CN111019466A - Paint for children furniture and preparation method thereof - Google Patents
Paint for children furniture and preparation method thereof Download PDFInfo
- Publication number
- CN111019466A CN111019466A CN201911399881.8A CN201911399881A CN111019466A CN 111019466 A CN111019466 A CN 111019466A CN 201911399881 A CN201911399881 A CN 201911399881A CN 111019466 A CN111019466 A CN 111019466A
- Authority
- CN
- China
- Prior art keywords
- emulsion
- children
- initiator
- added
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention claims a coating for children furniture and a preparation method thereof, wherein a soft monomer, a hard monomer, paraffin, styrene-butadiene latex and degraded starch solution are adopted, a pre-emulsion is prepared with partial deionized water, an initiator is added and stirred, the reaction is carried out until an emulsion with blue gloss is obtained, the residual pre-emulsion, dialdehyde modified nano-cellulose, a cross-linking agent and the initiator are dropwise added, the mixture is subjected to heat preservation and filtration after the initiator is completely dripped, and then the emulsion for children is obtained, and finally the deionized water and the auxiliary agent are added to prepare the wood coating for children with a core-shell structure, wherein the adhesive force, the wear resistance, the pollution resistance and the doodling resistance of the wood coating are synergistically improved by the addition of the dialdehyde modified nano-cellulose and the styrene-butadiene.
Description
Technical Field
The invention relates to a coating for children furniture and a preparation method thereof, belonging to the technical field of wood processing.
Background
With the improvement of living standard of people, furniture products specially used for children are more and more common. Children, as a physically developing group, also have more stringent quality requirements for the contacted furniture items than adults. Most of the children furniture is made of pine and other solid wood, and the performance of the furniture coating greatly determines the performance of the children furniture product.
The environmental protection is the most important index, and the emission of formaldehyde, VOCs and heavy metals of the children furniture products is ensured to reach the standard. Generally, the problem can be better solved by adopting a more environment-friendly water-based wood coating, but the water-based wood coating has inherently low physical strength and weak stain resistance, and the relative defects of the water-based wood coating are amplified due to the behavior specificity of children groups. The children furniture is often damaged by behaviors of graffiti, food decoction splashing, play collision and the like of children in the using process. Meanwhile, children are difficult to bump and collide in life, so that the children are more easily injured compared with adults, and the furniture products are not hard enough. This requires a water-based paint for children's furniture to have good stain resistance, scratch resistance, abrasion resistance and appropriate hardness. The common water-based paint can not well meet the use requirements of children furniture. Therefore, an elastic resin with excellent physical strength is developed to prepare the related woodware coating, and the problems can be well solved.
Disclosure of Invention
The invention provides a water-based wood coating for children furniture, which can solve the problems of poor pollution resistance and over softness of the children furniture, so that the prepared children furniture coating has better pollution resistance, scraping resistance, wear resistance and proper hardness, and the environmental protection property reaches the national relevant standard.
The wood lacquer emulsion is prepared from the following components: the components are calculated by weight portion
The soft monomer is selected from one or more of butyl acrylate, ethyl acrylate and isooctyl acrylate;
the hard monomer is one or more of styrene, methyl methacrylate, vinyl acetate, methyl acrylate, acrylic acid and acrylamide;
the crosslinking monomer is selected from acrylamide or acrylonitrile.
The initiator is selected from ammonium persulfate or potassium persulfate;
the degraded starch glue solution is degraded by original starch through amylase, and the solid content is 10-15%;
the dialdehyde modified nano-cellulose is prepared by adopting self-made dialdehyde modified nano-cellulose, adjusting the pH value of 2-4 wt% of the nano-cellulose solution to 4 by using 0.1mol/L hydrochloric acid solution, adding 6mmol/L sodium periodate at the rotation speed of 1000r/min and the temperature of 40-60 ℃, reacting for 6-7h, and cooling to obtain the dialdehyde modified nano-cellulose.
