the traceless removable adhesive coating can be widely applied to mouse pads, table pads, anti-collision stickers and the like;
2. the heat-resistant modifier enhances the heat deformation resistance, tensile strength and tearing strength of the polyurethane elastomer coating; the elongation at break of the polyurethane elastomer coating reaches 650 percent; especially, the carbon fiber with the diameter of 1-3 mm has high axial tensile modulus and self-lubricating property, so that the friction factor of the polyurethane elastomer coating is reduced, the self-lubricating capability of the polyurethane elastomer coating is improved, and the polyurethane elastomer coating is more wear-resistant. The carbon fibers also enhance the heat resistance of the polyurethane elastomer coating, so that the hardness retention rate of the polyurethane elastomer coating reaches 96% at a high temperature of 135 ℃;
3. the production method of the cloth with the traceless removable adhesive coating is simple in process and suitable for large-scale production, and the prepared product has the advantages of uniform coating of the traceless removable adhesive coating, no air bubbles and high flatness of the product.
Drawings
In order to more clearly illustrate the technical solutions in the embodiments of the present invention, the drawings needed to be used in the embodiments or the prior art descriptions will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art to obtain other drawings based on these drawings without inventive exercise.
Fig. 1 is a schematic structural diagram of a cloth with a traceless removable adhesive coating according to an embodiment of the present invention.
Fig. 2 is another schematic structural diagram of a cloth with a traceless removable adhesive coating according to an embodiment of the present invention.
Detailed Description
Reference will now be made in detail to embodiments of the present invention, examples of which are illustrated in the accompanying drawings, wherein like or similar reference numerals refer to the same or similar elements or elements having the same or similar function throughout. The embodiments described below with reference to the drawings are exemplary and intended to be illustrative of the embodiments of the present invention, and should not be construed as limiting the invention.
Example one
As shown in fig. 1 and fig. 2, the present embodiment provides a cloth with a traceless removable adhesive coating, including a cloth base layer 100 and a traceless removable adhesive coating 200 disposed on a surface of the cloth base layer 100, where the traceless removable adhesive coating 200 is a polyurethane elastomer coating, and includes the following components: a component A and a component B; the mass ratio of the component A to the component B is 100: 25.
the component A comprises the following components in parts by weight: 30Kg of diphenylmethane diisocyanate, 1Kg of polymethylene polyphenyl polyisocyanate, and 45Kg of polyether polyol.
The component B comprises the following components in parts by weight: 95Kg of polypropylene oxide ether polyol, 0.5Kg of zinc-based catalyst, 2Kg of heat-resistant modifier and 1Kg of anti-yellowing agent.
The polyether polyol in the component A is polypropylene oxide polyether polyol with the number average molecular weight of 400 and the functionality of 2; the content of isocyanic acid radical of the diphenylmethane diisocyanate is 28%; the content of isocyanic acid radical of the polymethylene polyphenyl polyisocyanate is 30%.
The polypropylene oxide polyether polyol in the component B is polypropylene oxide polyether polyol with the number average molecular weight of 1000 and the functionality of 2.
The heat-resistant modifier is carbon fiber with the length of 1 mm.
The fabric base layer 100 is made of polyester fabric.
The embodiment also provides a production method of the cloth with the traceless removable adhesive coating, which specifically comprises the following steps:
1) preparation of the component A: weighing diphenylmethane diisocyanate, polyether polyol and polymethylene polyphenyl polyisocyanate according to the proportion, uniformly stirring, and heating to 70 ℃ for 1 hour; then preserving the heat for 2.5 hours, cooling to room temperature to obtain the component A with the content of isocyanic acid radical of 6 percent;
2) preparation of the component B: weighing the polypropylene oxide ether polyol, the zinc catalyst, the heat-resistant modifier and the anti-yellowing agent according to the proportion, and uniformly stirring; vacuum dehydrating at 100 deg.C to obtain component B;
3) mixing of two components: the component A and the component B are respectively stored in vacuum by two containers and then are respectively led into the same spray gun according to the mass ratio, and the component A and the component B are stirred and mixed uniformly in the spray gun to obtain a mixture;
4) coating and thermosetting molding: injecting the mixture into a coater by a spray gun; coating the mixture on one side of the cloth substrate by a glue homogenizing roller of the coating machine; conveying the coated semi-finished product into a baking device for drying, wherein the drying temperature is 90 ℃; and (3) performing thermosetting molding on the semi-finished product in a baking device to obtain the cloth with the traceless removable adhesive coating.
