CN111041529B - Electro-deposition 3D printing device - Google Patents

Electro-deposition 3D printing device Download PDF

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Publication number
CN111041529B
CN111041529B CN201911348401.5A CN201911348401A CN111041529B CN 111041529 B CN111041529 B CN 111041529B CN 201911348401 A CN201911348401 A CN 201911348401A CN 111041529 B CN111041529 B CN 111041529B
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printing
accommodating cavity
printing head
liquid storage
storage tank
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CN111041529A (en
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袁和平
谢玉臣
饶正平
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Xiamen University of Technology
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Xiamen University of Technology
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D1/00Electroforming
    • C25D1/0033D structures, e.g. superposed patterned layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y30/00Apparatus for additive manufacturing; Details thereof or accessories therefor

Abstract

The invention provides an electrodeposition 3D printing head and a device, comprising: the printing head comprises a first accommodating cavity and a second accommodating cavity which are arranged inside the printing head, a raw material supply port and a waste recovery port which are arranged on the side part of the printing head, a bottom opening arranged at the lower part of the printing head and a gap arranged on two sides of the bottom opening; the first accommodating cavity is communicated with the raw material supply port and the bottom opening, the second accommodating cavity is communicated with the waste recovery port and the gap, a printing electrode is arranged at the bottom opening and used for being connected to a sealed liquid storage tank through a pipeline, and the printing electrode is used for being connected with a power supply. The invention aims to perfect the electrolyte circulation problem in the electrodeposition 3D printing process, drain redundant electrolyte on the surface of a workpiece in time, accelerate the ion exchange speed, effectively avoid the problem of unstable printing quality caused by inconsistent electrolyte concentration and avoid the problem of blockage of a printing head.

Description

Electro-deposition 3D printing device
Technical Field
The invention relates to the field of electro-deposition 3D printing, in particular to an electro-deposition 3D printing device
Background
The existing 3D printing method for quickly forming electrodeposited metal is mainly characterized in that a metal wire is connected with a positive electrode of a working power supply to obtain a high potential, a workbench is connected with a negative electrode of the power supply to obtain a low potential, the workbench and the power supply form a complete loop in electrolyte to enable metal ions in the electrolyte to be deposited on the workbench in an electron mode, and deposited metal layers are continuously superposed according to a certain rule to form parts in a required shape, however, in the prior art, a perfect electrolyte circulating system is not provided, the concentration of the electrolyte in the printing process cannot be guaranteed to be kept within a certain range, the working time is limited, and the machine is required to be stopped firstly when the electrolyte is replaced; when having the cavity when printing part inside, can not in time arrange the unnecessary electrolyte in the cavity totally, easy oxidation when breaking away from the workstation with it, current be provided with recovery unit beat printer head can inhale the inside jam that forms of printer head with the particulate matter.
Disclosure of Invention
In view of this, the invention provides an electrodeposition 3D printing device, which aims to perfect the electrolyte circulation problem in the electrodeposition 3D printing process, drain the redundant electrolyte on the surface of a workpiece in time, accelerate the ion exchange speed, effectively avoid the problem of unstable printing quality caused by inconsistent electrolyte concentration, and avoid the problem of blockage of a printing head.
The invention is realized by the following steps:
a first embodiment of the present invention provides an electrodeposition 3D print head including: the printing head comprises a first accommodating cavity and a second accommodating cavity which are arranged inside the printing head, a raw material supply port and a waste recovery port which are arranged on the side part of the printing head, a bottom opening arranged at the lower part of the printing head and gaps arranged at two sides of the bottom opening;
the first accommodating cavity is communicated with the raw material supply port and the bottom opening, the second accommodating cavity is communicated with the waste recovery port and the gap, a printing electrode is arranged at the bottom opening and used for being connected to a sealed liquid storage tank through a pipeline, and the printing electrode is used for being connected with a power supply.
Preferably, the printing electrode is a titanium wire, and the printing electrode is used for being electrically connected with the positive electrode of the power supply.
