CN111014531A - Cold forging lubricating method based on net-shaped storage structure - Google Patents

Cold forging lubricating method based on net-shaped storage structure Download PDF

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CN111014531A
CN111014531A CN201911227296.XA CN201911227296A CN111014531A CN 111014531 A CN111014531 A CN 111014531A CN 201911227296 A CN201911227296 A CN 201911227296A CN 111014531 A CN111014531 A CN 111014531A
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storage structure
lubricating
blank
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net
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CN111014531B (en
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李子博
胡成亮
赵震
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Shanghai Jiaotong University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21JFORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
    • B21J3/00Lubricating during forging or pressing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21JFORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
    • B21J5/00Methods for forging, hammering, or pressing; Special equipment or accessories therefor
    • B21J5/02Die forging; Trimming by making use of special dies ; Punching during forging

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Abstract

A lubricating method in the field of cold forging of metal materials is a cold forging lubricating method based on a net-shaped storage structure, and the surface lubricating treatment is realized by preparing a multi-layer net-shaped storage structure, fully soaking the multi-layer net-shaped storage structure by a thermosetting lubricating medium, adhering the net-shaped storage structure soaked with the lubricating medium to a cold forging blank subjected to surface treatment, heating and curing the cold forging blank to form a composite lubricating layer. The invention can quickly realize the lubrication treatment of the blank, is used for the subsequent cold forging processing, greatly reduces the harm to the environment, and does not need to continuously add the lubricant in the subsequent use process.

Description

Cold forging lubricating method based on net-shaped storage structure
Technical Field
The invention relates to a technology in the field of cold forging processing, in particular to a cold forging lubricating method based on a net-shaped storage structure.
Background
In the cold forging process, the friction is generated between the die and the blank on a contact interface, the surface of the die is easily damaged under the condition of no lubrication, and the batch production cannot be realized. Therefore, the cold forging process must be well lubricated to improve the surface quality of the forging and the service life of the die. The phosphorization and saponification treatment is a classic lubrication treatment mode in cold forging processing, and a porous phosphate coating is formed on the surface of the treated metal and is used for storing saponified fat to play a role in lubrication. However, the process has many steps and long flow, and is accompanied with the problem of environmental pollution such as heavy metal ions, acid mist, wastewater and the like, and the application of the process is restricted by strict laws at present. Meanwhile, many products after cold forging processing need to be continuously added with lubricant to ensure normal use, and the subsequent operation is relatively complex. Therefore, it is urgently required to develop a new cold forging lubrication method which can solve the above-mentioned problems.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides the cold forging lubricating method based on the net-shaped storage structure, which can quickly realize the lubricating treatment of the blank, and does not need to supplement additional lubricant during the subsequent cold forging and use, thereby greatly reducing the harm to the environment and simplifying the lubricating treatment process.
The invention is realized by the following technical scheme:
the invention realizes the surface lubrication treatment by preparing a multi-layer reticular storage structure, fully impregnating the reticular storage structure with the thermosetting lubricating medium, adhering the reticular storage structure impregnated with the lubricating medium on the cold forging blank subjected to the surface treatment, heating and curing the reticular storage structure to form a composite lubricating layer.
The multilayer mesh storage structure is formed by stacking a plurality of single-layer mesh storage structures, warp-wise fiber bundles and weft-wise fiber bundles are staggered between adjacent single layers and are stacked, and the multiple layers are connected by using an orthogonal interlocking structure.
The multilayer mesh memory structure is preferably three layers.
The multilayer reticular storage structure is made of fiber materials, and the material parameters preferably meet the following requirements: elongation at break deltag>18% initial modulus Eg>20cN/dtex, fiber diameter
Figure BDA0002302587910000011
And surface expansion ratio η when the blank is cold forgeds>Time 2 (η)s=SAfter forging/SBefore forging) Elongation at break deltag>41 percent; further preferred is polytetrafluoroethylene or polyacrylonitrile in a cylindrical shape.