In step 4), the other side of the cloth substrate 100 is coated with a protective film 300. The protective film is a PET film.
In step 3), the stirring speed of the spray gun is 2800 rpm.
The coating speed of the coating machine is 5 m/min.
Example two
The difference between the present embodiment and the first embodiment is: the heat-resistant modifier is carbon fiber with the length of 2 mm.
The rest of this embodiment is the same as the first embodiment, and the unexplained features in this embodiment are explained by the first embodiment, which is not described herein again.
EXAMPLE III
The difference between the present embodiment and the first embodiment is: the heat-resistant modifier is carbon fiber with the length of 3 mm.
The rest of this embodiment is the same as the first embodiment, and the unexplained features in this embodiment are explained by the first embodiment, which is not described herein again.
Example four
As shown in fig. 1 and fig. 2, the present embodiment provides a cloth with a traceless removable adhesive coating, including a cloth base layer and a traceless removable adhesive coating disposed on a surface of the cloth base layer, where the traceless removable adhesive coating is a polyurethane elastomer coating, and includes the following components: a component A and a component B; the mass ratio of the component A to the component B is 100: 27.5.
the component A comprises the following components in parts by weight: 400Kg of diphenylmethane diisocyanate, 50Kg of polymethylene polyphenyl polyisocyanate, and 550Kg of polyether polyol.
The component B comprises the following components in parts by weight: 965Kg of polypropylene oxide ether polyol, 7.5Kg of zinc-based catalyst, 25Kg of heat resistant modifier and 15Kg of anti-yellowing agent.
The heat-resistant modifier is glass fiber. The cloth base layer 100 is made of nylon cloth.
The embodiment also provides a production method of the cloth with the traceless removable adhesive coating, which specifically comprises the following steps:
1) preparation of the component A: weighing diphenylmethane diisocyanate, polyether polyol and polymethylene polyphenyl polyisocyanate according to the proportion, uniformly stirring, heating to 75 ℃, and heating for 1.25 hours; then preserving the heat for 2.75 hours, cooling to room temperature to obtain the component A with the content of isocyanate groups of 8 percent;
2) preparation of the component B: weighing the polypropylene oxide ether polyol, the zinc catalyst, the heat-resistant modifier and the anti-yellowing agent according to the proportion, and uniformly stirring; vacuum dehydrating at 105 deg.C to obtain component B;
3) mixing of two components: the component A and the component B are respectively stored in vacuum by two containers and then are respectively led into the same spray gun according to the mass ratio, and the component A and the component B are stirred and mixed uniformly in the spray gun to obtain a mixture;
4) coating and thermosetting molding: injecting the mixture into a coater by a spray gun; coating the mixture on one side of the cloth substrate by a glue homogenizing roller of the coating machine; conveying the coated semi-finished product into a baking device for drying, wherein the drying temperature is 110 ℃; and (3) performing thermosetting molding on the semi-finished product in a baking device to obtain the cloth with the traceless removable adhesive coating.
In step 4), the other side of the cloth substrate 100 is coated with a protective film 300. The protective film is a PET film.
In the step 3), the stirring speed of the spray gun is 3000 rpm.
The coating speed of the coater was 7.5 m/min.