Preferably, the scrap recovery port is disposed below the raw material supply port.
Preferably, the method further comprises the following steps: the rubber plug comprises a first rubber plug, a second rubber plug, an end cover and a clamping sleeve;
wherein, press from both sides tight cover and inlay the open-top in first holding chamber, the second rubber buffer is arranged in press from both sides tight cover top, be provided with the internal thread in the end cover for with set up the screw-thread fit at first holding chamber top is fixed second rubber buffer and press from both sides tight cover, first rubber buffer set up in first holding chamber bottom.
Preferably, the center of first rubber buffer is provided with first opening, the center of second rubber buffer is provided with the second opening, first opening week is equipped with at least one hole of permeating water, the hole of permeating water with bottom opening and first holding chamber intercommunication, the printing electrode passes first opening, clamping sleeve, second opening and end cover are connected with the anodal electricity of power.
A second embodiment of the present invention provides a deposition 3D printing apparatus, including: the device comprises a rack, a collecting tank movably arranged on the rack, a support frame fixed on the rack and configured above the collecting tank, an electrolytic power supply, a vacuum pump and a sealed liquid storage tank which are arranged on the rack, and any electrodeposition 3D printing head as described above;
the printing head is movably mounted on the support frame, the printing electrode is electrically connected with the anode of the electrolysis power supply, the collecting tank is electrically connected with the cathode of the electrolysis power supply, the waste recovery port and the collecting tank are connected with the sealed liquid storage tank through a pipeline, the raw material supply port is connected to the output end of the vacuum pump through a pipeline, and the input end of the vacuum pump is connected with the sealed liquid storage tank.
Preferably, the method further comprises the following steps: and the heating device is arranged in the sealed liquid storage tank.
Preferably, the support frame comprises a cross bar and a fixed plate movably mounted on the cross bar, and the printing head is mounted on the fixed plate;
preferably, the collecting groove is controlled by a motor to move in the Y-axis direction, the cross bar is controlled by a motor to move in the Z-axis direction, and the fixing plate is controlled by a motor to move in the X-axis direction.
Preferably, the bottom layer of the collecting tank moves on the rack through a motor, the middle layer of the collecting tank is an insulating layer, and the top layer of the collecting tank is a conductive layer.
According to the electro-deposition 3D printing device provided by the invention, the first accommodating cavity of the printing head is connected to the output end of the vacuum pump through the raw material supply port, the input end of the vacuum pump is connected to the sealed liquid storage tank, so that the electrolyte in the sealed liquid storage tank is pumped into the first accommodating cavity by the vacuum pump, the sealed liquid storage tank is kept in a vacuum state, the second accommodating cavity is communicated with the gap beside the opening at the lower end of the printing head and is directly connected to the sealed liquid storage tank through the waste material outlet, negative pressure exists in a pipeline connected with the gap due to the atmospheric pressure, surrounding electrolyte can be sucked back into the sealed liquid storage tank, the heating device arranged in the sealed liquid storage tank can accelerate the completion of electrolysis, the problem of blockage of the printing head is effectively avoided due to the arrangement of the gap and the printing port, and the consistency of the concentration of electrolysis is ensured.
Drawings
FIG. 1 is a cross-sectional view of a printhead provided by an embodiment of the present invention;
FIG. 2 is an exploded view of a printhead provided by an embodiment of the present invention;
fig. 3 is a schematic structural view of a first rubber plug provided in an embodiment of the present invention;
fig. 4 is a schematic structural view of a second rubber plug provided in the embodiment of the present invention;
FIG. 5 is a schematic structural view of a clamping sleeve provided in an embodiment of the present invention in an unclamped state;
FIG. 6 is a schematic structural view of a clamping sleeve provided in an embodiment of the present invention in a clamping state;
FIG. 7 is a schematic structural diagram of a printing apparatus according to an embodiment of the present invention;
FIG. 8 is a schematic view of the overall flow path of a printing apparatus according to an embodiment of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention more apparent, the technical solutions of the embodiments of the present invention will be described clearly and completely with reference to the accompanying drawings of the embodiments of the present invention, and it is obvious that the described embodiments are some, but not all embodiments of the present invention. All other embodiments, which can be obtained by a person skilled in the art without any inventive step based on the embodiments of the present invention, are within the scope of the present invention. Thus, the following detailed description of the embodiments of the present invention, presented in the figures, is not intended to limit the scope of the invention, as claimed, but is merely representative of selected embodiments of the invention. All other embodiments, which can be obtained by a person skilled in the art without any inventive step based on the embodiments of the present invention, are within the scope of the present invention.