Each layer of the multi-layer mesh storage structure is woven by warp-wise and weft-wise fiber bundles to obtain weaving units, and the weaving units repeatedly extend in the warp direction and the weft direction to form the multi-layer mesh storage structure, wherein the warp-wise and weft-wise fiber bundles are respectively formed by ngAnd nwRoot cylindrical fibers and satisfies ng=nwThe cross section of the weaving unit is in a fan blade shape, and the weaving unit is 80-120.
The weaving unit obtained by the weaving satisfies
Figure BDA0002302587910000021
Wherein:
Figure BDA0002302587910000022
every n warp yarns for a weft yarn are interwoven,
Figure BDA0002302587910000023
for one warp yarn to interlace every n weft yarns αgTo weave corners, 0<αg≤90°。
The material parameters of the thermosetting lubricating medium preferably satisfy the following conditions: curing temperature Ts80-130 ℃ and average particle diameter
Figure BDA0002302587910000024
The solution viscosity η is 0.015 to 0.020Pa · s, and the pH is 9 to 10, and further preferably a PTFE concentrated solution or a nylon 6 fiber concentrated solution.
The impregnation is as follows: putting the multi-layer net-shaped storage structure into a thermosetting lubricating medium for soaking for a time ts≥0.5h。
Preferably, the surface treatment is performed to satisfy Ra 5 to 7.5 μm, that is, the roughness Ra of the contact surface between the blank and the mesh-like storage structure is increased, and the surface treatment is performed by, but not limited to, sandblasting or the like.
The composite lubricating layer arranged on the surface of the blank is as follows: according to the surface area S of the composite lubricating layer contacted with the blanknCutting the mesh storage structure into areas S using laser cuttingc=1.1~1.15SnAfter cutting is finished, the cutting toolAnd (4) removing burrs of the composite lubricating layer and flatly paving the composite lubricating layer on the surface of the blank.
The heating temperature T in the heating and curinghThe corresponding relation is satisfied: when the solidification temperature of the lubricating medium meets TsWhen the temperature is 80-10 ℃, Th130-160 ℃; when T issT at 100-130 ℃h160-190 ℃. Holding time t for solidifying lubricanth=1.5~2.5h。
The heating solidification is preferably carried out by clamping the net-shaped storage structure and the metal blank by using a clamping tool, and the clamping force F is further preferably selectedN=200~400N。
The invention relates to a lubricated surface prepared by the method, wherein the shear friction factor m of the lubricated surface is 0.10-0.17, and when the fiber is polyacrylonitrile, αg90 degrees, using PTFE concentrated solution as lubricating medium, surface treating, Ra 7 μm, FN=400N,Th=190℃,thWhen m is 2.5h, m is 0.10-0.13, and η follows the blanksIncreasing the friction factor and floating the friction factor, when the fiber is polytetrafluoroethylene, αg60 degrees, the concentrated solution of nylon 6 fiber is used as lubricating medium, Ra is 5 μm after surface treatment, FN=300N,Th=150℃,thWhen 2h, m is 0.17 and remains stable.
Technical effects
Compared with the prior art, the invention integrally solves the technical problems that: the traditional phosphorization saponification lubricating method which has multiple working procedures and great harm to the environment in the field of cold forging processing is replaced, and a treatment mode of continuously lubricating cold forging blanks without adding a lubricating agent is provided. The unexpected technical effects that result from this include:
the invention adopts a mode of heating and solidifying a lubricating medium to finish the lubricating treatment of the blank. The net-shaped storage structure is formed by weaving single-layer or multi-layer fiber bundles, and is fully soaked in a lubricating medium and then is adhered to the blank subjected to surface treatment. And then the cold forging blank is lubricated by the net-shaped storage structure after being heated and solidified by the lubricating medium.
