CN111045119B - Surface treatment film and polaroid thereof - Google Patents
Surface treatment film and polaroid thereof Download PDFInfo
- Publication number
- CN111045119B CN111045119B CN201911318205.3A CN201911318205A CN111045119B CN 111045119 B CN111045119 B CN 111045119B CN 201911318205 A CN201911318205 A CN 201911318205A CN 111045119 B CN111045119 B CN 111045119B
- Authority
- CN
- China
- Prior art keywords
- coating
- surface treatment
- nano
- treatment film
- organic particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000004381 surface treatment Methods 0.000 title claims abstract description 44
- 238000000576 coating method Methods 0.000 claims abstract description 162
- 239000011248 coating agent Substances 0.000 claims abstract description 161
- 239000002245 particle Substances 0.000 claims abstract description 54
- 239000011146 organic particle Substances 0.000 claims abstract description 53
- 230000014509 gene expression Effects 0.000 claims abstract description 4
- 239000011247 coating layer Substances 0.000 claims description 47
- 239000004925 Acrylic resin Substances 0.000 claims description 15
- 229920000178 Acrylic resin Polymers 0.000 claims description 15
- 239000000178 monomer Substances 0.000 claims description 13
- 239000002105 nanoparticle Substances 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 8
- SAPGBCWOQLHKKZ-UHFFFAOYSA-N 6-(2-methylprop-2-enoyloxy)hexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCOC(=O)C(C)=C SAPGBCWOQLHKKZ-UHFFFAOYSA-N 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- XRMBQHTWUBGQDN-UHFFFAOYSA-N [2-[2,2-bis(prop-2-enoyloxymethyl)butoxymethyl]-2-(prop-2-enoyloxymethyl)butyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(CC)COCC(CC)(COC(=O)C=C)COC(=O)C=C XRMBQHTWUBGQDN-UHFFFAOYSA-N 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- 230000001588 bifunctional effect Effects 0.000 claims description 6
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 6
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 5
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 5
- LTHJXDSHSVNJKG-UHFFFAOYSA-N 2-[2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOCCOC(=O)C(C)=C LTHJXDSHSVNJKG-UHFFFAOYSA-N 0.000 claims description 4
- FDSUVTROAWLVJA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)COCC(CO)(CO)CO FDSUVTROAWLVJA-UHFFFAOYSA-N 0.000 claims description 4
- ULQMPOIOSDXIGC-UHFFFAOYSA-N [2,2-dimethyl-3-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(C)(C)COC(=O)C(C)=C ULQMPOIOSDXIGC-UHFFFAOYSA-N 0.000 claims description 4
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- DLINORNFHVEIFE-UHFFFAOYSA-N hydrogen peroxide;zinc Chemical compound [Zn].OO DLINORNFHVEIFE-UHFFFAOYSA-N 0.000 claims description 3
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 3
- 239000001095 magnesium carbonate Substances 0.000 claims description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 3
- 239000005543 nano-size silicon particle Substances 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 claims description 2
- 239000004973 liquid crystal related substance Substances 0.000 abstract description 10
- 239000010408 film Substances 0.000 description 70
- 239000000126 substance Substances 0.000 description 29
- 239000000463 material Substances 0.000 description 25
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 21
- 238000001035 drying Methods 0.000 description 17
- 238000003756 stirring Methods 0.000 description 17
- 238000003848 UV Light-Curing Methods 0.000 description 16
- -1 polyethylene terephthalate Polymers 0.000 description 14
- 238000011156 evaluation Methods 0.000 description 12
- 239000011347 resin Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 206010052128 Glare Diseases 0.000 description 8
- 238000001723 curing Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 5
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 229920002799 BoPET Polymers 0.000 description 3
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000003678 scratch resistant effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- 206010052143 Ocular discomfort Diseases 0.000 description 1
- 244000028419 Styrax benzoin Species 0.000 description 1
- 235000000126 Styrax benzoin Nutrition 0.000 description 1
- 235000008411 Sumatra benzointree Nutrition 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229960002130 benzoin Drugs 0.000 description 1
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- MZRQZJOUYWKDNH-UHFFFAOYSA-N diphenylphosphoryl-(2,3,4-trimethylphenyl)methanone Chemical compound CC1=C(C)C(C)=CC=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MZRQZJOUYWKDNH-UHFFFAOYSA-N 0.000 description 1
- 230000004313 glare Effects 0.000 description 1
- 235000019382 gum benzoic Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
- G02B1/113—Anti-reflection coatings using inorganic layer materials only
- G02B1/115—Multilayers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/12—Optical coatings produced by application to, or surface treatment of, optical elements by surface treatment, e.g. by irradiation
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
- G02B5/3033—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
- G02B5/3041—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks
- G02B5/305—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks including organic materials, e.g. polymeric layers
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/133502—Antiglare, refractive index matching layers
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/133528—Polarisers
Abstract
The invention relates to a surface treatment film and a polaroid thereof, which comprises a transparent support body, a first coating coated on the surface of the transparent support body and a second coating arranged on the surface of the first coating, and is characterized in that: the first organic particles and the second organic particles in the first coating are monodisperse organic particles, the particle size D1 of the first organic particles, the particle size D2 of the second organic particles, the coating thickness H1 of the first coating and the coating thickness of the second coating satisfy the relational expressions of (1) to (4): (1)2D2 < D1, (2) H1+ H2 < D1, and (3) D1-H1-H2 < 1 μm with the diameter of 0.1 μm. The invention controls the proportion of the internal haze and the total haze, so that the surface treatment film has excellent anti-dazzle function and anti-flash point function, and is particularly suitable for the surface of a high-precision liquid crystal panel.
Description
Technical Field
The invention relates to the technical field of thin films, in particular to a surface treatment film.