The styrene-butadiene latex is used for preparing chewing gum, and has pH of 6-7.
The preparation method of the children paint comprises the following steps:
1. pre-emulsification: weighing soft monomer, hard monomer, paraffin, styrene-butadiene latex and degraded starch solution, mixing with 1/3-1/2 deionized water, homogenizing, stirring for 10-30min to obtain pre-emulsion;
2. preparing an emulsion: adding a pH regulator and the rest deionized water into a reaction kettle provided with a stirring device, a condensing device, a nitrogen protection device and a feeding device, uniformly stirring, pouring 1/3 pre-emulsion and 1/3 initiator into the reaction kettle, heating to 80 ℃, stirring, reacting to obtain emulsion with blue gloss, beginning to dropwise add the rest pre-emulsion, dialdehyde modified nano-cellulose, a cross-linking agent and an initiator, controlling the pre-emulsion to be completely dripped within 3-4 h, controlling the initiator to be completely dripped within 4-5 h, keeping the temperature at 80-85 ℃, controlling the stirring speed at 100r/min, keeping the temperature for 30min after the initiator is completely dripped, filtering and discharging, adjusting the pH to 7-8, and sealing for later use;
3. and (3) wood lacquer modulation: and mixing the prepared emulsion with deionized water, a wetting and leveling agent, a defoaming agent, a thickening agent, a film-forming assistant and a wax emulsion according to a certain proportion to prepare the water-based wood lacquer with the core-shell structure, wherein the solid content of the water-based wood lacquer is 30-40%.
The wetting and leveling agent is BYK-346, the defoaming agent is BYK-019, the thickening agent is PE-625, the film-forming additive is TEXNALA-12, and the wax emulsion is BYK-513.
Further, based on 100 parts by weight of the emulsion, 10-20 parts by weight of deionized water, 0.1-0.5 part by weight of a wetting and leveling agent, 0.2-0.5 part by weight of a defoaming agent, 0.5-1.5 parts by weight of a thickening agent, 3-5 parts by weight of a film-forming assistant and 5-10 parts by weight of a wax emulsion are added in the step 3.
The invention has the following effects:
1) according to the invention, dialdehyde modified nano-cellulose is added when the coating resin is prepared, and the modified cellulose has aldehyde group and alcoholic hydroxyl group, and can react with monomers in a system and active groups in a wood base material simultaneously, so that the physical properties such as the adhesive force of the coating, the hardness of a coating film of the coating and the like are improved.
2) The styrene-butadiene latex is added when the coating resin is prepared, and the components can endow the coating with better elasticity, scratch resistance, stain resistance and scrawling resistance.
3) According to the invention, due to the addition of the dialdehyde modified nano-cellulose and the styrene-butadiene latex, the coating has high adhesive force, hardness, pollution resistance and scraping resistance under the synergistic effect, and the coating is superior to the existing national standards of children furniture: GB/T33394-2016 waterborne wood coating for children room decoration.
Detailed Description
EXAMPLE 1
1) Pre-emulsification: weighing 80g of butyl acrylate, 60g of styrene, 40g of methyl methacrylate, 2g of paraffin, 10g of styrene-butadiene latex and 15g of degraded starch solution (with the solid content of 12%), mixing with 135g of deionized water, homogenizing and stirring for 20min to obtain a pre-emulsion;
2) preparing an emulsion: adding a pH regulator and 135g of deionized water into a reaction kettle provided with a stirring device, a condensing device, a nitrogen protection device and a feeding device, uniformly stirring, pouring 1/3 pre-emulsion and 0.5g of ammonium persulfate into the reaction kettle, heating to 80 ℃, stirring, reacting to obtain emulsion with blue gloss, beginning to dropwise add the rest pre-emulsion, 0.3g of dialdehyde modified nano-cellulose, 3g of acrylamide and 1g of ammonium persulfate, controlling the pre-emulsion to be completely dripped within 3 hours, controlling the initiator to be completely dripped within about 4 hours, keeping the temperature at 85 ℃, controlling the stirring speed at 100r/min, keeping the temperature for 30min after the initiator is completely dripped, filtering and discharging, adjusting the pH to 7-8, and sealing for later use;
3) and (3) wood lacquer modulation: and mixing the prepared emulsion with 50g of deionized water, 0.1g of wetting and leveling agent BYK-346, 0.2g of defoaming agent BYK-019, 0.5g of thickening agent PE-625, 3g of film-forming aid TEXNALA-12 and 5g of wax emulsion BYK-513 to prepare the core-shell water-based wood paint with the solid content of 35%.