Drawings
FIG. 1 is a schematic view of a multi-layered web storage structure adhered to a surface of a blank;
in the figure: a is a three-layer mesh memory structure, b is a partial enlarged schematic diagram of a, and c is an enlarged schematic diagram of part I;
FIG. 2 is a flow chart of the construction of the composite lubricating layer;
in the figure: a is surface treatment, b is clamping and adding a composite lubricating layer, and c is heating and curing treatment.
Detailed Description
Example 1
The embodiment relates to a cold forging lubricating method based on a net-shaped storage structure, wherein a PTFE concentrated solution is used for soaking a three-layer net-shaped storage structure, sand blasting is carried out on a metal blank, a clamping tool is used for clamping the net-shaped storage structure on the surface of the blank, and then the blank is placed into a high-temperature box for heating and curing, so that the lubricating treatment is completed.
This example uses a martensitic precipitation hardening stainless steel 05Cr17Ni4Cu4Nb to produce a metal blank in the form of a flanged ring having an outer diameter
Figure BDA0002302587910000031
Flange thickness hb2mm, the outer diameter of the metal ring is
Figure BDA0002302587910000032
An inner diameter of
Figure BDA0002302587910000033
First step, a three-layer mesh memory structure is prepared due to target ηs>2, so delta is selectedg=46%,Eg=30.8cN/dtex,
Figure BDA0002302587910000034
The acrylic fiber (polyacrylonitrile) is formed by respectively combining a warp-wise fiber bundle and a weft-wise fiber bundleg=nw100 cylindrical acrylic fibers are polymerized, and the section of the acrylic fiber is in a fan blade shape.
The single-layer storage structure is woven in a mode of three-layer, one-layer, two-layer, twill and four-layer satin, and the warp parameters and the weft parameters of each layer are respectively
Figure BDA0002302587910000035
αg90 degrees, and the fiber parameters meet the following conditions:
Figure BDA0002302587910000036
the warp and weft fiber bundles are staggered and stacked between two single layers, and the multiple layers are connected by an orthogonal interlocking structure.
Step two, lubricating treatment: and selecting a PTFE concentrated solution as a thermosetting lubricating medium for impregnating the three-layer mesh storage structure. Curing temperature T of PTFE concentrates130 ℃ C, average particle diameter of
Figure BDA0002302587910000037
The viscosity of the colloidal solution η is 0.019 Pa.s, the pH value is 9.8, and when the three-layer net-shaped storage structure is impregnated with the PTFE concentrated solution, the impregnation time t iss=1h。
Step three, blank surface treatment: as shown in fig. 1, the blank is surface-treated by sandblasting, and then a mesh-like storage structure is attached, specifically: setting the target surface as the upper and lower end surfaces of a circular ring and the diameter of sand grains
Figure BDA0002302587910000038
Water content less than 2%, hard particles with edges and corners, and air pressure P of air machinea=6.0~6.5X105Pa, air pressure amplitude Delta P is 0.5-1.0X 105Pa, the distance L between the nozzle and the metal surface is 100-300 mm, and the included angle between the sand blasting direction and the surface normal line is αs15 ~ 30 degrees, the cyclic annular removes the shower nozzle and slowly sandblasts 3 ~ 7 circles, shields the protection to the non-sandblast position before the sandblast. In this embodiment, the values of the parameters are
Figure BDA0002302587910000039
Pa=6.5X105Pa,L=200mm,αs22.5. The surface roughness Ra of the sand blasted was 7 μm.
The reticular storage structure adhered to the blank surface is obtained by laser cutting, and the surface area S is obtained after cuttingc=1.15Sn,SnIs the surface area of the web-like storage structure in contact with the web. After cutting, the burrs are removed and laid flat on the target surface of the blank.
