CN111041940A - Prefabricated self-adhesive luminous coiled material structure and prefabricating method thereof - Google Patents

Prefabricated self-adhesive luminous coiled material structure and prefabricating method thereof Download PDF

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Publication number
CN111041940A
CN111041940A CN201911315217.0A CN201911315217A CN111041940A CN 111041940 A CN111041940 A CN 111041940A CN 201911315217 A CN201911315217 A CN 201911315217A CN 111041940 A CN111041940 A CN 111041940A
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China
Prior art keywords
layer
self
adhesive
noctilucent
coiled material
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CN201911315217.0A
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Chinese (zh)
Inventor
袁月
李军代
罗攀
闫国杰
岳国柱
邱轶
邓国民
许严
周维维
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Shanghai Puxing Road & Bridge Construction Engineering Co ltd
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Shanghai Puxing Road & Bridge Construction Engineering Co ltd
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Priority to CN201911315217.0A priority Critical patent/CN111041940A/en
Publication of CN111041940A publication Critical patent/CN111041940A/en
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    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C15/00Pavings specially adapted for footpaths, sidewalks or cycle tracks
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29Laminated material
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C17/00Pavement lights, i.e. translucent constructions forming part of the surface
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C23/00Auxiliary devices or arrangements for constructing, repairing, reconditioning, or taking-up road or like surfaces
    • E01C23/03Arrangements for curing paving; Devices for applying curing means; Devices for laying prefabricated underlay, e.g. sheets, membranes; Protecting paving under construction or while curing, e.g. use of tents

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Road Signs Or Road Markings (AREA)

Abstract

The invention discloses a prefabricated self-adhesive luminous coiled material structure and a prefabricating method thereof, wherein the prefabricated self-adhesive luminous coiled material structure comprises the following components: the luminous surface layer, the adhesive layer, the coiled material bottom layer and the self-adhesive layer are sequentially stacked; the noctilucent surface layer comprises solid particles, a binding material and a noctilucent material, and the solid particles, the binding material and the noctilucent material are mixed and spread to form the noctilucent surface layer; the self-adhesion layer includes self-adhesion layer and self-adhesion protective film, and the self-adhesion layer is close to setting up on one side of the coiled material bottom, and the surface of coiled material bottom one side is kept away from in the self-adhesion layer in the self-adhesion protective film, and the self-adhesion protective film is connected with the self-adhesion layer is detachable. The invention realizes the rapid construction and the environment-friendly construction of the noctilucent structure and has good noctilucent effect.

Description

Prefabricated self-adhesive luminous coiled material structure and prefabricating method thereof
Technical Field
The invention relates to the technical field of road landscape pavement, in particular to a prefabricated self-adhesive luminous coiled material structure and a prefabricating method thereof.
Background
Asphalt pavement construction has a history of hundreds of years, and in China, asphalt pavements are firstly applied in the sea from the last twentieth century and have a construction history of nearly one hundred years to date. At present, the research on black asphalt pavements is mature and complete, and the black asphalt pavements are deeply researched in the aspects of asphalt pavement construction, evaluation, maintenance, regeneration and the like, and the black asphalt pavements also become the main form of road pavements in China.
In recent years, with the development of economic construction in China, a great deal of functional pavement construction appears, and the noctilucent pavement is rapidly researched and developed as an important technology.
However, in research and construction practice, the current construction standard of the luminous road surface is not perfect, and the road base layer and the whole structure of the road have no unified standard, so that the construction and development of the luminous road surface are limited; in addition, the existing luminous road surface is mainly used as a part of landscape pavement, and is often designed to build an area with irregular line shape and shape with the road, so that the requirement on convenient construction of the luminous road surface landscape pavement is high; meanwhile, the existing noctilucent pavement landscape pavement is usually designed and built in a core area with dense people flow and leisure living, and has high requirements on the construction rapidity and the construction environment.
Therefore, the research on the luminous road landscape pavement structure which can be quickly constructed, is environment-friendly in construction and has good performance is an urgent problem to be solved.
Disclosure of Invention
In order to solve the problems of the prior art, the invention provides a prefabricated self-adhesive type noctilucent coiled material structure and a prefabricating method thereof, which realize the rapid construction and the environment-friendly construction of a noctilucent structure and have good noctilucent effect.
