CN110959625A - Bird repellent composition and application thereof - Google Patents

Bird repellent composition and application thereof Download PDF

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Publication number
CN110959625A
CN110959625A CN201811143549.0A CN201811143549A CN110959625A CN 110959625 A CN110959625 A CN 110959625A CN 201811143549 A CN201811143549 A CN 201811143549A CN 110959625 A CN110959625 A CN 110959625A
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Prior art keywords
bird repellent
repellent composition
dipentamethylenethiuram tetrasulfide
tetrasulfide
bird
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Inventor
何东升
张振业
陈俊鹏
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Ningbo Sunjoy Agroscience Co Ltd
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Ningbo Sunjoy Agroscience Co Ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/26—Oxidation products of dithiocarbamic acid derivatives, e.g. thiuram sulfides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/32—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A01N47/14—Di-thio analogues thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention provides a bird repellent composition, which comprises active components of dipentamethylenethiuram tetrasulfide and at least one of anthraquinone, dithianon, thiram, ziram, zineb, mancozeb, propineb, methyl anthranilate, zinc dibutyl dithiocarbamate and zinc ethyl phenyl dithiocarbamate. The bird repellent composition containing the dipentamethylenethiuram tetrasulfide provided by the invention can effectively reduce the feeding of birds to crop seeds or sprouts, has an obvious avoidance effect, protects the normal planting and management of crops, improves the yield of the crops and reduces the cost of seedling culture; in addition, the dipentamethylenethiuram tetrasulfide is a nontoxic compound and has small harm to human bodies; and the dipentylene thiuram tetrasulfide has the characteristic of stable storage, so that the storage stability of the bird repellent agent and the bird repellent agent composition containing the dipentylene thiuram tetrasulfide is also improved, and the storage time of the bird repellent agent and the bird repellent agent composition is prolonged.

Description

Bird repellent composition and application thereof
Technical Field
The invention belongs to the technical field of agricultural chemical bird repelling, and particularly relates to a bird repellent composition and application thereof.
Background
Due to the increase of returned agricultural areas and greening areas, bird habitats are increased, and in addition, the protection consciousness of people on birds is enhanced, the number of birds is more and more, the birds in paddy fields, orchards and other fields are seriously damaged, and the loss of the birds to crops in agriculture is more and more.
The existing bird repelling measures are generally measures such as gun horn repelling, net lapping covering, bird repelling agent spraying and the like. The gun horn driving, the lapping and covering and other measures have very high labor and material costs. In some areas with serious bird damage, farmers illegally use high-toxicity carbosulfan for seed dressing to kill birds invading farmlands in order to reduce loss. Farmers lack effective repelling means.
Dipentamethylenethiuram tetrasulfide is gray yellow powder, has a specific gravity of 1.41-1.50, a melting point of not less than 110 ℃, is soluble in carbon disulfide, chloroform and carbon tetrachloride, and is insoluble in water; no smell, no toxicity and stable storage. Tetrakis-amylene thiuram is commonly used as an accelerator for natural rubber, ethylene propylene rubber, neoprene rubber, styrene butadiene rubber, butyl rubber, nitrile rubber, isoprene rubber, chlorosulfonated polyethylene rubber, and also as a vulcanizing agent. When used as a vulcanizing agent, the vulcanized rubber is heat-resistant and has excellent aging resistance.
Disclosure of Invention
The first purpose of the invention is to provide a bird repellent composition aiming at the defects in the prior art.
For this reason, the above object of the present invention is achieved by the following technical solutions:
a bird repellent composition is characterized in that the effective component of the bird repellent composition comprises dipentamethylenethiuram tetrasulfide.
While adopting the above technical scheme, the present invention can also adopt or combine the following further technical schemes:
preferably, the bird repellent composition further comprises at least one of anthraquinone, dithianon, thiram, ziram, zineb, mancozeb, propineb, methyl anthranilate, zinc dibutyl dithiocarbamate, and zinc ethyl phenyl dithiocarbamate.
Preferably, the weight percentage content of the dipentamethylenethiuram tetrasulfide is 10-90%.
Preferably, the content of the dipentamethylenethiuram tetrasulfide is 10-60% by mass.
Preferably, the weight percentage content of the dipentamethylenethiuram tetrasulfide is most preferably 20-50%.
The second purpose of the invention is to provide a dosage form of the bird repellent composition aiming at the defects in the prior art.