In the description of the present invention, it is to be understood that the terms "center", "longitudinal", "lateral", "length", "width", "thickness", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", "clockwise", "counterclockwise", and the like, indicate orientations and positional relationships based on those shown in the drawings, and are used only for convenience of description and simplicity of description, and do not indicate or imply that the equipment or element being referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be considered as limiting the present invention.
In the present invention, unless otherwise expressly stated or limited, the terms "mounted," "connected," "secured," and the like are to be construed broadly and can, for example, be fixedly connected, detachably connected, or integrally formed; can be mechanically or electrically connected; either directly or indirectly through intervening media, either internally or in any other relationship. The specific meanings of the above terms in the present invention can be understood by those skilled in the art according to specific situations.
In the present invention, unless otherwise expressly stated or limited, "above" or "below" a first feature means that the first and second features are in direct contact, or that the first and second features are not in direct contact but are in contact with each other via another feature therebetween. Also, the first feature being "on," "above" and "over" the second feature includes the first feature being directly on and obliquely above the second feature, or merely indicating that the first feature is at a higher level than the second feature. A first feature being "under," "below," and "beneath" a second feature includes the first feature being directly under and obliquely below the second feature, or simply meaning that the first feature is at a lesser elevation than the second feature.
The following detailed description of specific embodiments of the invention refers to the accompanying drawings.
The invention provides an electrodeposition 3D printing device, aiming at perfecting the electrolyte circulation problem in the electrodeposition 3D printing process, draining redundant electrolyte on the surface of a workpiece in time, accelerating the ion exchange speed, effectively avoiding the problem of uneven printing quality instability caused by inconsistent electrolyte concentration and avoiding the problem of blockage of a printing head.
Referring to fig. 1 and 2, a first embodiment of the invention provides an electrodeposition 3D print head, including: the printing device comprises a first accommodating cavity 2 and a second accommodating cavity 3 which are arranged inside the printing head 1, a raw material supply port 4 and a waste recovery port 5 which are arranged on the side part of the printing head 1, a bottom opening 7 arranged at the lower part of the printing head 1 and gaps 6 arranged on two sides of the bottom opening 7;
the first accommodating cavity 2 is communicated with the raw material supply port 4 and the bottom opening 7, the second accommodating cavity 3 is communicated with the waste recovery port 5 and the gap 6, a printing electrode 8 is arranged at the bottom opening 7, the raw material supply port 4 and the waste recovery port 5 are used for being connected to a sealed liquid storage tank 16 through pipelines, and the printing electrode 8 is used for being connected with a power supply.
It should be noted that after the power is turned on, the electrolyte is pumped from the sealed reservoir 16 into the first accommodating chamber 2, the electrolyte flows from the first accommodating chamber 2 to the printing electrode 8, the second gap 6 is communicated with the second accommodating cavity 3 and is arranged beside the electrode of the printing electrode 8, because the sealed liquid storage tank 16 is in a vacuum state, negative pressure can be generated in the gap 6 and the pipeline of the second accommodating cavity 3, redundant electrolyte is sucked back into the sealed liquid storage tank 16 in time, the electrolyte is prevented from remaining on the surface of the printed workpiece, so that when electrolytic printing is performed, the uneven printing is caused by the inconsistent concentration of the electrolyte, and since the gap 6 is provided on the peripheral side of the opening 7, when the suction is performed, the metal particles to be deposited are not sucked into the printing head, so that the inside of the printing head 1 is not blocked.