Step four, heating and curing: as shown in FIG. 2, a clamping tool is used, as FNA clamping force of 400N clamps the web storage structure to the blank and the whole is placed in a high temperature oven for heat curing. Heating temperature Th190 deg.C, holding time th=2.5h。
After all the lubrication treatment steps are finished, the lubrication method is evaluated by using a ring upsetting method to evaluate the lubrication conditions, wherein the deformation speed is 20mm/s, and the result shows that the shear friction factor m is 0.10-0.13 in the embodiment and is η along with the blanksIncreasing the friction factor, and floating the friction factor until the height variation of the ring reaches 54.5 percent and the surface expansion ratio of the blank reaches ηsWhen 2.26, the net-like storage structure may not completely cover the blank.
Example 2
The cold-forged blank of this example was the same as example 1.
First step, preparation of a three-layer mesh memory Structure, unlike example 1, due to object ηs<1.5, therefore, delta is selectedg=19%,Eg=106.3cN/dtex,
Figure BDA0002302587910000041
The warp and weft fiber bundles are respectively composed of ng=nw116 cylindrical teflon fibers are polymerized, and the section of the fiber is in a fan blade shape.
The single-layer storage structure is woven in a mode of three-layer, one-layer, two-layer, twill and four-layer satin, and the warp parameters and the weft parameters of each layer are respectively
Figure BDA0002302587910000042
αg60 degrees, and the fiber parameters meet the following conditions:
Figure BDA0002302587910000043
staggered warp and weft fiber bundle stacking between two monolayersThe layers are joined using an orthogonal interlocking structure.
Step two, lubricating treatment: unlike example 1, a nylon 6 fiber concentrate was chosen as the thermosetting lubricating medium for impregnating the three-layer reticulated storage structure. Curing temperature T of nylon 6 fiber concentrated solutions90 ℃ and an average particle diameter of
Figure BDA0002302587910000044
The viscosity of the colloidal solution η is 0.015 Pa.s, the pH value is 9.2, and when the three-layer net-shaped storage structure is soaked by using nylon 6 fiber concentrated solution, the soaking time t iss=0.5h。
Step three, blank surface treatment: the method comprises the following steps of carrying out surface treatment on a blank by using a sand blasting method, and then pasting a net-shaped storage structure, wherein the method specifically comprises the following steps: setting the target surface as the upper and lower end surfaces of a circular ring and the diameter of sand grains
Figure BDA0002302587910000045
Water content less than 2%, hard particles with edges and corners, and air pressure P of air machinea=6.0~6.5×105Pa, air pressure amplitude Delta P is 0.5-1.0 x105Pa, the distance L between the nozzle and the metal surface is 100-300 mm, and the included angle between the sand blasting direction and the surface normal line is αs15 ~ 30 degrees, the cyclic annular removes the shower nozzle and slowly sandblasts 3 ~ 7 circles, shields the protection to the non-sandblast position before the sandblast. Different from the embodiment 1, the values of the parameters are
Figure BDA0002302587910000046
Pa=6.0×105Pa,L=200mm,αs27.5 °; the surface roughness Ra of the sand blasted was 5 μm.
The reticular storage structure adhered to the blank surface is obtained by laser cutting, and the surface area S is obtained after cuttingc=1.15Sn,SnIs the surface area of the web-like storage structure in contact with the web. After cutting, the burrs are removed and laid flat on the target surface of the blank.
Step four, heating and curing: using a clamping tool with FN300N clamping force clamps the web storage structure to the blankAnd tightly tightening, and putting the whole into a high-temperature box for heating and curing. Heating temperature ThKeeping the temperature at 150 ℃ for th=2h。
The lubrication process was evaluated after completion of all steps of lubrication treatment by using ring upsetting method to evaluate the lubrication conditions and the deformation speed v was 20mm/s, and the results showed that the shear friction factor in this example was stably maintained at m 0.17 until the amount of change in the height of the ring reached 28.5% and the surface expansion ratio of the billet reached ηsWhen the thickness is 1.441, the net-shaped storage structure cannot completely cover the blank.
The foregoing embodiments may be modified in many different ways by those skilled in the art without departing from the spirit and scope of the invention, which is defined by the appended claims and all changes that come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.