The technical scheme provided by the invention is as follows:
a prefabricated self-adhesive night light coiled material structure, includes: the luminous surface layer, the adhesive layer, the coiled material bottom layer and the self-adhesive layer are sequentially stacked; the noctilucent surface layer comprises solid particles, a binder and a noctilucent material, and the solid particles, the binder and the noctilucent material are mixed and spread to form the noctilucent surface layer; the self-adhesion layer includes self-adhesion layer and self-adhesion protective film, the self-adhesion layer is close to coiled material bottom one side sets up, the self-adhesion protective film is in the self-adhesion layer is kept away from the surface of coiled material bottom one side, the self-adhesion protective film with the detachable connection in self-adhesion layer.
In the technical scheme, the whole luminous structure construction can be realized only by tearing off the self-adhesive protective film from the self-adhesive layer, so that the luminous structure is very convenient, simple, quick, environment-friendly and efficient; the prefabricated luminous structure can be directly constructed and paved at a position where noctilucence is needed, the whole construction process does not need to block a construction site, does not need to open a groove, does not need to mix, pave, maintain health and other operation processes, and the film is directly torn, pasted and compacted, so that the adverse effects (such as noise pollution, dust pollution and odor pollution) of the construction process and the construction process on the surrounding environment are greatly reduced; the noctilucent structure is high in applicability, applicable to noctilucent demand areas (landscape road surfaces or corner areas and the like) with different shapes or structures, and applicable to different base layer road surfaces, solid particles, binders and noctilucent materials are mixed and paved, the noctilucent materials are evenly distributed and have strong adhesive force, and the noctilucent structure is wear-resistant, durable and good in noctilucent effect, and meets the requirements of landscape design. Preferably, the noctilucent surface layer is of a full-thickness noctilucent structure, so that the noctilucent effect of the invention is three-dimensional luminescence, and the whole noctilucent performance is not influenced even if part of solid particles and/or noctilucent materials fall off under the action of the environment, so that the noctilucent performance of the invention has high durability.
Further, the particle size of the solid particles is 2-15 mm.
In the technical scheme, the balance and uniformity of noctilucence diffusion are improved by the particle size of the solid particles, softness of a noctilucence effect is improved, and eyes are protected and are not dazzled.
Further, the binder is a thermoplastic transparent binder, and the thermoplastic transparent binder is prepared from transparent base oil, SBS and hydrogenated resin.
In the technical scheme, the thermoplastic transparent binder greatly improves the deformation performance of the noctilucent surface layer, improves the adaptability of the noctilucent surface layer to the bottom layer of the coiled material, improves the adaptability of the noctilucent structure to temperature and climate, and realizes the fatigue resistance and weather resistance of the noctilucent structure.
Further, the noctilucent material is a mixture of strontium aluminate and rare elements, the particle size of the mixture is 5-45 mu m, and the density of the mixture is 3.4-3.6 g/cm3And the luminous peak of the mixture is 520 +/-5 nm.
In the technical scheme, the long-term durability and the brightness of the noctilucent effect are ensured.
Further, the solid particles, the binder and the noctilucent material account for 88-94% by mass, 3.5-5% by mass and 2.5-7% by mass of the noctilucent surface layer respectively.
In the technical scheme, the durability and the wear resistance of the noctilucent structure are improved due to the high specific gravity of the solid particles, the cost of the noctilucent structure is reduced due to the small specific gravity of the noctilucent material, and the noctilucent structure is low in cost and durable for a long time while meeting the noctilucent effect.
Further, the adhesive layer is a transparent epoxy resin layer, the transparent epoxy resin is prepared from epoxy resin, a curing agent and a diluent, and the epoxy resin, the curing agent and the diluent account for 60-80%, 15-30% and 5-10% of the transparent epoxy resin by mass respectively.
In the technical scheme, the adhesive force of the noctilucent material is improved, the distribution balance and uniformity of the noctilucent material are improved, and the overall performance of the noctilucent effect is improved. Preferably, the transparent epoxy resin layer forms the function similar to a reflecting mirror, has the enhancement function on the noctilucent effect of the noctilucent surface layer, ensures that the noctilucent effect is more excellent,
further, the coiled material bottom is self-adhesive waterproof coiled material layer, self-adhesive waterproof coiled material layer includes waterproof layer and self-adhesive bonding layer, the waterproof layer is close to bonding layer one side sets up, the self-adhesive bonding layer forms the self-adhesive bonding layer.