With reference to fig. 2, the print head 1 may be composed of an upper portion and a lower portion, the upper portion is composed of a tee, the first accommodating chamber 2 is composed of an upper portion and a lower portion, a side portion of the tee is used as the raw material supply port 4 to be connected to the sealed liquid storage tank 16, a lower end of the tee is used to be connected to a lower portion of the print head, and an upper end of the tee is used to connect the printing electrode to an external power source.
In this embodiment, the printing electrode 8 is preferably a titanium wire, and the printing electrode is configured to be electrically connected to the positive electrode of the power supply, and it should be noted that in other embodiments, the printing electrode may also be one of a platinum wire, a rhodium wire, or other inert metals, which is not specifically limited herein, but these solutions are within the protection scope of the present invention, and it is noted that the titanium wire is electrically connected to the positive electrode of the power supply, and the printing electrode 8 serves as an anode during the printing electrolysis process.
Referring to fig. 3 to fig. 6, in the present embodiment, the method further includes: a first rubber plug 19, a second rubber plug 21, an end cover 18 and a clamping sleeve 20;
wherein, press from both sides tight cover 20 and inlay the open-top in first holding chamber 2, second rubber buffer 21 is arranged in press from both sides tight cover 20 top, be provided with the internal thread in the end cover 18 for with set up the external screw thread fit at first holding chamber 2 top compresses tightly second rubber buffer 21 and clamp cover 20, first rubber buffer 19 set up in first holding chamber 2 bottom.
It should be noted that the lower end of the clamping sleeve 20 is a cone structure formed by blades, and when the end cover 18 is screwed downwards, the end cover presses against the second rubber plug 21, so that the second rubber plug 21 presses against the clamping sleeve 20, the blades contract, and the printing electrodes 8 are clamped, and shaking of the electrodes is effectively avoided.
In this embodiment, the center of first rubber buffer 19 is provided with first opening 23, the center of second rubber buffer 21 is provided with second opening 24, first opening 23 week is equipped with at least one hole 22 of permeating water, the hole 22 of permeating water with bottom opening and first holding chamber 2 intercommunication, printing electrode 8 passes first opening 23, clamping sleeve 20, second opening 24 and end cover 18 are connected with the positive pole electrical connection of power.
It should be noted that the printing electrode 8 sequentially passes through the bottom opening, the first opening 23 of the first rubber plug 19, the clamping sleeve 20, the opening of the second rubber plug 21 and the end cover 18, wherein the first rubber plug 19 and the second rubber plug 21 play a role in fixing the printing electrode 8, so that the printing electrode 8 does not affect shaking of working fluid, the second rubber plug 21 simultaneously plays a role in sealing, the water permeable holes 22 circumferentially arranged near the first opening 23 are used for communicating the bottom opening with the first accommodating cavity 2 to ensure flowing of the liquid, and the number of the water permeable holes 22 is 8, but is not limited thereto.
In the present embodiment, the scrap collecting port 5 is provided below the raw material supply port 4. The waste recycling port 5 is disposed closer to the lower end of the print head 1 to easily suck the residual waste liquid back to the sealed liquid storage tank 16, however, in other embodiments, the waste recycling port 5 may be disposed above the raw material supply port 4, or at other positions, which may be set according to practical situations, and is not limited herein, but these schemes are within the protection scope of the present invention.
