CN1110263A - Golden lustre mirror face ceramics and manufacturing method thereof - Google Patents

Golden lustre mirror face ceramics and manufacturing method thereof Download PDF

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Publication number
CN1110263A
CN1110263A CN 94110923 CN94110923A CN1110263A CN 1110263 A CN1110263 A CN 1110263A CN 94110923 CN94110923 CN 94110923 CN 94110923 A CN94110923 A CN 94110923A CN 1110263 A CN1110263 A CN 1110263A
Authority
CN
China
Prior art keywords
lustre
mirror face
preparation
metal
ceramic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 94110923
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Chinese (zh)
Inventor
许支农
贺工波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN 94110923 priority Critical patent/CN1110263A/en
Publication of CN1110263A publication Critical patent/CN1110263A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5007—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with salts or salty compositions, e.g. for salt glazing
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482—Coating or impregnation materials
    • C04B2111/00577—Coating or impregnation materials applied by spraying
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80—Optical properties, e.g. transparency or reflexibility
    • C04B2111/82—Coloured materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The present invention discloses a gold lustre mirror surface ceramic and its preparation method. A metallic organic material colloidal liquor made up by using metal salt, metallic inorganic material, natural resin, perfume oil and organic solvent is sprayed on the surface of ceramic product, and is dried in the air, and then is fed into a high-temp. furnace and fired, so that the invented gold lustre mirror surface ceramic can be made up. Said invention not only produces the metal lustre and clear mirror surface effect on the ceramic surface and retains the pattern and colour of original product, but also can raise the corrosion resistance of original ceramic product, and can greatly raise the practicality and ornamental property of ceramic product.

Description

Golden lustre mirror face ceramics and manufacturing method thereof
The present invention relates to belong to a kind of golden lustre mirror face ceramics and making method in additional product and the technology that has metalluster thing layer in ceramic surface.
At present, the golden light ceramic glaze of development can improve the glossiness of ceramic surface, but not have the transparency both at home and abroad, makes former overglaze decorative pattern and color covered fully, has only single golden light glaze color.
The purpose of this invention is to provide and a kind ofly can make former Ceramic glaze have metalluster, produce mirror effect, and keep golden lustre mirror face ceramics of former Ceramic glaze decorative pattern and color and preparation method thereof.
The present invention is achieved in that a kind of metallorganics coating of preparation, and it is as follows to fill a prescription, and gets metal-salt and metal inorganic thing 1～5, natural resin 100～500, perfume oil 10～20, organic solvent 500～1000 by mole number; A kind of metal-salt and metal inorganic thing are joined in the mixture of the natural resin of hot melt and butanols, continue heating, and constantly stir, after the cooling, add perfume oil and soak, and then add the organic solvent stirring and evenly mixing.Left standstill several days, and got the upper strata Colloidal fluid and be sprayed on ceramic surface, dry, send into high-temperature firing in the kiln, then realize the present invention.
Used metal-salt and the desirable Bismuth trinitrate of metal inorganic thing, lead nitrate, titanium chloride, tin chloride, Palladous chloride, metatitanic acid etc.; The desirable turps of used perfume oil, camphor wet goods; The desirable dimethylbenzene of organic solvent, acetone, chloroform, naphthane, benzene, N-BUTYL ACETATE, butanols etc.
The present invention can not only produce metalluster and mirror effect clearly on ceramic surface, the decorative pattern and the color that keep former ceramic, make richer aesthetic feeling of ceramic and the luxurious sense of adoring, and be attached to lip-deep metal oxide layer of ceramic and metal level, increase the wear-resisting and erosion resistance of former ceramic, greatly improved the practicality and the sight of ceramic.
Below in conjunction with embodiment the present invention is described in further detail:
Embodiment 1:
Get 2 molar nitric acid bismuths, 0.5 mole Palladous chloride, join in the mixture of 300 moles of thermoplastic resins and butanols, 150 ℃ of following stirring heating of temperature 20 minutes, cooling back adds 10 moles of white oil of camphor, soaks 12 hours under the room temperature, and then adds 700 moles of dimethylbenzene, 100 moles of naphthanes, stirred 20 minutes, left standstill 72 hours, it is standby to take out the upper strata jelly.The dirty processing of ceramic floor brick glaze face is clean, with hairbrush jelly is brushed on the floor tile surface, after half an hour, the ceramic floor brick is put into retort furnace, to fire 1 hour at 650 ℃, the cooling back is the golden lustre mirror face ceramics goods.
Embodiment 2:
Get 3 moles of tin chlorides, 0.5 mole titanium tetrachloride, add in the mixture of 400 moles of hot melt natural resins and 4 moles of butanols, heated while stirring 25 minutes 120 ℃ of temperature, after the cooling, add 10 moles of white oil of camphor, soaked 32 hours, add 700 moles of dimethylbenzene and 150 moles of naphthanes again, stir after 20 minutes, left standstill 72 hours, inclining, it is standby the upper strata jelly.A mural painting ceramic plate surface is cleaned, with spray gun the jelly that takes out is sprayed one deck equably on ceramics, after treating to dry half an hour, put in the retort furnace, under 800～1000 ℃, fired 45 minutes, after the cooling, take out, the mural painting ceramic plate of a golden lustre mirror face is made.