In the technical scheme, the self-adhesive waterproof roll material layer integrates the roll material bottom layer and the self-adhesive layer, so that the prefabrication process is simplified, and the prefabrication efficiency is improved.
Further, the thickness of the bottom layer of the coiled material is 2-5 mm; and/or the thickness of the noctilucent surface layer is 3-16 mm; and/or the thickness of the adhesive layer is 1-3 mm; and/or the porosity of the noctilucent surface layer is 10-40%.
In the technical scheme, the thickness of each layer of the noctilucent structure is small, and the use of a road surface is not influenced. The arrangement of the porosity improves the water permeability of the invention, and simultaneously, rainwater can wash away dust accumulated in the invention, so that the cleanness and clean environment of the invention are ensured, the luminous effect of the invention is ensured, meanwhile, the luminous long-acting durability of the invention is prolonged, and the applicability of the invention to different base layer pavements can be improved; the arrangement of the porosity improves the deformation performance of the noctilucent structure, improves the adaptability of the noctilucent surface layer to the bottom layer of the coiled material, improves the adaptability of the noctilucent structure to temperature and climate, and realizes the fatigue resistance and weather resistance of the noctilucent structure.
The invention also discloses a prefabricating method of the prefabricated self-adhesive luminous coiled material structure, which comprises the following steps:
laying a bottom layer of the coiled material;
coating an adhesive layer on one side surface of the bottom layer of the coiled material, and forming a self-adhesive layer on the other side surface of the bottom layer;
and mixing the solid particles, the binder and the noctilucent material to form a noctilucent mixture, and paving the noctilucent mixture on the surface of one side of the adhesive layer, which is far away from the bottom layer of the coiled material, so as to form a noctilucent surface layer.
In the technical scheme, the construction process of the luminous structure is very simple and convenient and is easy to realize.
Further, the binder is a thermoplastic transparent binder, and the thermoplastic transparent binder is prepared from transparent base oil, SBS and hydrogenated resin; and/or the noctilucent material is a mixture of strontium aluminate and rare elements, the particle size of the mixture is 5-45 mu m, and the density of the mixture is 3.4-3.6 g/cm3The luminous peak of the mixture is 520 +/-5 nm; and/or the adhesive layer is a transparent epoxy resin layer, the transparent epoxy resin is prepared from epoxy resin, a curing agent and a diluent, and the epoxy resin, the curing agent and the diluent respectively account for 60-80%, 15-30% and 5-10% of the transparent epoxy resin by mass percent; and/or, the coiled material bottom is self-adhesive waterproof coiled material layer, self-adhesive waterproof coiled material layer includes waterproof layer and self-adhesive bonding layer, the waterproof layer is close to bonding layer one side sets up, the self-adhesive bonding layer forms the self-adhesive bonding layer.
Compared with the prior art, the prefabricated self-adhesive luminous coiled material structure and the prefabricating method thereof have the beneficial effects that: the rapid construction and the environment-friendly construction of the noctilucent structure are realized, and the noctilucent effect is good.
Drawings
The above features, technical features, advantages and implementation of a prefabricated self-adhesive luminous coil structure and a prefabrication method thereof will be further explained in a clearly understandable way with reference to the accompanying drawings.
FIG. 1 is a schematic structural diagram of one embodiment of a prefabricated self-adhesive luminous coiled material structure of the invention;
fig. 2 is a flow chart of an embodiment of a prefabrication method of the prefabricated self-adhesive luminous coiled material structure.
The reference numbers illustrate:
1. luminous surface layer, 2 adhesive layer, 3 coiled material bottom layer, 41 self-adhesive layer and 42 self-adhesive protective film.
Detailed Description
In the following description, for purposes of explanation and not limitation, specific details are set forth, such as particular system structures, techniques, etc. in order to provide a thorough understanding of the embodiments of the present application. However, it will be apparent to one skilled in the art that the present application may be practiced in other embodiments that depart from these specific details. In other instances, detailed descriptions of well-known systems, devices, circuits, and methods are omitted so as not to obscure the description of the present application with unnecessary detail.