EXAMPLE five
As shown in fig. 1 and fig. 2, the present embodiment provides a cloth with a traceless removable adhesive coating, including a cloth base layer and a traceless removable adhesive coating disposed on a surface of the cloth base layer, where the traceless removable adhesive coating is a polyurethane elastomer coating, and includes the following components: a component A and a component B; the mass ratio of the component A to the component B is 100: 30.
the component A comprises the following components in parts by weight: 1000Kg of diphenylmethane diisocyanate, 200Kg of polymethylene polyphenyl polyisocyanate, and 1300Kg of polyether polyol.
The component B comprises the following components in parts by weight: 1960Kg of polypropylene oxide ether polyol, 20Kg of zinc-based catalyst, 60Kg of heat resistant modifier and 40Kg of anti-yellowing agent.
The heat-resistant modifier is graphene with length. The fabric base layer 100 is made of PG fabric.
The embodiment also provides a production method of the cloth with the traceless removable adhesive coating, which specifically comprises the following steps:
1) preparation of the component A: weighing diphenylmethane diisocyanate, polyether polyol and polymethylene polyphenyl polyisocyanate according to the proportion, uniformly stirring, and heating to 80 ℃ for 1.5 hours; then preserving the heat for 3 hours, cooling to room temperature to prepare the component A with the content of isocyanate groups of 10 percent;
2) preparation of the component B: weighing the polypropylene oxide ether polyol, the zinc catalyst, the heat-resistant modifier and the anti-yellowing agent according to the proportion, and uniformly stirring; vacuum dehydrating at 110 deg.C to obtain component B;
3) mixing of two components: the component A and the component B are respectively stored in vacuum by two containers and then are respectively led into the same spray gun according to the mass ratio, and the component A and the component B are stirred and mixed uniformly in the spray gun to obtain a mixture;
4) coating and thermosetting molding: injecting the mixture into a coater by a spray gun; coating the mixture on one side of the cloth substrate by a glue homogenizing roller of the coating machine; conveying the coated semi-finished product into a baking device for drying, wherein the drying temperature is 130 ℃; and (3) performing thermosetting molding on the semi-finished product in a baking device to obtain the cloth with the traceless removable adhesive coating.
In step 4), the other side of the cloth substrate 100 is coated with a protective film 300. The protective film is a PET film.
In the step 3), the stirring speed of the spray gun is 3200 rpm.
The coating speed of the coating machine is 10 m/min.
EXAMPLE six
The difference between this embodiment and the fifth embodiment is that: the heat-resistant modifier is a carbon nano tube with the length.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents and improvements made within the spirit and principle of the present invention are intended to be included within the scope of the present invention.
Claims (10)
1. The cloth with the traceless removable adhesive coating comprises a cloth base layer and the traceless removable adhesive coating arranged on the surface of the cloth base layer, and is characterized in that the traceless removable adhesive coating is a polyurethane elastomer coating and comprises the following components: a component A and a component B; the mass ratio of the component A to the component B is 100: 25-30;
the component A comprises the following components in parts by weight: 30-50 parts by weight of diphenylmethane diisocyanate, 1-10 parts by weight of polymethylene polyphenyl polyisocyanate and 45-65 parts by weight of polyether polyol;
the component B comprises the following components in parts by weight: 95-98 parts by weight of polypropylene oxide ether polyol, 0.5-1 part by weight of zinc catalyst, 2-3 parts by weight of heat-resistant modifier and 1-2 parts by weight of anti-yellowing agent.
2. The cloth with the traceless removable adhesive coating layer according to claim 1, wherein the polyether polyol in the component A is polypropylene oxide polyether polyol with the number average molecular weight of 400-2000 and the functionality of 2 or 3; the content of isocyanic acid radical of the diphenylmethane diisocyanate is 28% -30%; the content of isocyanic acid radical of the polymethylene polyphenyl polyisocyanate is 30-32%.