Background
When the liquid crystal display panel and the touch panel are used, when external light such as an indoor fluorescent lamp or sunlight is incident on the surface of the display device, strong glare is generated, which causes visual discomfort, and the display feeling of visibility is also reduced by reflection or reflection. Therefore, in order to suppress this, an anti-glare treatment is generally applied to the surface of the image display device.
The general anti-glare film is mainly prepared by two processes. One is to coat a layer of resin on the surface of the film and imprint the resin into an uneven structure by an imprinting mode to achieve the anti-glare effect. In the method, other substances are not added into the resin, so that light rays cannot be reflected by the substances with large refractive index difference in the resin, so that the internal haze is low, the image display device has stronger bright and black feeling, and the display effect is better. However, this method cannot solve the problem that the antiglare film is not scratch-resistant. Another process of the anti-glare film is to add micron-sized particles into resin, and the particles generate a concave-convex structure on the surface of the resin to achieve the anti-glare effect. Although the method of adding particles can solve the problem that the anti-glare film is not scratch-resistant, the particles are also present in the resin, and these particles scatter light, so that the image display device has a poor "light-black feeling". Particularly, with the recent high definition of liquid crystal panels, the process causes the phenomenon of uneven brightness and darkness or uneven color of the display pattern, i.e., a plurality of flickering "bright spots", which is called "spark" phenomenon, and this phenomenon brings great trouble to people.
Disclosure of Invention
The technical problem to be solved by the invention is to provide a surface treatment film and a polaroid aiming at the defects in the prior art, wherein the treatment film has excellent anti-dazzle function and anti-flash point function.
In order to solve the technical problems, the invention adopts the technical scheme that:
a surface treatment film comprises a transparent support, a first coating layer and a second coating layer are sequentially coated on one surface of the transparent support; the first coating is formed by coating and curing a coating liquid prepared from the following components in parts by mass:
5-20% of bifunctional monomer
10-40 of a polyfunctional monomer
0.5 to 5% of photoinitiator
0.1-5 parts of leveling auxiliary agent
40-60% of organic solvent
0.1 to 1 part of first organic particles
Second organic particles 0.5 to 2
The second coating is formed by coating and curing a coating liquid prepared from the following components in parts by mass:
3-30 parts of acrylic resin
0.3 to 5% of photoinitiator
0.1-3 parts of leveling auxiliary agent
65-90% of an organic solvent
0.5 to 3 parts of nanoparticles
The thickness of the first coating H1 is 3-14 μm, and the thickness of the second coating H2 is 0.1-1 μm; the first organic particles and the second organic particles in the first coating are monodisperse organic particles; the particle size D1 of the first organic particles and the particle size D2 of the second organic particles satisfy the relation (1)2D2 < D1; (2) h1+ H2 < D1; (3) D1-H1-H2 is less than or equal to 0.1 mu m and less than or equal to 0.4 mu m.
The surface treatment film has an internal haze M and a total haze N satisfying the following conditional expressions:
（1）M＜N；
（2）0.5%≤N≤10%；
（3）40%≤M/N≤49%。
in the surface treatment film, the bifunctional monomer is one of 1, 6-hexanediol dimethacrylate, neopentyl glycol dimethacrylate or tetraethylene glycol dimethacrylate; the multifunctional monomer is one of di-trimethylolpropane tetraacrylate, dipentaerythritol pentaacrylate or dipentaerythritol hexaacrylate.
In the surface treatment film, the refractive index of the acrylic resin in the second coating is 1.52-1.55; the nano particles are one of nano titanium dioxide, nano silicon dioxide, nano zinc dioxide, nano magnesium carbonate, nano zirconium dioxide, nano aluminum oxide, nano calcium carbonate or nano barium sulfate, and the particle size range of the nano particles is 60-100 nm.
In the surface treatment film, the leveling assistant in the first coating is an acrylate leveling agent; the leveling auxiliary agent in the second coating is an organic silicon leveling agent.
In the surface treatment film, the first coating and the second coating are cured by ultraviolet light, and the UV illumination energy for curing the first coating is 50mJ/cm2～100 mJ/cm2And the UV irradiation energy used for curing the second coating is 400mJ/cm2～800 mJ/cm2。
In the surface treatment film, the transparent support is one of PET, TAC and PMMA, and the thickness of the transparent support is 25-100 μm.
Another object of the present invention is to provide a polarizer, which comprises the following technical solutions:
a polarizer is provided with a polarizing element formed on the other surface of the transparent support of the surface-treated film, and the surface-treated film.
Advantageous effects
Compared with the prior art, the invention has the following advantages:
the invention adopts a two-layer structure, the particle size and the coating thickness are optimized, and the relation (1)2D2 < D1 is satisfied; (2) h1+ H2 < D1; (3) D1-H1-H2 is not less than 0.1 mu m and not more than 0.4 mu m, and the proportion of the internal haze and the total haze is controlled, so that the surface treatment film has excellent anti-dazzle function and anti-flash point function, and is particularly suitable for the surface of a high-precision liquid crystal panel.
Drawings
FIG. 1 is a schematic view of the structure of a surface-treated film according to the present invention.
In the drawings, each reference numeral indicates 1: a transparent support; 2: a first coating layer; 3; a second coating layer; 21: first organic particles; 22: second organic particles; 32: nanoparticles
Detailed Description
The transparent support used in the present invention is a plastic film or sheet such as polyethylene terephthalate (PET), cellulose Triacetate (TAC), or polymethyl methacrylate (PMMA). The support suitable for the present invention is a transparent substrate having a thickness of 25 μm to 100 μm, preferably 40 μm to 80 μm.