For this reason, the above object of the present invention is achieved by the following technical solutions:
the dosage form of the bird repellent composition is characterized in that the dosage form of the bird repellent composition is based on the bird repellent composition, and the bird repellent composition is prepared into any one of a seed treatment solid preparation, a seed treatment liquid preparation, a suspending agent, a water dispersible granule, a wettable powder, a granule, a bait preparation, a corrosion inhibitor, a soluble liquid agent, missible oil, a microemulsion, an oil suspending agent and a suspoemulsion.
While adopting the above technical scheme, the present invention can also adopt or combine the following further technical schemes:
preferably, the bird repellent agent composition further comprises a dispersant component and/or a surfactant component, the dispersant component is 10-80% by mass, and the dispersant is one or a combination of more of kaolin, talcum powder, gypsum powder, diatomite and water.
Preferably, the surfactant is selected from the group consisting of sodium dodecyl sulfonate, sodium lauryl sulfate, sodium dodecyl benzene sulfonate, sodium dioctyl succinate, sodium glycocholate, carboxybetaines, polyoxyethylene alkyl aryl ethers, polyoxyethylene alkyl ethers, alkyl benzene sulfonates, alkyl naphthalene sulfonates, and the like, magnesium aluminum silicate, xanthan gum, acrylate copolymers, sodium lignosulfonates, and combinations of one or more of polyoxyethylene alkyl aryl phenols.
Preferably, the mass percentage of the surfactant is 1-3%.
The invention also aims to provide an application of the bird repellent composition aiming at the defects in the prior art.
For this reason, the above object of the present invention is achieved by the following technical solutions:
the application of the bird repellent composition is characterized in that the bird repellent composition is prepared into a required dosage form and is used for crops, buildings, gardens and airports to protect plants, buildings and aircrafts from being damaged by birds.
Through test comparison, the thiuram tetrasulfide has different action mechanisms on repelling known birds and animals, can release active sulfur, irritate the esophagus of animals, cause vomit of birds and generate strong discomfort, thereby generating the antifeedant effect. Has value in development and use as bird repellent.
Tests prove that the dipentamethylenethiuram tetrasulfide and the bird repellent with other action mechanisms can produce synergistic effect or additive effect. The combination of two elements or three elements has the effects of increasing the bird repelling effect and reducing the cost.
The invention provides a bird repellent composition containing dipentamethylenethiuram tetrasulfide, which can effectively reduce the feeding of birds to crop seeds or sprouts, has obvious avoidance effect, protects the normal planting and management of crops, improves the yield of the crops and reduces the cost of seedling culture; in addition, the dipentamethylenethiuram tetrasulfide is a nontoxic compound and has small harm to human bodies; and the dipentylene thiuram tetrasulfide has the characteristic of stable storage, so that the storage stability of the bird repellent composition containing the dipentylene thiuram tetrasulfide is also improved, and the storage time of the bird repellent and the bird repellent composition is prolonged.
Detailed Description
The present invention is described in further detail with reference to specific embodiments.
A single suspension seed coating agent and a binary suspension seed coating agent containing 50% of dipentamethylenethiuram tetrasulfide are prepared by taking ceratin beasts as experimental objects, the suspension seed coating agent is mixed with wheat seeds, and the mixture is dried in the air and then tested, wherein specific experimental parameters and results are shown in tables 1 and 2. Wherein table 1 shows the repellent effect of a 50% wt dipentamethylenethiuram tetrasulfide single-agent suspension on ceratin birds.
TABLE 1
Figure RE-GDA0001853555940000031
Note: the feeding rate is 100 (original wheat seed weight-the weight of the fed wheat seeds)/the original wheat seed weight; relative food refusal rate is 100 (CK food intake rate-treatment food intake rate)/CK food intake rate.
The experimental results show that: the suspension seed coating containing dipentamethylenethiuram tetrasulfide has good antifeedant effect on the ceratin birds, and the antifeedant effect is increased along with the increase of the dosage. When the dosage is 5g/kg, the relative antifeedant rate is only 27.37 percent, but when the dosage is increased to 10g/kg, the control effect is improved to 82.84 percent.
In the experiment, the safety risk of wheat germination caused by high-dosage dipentamethylenethiuram tetrasulfide is found, the growth inhibition effect on wheat starts to obviously appear at the dosage of 10g/kg, and the fresh weight inhibition rate is higher than the plant height inhibition rate, as shown in the following table 2.
TABLE 2
Figure RE-GDA0001853555940000041
It was also found that the efficacy of the dipentamethylenethiuram tetrasulfide when it was mixed with other components was increased as compared with the effect of the monotherapy of dipentamethylenethiuram tetrasulfide, and that the safety of the mixture to the test materials was improved although the effect of some of the mixtures was lower than that of the monotherapy of dipentamethylenethiuram tetrasulfide. In the above table, the fresh weight and the plant height are the fresh weight and the plant height of malt at the time of germination, respectively.