Claims (11)

1. A lubrication method in the field of metal material cold forging processing is characterized in that a multi-layer net-shaped storage structure is prepared and fully impregnated by a thermosetting lubrication medium, then the net-shaped storage structure impregnated with the lubrication medium is adhered to a cold forging blank subjected to surface treatment and is heated and cured to form a composite lubrication layer, and surface lubrication treatment is realized;
the multilayer mesh storage structure is formed by stacking a plurality of single-layer mesh storage structures, warp-wise fiber bundles and weft-wise fiber bundles are staggered between adjacent single layers and are stacked, and the multiple layers are connected by using an orthogonal interlocking structure.
2. The method as claimed in claim 1, wherein said multilayer network storage structure is made of fibrous material having material parameters satisfying: elongation at break deltag>18% initial modulus Eg>20cN/dtex, fiber diameter
Figure FDA0002302587900000011
And surface expansion ratio η when the blank is cold forgeds>Time 2 (η)s=SAfter forging/SBefore forging) Break off ofElongation deltag>41%。
3. A method according to claim 1 or 2, wherein the multi-layered network storage structure is made of cylindrical polytetrafluoroethylene or polyacrylonitrile.
4. The method as claimed in claim 1 or 2, wherein each of the plurality of layers of the mesh-like storage structures is woven by warp and weft fiber bundles to obtain woven units, and the woven units are repeatedly extended in the warp and weft directions, wherein the warp and weft fiber bundles are ngAnd nwRoot cylindrical fibers and satisfies ng=nwThe cross section of the weaving unit is in a fan blade shape, and the weaving unit is 80-120.
5. The method of claim 4, wherein said knitting results in knitted units that satisfy
Figure FDA0002302587900000012
Wherein:
Figure FDA0002302587900000013
every n warp yarns for a weft yarn are interwoven,
Figure FDA0002302587900000014
for one warp yarn to interlace every n weft yarns αgTo weave corners, 0<αg≤90°。
6. The method of claim 1, wherein the thermosetting lubricating medium has material parameters that satisfy: curing temperature Ts80-130 ℃ and average particle diameter
Figure FDA0002302587900000015
The solution viscosity η is 0.015-0.020 Pa · s, and the pH value is 9-10.
7. The method of claim 1 or 6, wherein the thermosetting lubricating medium is a PTFE concentrate or a nylon 6 fiber concentrate.
8. The method of claim 1, wherein said impregnating comprises: putting the multi-layer net-shaped storage structure into a thermosetting lubricating medium for soaking for a time ts≥0.5h。
9. The method as claimed in claim 1, wherein the composite lubricating layer is arranged on the surface of the blank by: according to the surface area S of the composite lubricating layer contacted with the blanknCutting the mesh storage structure into areas S using laser cuttingc=1.1~1.15SnAnd removing burrs of the composite lubricating layer after cutting is finished and flatly paving the burrs on the surface of the blank.
10. The method as set forth in claim 1, wherein the heating temperature T in said heat curinghThe corresponding relation is satisfied: when the solidification temperature of the lubricating medium meets TsWhen the temperature is 80-10 ℃, Th130-160 ℃; when T issT at 100-130 ℃h160-190 ℃, and the heat preservation time t of the solidified lubricanth=1.5~2.5h。
11. The lubricating surface prepared by the method is characterized in that the shear friction factor m is 0.10-0.17, and when the fiber is polyacrylonitrile, αg90 degrees, using PTFE concentrated solution as lubricating medium, surface treating, Ra 7 μm, FN=400N,Th=190℃,thWhen m is 2.5h, m is 0.10-0.13, and η follows the blanksIncreasing the friction factor and floating the friction factor, when the fiber is polytetrafluoroethylene, αg60 degrees, the concentrated solution of nylon 6 fiber is used as lubricating medium, Ra is 5 μm after surface treatment, FN=300N,Th=150℃,thWhen 2h, m is 0.17 and remains stable.
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