In the invention, the first coating of the surface treatment film is formed by curing a coating liquid consisting of a bifunctional monomer, a multifunctional monomer, a photoinitiator, a leveling auxiliary agent, an organic solvent, first organic particles and second organic particles, and the second coating is formed by curing a coating liquid consisting of acrylic resin, a photoinitiator, a leveling auxiliary agent, an organic solvent and nanoparticles. The surface treatment film of the present invention is applied to the outermost side of a display, which is easily touched by foreign objects or hands when used, so that the surface treatment film needs to have certain hardness and scratch resistance. The first coating layer selects bifunctional monomers and polyfunctional monomers, the second coating layer selects acrylic resin as a film forming material of the resin, and a surface treatment film formed by curing has higher hardness and excellent scratch resistance while the construction performance of the coating is ensured.
In the formula provided by the invention, the dosage of the bifunctional monomer is controlled to be 5-20 parts by mass, the dosage of the polyfunctional monomer is controlled to be 10-40 parts by mass, and the dosage of the acrylic resin is controlled to be 3-30 parts by mass.
The second coating is arranged on the surface of the first coating, and the first coating needs to have higher surface tension, and the invention adopts two methods, namely, the UV energy during the construction of the second coating is controlled to be between 50mJ/cm2～100 mJ/cm2And secondly, the first coating is selected from acrylic leveling aids, such as BYK-350, BYK-355, BYK-390 and the like in Pico chemistry. The leveling aid in the second coating layer is intended to uniformly disperse the particles in the coating layer and is not limited to acrylic or silicone based leveling aids, preferably bisk chemical silicone based leveling aids such as BYK-301, BYK-306, BYK-377.
The surface treatment film of the present invention is used in a high-definition liquid crystal display, and the surface treatment film is required to have a certain antiglare property and a low flicker point. In order to achieve the effect, the invention sequentially coats a first coating layer and a second coating layer on a transparent support, and controls the coating thickness of the first coating layer and the second coating layer and the particle size of the first organic particles to satisfy (1)2D2 < D1, (2) H1+ H2 < D1, and (3)0.1 mu m < D1-H1-H2 < 0.4 mu m. The height range of the first organic particle protruding coating is 0.1-0.4 mu m, and a certain anti-dazzle property and haze can be provided, the thickness of the first coating H1 is 3-14 mu m, the thickness of the second coating H2 is 0.1-1 mu m, the first organic particle and the second organic particle in the first coating are monodisperse organic particles, the monodisperse particles are selected to conveniently control the exposed height of the particle protruding coating, and the thickness of the first coating and the second coating needs to consider the scratch resistance, the construction performance and the optical performance of the coatings.
In the invention, the second organic particles in the first coating layer have proper internal haze due to the difference of the refractive index and the second coating layer, and the second coating layer contains the nano particles, so that when light rays penetrate through the surface treatment film, the light rays are refracted and scattered at the interfaces of the first organic particles, the second organic particles, the nano particles and the resin layer, and meanwhile, the diffuse reflection of the light rays on the surface of the coating layer is reduced, so that the coating layer has better anti-dazzle property and low flash point characteristic. Meanwhile, the internal haze and the total haze of the surface treatment film meet the requirements that (1) M is less than N, (2) N is less than or equal to 10 percent, and (3) M/N is more than or equal to 40 percent and less than or equal to 49 percent, and when the surface treatment film is used for a high-definition display, the display effect has the beneficial visual effects of low flash point, high contrast and the like.
In the invention, the nano particles are one of nano titanium dioxide, nano silicon dioxide, nano zinc dioxide, nano magnesium carbonate, nano zirconium dioxide, nano aluminum oxide, nano calcium carbonate or nano barium sulfate, the particle size range of the nano particles is 60 nm-100 nm, and the using amount of the nano particles is controlled to be 0.5-3 parts by mass.
The refractive index of the acrylic resin in the second coating is 1.52-1.55, and the refractive index of the organic particles is 1.59, so that the proportion of the internal haze and the total haze is controlled through the refractive index difference between the particles and the resin coating, the number of the particles and the coating thickness, and a better visual effect is achieved. The amount of the first organic particles is controlled to 0.1 to 1 part by mass, and the amount of the second organic particles is controlled to 0.5 to 2 parts by mass.
The photoinitiator selected by the invention is 1-hydroxycyclohexyl phenyl ketone (184), 2-hydroxy-methyl phenyl propane-1-ketone (1173), benzoin dimethyl ether (651), 2, 4, 6 (trimethyl benzoyl) diphenyl phosphine oxide (TPO) and the like. After the second coating layer was applied, the UV light irradiation energy used for curing the second coating layer was 400mJ/cm2～800 mJ/cm2. The higher UV energy can cure both the second coating and the first coating again, resulting in a surface treatment film with better scratch resistance and excellent optical effects.
The coating liquid in the present invention requires addition of a solvent, and organic solvents such as: alcohols such as methanol, ethanol, propanol; ketones such as acetone, butanone, methyl isobutyl ketone; esters such as ethyl acetate, butyl acetate, ethyl propionate.
The polarizer of the present invention is formed on the other surface of the transparent support in the surface treatment film.
The present invention is further illustrated by the following examples, but the embodiments of the present invention are not limited to these examples.
Example 1
5g of 1, 6-hexanediol dimethacrylate (sartomer, trade name: SR239NS, functionality: 2), 40g of ditrimethylolpropane tetraacrylate (sartomer, trade name: SR355NS, functionality: 4), 5g of a photoinitiator (manufactured by Tianjin Tianjiao chemical Co., Ltd., trade name: 184), 0.1g of a leveling aid (BYK-350), 0.1g of first organic particles (Soundai chemical, model MX-1500H, particle size 15 μm), 1.8g of second organic particles (Soundai chemical, model SX-500H, particle size 5 μm) and 48g of ethanol were placed in a stirring pot, stirred at a speed of 1000r/min for 6H, further stirred at a speed of 500r/min for 2H, and finally stirred uniformly to obtain a coating material for the first coating layer.