It will be understood that the terms "comprises" and/or "comprising," when used in this specification and the appended claims, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
For the sake of simplicity, the drawings only schematically show the parts relevant to the present invention, and they do not represent the actual structure as a product. In addition, in order to make the drawings concise and understandable, components having the same structure or function in some of the drawings are only schematically illustrated or only labeled. In this document, "one" means not only "only one" but also a case of "more than one". In this context, it is to be understood that, unless otherwise explicitly stated or limited, the terms "mounted," "connected," and "connected" are to be construed broadly, e.g., as meaning either a fixed connection, a removable connection, or an integral connection; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art. It should be further understood that the term "and/or" as used in this specification and the appended claims refers to and includes any and all possible combinations of one or more of the associated listed items.
In one embodiment of the present invention, as shown in fig. 1, a prefabricated self-adhesive luminous roll structure comprises: the luminous surface layer 1, the adhesive layer 2, the coiled material bottom layer 3 and the self-adhesive layer are sequentially stacked; the noctilucent surface layer 1 comprises solid particles, a binder and a noctilucent material, and the solid particles, the binder and the noctilucent material are mixed and spread to form the noctilucent surface layer 1; the self-adhesion layer includes self-adhesion layer 41 and self-adhesion protective film 42, and self-adhesion layer 41 is close to setting up on one side of coiled material bottom 3, and the attached surface of keeping away from coiled material bottom 3 one side in self-adhesion layer 41 of self-adhesion protective film 42, self-adhesion protective film 42 and the detachable connection of self-adhesion layer 41. The luminous structure can be prefabricated and then transported to a position where the luminous structure needs to be laid, the whole construction process is completed only by tearing off the self-adhesive protective film 42 from the self-adhesive layer 41, then laying the luminous structure in the position where the luminous structure needs to be arranged by utilizing the adsorption force of the self-adhesive layer 41, and then compacting, a construction road section or a construction area does not need to be sealed, dust or peculiar smell cannot be generated in the whole process, the environment is protected, and the construction is rapid and environment-friendly.
Preferably, the mass percentages of the solid particles, the binder and the noctilucent material in the noctilucent surface layer 1 are respectively 88-94%, 3.5-5% and 2.5-7%. Preferably, the thickness of the noctilucent surface layer 1 is 3-16 mm; the porosity of the noctilucent surface layer 1 is 10-40%; the thickness of the adhesive layer 2 is 1-3 mm; the thickness of the bottom layer 3 of the coiled material is 2-5 mm; the thickness dimension of the self-adhesive layer 41 is 0.2-0.4 mm.
Preferably, the particle size of the solid particles is 2-15 mm. In practice, the solid particles are preferably stone particles, preferably white stone with mirror effect, such as white pebbles, white spar, etc. Of course, the solid particles also include transparent powder, such as transparent glass powder or resin powder. Preferably, the binder is a thermoplastic transparent binder formed from a transparent base oil, SBS (styrene Block Copolymers) and hydrogenated resin. Preferably, the mass percentages of the epoxy resin, the curing agent and the diluent in the transparent epoxy resin are respectively 60-80%, 15-30% and 5-10%. Preferably, the luminous material is strontium aluminate and rare elementThe mixture has a particle size of 5-45 μm and a density of 3.4-3.6 g/cm3The mixture has a luminescence peak of 520 + -5 nm.
Preferably, the adhesive layer 2 is a transparent epoxy resin layer, the transparent epoxy resin layer is prepared from epoxy resin, a curing agent and a diluent, and the epoxy resin, the curing agent and the diluent account for 60-80%, 15-30% and 5-10% of the transparent epoxy resin by mass percent respectively.
Preferably, coiled material bottom 3 is self-adhesive waterproofing membrane layer, and self-adhesive waterproofing membrane layer includes waterproof layer and self-adhesive bonding layer, and the waterproof layer is close to 2 one sides of bonding layer and sets up, and self-adhesive bonding layer forms the self-adhesive bonding layer. In practical applications, the waterproof layer may be formed by spraying, brushing, spreading, etc. a waterproof mixture containing a resin polymer as a main component, wherein the resin polymer may be HDPE (High Density Polyethylene), PVC (Polyvinyl chloride), EVA (Ethylene Vinyl Acetate Copolymer), or EVB (thermal mortar).
Preferably, the self-adhesive layer 41 is a self-adhesive layer formed by brushing or spraying a self-adhesive glue, and the self-adhesive protective film 42 is preferably a polymeric self-adhesive film, which may be a polyethylene film, a rubber film, or a nylon film.