EXAMPLE 2
1) Pre-emulsification: weighing 100g of ethyl acrylate, 60g of vinyl acetate, 60g of methyl acrylate, 3g of paraffin, 8g of styrene-butadiene latex and 20g of degraded starch solution (the solid content is 12%), mixing with 135g of deionized water, homogenizing and stirring for 30min to obtain a pre-emulsion;
2) preparing an emulsion: adding a pH regulator and 135g of deionized water into a reaction kettle provided with a stirring device, a condensing device, a nitrogen protection device and a feeding device, uniformly stirring, pouring 1/2 pre-emulsion and 0.5g of potassium persulfate into the reaction kettle, heating to 80 ℃, stirring, reacting to obtain emulsion with blue gloss, beginning to dropwise add the rest pre-emulsion and 1g of dialdehyde modified nano-cellulose, 3g of acrylonitrile and 1g of potassium persulfate, controlling the pre-emulsion to be completely dripped within 3 hours, controlling the initiator to be completely dripped within about 4 hours, keeping the temperature at 85 ℃, controlling the stirring speed at 100r/min, keeping the temperature for 30min after the initiator is completely dripped, filtering and discharging, adjusting the pH to 7-8, and sealing for later use;
3) and (3) wood lacquer modulation: and mixing the prepared emulsion with 80g of deionized water, 0.2g of wetting and leveling agent BYK-346, 0.4g of defoaming agent BYK-019, 0.7g of thickening agent PE-625, 5g of film-forming aid TEXNALA-12 and 8g of wax emulsion BYK-513 to prepare the core-shell water-based wood paint with the solid content of 35%.
Comparative example 1
Comparative example 1 the same procedure as in example 1 was followed except that the dialdehyde-modified nanocellulose was not added.
Comparative example 2
Comparative example 2 the same procedure as in example 1 was conducted except that no styrene-butadiene latex was added.
Comparative example 3
Comparative example 3 the same procedure as in example 1 was followed except that the dialdehyde-modified nanocellulose and styrene-butadiene latex were not added.
Testing the effects
According to the national standards of furniture for children: the examples and comparative examples were tested with the waterborne wood coating for children's room decoration of GB/T33394-2016.
The test results are shown in Table 1
TABLE 1
According to the table 1, it can be shown that the children latex paint obtained by adding the dialdehyde modified nano-cellulose and the styrene-butadiene latex has better adhesive force, wear resistance, pollution resistance and anti-graffiti property.
Finally, it should be noted that: the above embodiments are only used to illustrate the present invention and do not limit the technical solutions described in the present invention; thus, while the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted; all such modifications and variations are intended to be included herein within the scope of this disclosure and the present invention and protected by the following claims.
Claims (9)
1. The wood lacquer emulsion for children is characterized by being prepared from the following components in parts by weight:
2. the emulsion according to claim 1, wherein the soft monomer is selected from one or more of butyl acrylate, ethyl acrylate and isooctyl acrylate; the hard monomer is one or more of styrene, methyl methacrylate, vinyl acetate, methyl acrylate, acrylic acid and acrylamide.