3g of acrylic resin (trade name: HR6200, functionality: 2, refractive index 1.53), 5g of photoinitiator (trade name: 184, manufactured by Tianjin Tianjiao chemical Co., Ltd.), 0.1g of leveling assistant (Pic chemical BYK-301), 1.9g of nano zinc oxide particles (Pic chemical NANOBYK-3860, particle size 60 nm) and 90g of ethyl acetate were placed in a stirring pot, stirred at a speed of 200r/min for 5 hours, and stirred uniformly to obtain a coating material for a second coating.
Coating the first coating on one surface of a PMMA film with the thickness of 25 microns by using the coating material, drying for 5min at the temperature of 90 ℃ in an oven, and then using ultraviolet light energy of 100mJ/cm2Carrying out UV curing on the film by using the ultraviolet light to obtain a first coating; then coating the second coating on the surface of the first coating, drying for 5min at the temperature of 90 ℃ in an oven, and using ultraviolet light energy of 500mJ/cm2The ultraviolet light carries out UV curing on the film to obtain a second coating, and finally the surface treatment film is formed. The thickness of the first coating layer H1 was 14 μm, and the thickness of the second coating layer H2 was 0.9. mu.m, and the evaluation results are shown in Table 1.
Example 2
20g of neopentyl glycol dimethacrylate (Saedoma, trade name: SR248, functionality: 2), 32g of dipentaerythritol pentaacrylate (Saedoma, trade name: SR399, functionality: 5), 0.5g of a photoinitiator (manufactured by Tianjin Tianjiao chemical Co., Ltd., trade name: 1173), 5g of a leveling aid (Pic chemical BYK-355), 0.5g of a first organic particle (Soundai chemical, model MX-1000, particle size 10 μm), 2g of a second organic particle (SX model MX-350H, particle size 3.5 μm) and 40g of isopropanol were placed in a stirring pot, stirred at a speed of 1000r/min for 6H, further stirred at a speed of 500r/min for 2H, and finally stirred uniformly to obtain a coating material for a first coating.
30g of an acrylic resin (Saedorma, trade name: SR541, functionality: 2, refractive index 1.52), 1.5g of a photoinitiator (product name: 184, manufactured by Tianjin Tianjiao chemical Co., Ltd.), 3g of a leveling aid (BYK-306), 0.5g of nano zirconium dioxide particles (DK 417-35, particle size 70nm, Beijing Deke island science and technology Co., Ltd.), and 65g of butyl acetate were placed in a stirring pot, stirred at a speed of 200r/min for 5 hours, and stirred uniformly to obtain a coating material for a second coating.
Coating the first coating on one surface of a PET film with the thickness of 100 microns by using the coating material, drying for 5min at the temperature of 90 ℃ in an oven, and then using ultraviolet light energy of 50mJ/cm2Carrying out UV curing on the film by using the ultraviolet light to obtain a first coating; then coating the second coating on the surface of the first coating, drying for 5min at the temperature of 90 ℃ in an oven, and using ultraviolet light energy of 800mJ/cm2The ultraviolet light carries out UV curing on the film to obtain a second coating, and finally the surface treatment film is formed. The thickness of the first coating layer H1 was 8.6 μm, and the thickness of the second coating layer H2 was 1 μm, and the evaluation results are shown in Table 1.
Example 3
20g of tetraethylene glycol dimethacrylate (Saedoma, trade name: SR209, functionality: 2), 10g of dipentaerythritol hexaacrylate (Changxing chemical, trade name: EM266, functionality: 4), 4g of a photoinitiator (manufactured by Tianjin Tianjiao chemical Co., Ltd., trade name: TPO), 4.5g of a leveling aid (Pic chemical BYK-390), 1g of a first organic particle (Sundao chemical, model SX-500H, particle size 5 μm), 0.5g of a second organic particle (Sundao chemical, model MX-180TA, particle size 1.8 μm) and 60g of ethyl acetate were placed in a stirring pot, stirred at a speed of 1000r/min for 6H, further stirred at a speed of 500r/min for 2H, and finally stirred uniformly to obtain a coating material for a first coating.
20g of an acrylic resin (trade name: PE250, functionality: 2, refractive index: 1.55), 0.3g of a photoinitiator (trade name: 127, manufactured by Tianjin Tianjiao chemical Co., Ltd.), 1.5g of a leveling aid (BYK-377, Bike chemical), 3g of nano silica particles (TSD-L20N, Nanjing Tianxing New Material Co., Ltd., particle size 100 nm) and 75.2g of butanone were placed in a stirring pot, stirred at a speed of 200r/min for 5 hours, and stirred uniformly to obtain a coating material for a second coating.
Coating the first coating layer on one surface of a TAC film with the thickness of 60 microns by using a coating material, drying for 5min at the temperature of 90 ℃ in an oven, and using ultraviolet light energy of 60mJ/cm2UV curing the film to obtain a first coating(ii) a Then coating the second coating on the surface of the first coating, drying for 5min at the temperature of 90 ℃ in an oven, and using ultraviolet light energy of 400mJ/cm2The ultraviolet light carries out UV curing on the film to obtain a second coating, and finally the surface treatment film is formed. The thickness of the first coating layer H1 was 4.7 μm, and the thickness of the second coating layer H2 was 0.1. mu.m, and the evaluation results are shown in Table 1.
Example 4
15g of 1, 6-hexanediol dimethacrylate (sartomer, trade name: SR239NS, functionality: 2), 29g of ditrimethylolpropane tetraacrylate (sartomer, trade name: SR355NS, functionality: 4), 1g of a photoinitiator (manufactured by Tianjin Tianjiao chemical Co., Ltd., trade name: 819), 3g of a leveling aid (Bick chemical BYK-390), 0.4g of first organic particles (Sundaku, model SX-350H, particle size 3.5 μm), 1.6g of second organic particles (Sundaku, model MX-150H, particle size 1.5 μm) and 50g of ethanol were placed in a stirring pot, stirred at a speed of 1000r/min for 6H, further stirred at a speed of 500r/min for 2H, and finally stirred uniformly to obtain a coating material for the first coating layer.