Referring to fig. 7 and 8, a deposition 3D printing apparatus according to a second embodiment of the present invention includes: a frame 12, a collecting tank 15 movably mounted on the frame 12, a support frame fixed on the frame 12 and configured above the collecting tank 15, an electrolytic power supply 10 mounted on the frame 12, a vacuum pump 17 and a sealed liquid storage tank 16, and the electrodeposition 3D printing head as described above;
the printing head 1 is movably mounted on the support frame, the printing electrode 8 is electrically connected with the anode of the electrolysis power supply 10, the collecting tank 15 is electrically connected with the cathode of the electrolysis power supply 10, the waste recovery port 5 and the collecting tank 15 are connected with the sealed liquid storage tank 16 through a pipeline, the raw material supply port 4 is connected with the output end of the vacuum pump 17 through a pipeline, and the input end of the vacuum pump 17 is connected with the sealed liquid storage tank 16.
It should be noted that the collecting tank 15 is used for placing a workpiece to be printed, an opening is formed in the bottom of the collecting tank 15, the opening is connected to the sealed liquid storage tank 16 through a pipeline so as to facilitate recycling of the electrolyte, and the vacuum pump 17 is used for pumping the electrolyte in the sealed liquid storage tank 16 into the first accommodating cavity 2 and ensuring that the sealed liquid storage tank 16 is in a sealed vacuum state, so that the gap can suck the electrolyte around the printing electrode 8 back into the sealed liquid storage tank 16.
In this embodiment, the method further includes: and the heating device 25 is arranged in the sealed liquid storage tank. The heating device 25 is used for heating the electrolyte in the sealed liquid storage tank 16, so that the electrolysis process is accelerated, and the concentration of the electrolyte is uniform.
In this embodiment, the supporting frame comprises a cross bar 13 and a fixing plate 14 movably mounted on the cross bar 13, and the print head 1 is mounted on the fixing plate 14;
in this embodiment, the collecting trough 15 is controlled by a motor to move in the Y-axis direction, the cross bar 13 is controlled by a motor to move in the Z-axis direction, and the fixing plate 14 is controlled by a motor to move in the X-axis direction.
It should be noted that the cross bar 13 is driven by two motors, so that the printing head 1 can move in the Z-axis direction (i.e., the cross bar 13 drives the printing head 1 to move up and down), the fixing plate 14 is driven by one motor, so that the printing head 1 moves left and right on the cross bar 13 (X-axis) (i.e., the fixing plate 14 drives the printing head 1 to move left and right), the printing head 1 moves in the XOZ plane, and the collecting tank 15 is driven by one motor to move in the Y-axis direction (i.e., the collecting tank 15 drives the attack to be printed to move in the front-back direction). It should be noted that, the rack 12 is provided with a control power supply 11 for connecting a motor and a control device for controlling the rotation of the motor, the control may be a computer, a PLC or a single chip microcomputer, the motor may be a stepping motor or a servo motor, and the embodiments are not limited in this respect.
In this embodiment, the bottom layer of the collecting groove 15 moves on the frame 12 through a motor, the middle layer of the collecting groove 15 is an insulating layer, and the top layer of the collecting groove 15 is a conductive layer.
It should be noted that the conductive layer is electrically connected to the negative electrode of the electrolysis power supply 10, the conductive layer serves as a cathode during the electrolysis process, the conductive layer, the printing electrode 8 and the electrolysis power supply 10 form a complete loop, metal ions are attracted to the surface of the conductive layer to obtain electrons, the electrons are reduced to metal and deposited on the conductive layer, the printing head travels along a preset track, and the precipitated metal particles are deposited on the conductive layer by layer in a certain order to obtain the required parts.
Based on the electro-deposition 3D printing head and the device provided by the invention, the first containing cavity of the printing head is connected to the output end of the vacuum pump through the raw material supply port, the input end of the vacuum pump is connected to the sealed liquid storage tank, so that the electrolyte in the sealed liquid storage tank is pumped into the first containing cavity by the vacuum pump, the sealed liquid storage tank is kept in a vacuum state, the second containing cavity is communicated with the gap beside the lower end opening of the printing head and is directly connected to the sealed liquid storage tank through the waste material outlet, negative pressure exists in a pipeline connected with the gap due to the atmospheric pressure, the surrounding electrolyte can be sucked back into the sealed liquid storage tank, the heating device arranged in the sealed liquid storage tank can accelerate the completion of electrolysis, the problem of the blockage of the printing head is effectively avoided due to the arrangement of the gap and the printing port, and the consistency of the concentration of the electrolysis is ensured.