3. The emulsion of claim 1, wherein said crosslinking monomer is selected from the group consisting of acrylamide and acrylonitrile.
4. An emulsion according to claim 1, wherein the initiator is selected from ammonium persulfate or potassium persulfate.
5. The emulsion according to claim 1, wherein the degraded starch glue solution is obtained by degrading native starch with amylase, and has a solid content of 10-15%.
6. The emulsion according to claim 1, characterized in that the dialdehyde modified nanocellulose is prepared by the following method: and (3) adjusting the pH value of the nano-cellulose solution to 4 by using 0.1mol/L hydrochloric acid solution, adding 6mmol/L sodium periodate at the rotation speed of 1000r/min and the temperature of 40-60 ℃, reacting for 6-7h, and cooling to obtain the dialdehyde modified nano-cellulose.
7. The preparation method of the children paint is characterized by comprising the following steps:
1) preparation of pre-emulsion: weighing the components of claim 1, mixing soft monomer, hard monomer, paraffin, styrene-butadiene latex and degraded starch solution with 1/3-1/2 deionized water, homogenizing and stirring for 10-30min to obtain pre-emulsion;
2) preparing an emulsion: adding a pH regulator and the rest deionized water into a reaction kettle provided with a stirring device, a condensing device, a nitrogen protection device and a feeding device, uniformly stirring, pouring 1/3 dosage of pre-emulsion and 1/3 dosage of initiator into the reaction kettle, heating to 80 ℃, stirring, reacting to obtain emulsion with blue gloss, beginning to dropwise add the rest pre-emulsion, dialdehyde modified nano-cellulose, cross-linking agent mixed solution and initiator, controlling the pre-emulsion to be completely dripped within 3h-4h, controlling the initiator to be completely dripped within 4h-5h, keeping the temperature at 80-85 ℃, controlling the stirring speed at 100r/min, keeping the temperature for 30min after the initiator is completely dripped, filtering and discharging, adjusting the pH to 7-8, and sealing for later use;
3) and (3) wood lacquer modulation: and mixing the prepared emulsion with deionized water, a wetting and leveling agent, a defoaming agent, a thickening agent, a film-forming assistant and a wax emulsion according to a certain proportion to prepare the water-based wood lacquer with the core-shell structure, wherein the solid content is 30-40%.
8. The children's paint as claimed in claim 7, wherein the wetting and leveling agent is BYK-346, the defoaming agent is BYK-019, the thickener is PE-625, the film-forming aid is texanala-12, and the wax emulsion is BYK-513.
9. The children paint as claimed in claim 7, wherein the deionized water is added in 10-20 parts by weight, the wetting and leveling agent is added in 0.1-0.5 part by weight, the defoamer is added in 0.2-0.5 part by weight, the thickener is added in 0.5-1.5 part by weight, the film forming aid is added in 3-5 parts by weight, and the wax emulsion is added in 5-10 parts by weight, relative to 100 parts by weight of the emulsion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911399881.8A CN111019466A (en) | 2019-12-31 | 2019-12-31 | Paint for children furniture and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911399881.8A CN111019466A (en) | 2019-12-31 | 2019-12-31 | Paint for children furniture and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111019466A true CN111019466A (en) | 2020-04-17 |
Family
ID=70196063