15g of acrylic resin (trade name: SR349NS, functionality: 2, refractive index 1.54), 4g of photoinitiator (trade name: 184, manufactured by Tianjin Tianjiao chemical Co., Ltd.), 0.5g of leveling assistant (BYK-301), and 1.5g of nano titanium dioxide particles (DK-TiO, Technology Co., Ltd., Beijing German island, Ltd.)2-A60, particle size 60 nm) and 79g of ethyl acetate are placed in a stirring pot and stirred for 5 hours at the speed of 200r/min, and the stirring is uniform to obtain a coating material for a second coating.
Coating the first coating on one surface of a PET film with the thickness of 80 microns by using the coating material, drying for 5min at the temperature of 90 ℃ in an oven, and then using ultraviolet light energy of 80mJ/cm2Carrying out UV curing on the film by using the ultraviolet light to obtain a first coating; then coating the second coating on the surface of the first coating, drying for 5min at the temperature of 90 ℃ in an oven, and using ultraviolet energy of 600mJ/cm2The ultraviolet light carries out UV curing on the film to obtain a second coating, and finally the surface treatment film is formed. First of allThe coating thickness H1 was 3 μm thick, and the second coating thickness H2 was 0.2 μm thick, and the evaluation results are shown in Table 1.
Example 5
10g of 1, 6-hexanediol dimethacrylate (sartomer, trade name: SR239NS, functionality: 2), 25g of ditrimethylolpropane tetraacrylate (sartomer, trade name: SR355NS, functionality: 4), 3g of a photoinitiator (manufactured by Tianjin Tianjiao chemical Co., Ltd., trade name: 1173), 0.5g of a leveling aid (BYK-350), 0.8g of first organic particles (Soundai chemical, model MX-1000, particle size 10 μm), 1.5g of second organic particles (Soundai chemical, model SX-180TA, particle size 1.8 μm) and 59.2g of ethyl acetate were placed in a stirring pot, stirred at a speed of 1000r/min for 6h, further stirred at a speed of 500r/min for 2h and finally stirred uniformly to obtain a coating material for a first coating.
10g of an acrylic resin (trade name: HR6200, functionality: 2), 2g of a photoinitiator (trade name: 910, manufactured by Tianjin Tianjiao chemical Co., Ltd.), 2.5g of a leveling aid (BYK-377, Nissan chemical Co., Ltd.), 2g of nano silica particles (MEK-AB 506, particle size 80 nm) and 83.5g of methyl isobutyl ketone were placed in a stirring pot, stirred at a speed of 200r/min for 5 hours, and stirred uniformly to obtain a coating material for a second coating.
Coating the first coating layer with coating material on one surface of a TAC film with the thickness of 40 microns, drying for 5min at the temperature of 90 ℃ in an oven, and using ultraviolet light energy of 75mJ/cm2Carrying out UV curing on the film by using the ultraviolet light to obtain a first coating; then coating the second coating on the surface of the first coating, drying for 5min at the temperature of 90 ℃ in an oven, and using ultraviolet energy of 600mJ/cm2The ultraviolet light carries out UV curing on the film to obtain a second coating, and finally the surface treatment film is formed. The thickness of the first coating layer H1 was 9.1 μm, and the thickness of the second coating layer H2 was 0.6. mu.m, and the evaluation results are shown in Table 1.
Comparative example 1
5g of 1, 6-hexanediol dimethacrylate (sartomer, trade name: SR239NS, functionality: 2), 40g of ditrimethylolpropane tetraacrylate (sartomer, trade name: SR355NS, functionality: 4), 5g of a photoinitiator (manufactured by Tianjin Tianjiao chemical Co., Ltd., trade name: 184), 0.1g of a leveling aid (BYK-350), 0.1g of first organic particles (Soundai chemical, type MX-1500H, particle size 15 μm), 1.8g of second organic particles (Soundai chemical, type MX-1000, particle size 10 μm) and 48g of ethanol were placed in a stirring pot, stirred at a speed of 1000r/min for 6H, further stirred at a speed of 500r/min for 2H, and finally stirred uniformly to obtain a coating material for the first coating layer.
3g of acrylic resin (trade name: HR6200, functionality: 2, refractive index 1.53), 5g of photoinitiator (trade name: 184, manufactured by Tianjin Tianjiao chemical Co., Ltd.), 0.1g of leveling assistant (Pic chemical BYK-301), 1.9g of nano zinc oxide particles (Pic chemical NANOBYK-3860, particle size 60 nm) and 90g of ethyl acetate were placed in a stirring pot, stirred at a speed of 200r/min for 5 hours, and stirred uniformly to obtain a coating material for a second coating.
Coating the first coating on one surface of a PMMA film with the thickness of 25 microns by using the coating material, drying for 5min at the temperature of 90 ℃ in an oven, and then using ultraviolet light energy of 100mJ/cm2Carrying out UV curing on the film by using the ultraviolet light to obtain a first coating; then coating the second coating on the surface of the first coating, drying for 5min at the temperature of 90 ℃ in an oven, and using ultraviolet light energy of 500mJ/cm2The ultraviolet light carries out UV curing on the film to obtain a second coating, and finally the surface treatment film is formed. The thickness of the first coating layer H1 was 14 μm, and the thickness of the second coating layer H2 was 0.9. mu.m, and the evaluation results are shown in Table 1.