3. The cloth with the traceless removable adhesive coating layer according to claim 1, wherein the polypropylene oxide polyether polyol in the component B is the polypropylene oxide polyether polyol with the number average molecular weight of 1000-3000 and the functionality of 2 or 3.
4. The cloth with the traceless removable adhesive coating of claim 1, wherein the heat-resistant modifier is selected from one or more of carbon fiber, glass fiber, graphene and carbon nanotube.
5. The cloth with the traceless removable adhesive coating layer according to claim 1, wherein the heat-resistant modifier is carbon fiber with the length of 1-3 mm.
6. The cloth with the traceless removable adhesive coating layer according to any one of claims 1 to 5, wherein the material for manufacturing the cloth substrate layer is any one of polyester cloth, PG cloth and nylon cloth.
7. A production method of the cloth with the traceless removable adhesive coating, which is characterized by comprising the following steps:
1) preparation of the component A: weighing diphenylmethane diisocyanate, polyether polyol and polymethylene polyphenyl polyisocyanate according to the proportion, uniformly stirring, and heating to 70-80 ℃ for 1-1.5 hours; then preserving heat for 2.5-3 hours, and cooling to room temperature to prepare the component A with the content of the isocyanic acid radical of 6-10%;
2) preparation of the component B: weighing the polypropylene oxide ether polyol, the zinc catalyst, the heat-resistant modifier and the anti-yellowing agent according to the proportion, and uniformly stirring; vacuum dehydrating at 100-110 ℃ to obtain the component B;
3) mixing of two components: the component A and the component B are respectively stored in vacuum by two containers and then are respectively led into the same spray gun according to the mass ratio, and the component A and the component B are stirred and mixed uniformly in the spray gun to obtain a mixture;
4) coating and thermosetting molding: injecting the mixture into a coater by a spray gun; coating the mixture on one side of the cloth substrate by a glue homogenizing roller of the coating machine; conveying the coated semi-finished product into a baking device for drying at the temperature of 90-130 ℃; and (3) performing thermosetting molding on the semi-finished product in a baking device to obtain the cloth with the traceless removable adhesive coating.
8. The method for producing a cloth having a traceless removable adhesive coating according to claim 7, wherein in the step 4), the other side of the cloth substrate is coated with a protective film.
9. The method for producing the cloth with the traceless removable adhesive coating layer according to claim 7, wherein in the step 3), the stirring speed of the spray gun is 2800-3200 rpm.
10. The method for producing a cloth with a traceless removable adhesive coating according to claim 7, wherein the coating speed of the coating machine is 5-10 m/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911415509.1A CN111073534A (en) | 2019-12-31 | 2019-12-31 | Cloth with traceless removable adhesive coating and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911415509.1A CN111073534A (en) | 2019-12-31 | 2019-12-31 | Cloth with traceless removable adhesive coating and production method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111073534A true CN111073534A (en) | 2020-04-28 |
Family
ID=70320838
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911415509.1A Pending CN111073534A (en) | 2019-12-31 | 2019-12-31 | Cloth with traceless removable adhesive coating and production method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111073534A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102532864A (en) * | 2010-12-07 | 2012-07-04 | 合肥杰事杰新材料股份有限公司 | Continuous long fiber reinforced thermoplastic polyurethane material and preparation method thereof |
| CN102898969A (en) * | 2012-10-22 | 2013-01-30 | 东莞隽思印刷有限公司 | Water-washable non-setting adhesive and preparation method thereof |
| CN105131852A (en) * | 2015-09-09 | 2015-12-09 | 王涛 | Removable traceless glue and manufacturing process thereof |
| CN106928894A (en) * | 2016-10-20 | 2017-07-07 | 深圳市拓源新材料有限公司 | Seamless removable viscose glue and its curable precurser composition and preparation method |