Claims (4)

1, a kind of golden lustre mirror face ceramics and preparation method thereof is characterized in that: prepare a kind of metallorganics coating, prescription is: get metal-salt and metal inorganic thing 1～5, natural resin 100～500, perfume oil 10～20, organic solvent 500～1000 by mole number; Manufacture craft is that a kind of metal-salt and metal inorganic thing are joined in the mixture of the natural resin of hot melt and butanols, continue heating, and constantly stir, the cooling back adds perfume oil and soaks, and then add the organic solvent stirring and evenly mixing, and left standstill several days, get the upper strata Colloidal fluid and be sprayed on ceramic surface, dry, send into high-temperature firing in the kiln.
2, according to described a kind of golden lustre mirror face ceramics of claim 1 and preparation method thereof, it is characterized in that: used metal-salt and the desirable Bismuth trinitrate of metal inorganic thing, lead nitrate, titanium chloride, tin chloride, Palladous chloride, metatitanic acid etc.; The desirable turps of used perfume oil, camphor wet goods; The desirable dimethylbenzene of organic solvent, acetone, chloroform, naphthane, benzene, N-BUTYL ACETATE, butanols etc.
3, a kind of golden lustre mirror face ceramics according to claim 1 and preparation method thereof, it is characterized in that: 100～150 ℃ of preparation metallorganics coating reaction temperature, 20 minutes reaction times, churning time 20 minutes, soak time 12～72 hours, time of repose 12～72 hours.
4, according to described a kind of golden lustre mirror face ceramics of claim 1 and preparation method thereof, it is characterized in that: 600～1000 ℃ of golden lustre mirror face ceramics firing temperatures, 15～60 minutes firing times.
CN 94110923 1994-04-13 1994-04-13 Golden lustre mirror face ceramics and manufacturing method thereof Pending CN1110263A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 94110923 CN1110263A (en) 1994-04-13 1994-04-13 Golden lustre mirror face ceramics and manufacturing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 94110923 CN1110263A (en) 1994-04-13 1994-04-13 Golden lustre mirror face ceramics and manufacturing method thereof

Publications (1)

Publication Number Publication Date
CN1110263A true CN1110263A (en) 1995-10-18

Family

ID=5034840

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 94110923 Pending CN1110263A (en) 1994-04-13 1994-04-13 Golden lustre mirror face ceramics and manufacturing method thereof

Country Status (1)

Country Link
CN (1) CN1110263A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101973711A (en) * 2010-09-17 2011-02-16 深圳市永丰源瓷业有限公司 Glazing preparation and preparation method thereof
CN102218960A (en) * 2011-04-18 2011-10-19 陈伟煊 Manufacture method for polished electrooptic mirror face ceramic product

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101973711A (en) * 2010-09-17 2011-02-16 深圳市永丰源瓷业有限公司 Glazing preparation and preparation method thereof
CN102218960A (en) * 2011-04-18 2011-10-19 陈伟煊 Manufacture method for polished electrooptic mirror face ceramic product
CN102218960B (en) * 2011-04-18 2013-01-02 陈伟煊 Manufacture method for polished electrooptic mirror face ceramic product

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