Comparative example 2
20g of neopentyl glycol dimethacrylate (Saedoma, trade name: SR248, functionality: 2), 32g of dipentaerythritol pentaacrylate (Saedoma, trade name: SR399, functionality: 5), 0.5g of a photoinitiator (manufactured by Tianjin Tianjiao chemical Co., Ltd., trade name: 1173), 5g of a leveling aid (Pic chemical BYK-355), 0.5g of a first organic particle (Soundai chemical, model MX-1000, particle size 10 μm), 2g of a second organic particle (SX model MX-350H, particle size 3.5 μm) and 40g of isopropanol were placed in a stirring pot, stirred at a speed of 1000r/min for 6H, further stirred at a speed of 500r/min for 2H, and finally stirred uniformly to obtain a coating material for a first coating.
30g of an acrylic resin (Saedorma, trade name: SR541, functionality: 2, refractive index 1.52), 1.5g of a photoinitiator (product name: 184, manufactured by Tianjin Tianjiao chemical Co., Ltd.), 3g of a leveling aid (BYK-306), 0.5g of nano zirconium dioxide particles (DK 417-35, particle size 70nm, Beijing Deke island science and technology Co., Ltd.), and 65g of butyl acetate were placed in a stirring pot, stirred at a speed of 200r/min for 5 hours, and stirred uniformly to obtain a coating material for a second coating.
Coating the first coating on one surface of a PET film with the thickness of 100 microns by using the coating material, drying for 5min at the temperature of 90 ℃ in an oven, and then using ultraviolet light energy of 50mJ/cm2Carrying out UV curing on the film by using the ultraviolet light to obtain a first coating; then coating the second coating on the surface of the first coating, drying for 5min at the temperature of 90 ℃ in an oven, and using ultraviolet light energy of 800mJ/cm2The ultraviolet light carries out UV curing on the film to obtain a second coating, and finally the surface treatment film is formed. The thickness of the first coating layer H1 was 8.6 μm, and the thickness of the second coating layer H2 was 2 μm, and the evaluation results are shown in Table 1.
Comparative example 3
20g of tetraethylene glycol dimethacrylate (Saedoma, trade name: SR209, functionality: 2), 10g of dipentaerythritol hexaacrylate (Changxing chemical, trade name: EM266, functionality: 4), 4g of a photoinitiator (manufactured by Tianjin Tianjiao chemical Co., Ltd., trade name: TPO), 4.5g of a leveling aid (Pic chemical BYK-390), 1g of a first organic particle (Sundao chemical, model SX-500H, particle size 5 μm), 0.5g of a second organic particle (Sundao chemical, model MX-180TA, particle size 1.8 μm) and 60g of ethyl acetate were placed in a stirring pot, stirred at a speed of 1000r/min for 6H, further stirred at a speed of 500r/min for 2H, and finally stirred uniformly to obtain a coating material for a first coating.
20g of an acrylic resin (trade name: PE250, functionality: 2, refractive index: 1.55), 0.3g of a photoinitiator (trade name: 127, manufactured by Tianjin Tianjiao chemical Co., Ltd.), 1.5g of a leveling aid (BYK-377, Bike chemical), 3g of nano silica particles (TSD-L20N, Nanjing Tianxing New Material Co., Ltd., particle size 100 nm) and 75.2g of butanone were placed in a stirring pot, stirred at a speed of 200r/min for 5 hours, and stirred uniformly to obtain a coating material for a second coating.
Coating the first coating layer on one surface of a TAC film with the thickness of 60 microns by using a coating material, drying for 5min at the temperature of 90 ℃ in an oven, and using ultraviolet light energy of 60mJ/cm2Carrying out UV curing on the film by using the ultraviolet light to obtain a first coating; then coating the second coating on the surface of the first coating, drying for 5min at the temperature of 90 ℃ in an oven, and using ultraviolet light energy of 400mJ/cm2The ultraviolet light carries out UV curing on the film to obtain a second coating, and finally the surface treatment film is formed. The thickness of the first coating layer H1 was 3.7 μm, and the thickness of the second coating layer H2 was 0.1. mu.m, and the evaluation results are shown in Table 1.
Table 1: test data table for each example and comparative example
Comparing comparative example 1 and example 1, it can be seen that the particle diameter D1 of the first organic particles was 15 μm, the particle diameter D2 of the second organic particles was 10 μm, and the relational expression 2D2 < D1 was not satisfied, and the surface-treated film prepared was excellent in antiglare property, but was poor in antiglare property; as can be seen by comparing comparative example 2 and example 2, the particle diameter D1 of the first organic particles was 10 μm, the first coating thickness H1 was 8.6 μm, and the second coating thickness H2 was 2 μm, and the relationship H1+ H2 < D1 was not satisfied, the prepared surface-treatment film was excellent in flash point resistance, but was poor in antiglare property; as can be seen by comparing comparative example 3 with example 3, the particle diameter D1 of the first organic particles was 5 μm, the first coating thickness H1 was 3.7 μm, and the second coating thickness H2 was 0.1 μm, which did not satisfy the relationship of 0.1 μm. ltoreq.D 1-H1-H2. ltoreq.0.4. mu.m, the surface-treated film produced was excellent in antiglare property, but poor in antiglare property.
The test methods for the properties in the table are as follows:
(1) measurement of light transmittance and haze
Using a haze meter [ Nippon Denshoku Kogyo; the model is as follows: NDH2000N ], measure total light transmittance and haze.
(2) Pencil hardness test
Film hardness tester using pencil scratch [ manufactured by shanghai pushen chemical machinery ltd; the model is as follows: "BY" ] measuring pencil hardness.
(3) Internal haze testing method
Coating a transparent coating on the coating surface of the surface treatment film by using a coating instrument such as a wire bar or a silk bar: and (3) diluting acrylic acid monomer or oligomer (such as type HR 6042) with the refractive index close to that of the first organic particles (the refractive index difference is less than 0.02) and coating liquid with the solid content of 60% by using solvents such as ketones, esters and the like, and selecting a proper wire rod to control the thickness of the coating layer to be 6 microns after drying. Thus, the surface irregularities of the surface treatment film become a flat layer. This was done to test the haze of the surface-treated film, i.e., the internal haze.