| CN107686550A (en) * | 2017-07-20 | 2018-02-13 | 青岛科技大学 | One kind is without plasticizer, soft, high elongation rate of tensile failure polyurethane elastomer material composition and preparation method thereof |
-
2019
- 2019-12-31 CN CN201911415509.1A patent/CN111073534A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102532864A (en) * | 2010-12-07 | 2012-07-04 | 合肥杰事杰新材料股份有限公司 | Continuous long fiber reinforced thermoplastic polyurethane material and preparation method thereof |
| CN102898969A (en) * | 2012-10-22 | 2013-01-30 | 东莞隽思印刷有限公司 | Water-washable non-setting adhesive and preparation method thereof |
| CN105131852A (en) * | 2015-09-09 | 2015-12-09 | 王涛 | Removable traceless glue and manufacturing process thereof |
| CN106928894A (en) * | 2016-10-20 | 2017-07-07 | 深圳市拓源新材料有限公司 | Seamless removable viscose glue and its curable precurser composition and preparation method |
| CN107686550A (en) * | 2017-07-20 | 2018-02-13 | 青岛科技大学 | One kind is without plasticizer, soft, high elongation rate of tensile failure polyurethane elastomer material composition and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 李子东: "《胶黏剂助剂 第二版》", 30 June 2009, 化学工业出版社 * |
| 邹文俊: "《有机磨具制造》", 30 September 2001, 中国标准出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111704883B (en) | Solvent-free single-component moisture curing polyurethane adhesive suitable for wood and preparation method thereof | |
| CN110229645B (en) | High initial-adhesion single-component moisture curing reaction type polyurethane hot melt adhesive and preparation method thereof | |
| CN108912371B (en) | Solvent-free hydrophobic self-repairing polyurethane coating and preparation method thereof | |
| CN103450438A (en) | Waterborne polyurethane resin with high solid content and synthesis method thereof | |
| CN109181612B (en) | Water-resistant bio-based adhesive and preparation method thereof | |
| CZ2012651A3 (en) | Process for preparing polyurethane materials containing lignin and polyurethane material prepared in such a manner | |
| CN104263275B (en) | A kind of environment-friendly type adhesive label material | |
| CN110760286A (en) | Room-temperature-cured high-strength two-component polyurethane structural adhesive and preparation method thereof | |
| CN108048020B (en) | Single-component moisture-curing reaction type polyurethane hot melt adhesive and preparation method thereof | |
| CN113699802B (en) | Solvent-free polylactic acid bio-based polyurethane synthetic leather, preparation method and application | |
| CN109880050B (en) | Graphene substance modified elastomer material and preparation method thereof | |
| CN111320960A (en) | Low-viscosity high-temperature-resistant single-component solvent-free polyurethane adhesive and preparation method thereof | |
| CN110922928A (en) | Single-component solvent-free polyurethane adhesive and preparation method and application thereof | |
| CN111073534A (en) | Cloth with traceless removable adhesive coating and production method thereof | |
| CN102417579A (en) | Preparation method of yellowing-resistant polyurethane spinning coating agent | |
| CN108948320A (en) | It is a kind of for manufacturing the combination material of polyurethane sole materials | |
| CN112795359A (en) | Water-based spray glue for bags and handbags and preparation method thereof | |
| CN110922884A (en) | Polyurethane type spraying elastomer and preparation method thereof | |
| CN107652939B (en) | High-viscosity polyurethane low-hardness adhesive for coiled material and preparation method thereof | |
| CN112795361B (en) | Preparation method of high-heat-resistance redwood binder capable of being bent by thermal change | |
| CN113621128B (en) | Safety type phenolic resin modified polyurethane functional material and preparation method thereof | |
| CN115742514A (en) | High-temperature-resistant base membrane and preparation method thereof | |
| CN112745795B (en) | Waterborne polyurethane electrostatic flocking adhesive for injection molding and preparation method | |
| CN108840989B (en) | Modified polycarbonate type waterborne polyurethane emulsion and preparation method thereof | |
| CN110616059A (en) | Method for preparing PU (polyurethane) binder resin for synthetic leather |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200428 |