In another embodiment of the present invention, different from the above embodiments, the mass percentages of the solid particles, the binder and the noctilucent material in the embodiment are 90-93%, 4-5% and 3-6% respectively. Preferably, the mass percentages of the solid particles, the binder and the noctilucent material in the noctilucent surface layer 1 are 91-92%, 4-5% and 3-6%, respectively. Preferably, the mass percentages of the solid particles, the binder and the noctilucent material in the noctilucent surface layer 1 are 91-92%, 4-5% and 4-6%, respectively.
In another embodiment of the present invention, different from the above embodiments, the thickness of the noctilucent surface layer 1 of the present embodiment is 5mm to 10 mm; the porosity of the noctilucent surface layer 1 is 25-35%; the thickness of the adhesive layer 2 is 1-2 mm; the thickness dimension of coiled material bottom 3 is 2 ~ 5 mm. Preferably, the thickness of the noctilucent surface layer 1 is 6-9 mm; the porosity of the noctilucent surface layer 1 is 25-30%; the thickness of the adhesive layer 2 is 1-2 mm; the thickness dimension of coiled material bottom 3 is 2 ~ 5 mm. Preferably, the thickness of the noctilucent surface layer 1 is 8 mm; the porosity of the noctilucent surface layer 1 is 30 percent; the thickness of the adhesive layer 2 is 1 mm; the thickness dimension of the bottom layer 3 of the web is 3 mm.
In another embodiment of the present invention, unlike the above embodiments, the solid particles of the present embodiment have a particle size of 3 to 6 mm. Preferably, the particle size of the solid particles is 4-6 mm. Preferably, the solid particles have a particle size of 5 mm.
In another embodiment of the present invention, different from the above embodiments, the solid particles of the present embodiment have a particle size of 4 to 8 mm. Preferably, the solid particles have a particle size of 6 mm.
In another embodiment of the present invention, different from the above embodiments, the mass percentages of the epoxy resin, the curing agent and the diluent in the embodiment are 65-78%, 20-30% and 5-10% respectively. Preferably, the mass percentages of the epoxy resin, the curing agent and the diluent in the transparent epoxy resin are respectively 70-78%, 25-30% and 5-10%. The mass percentages of the epoxy resin, the curing agent and the diluent in the transparent epoxy resin are respectively 74%, 20% and 6%.
In another embodiment of the present invention, different from the above embodiments, the noctilucent material of the present embodiment is a mixture of strontium aluminate and rare elements, the particle size of the mixture is 25 to 30 μm, and the density of the mixture is 3.4 to 3.6g/cm3The luminescence peak of the mixture is 520 +/-5 nm. Preferably, the density of the mixture is 3.5g/cm3The luminescence peak of the mixture is 520 +/-5 nm.
In another embodiment of the present invention, different from the above embodiments, the mass percentages of the epoxy resin, the curing agent and the diluent in the embodiment are 65-75%, 15-25% and 5-10% respectively. Preferably, the mass percentages of the epoxy resin, the curing agent and the diluent in the transparent epoxy resin are respectively 70%, 20% and 7%.
In another embodiment of the present invention, different from the above embodiments, the bottom layer 3 is a waterproof roll layer, and the adhesive layer 2 and the self-adhesive layer 41 can be formed on both surfaces of the waterproof roll layer by painting or spraying. Of course, the adhesive layer 2 and the self-adhesive layer 41 can also be arranged on both surfaces of the waterproof roll layer by integrally spreading.
In another embodiment of the present invention, as shown in fig. 2, a method for prefabricating a self-adhesive luminous web structure includes the steps of:
laying a bottom layer of the coiled material;
coating an adhesive layer on one side surface of the bottom layer of the coiled material, and forming a self-adhesive layer on the other side surface of the bottom layer;
and mixing the solid particles, the binder and the noctilucent material to form a noctilucent mixture, and paving the noctilucent mixture on the surface of one side of the adhesive layer, which is far away from the bottom layer of the coiled material, so as to form a noctilucent surface layer.
In this embodiment, the mixing of the solid particles, the binder, and the luminescent material is completed only before the luminescent surface layer is formed, and therefore, the mixing of the luminescent mixture may be performed before or after the adhesive layer and the self-adhesive layer are formed.