(4) Anti-glare property evaluation method
The surface-treated films of the examples and comparative examples were bonded to a liquid crystal display (Apple iPad Air 3, dark gray, off state) using a transparent optical adhesive, and observed from a position vertically 50cm away from the center of the liquid crystal display under an illumination of 250lux, and in this case, any 100 persons were visually confirmed to see whether or not their own images (faces) could be clearly observed on the liquid crystal display. As a result of the evaluation, the case of 70 or more persons who did not observe clear images was "o", the case of 30 or more persons and less than 70 persons was "Δ", and the case of less than 30 persons was "x".
(5) Anti-flash point evaluation method
The surface-treated films of the examples and comparative examples were bonded to the screen surface of a liquid crystal display (iPhone X mobile phone, 458 ppi) using a transparent optical adhesive, and the liquid crystal display was observed from a position vertically 50cm from the center of the screen surface in a dark room while adjusting the screen to be in a green state, in which case the presence or absence of a flash point was visually judged by 100 arbitrary persons. As a result of the evaluation, a person who did not observe the flash point was "o" in the case of 70 or more persons, a person who was 30 or more and less than 70 persons was "Δ", and a person who was less than 30 persons was "x".
Claims (8)
1. A surface treatment film comprising a transparent support, characterized in that a first coating layer and a second coating layer are sequentially coated on one face of the transparent support; the first coating is formed by coating and curing a coating liquid prepared from the following components in parts by mass:
the second coating is formed by coating and curing a coating liquid prepared from the following components in parts by mass:
the thickness of the first coating H1 is 3-14 μm, and the thickness of the second coating H2 is 0.1-1 μm; the first organic particles and the second organic particles in the first coating are monodisperse organic particles; the particle size D1 of the first organic particles and the particle size D2 of the second organic particles satisfy the relation (1)2D2 < D1; (2) h1+ H2 < D1; (3) D1-H1-H2 is less than or equal to 0.1 mu m and less than or equal to 0.4 mu m.
2. The surface treatment film according to claim 1, wherein the surface treatment film has an internal haze M and a total haze N satisfying the following conditional expressions:
(1)M＜N；
(2)0.5％≤N≤10％；
(3)40％≤M/N≤49％。
3. the surface treatment film according to claim 1, wherein the bifunctional monomer is one of 1, 6-hexanediol dimethacrylate, neopentyl glycol dimethacrylate or tetraethylene glycol dimethacrylate; the multifunctional monomer is one of di-trimethylolpropane tetraacrylate, dipentaerythritol pentaacrylate or dipentaerythritol hexaacrylate.
4. The surface treatment film according to claim 1, wherein the refractive index of the acrylic resin in the second coating layer is 1.52 to 1.55; the nano particles are one of nano titanium dioxide, nano silicon dioxide, nano zinc dioxide, nano magnesium carbonate, nano zirconium dioxide, nano aluminum oxide, nano calcium carbonate or nano barium sulfate, and the particle size range of the nano particles is 60-100 nm.
5. The surface treatment film according to claim 1, wherein the leveling aid in the first coating layer is an acrylate-based leveling agent; the leveling auxiliary agent in the second coating is an organic silicon leveling agent.
6. The surface treatment film according to claim 1, wherein the first coating layer and the second coating layer are cured by ultraviolet light, and the first coating layer is cured by using 50mJ/cm of UV light irradiation energy2～100mJ/cm2And the UV irradiation energy used for curing the second coating is 400mJ/cm2～800mJ/cm2。
7. The surface treatment film according to claim 1, wherein the transparent support is one of PET, TAC, and PMMA, and has a thickness of 25 μm to 100 μm.
8. A polarizer using the surface-treated film according to any one of claims 1 to 7, and having a polarizing element formed on the other surface of the transparent support.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911318205.3A CN111045119B (en) | 2019-12-19 | 2019-12-19 | Surface treatment film and polaroid thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911318205.3A CN111045119B (en) | 2019-12-19 | 2019-12-19 | Surface treatment film and polaroid thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN111045119A CN111045119A (en) | 2020-04-21 |
| CN111045119B true CN111045119B (en) | 2021-07-27 |
Family
ID=70237907
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911318205.3A Active CN111045119B (en) | 2019-12-19 | 2019-12-19 | Surface treatment film and polaroid thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111045119B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112327394B (en) * | 2020-11-12 | 2023-03-14 | 苏州诺菲纳米科技有限公司 | Anti-glare film with high wear resistance and low flash point |
| CN114349997A (en) * | 2021-12-14 | 2022-04-15 | 合肥乐凯科技产业有限公司 | Optical film for rupture membrane |
| CN114316325A (en) * | 2021-12-14 | 2022-04-12 | 合肥乐凯科技产业有限公司 | Preparation method of optical film for explosion-proof film |
| CN115850803B (en) * | 2022-11-27 | 2024-02-13 | 合肥乐凯科技产业有限公司 | Antifog anti-dazzle hardening film |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW557363B (en) * | 2002-10-15 | 2003-10-11 | Optimax Tech Corp | Anti-glare film |
| JP3507344B2 (en) * | 1998-10-14 | 2004-03-15 | 大日本印刷株式会社 | Anti-glare film, polarizing plate and transmission type display device |