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911399881.8A Pending CN111019466A (en) | 2019-12-31 | 2019-12-31 | Paint for children furniture and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111019466A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112266665A (en) * | 2020-10-27 | 2021-01-26 | 安徽天锦云节能防水科技有限公司 | Anti-condensation and anti-mildew coating and preparation method thereof |
Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1649975A (en) * | 2002-04-26 | 2005-08-03 | Ge拜尔硅股份有限公司 | Use of an aqueous coating composition for the manufacture of surface coatings of seals |
| US20070049510A1 (en) * | 2005-08-31 | 2007-03-01 | Gary Fujii | Two-step coating removal process |
| TW200922945A (en) * | 2007-07-12 | 2009-06-01 | Evonik Roehm Gmbh | Emulsion polymer containing activators, process for preparing it and its use in two-component or multicomponent systems |
| CN102066433A (en) * | 2008-06-17 | 2011-05-18 | 阿克马法国公司 | Composition containing (meth)acrylic polymer and copolymer having associative groups |
| CN102146594A (en) * | 2011-05-09 | 2011-08-10 | 张家港耐尔纳米科技有限公司 | Oxidized cellulose nanofibers and preparation method thereof |
| CN102321326A (en) * | 2011-06-29 | 2012-01-18 | 三棵树涂料股份有限公司 | Acrylic ester elastic emulsion of room-temperature self crosslinking nucleocapsid structure and preparation method thereof |
| CN102827322A (en) * | 2012-08-14 | 2012-12-19 | 华南理工大学 | Preparation method and application of internal-external dual cross-linked core-shell structured acrylic acid emulsion |
| CN105037632A (en) * | 2015-06-24 | 2015-11-11 | 青岛科技大学 | Starch-based bio-latex with core-shell structure and preparation method thereof |
| CN105273557A (en) * | 2015-10-13 | 2016-01-27 | 中国林业科学研究院木材工业研究所 | Waterborne wood paint and preparation method thereof |
| CN106009136A (en) * | 2016-06-24 | 2016-10-12 | 宁波格林工艺玩具有限公司 | Preparation method of wood toy |
| CN108559025A (en) * | 2018-04-28 | 2018-09-21 | 浙江天晨胶业股份有限公司 | A kind of preparation method of wood paint base-material |
| CN109651558A (en) * | 2018-11-06 | 2019-04-19 | 广州集泰化工股份有限公司 | A kind of water soluble acrylic acid dispersion of self-crosslinking core-shell structure and its preparation method and application |
| CN110483676A (en) * | 2019-07-18 | 2019-11-22 | 广东腾龙化工科技有限公司 | A kind of butadiene-styrene copolymer latex of heterogeneous structure and its preparation method and application |
-
2019
- 2019-12-31 CN CN201911399881.8A patent/CN111019466A/en active Pending
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1649975A (en) * | 2002-04-26 | 2005-08-03 | Ge拜尔硅股份有限公司 | Use of an aqueous coating composition for the manufacture of surface coatings of seals |
| US20070049510A1 (en) * | 2005-08-31 | 2007-03-01 | Gary Fujii | Two-step coating removal process |
| TW200922945A (en) * | 2007-07-12 | 2009-06-01 | Evonik Roehm Gmbh | Emulsion polymer containing activators, process for preparing it and its use in two-component or multicomponent systems |
| CN102066433A (en) * | 2008-06-17 | 2011-05-18 | 阿克马法国公司 | Composition containing (meth)acrylic polymer and copolymer having associative groups |
| CN102146594A (en) * | 2011-05-09 | 2011-08-10 | 张家港耐尔纳米科技有限公司 | Oxidized cellulose nanofibers and preparation method thereof |
| CN102321326A (en) * | 2011-06-29 | 2012-01-18 | 三棵树涂料股份有限公司 | Acrylic ester elastic emulsion of room-temperature self crosslinking nucleocapsid structure and preparation method thereof |
| CN102827322A (en) * | 2012-08-14 | 2012-12-19 | 华南理工大学 | Preparation method and application of internal-external dual cross-linked core-shell structured acrylic acid emulsion |
| CN105037632A (en) * | 2015-06-24 | 2015-11-11 | 青岛科技大学 | Starch-based bio-latex with core-shell structure and preparation method thereof |
| CN105273557A (en) * | 2015-10-13 | 2016-01-27 | 中国林业科学研究院木材工业研究所 | Waterborne wood paint and preparation method thereof |