Preferably, the mass percentages of the solid particles, the binder and the noctilucent material in the noctilucent surface layer are respectively 88-94%, 3.5-5% and 2.5-7%. Preferably, the thickness of the noctilucent surface layer is 3-16 mm; the porosity of the noctilucent surface layer is 10-40%; the thickness of the adhesive layer is 1-3 mm; the thickness of the bottom layer of the coiled material is 2-5 mm; the thickness of the self-adhesive layer is 0.2-0.4 mm.
Preferably, the particle size of the solid particles is 2-15 mm. In practice, the solid particles are preferably stone particles, preferably white stone with mirror effect, such as white pebbles, white spar, etc. Of course, the solid particles also include transparent powder, such as transparent glass powder or resin powder. Preferably, the binder is a thermoplastic transparent binder formed from a transparent base oil, SBS (styrene Block Copolymers) and hydrogenated resin. Preferably, the mass percentages of the epoxy resin, the curing agent and the diluent in the transparent epoxy resin are respectively 60-80% and 15E30% and 5-10%. Preferably, the noctilucent material is a mixture of strontium aluminate and rare elements, the particle size of the mixture is 5-45 mu m, and the density of the mixture is 3.4-3.6 g/cm3The mixture has a luminescence peak of 520 + -5 nm.
Preferably, the adhesive layer is a transparent epoxy resin layer, the transparent epoxy resin layer is prepared from epoxy resin, a curing agent and a diluent, and the epoxy resin, the curing agent and the diluent account for 60-80%, 15-30% and 5-10% of the transparent epoxy resin by mass percent respectively.
Preferably, the coiled material bottom is self-adhesive waterproof coiled material layer, and self-adhesive waterproof coiled material layer includes waterproof layer and self-adhesive bonding layer, and the waterproof layer is close to bonding layer one side setting, and self-adhesive bonding layer forms the self-adhesive bonding layer. In practical applications, the waterproof layer may be formed by spraying, brushing, spreading, etc. a waterproof mixture containing a resin polymer as a main component, wherein the resin polymer may be HDPE (High Density Polyethylene), PVC (Polyvinyl chloride), EVA (Ethylene Vinyl Acetate Copolymer), or EVB (thermal mortar).
Preferably, the self-adhesive layer is a self-adhesive glue layer formed by brushing or spraying a self-adhesive glue, the self-adhesive protective film is preferably a macromolecular self-adhesive film, and the macromolecular self-adhesive film can be a polyethylene film, a rubber film or a nylon film.
In another embodiment of the present invention, different from the above embodiments, the mass percentages of the solid particles, the binder and the noctilucent material in the embodiment are 90-93%, 4-5% and 3-6% respectively. Preferably, the mass percentages of the solid particles, the binder and the noctilucent material in the noctilucent surface layer are 91-92%, 4-5% and 3-6%, respectively. Preferably, the mass percentages of the solid particles, the binder and the noctilucent material in the noctilucent surface layer are 91-92%, 4-5% and 4-6%, respectively.
In another embodiment of the present invention, different from the above embodiments, the thickness of the noctilucent surface layer of the present embodiment is 5mm to 10 mm; the porosity of the noctilucent surface layer is 25-35%; the thickness of the adhesive layer is 1-2 mm; the thickness dimension of coiled material bottom is 2 ~ 5 mm. Preferably, the thickness of the noctilucent surface layer is 6-9 mm; the porosity of the noctilucent surface layer is 25-30%; the thickness of the adhesive layer is 1-2 mm; the thickness dimension of coiled material bottom is 2 ~ 5 mm. Preferably, the thickness of the noctilucent surface layer is 8 mm; the porosity of the noctilucent surface layer is 30 percent; the thickness of the adhesive layer is 1 mm; the thickness dimension of the bottom layer of the coil was 3 mm.
In another embodiment of the present invention, unlike the above embodiments, the solid particles of the present embodiment have a particle size of 3 to 6 mm. Preferably, the particle size of the solid particles is 4-6 mm. Preferably, the solid particles have a particle size of 5 mm.
In another embodiment of the present invention, different from the above embodiments, the solid particles of the present embodiment have a particle size of 4 to 8 mm. Preferably, the solid particles have a particle size of 6 mm.