| JP2007203712A (en) * | 2006-02-06 | 2007-08-16 | Fujifilm Corp | Laminated film, its manufacturing method, optical sheet using laminated film, and display device |
| JP2007331231A (en) * | 2006-06-15 | 2007-12-27 | Nippon Rikagaku Kogyo Kk | Film for whiteboard |
| CN101308220A (en) * | 2007-03-19 | 2008-11-19 | 大日本印刷株式会社 | Anti-dazzling optical laminate |
| CN102483475A (en) * | 2009-09-04 | 2012-05-30 | 住友化学株式会社 | Light-diffusing film, manufacturing method therefor, light-diffusing polarizing plate, and liquid-crystal display device |
| US8974066B2 (en) * | 2013-03-14 | 2015-03-10 | Intermolecular, Inc. | Optical coatings with plate-shaped particles and methods for forming the same |
| CN104817951A (en) * | 2015-05-26 | 2015-08-05 | 张家港康得新光电材料有限公司 | Anti-dazzle coating and anti-dazzle hardening film |
| CN105378510A (en) * | 2013-07-05 | 2016-03-02 | 株式会社钟化 | Anti-glare film for solar cell module, solar cell module provided with anti-glare film, and method for manufacturing same |
| CN105566963A (en) * | 2015-12-25 | 2016-05-11 | 佛山佛塑科技集团股份有限公司 | Non-glare coating and non-glare membrane |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106338783B (en) * | 2015-09-17 | 2018-08-14 | 湖北航天化学技术研究所 | A kind of anti-dazzle antireflective optical film and its preparation method and application |
-
2019
- 2019-12-19 CN CN201911318205.3A patent/CN111045119B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3507344B2 (en) * | 1998-10-14 | 2004-03-15 | 大日本印刷株式会社 | Anti-glare film, polarizing plate and transmission type display device |
| TW557363B (en) * | 2002-10-15 | 2003-10-11 | Optimax Tech Corp | Anti-glare film |
| JP2007203712A (en) * | 2006-02-06 | 2007-08-16 | Fujifilm Corp | Laminated film, its manufacturing method, optical sheet using laminated film, and display device |
| JP2007331231A (en) * | 2006-06-15 | 2007-12-27 | Nippon Rikagaku Kogyo Kk | Film for whiteboard |
| CN101308220A (en) * | 2007-03-19 | 2008-11-19 | 大日本印刷株式会社 | Anti-dazzling optical laminate |
| CN102483475A (en) * | 2009-09-04 | 2012-05-30 | 住友化学株式会社 | Light-diffusing film, manufacturing method therefor, light-diffusing polarizing plate, and liquid-crystal display device |
| US8974066B2 (en) * | 2013-03-14 | 2015-03-10 | Intermolecular, Inc. | Optical coatings with plate-shaped particles and methods for forming the same |
| CN105378510A (en) * | 2013-07-05 | 2016-03-02 | 株式会社钟化 | Anti-glare film for solar cell module, solar cell module provided with anti-glare film, and method for manufacturing same |
| CN104817951A (en) * | 2015-05-26 | 2015-08-05 | 张家港康得新光电材料有限公司 | Anti-dazzle coating and anti-dazzle hardening film |
| CN105566963A (en) * | 2015-12-25 | 2016-05-11 | 佛山佛塑科技集团股份有限公司 | Non-glare coating and non-glare membrane |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111045119A (en) | 2020-04-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111045119B (en) | Surface treatment film and polaroid thereof | |
| KR101202089B1 (en) | Optical multilayer body, polarizing plate using same, and image display | |
| KR100959049B1 (en) | Antiglare hardcoat film | |
| JP5103825B2 (en) | OPTICAL LAMINATE, ITS MANUFACTURING METHOD, POLARIZING PLATE, AND IMAGE DISPLAY DEVICE | |
| JP5252811B2 (en) | Anti-glare hard coat film, polarizing plate and image display device | |
| WO2013099931A1 (en) | Anti-glare film, polarizing plate and image display device | |
| JP4187186B2 (en) | Anti-glare film | |
| JP2007041533A (en) | Antiglare hardcoat film | |
| TW200916836A (en) | Optical film and its production method, and glare-proof polarizer using same and display apparatus | |
| KR20110018286A (en) | Optical film and manufacturing method therefor, anti-glare film, polarizing element with optical layer, and display device | |
| KR20130105510A (en) | Optical film, polarizing plate, liquid-crystal panel and image display device | |
| JP2009020288A (en) | Antiglare film, method of manufacturing the same, polarizer, and display device | |
| WO2006088204A1 (en) | Anti-glare optical multilayer body | |
| KR20110037841A (en) | Hard-coated antiglare film, and polarizing plate and image display including the same | |
| JP2014059334A (en) | Optical film, polarizing plate, liquid crystal panel, and image displaying device | |
| CN111100314B (en) | Preparation method of anti-glare hardened film for polarizer | |
| KR20070097361A (en) | Hard-coated antiglare film, method of manufacturing the same, optical device, polarizing plate, and image display | |
| JP2009288650A (en) | Antiglare hard coat film, polarizing plate and image display apparatus using the same | |
| CN114213694B (en) | Anti-glare film with high haze and low flash point and preparation method thereof | |
| TWI693734B (en) | Anti-glare film and polarizer with the same | |
| CN100353187C (en) | Antiglare film | |
| JP6565094B2 (en) | Touch panel, display device, optical sheet, optical sheet sorting method, and optical sheet manufacturing method | |
| JPH0642004B2 (en) | Anti-glare synthetic resin light transmissive body | |
| JP2015172835A (en) | Touch panel, display device and optical sheet, and method of selecting optical sheet and method of manufacturing optical sheet | |
| JP2013238867A (en) | Optical film and manufacturing method therefor, anti-glare film, polarizing element with optical layer, and display device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A surface treatment film and its polarizing film Effective date of registration: 20231212 Granted publication date: 20210727 Pledgee: Industrial and Commercial Bank of China Limited Hefei Changdong sub branch Pledgor: HEFEI LUCKY SCIENCE & TECHNOLOGY INDUSTRY Co.,Ltd. Registration number: Y2023980071021 |