| CN106009136A (en) * | 2016-06-24 | 2016-10-12 | 宁波格林工艺玩具有限公司 | Preparation method of wood toy |
| CN108559025A (en) * | 2018-04-28 | 2018-09-21 | 浙江天晨胶业股份有限公司 | A kind of preparation method of wood paint base-material |
| CN109651558A (en) * | 2018-11-06 | 2019-04-19 | 广州集泰化工股份有限公司 | A kind of water soluble acrylic acid dispersion of self-crosslinking core-shell structure and its preparation method and application |
| CN110483676A (en) * | 2019-07-18 | 2019-11-22 | 广东腾龙化工科技有限公司 | A kind of butadiene-styrene copolymer latex of heterogeneous structure and its preparation method and application |
Non-Patent Citations (4)
| Title |
|---|
| 李肇强: "《现代涂料的生产及应用》", 31 March 2017, 上海：上海科学技术文献出版社 * |
| 燃料化学工业出版社: "《化工辞典》", 30 September 1973, 燃料化学工业出版社 * |
| 肖千云等: "《舰船腐蚀与防护技术》", 31 December 2012, 哈尔滨：哈尔滨工程大学出版社 * |
| 闫福安等: "核壳结构丙烯酸酯乳液合成及其木器封闭底漆的制备", 《中国涂料》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112266665A (en) * | 2020-10-27 | 2021-01-26 | 安徽天锦云节能防水科技有限公司 | Anti-condensation and anti-mildew coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4219454A (en) | Vinyl acetate copolymer emulsions for paint | |
| CN107434842B (en) | Core-shell structure hydroxyl acrylic resin emulsion and preparation method and application thereof | |
| CN109929067B (en) | Acrylate emulsion with core-shell structure and preparation method and application thereof | |
| CN110511388B (en) | Modified hydroxyl acrylic emulsion for water-based metal decorating paint and preparation method thereof | |
| CN111454402B (en) | Acrylate emulsion leather finishing agent and preparation method thereof | |
| CN112266677B (en) | Hydroxyl acrylic acid dispersoid and acrylic acid anticorrosive paint | |
| CN112266439B (en) | Ammonia-free waterproof emulsion and preparation method thereof | |
| CN104804126A (en) | Modified self-crosslinking water-based acrylic resin and preparation method thereof | |
| CN109369839B (en) | Self-crosslinking vinyl chloride copolymer emulsion and preparation method thereof | |
| CN111019466A (en) | Paint for children furniture and preparation method thereof | |
| CN112321774A (en) | Waterborne polyurethane/acrylate composite emulsion for single-component plastic silver paint and preparation method thereof | |
| CN109679017B (en) | Single-component aqueous acrylic acid dispersion and preparation method thereof | |
| CN109705257B (en) | Humidity-adjusting acrylic emulsion and preparation method thereof | |
| US5286778A (en) | Latices and waterborne compositions for wood stains, sealers, and the like | |
| EP0647689A1 (en) | Correction fluid | |
| JPH0370763A (en) | Aqueous composition of acid-functional acrylsilanol polymer base | |
| JPS6318602B2 (en) | ||
| EP0741764A1 (en) | Waterborne wiping stain for wood | |
| CN107828006B (en) | Preparation method of high-heat-resistance water-based acrylic resin and obtained product | |
| CN114437631A (en) | UV (ultraviolet) matte white finish on melamine board and preparation thereof | |
| CN113583597A (en) | Preparation process of water-based sealing adhesive | |
| EP0508536A1 (en) | Aqueous dispersions of self-crosslinking acrylic polymers and water-based thermosetting compositions therefrom | |
| CN114213918A (en) | Water-based wood clear primer and preparation method thereof | |
| CN107987198B (en) | Metal chelating type cationic emulsion for waterborne wood sealing primer and preparation method thereof | |
| CN111087886A (en) | Water-based paint for reconstituted bamboo and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20200417 |
|
| WD01 | Invention patent application deemed withdrawn after publication |