In another embodiment of the present invention, different from the above embodiments, the mass percentages of the epoxy resin, the curing agent and the diluent in the embodiment are 65-78%, 20-30% and 5-10% respectively. Preferably, the mass percentages of the epoxy resin, the curing agent and the diluent in the transparent epoxy resin are respectively 70-78%, 25-30% and 5-10%. The mass percentages of the epoxy resin, the curing agent and the diluent in the transparent epoxy resin are respectively 74%, 20% and 6%.
In another embodiment of the present invention, different from the above embodiments, the noctilucent material of the present embodiment is a mixture of strontium aluminate and rare elements, the particle size of the mixture is 25 to 30 μm, and the density of the mixture is 3.4 to 3.6g/cm3The luminescence peak of the mixture is 520 +/-5 nm. Preferably, the density of the mixture is 3.5g/cm3The luminescence peak of the mixture is 520 +/-5 nm.
In another embodiment of the present invention, different from the above embodiments, the mass percentages of the epoxy resin, the curing agent and the diluent in the embodiment are 65-75%, 15-25% and 5-10% respectively. Preferably, the mass percentages of the epoxy resin, the curing agent and the diluent in the transparent epoxy resin are respectively 70%, 20% and 7%.
In another embodiment of the present invention, different from the above embodiments, the bottom layer of the roll is a waterproof roll layer, and the adhesive layer and the self-adhesive layer can be formed on both surfaces of the waterproof roll layer by painting or spraying. Of course, the adhesive layer and the self-adhesive layer can also be arranged on the two surfaces of the waterproof roll material layer in an integral spreading mode.
Exemplarily, the prefabricated self-adhesive luminous coiled material structure comprises from top to bottom: the adhesive layer is arranged on the bottom layer of the coiled material; wherein: the noctilucent surface layer is a full-thickness noctilucent mixed material layer and comprises stone, a binder and a noctilucent material. White pebbles with the grain diameter of 3-6 mm are adopted as stones of the mixed material layer; the binder is a thermoplastic transparent binder, and the thermoplastic transparent binder is prepared from transparent base oil, SBS and hydrogenated resin; the noctilucent material is a mixture of strontium aluminate and rare elements, the particle size is 5 mu m, and the density is 3.4g/cm3Luminescence peak 520 nm; the thickness of the noctilucent surface layer is 8mm, wherein the mass percentages of the stone, the binder and the noctilucent material are respectively as follows: 90.5%, 4.5%, 57%; the adhesive layer is a transparent epoxy resin layer, the thickness is 2mm, the adhesive layer comprises the following raw materials of epoxy resin, a curing agent and a diluent in percentage by mass: 75.0%, 20.0%, 5.0%; the bottom layer of the coiled material is a self-adhesive waterproof coiled material with the thickness of 5mm, wherein the waterproof coiled material can be made of a waterproof material taking resin type macromolecules (PVC) as a main body; the self-adhesive layer comprises a self-adhesive layer and a self-adhesive film, and the self-adhesive film is a high-molecular self-adhesive film such as a polyethylene film.
The prefabricating method of the prefabricated self-adhesive luminous coiled material structure comprises the following steps: paving the self-adhesive waterproof coiled material to form a coiled material bottom layer, and uniformly coating transparent epoxy resin on a waterproof layer of the self-adhesive waterproof coiled material to form a bonding layer, wherein the weight of the transparent epoxy resin used for each square of the waterproof layer is 0.4 kg; after the epoxy resin is preliminarily formed into strength (for example, after the epoxy resin is coated for 1 hour), additionally paving a noctilucent mixture of 8mm on the surface of one side of the adhesive layer, which is far away from the waterproof layer, wherein the noctilucent mixture is formed by mixing solid particles, a binder and a noctilucent material; the self-adhesive type adhesive layer of the waterproof layer of the self-adhesive waterproof roll forms a self-adhesive layer (comprising a self-adhesive layer and a self-adhesive film). In the practical application process, the self-adhesive film is only needed to be torn off from the self-adhesive layer, and the self-adhesive layer is adhered to the position where the noctilucence is needed to be laid.
It should be noted that the above embodiments can be freely combined as necessary. The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.

