CN111032572B - 分子筛ssz-113、其合成及应用 - Google Patents

分子筛ssz-113、其合成及应用 Download PDF

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Publication number
CN111032572B
CN111032572B CN201880051346.0A CN201880051346A CN111032572B CN 111032572 B CN111032572 B CN 111032572B CN 201880051346 A CN201880051346 A CN 201880051346A CN 111032572 B CN111032572 B CN 111032572B
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sio
geo
molecular sieve
ray diffraction
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CN111032572A (zh
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S·I·佐内斯
谢丹
陈聪岩
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Chevron USA Inc
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Chevron USA Inc
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/047—Germanosilicates; Aluminogermanosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7015—CHA-type, e.g. Chabazite, LZ-218
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/34—Reaction with organic or organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/30—Three-dimensional structures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
CN201880051346.0A 2018-02-20 2018-11-19 分子筛ssz-113、其合成及应用 Active CN111032572B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201862632694P 2018-02-20 2018-02-20
US62/632,694 2018-02-20
PCT/IB2018/059086 WO2019162745A1 (en) 2018-02-20 2018-11-19 Molecular sieve ssz-113, its synthesis and use

Publications (2)

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CN111032572A CN111032572A (zh) 2020-04-17
CN111032572B true CN111032572B (zh) 2023-01-24

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US (1) US10384951B1 (https=)
EP (1) EP3755660B1 (https=)
JP (1) JP7097950B2 (https=)
KR (1) KR102632794B1 (https=)
CN (1) CN111032572B (https=)
WO (1) WO2019162745A1 (https=)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114929622B (zh) * 2020-01-16 2024-03-01 雪佛龙美国公司 分子筛ssz-116、其合成和用途
KR102876684B1 (ko) * 2020-01-16 2025-10-27 셰브런 유.에스.에이.인크. 분자체 ssz-117, 이의 합성 및 용도
US11161749B1 (en) 2020-05-22 2021-11-02 Chevron U.S.A. Inc. Molecular sieve SSZ-120, its synthesis and use
JP7622098B2 (ja) * 2020-05-28 2025-01-27 シェブロン ユー．エス．エー． インコーポレイテッド アルミノゲルマノケイ酸塩分子ふるいｓｓｚ－１２１、その合成及び使用
US12544744B2 (en) * 2022-05-31 2026-02-10 Chevron U.S.A. Inc. Molecular sieve boron SSZ-113
JP2025519221A (ja) * 2022-05-31 2025-06-24 シェブロン ユー．エス．エー． インコーポレイテッド 高い酸度を有するモレキュラーシーブｓｓｚ－１２１、その合成及び使用
CN119233947A (zh) * 2022-05-31 2024-12-31 雪佛龙美国公司 具有高酸度的分子筛SSZ-117x
JP2025519220A (ja) * 2022-05-31 2025-06-24 シェブロン ユー．エス．エー． インコーポレイテッド 高い酸度を有するモレキュラーシーブｓｓｚ－１１３、その合成及び使用
KR20250099216A (ko) * 2022-11-01 2025-07-01 셰브런 유.에스.에이.인크. 분자체 ssz-124, 이의 합성 및 용도

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4483835A (en) * 1983-11-14 1984-11-20 Chevron Research Company Process for preparing molecular sieves using imidazole template
US6043179A (en) * 1997-08-13 2000-03-28 California Institute Of Technology Zeolite CIT-5 and method of making
US7157075B1 (en) * 2005-08-30 2007-01-02 Chevron U.S.A. Inc. Process for preparing MTT zeolites using nitrogen-containing organic compounds
FR2918979B1 (fr) 2007-07-20 2011-05-27 Inst Francais Du Petrole Solide cristallise im-16 et son procede de preparation
FR2923477B1 (fr) * 2007-11-12 2011-03-18 Inst Francais Du Petrole Solide cristallise im-18 et son procede de preparation
US7820141B2 (en) * 2008-10-10 2010-10-26 Chevron U.S.A. Inc. Molecular sieve SSZ-82 composition of matter and synthesis thereof
US8500991B2 (en) * 2008-12-16 2013-08-06 Exxonmobil Research And Engineering Company High activity MTT framework type molecular sieves
FR2940266B1 (fr) * 2008-12-18 2010-12-31 Inst Francais Du Petrole Solide cristallise im-20 et son procede de preparation
US8562942B2 (en) 2009-04-09 2013-10-22 California Institute Of Technology Molecular sieves and related methods and structure directing agents
JP5687762B2 (ja) * 2010-06-25 2015-03-18 シェブロン ユー．エス．エー． インコーポレイテッド モレキュラーシーブｓｓｚ−８１
WO2011163016A2 (en) * 2010-06-25 2011-12-29 Chevron U.S.A. Inc. Processes using molecular sieve ssz-81
US9266744B2 (en) * 2013-10-10 2016-02-23 Chevron U.S.A. Inc. Synthesis of borosilicate ton-framework type molecular sieves
US9908783B2 (en) 2014-01-22 2018-03-06 California Institute Of Technology Methods for producing crystalline microporous solids with the RTH topology and compositions derived from the same
US11203013B2 (en) * 2017-01-20 2021-12-21 California Institute Of Technology Enantiomerically enriched, polycrystalline molecular sieves

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Publication number Publication date
JP2021513944A (ja) 2021-06-03
EP3755660A1 (en) 2020-12-30
KR102632794B1 (ko) 2024-02-02
KR20200122311A (ko) 2020-10-27
JP7097950B2 (ja) 2022-07-08
CN111032572A (zh) 2020-04-17
US20190256364A1 (en) 2019-08-22
US10384951B1 (en) 2019-08-20
EP3755660B1 (en) 2024-10-09
WO2019162745A1 (en) 2019-08-29

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