The above is only a preferred embodiment of the present invention, and the protection scope of the present invention is not limited to the above-mentioned embodiments, and all technical solutions belonging to the idea of the present invention belong to the protection scope of the present invention.

Claims (5)

1. An electro-deposition 3D printing device, comprising: the device comprises an electrodeposition 3D printing head, a rack, a collecting tank movably arranged on the rack, a support frame fixed on the rack and configured above the collecting tank, an electrolysis power supply arranged on the rack, a vacuum pump and a sealed liquid storage tank;
the printing head comprises a first accommodating cavity and a second accommodating cavity which are arranged inside the printing head, a raw material supply port and a waste recovery port which are arranged on the side part of the printing head, a bottom opening arranged at the lower part of the printing head and a gap arranged on two sides of the bottom opening; the first accommodating cavity is communicated with the raw material supply port and the bottom opening, the second accommodating cavity is communicated with the waste recovery port and the gap, a printing electrode is arranged at the bottom opening, the raw material supply port and the waste recovery port are used for being connected to a sealed liquid storage tank through pipelines, and the printing electrode is used for being connected with a power supply; the waste recovery port is arranged below the raw material supply port;
the printing head also comprises a first rubber plug, a second rubber plug, an end cover and a clamping sleeve; the clamping sleeve is embedded in an opening in the top of the first accommodating cavity, the second rubber plug is arranged above the clamping sleeve, an internal thread is arranged in the end cover and used for being matched with an external thread arranged at the top of the first accommodating cavity to tightly press the second rubber plug and the clamping sleeve, and the first rubber plug is arranged at the bottom of the first accommodating cavity;
a first opening is formed in the center of the first rubber plug, a second opening is formed in the center of the second rubber plug, at least one water permeable hole is formed in the periphery of the first opening and is communicated with the bottom opening and the first accommodating cavity, and the printing electrode penetrates through the first opening, the clamping sleeve, the second opening and the end cover and is electrically connected with the positive electrode of the power supply;
the printing head is movably mounted on the support frame, the printing electrode is electrically connected with the anode of the electrolytic power supply, the collecting tank is electrically connected with the cathode of the electrolytic power supply, the waste recovery port and the collecting tank are connected with the pipeline of the sealed liquid storage tank, the pipeline of the raw material supply port is connected with the output end of the vacuum pump, the input end of the vacuum pump is connected with the sealed liquid storage tank, the sealed liquid storage tank is in a vacuum state, negative pressure can be generated in the gap and the pipeline of the second accommodating cavity, redundant electrolyte is sucked back into the sealed liquid storage tank in time, and the electrolyte is prevented from remaining on the surface of a printed workpiece; the bottom layer of the collecting tank moves on the rack through a motor, the middle layer of the collecting tank is an insulating layer, and the top layer of the collecting tank is a conducting layer.
2. The electrodeposition 3D printing device according to claim 1, wherein the printing electrode of the print head is a titanium wire, and the printing electrode is configured to be electrically connected to a positive electrode of a power supply.
3. An electro-deposition 3D printing device according to claim 1, further comprising: and the heating device is arranged in the sealed liquid storage tank.
4. The electro-deposition 3D printing device as claimed in claim 1, wherein the support frame comprises a cross bar and a fixed plate movably mounted on the cross bar, and the printing head is mounted on the fixed plate.
5. The electrodeposition 3D printing apparatus according to claim 4, wherein the collecting tank is controlled by a motor to move in a Y-axis direction, the cross bar is controlled by a motor to move in a Z-axis direction, and the fixing plate is controlled by a motor to move in an X-axis direction.
CN201911348401.5A 2019-12-24 2019-12-24 Electro-deposition 3D printing device Active CN111041529B (en)

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