Claims (10)

1. The utility model provides a prefabricated self-adhesive formula night light coiled material structure which characterized in that includes:
the luminous surface layer, the adhesive layer, the coiled material bottom layer and the self-adhesive layer are sequentially stacked;
the noctilucent surface layer comprises solid particles, a binder and a noctilucent material, and the solid particles, the binder and the noctilucent material are mixed and spread to form the noctilucent surface layer;
the self-adhesion layer includes self-adhesion layer and self-adhesion protective film, the self-adhesion layer is close to coiled material bottom one side sets up, the self-adhesion protective film is in the self-adhesion layer is kept away from the surface of coiled material bottom one side, the self-adhesion protective film with the detachable connection in self-adhesion layer.
2. The prefabricated self-adhesive luminous coil structure of claim 1, wherein:
the particle size of the solid particles is 2-15 mm.
3. The prefabricated self-adhesive luminous coil structure of claim 1, wherein:
the binder is a thermoplastic transparent binder, and the thermoplastic transparent binder is prepared from transparent base oil, SBS and hydrogenated resin.
4. The prefabricated self-adhesive luminous coil structure of claim 1, wherein:
the noctilucent material is strontium aluminate and rare elementsThe particle size of the mixture is 5-45 mu m, and the density of the mixture is 3.4-3.6 g/cm3And the luminous peak of the mixture is 520 +/-5 nm.
5. The prefabricated self-adhesive luminous coil structure of claim 1, wherein:
the solid particles, the binder and the noctilucent material account for 88-94% by mass, 3.5-5% by mass and 2.5-7% by mass of the noctilucent surface layer respectively.
6. The prefabricated self-adhesive luminous coil structure of claim 1, wherein:
the adhesive layer is a transparent epoxy resin layer, the transparent epoxy resin is prepared from epoxy resin, a curing agent and a diluent, and the epoxy resin, the curing agent and the diluent account for 60-80%, 15-30% and 5-10% of the transparent epoxy resin respectively in percentage by mass.
7. The prefabricated self-adhesive luminous coil structure of claim 1, wherein:
the coiled material bottom is self-adhesive waterproof coiled material layer, self-adhesive waterproof coiled material layer includes waterproof layer and self-adhesive bonding layer, the waterproof layer is close to bonding layer one side sets up, the self-adhesive bonding layer forms self-adhesive bonding layer.
8. The pre-fabricated self-adhesive luminous web structure of any one of claims 1 to 7, wherein:
the thickness of the bottom layer of the coiled material is 2-5 mm; and/or the presence of a gas in the gas,
the thickness of the noctilucent surface layer is 3-16 mm; and/or the presence of a gas in the gas,
the thickness of the adhesive layer is 1-3 mm; and/or the presence of a gas in the gas,
the porosity of the noctilucent surface layer is 10-40%.
9. A prefabricating method of a prefabricated self-adhesive luminous coiled material structure is characterized by comprising the following steps:
laying a bottom layer of the coiled material;
coating an adhesive layer on one side surface of the bottom layer of the coiled material, and forming a self-adhesive layer on the other side surface of the bottom layer;
and mixing the solid particles, the binder and the noctilucent material to form a noctilucent mixture, and paving the noctilucent mixture on the surface of one side of the adhesive layer, which is far away from the bottom layer of the coiled material, so as to form a noctilucent surface layer.
10. A method of prefabricating a prefabricated self-adhesive luminous coil structure as claimed in claim 9, wherein:
the binder is a thermoplastic transparent binder, and the thermoplastic transparent binder is prepared from transparent base oil, SBS and hydrogenated resin; and/or the presence of a gas in the gas,
the noctilucent material is a mixture of strontium aluminate and rare elements, the particle size of the mixture is 5-45 mu m, and the density of the mixture is 3.4-3.6 g/cm3The luminous peak of the mixture is 520 +/-5 nm; and/or the presence of a gas in the gas,
the adhesive layer is a transparent epoxy resin layer, the transparent epoxy resin is prepared from epoxy resin, a curing agent and a diluent, and the epoxy resin, the curing agent and the diluent respectively account for 60-80%, 15-30% and 5-10% of the transparent epoxy resin by mass percent; and/or the presence of a gas in the gas,
the coiled material bottom is self-adhesive waterproof coiled material layer, self-adhesive waterproof coiled material layer includes waterproof layer and self-adhesive bonding layer, the waterproof layer is close to bonding layer one side sets up, the self-adhesive bonding layer forms self-adhesive bonding layer.
CN201911315217.0A 2019-12-19 2019-12-19 Prefabricated self-adhesive luminous coiled material structure and prefabricating method thereof Pending CN111041940A (en)

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