Taking ceratin beak as an experimental object, preparing a suspension seed coating containing 50 mass percent of dipentamethylenethiuram tetrasulfide and 50 mass percent of other active ingredients, mixing the suspension seed coating with wheat seeds, and performing an experiment after air drying, wherein specific experimental parameters and results are shown in table 3.
TABLE 3
Figure RE-GDA0001853555940000042
Figure RE-GDA0001853555940000051
The experimental results show that: (1) the dipentamethylenethiuram tetrasulfide, the dithianon and the like are mixed, so that the control effect can be increased or is equivalent to that of a single agent; (2) the synergy of the dipentamethylenethiuram tetrasulfide in combination with zinc ethylphenyldithiocarbamate is most obvious.
The test result shows that: the dipentamethylenethiuram tetrasulfide is used singly, 10g/kg of seeds are safe, but the phytotoxicity symptoms of blade yellowing and plant dwarfing can be visually observed at the treatment dosage of 20g/kg of seeds. The safety to crop seeds was greatly mitigated by the use of dipentamethylenethiuram tetrasulfide in combination with other ingredients, as shown in table 4.
TABLE 4
Figure RE-GDA0001853555940000052
Figure RE-GDA0001853555940000061
The ternary composition combination also achieves good prevention effect, as shown in Table 5. The control effect of the repellent composition is greater than that of a single agent by combining repellent components of 50 wt% of dipentamethylenethiuram tetrasulfide FS +50 wt% of methyl anthranilate FS +50 wt% of anthraquinone FS and three different action mechanisms. Ternary mixing is more significant in reducing the safety risk of crops.
TABLE 5
Figure RE-GDA0001853555940000062
The compositional relationship of the suspended seed coating made by mixing dipentamethylenethiuram tetrasulfide with anthraquinone is shown in table 6.
TABLE 6
Figure RE-GDA0001853555940000063
Figure RE-GDA0001853555940000071
Table 7 shows the composition relationship of a wet seed dressing agent prepared by mixing dipentamethylenethiuram tetrasulfide with dithianon, the total content being 80% by weight, wherein the main component was dipentamethylenethiuram tetrasulfide.
TABLE 7
Figure RE-GDA0001853555940000072
Figure RE-GDA0001853555940000081
Table 8 shows the compositional relationship of a dipentamethylenethiuram tetrasulfide suspension concentrate, containing 50% by weight of a total amount of dipentamethylenethiuram tetrasulfide and methyl anthranilate as the main component.
TABLE 8
Figure RE-GDA0001853555940000082
Table 9 shows wettable powders of dipentamethylenethiuram tetrasulfide and thiram, the total content being 90% by weight.
TABLE 9
Table 10 shows the relationship between the components of wettable powders of dipentamethylenethiuram tetrasulfide and propineb, the total content being 80% by weight.
Watch 10
Figure RE-GDA0001853555940000092
Figure RE-GDA0001853555940000101
The composition relationship of the suspended seed coating made of dipentamethylenethiuram tetrasulfide and zinc ethylphenyldithiocarbamate is shown in Table 11, with a total content of 50% by weight.
TABLE 11
Figure RE-GDA0001853555940000102
The composition relationship of the suspended seed coating made of dipentamethylenethiuram tetrasulfide and zinc dibutyldithiocarbamate, total content 80% wt, is shown in table 12.
TABLE 12
Figure RE-GDA0001853555940000111
Table 13 shows the composition relationship of the water dispersible granule prepared from dipentamethylenethiuram tetrasulfide and mancozeb, and the total content is 80 wt%.
Watch 13
Figure RE-GDA0001853555940000112
Figure RE-GDA0001853555940000121
Table 14 shows the composition relationship of a ternary mixture of dipentamethylenethiuram tetrasulfide, anthraquinone, zinc ethylphenyldithiocarbamate, in the form of a suspension seed coating, with a total content of 50% by weight.
TABLE 14
Figure RE-GDA0001853555940000122
Figure RE-GDA0001853555940000131
Table 15 shows the composition relationship of a ternary mixture of dipentaerythritol tetrasulfide, anthraquinone and methyl anthranilate, the formulation is a wet seed mixture, and the total content is 80% by weight.
Watch 15
Figure RE-GDA0001853555940000132
The preparation method of the bird repellent composition in each embodiment comprises the following steps:
for the embodiment without adding surfactant, dispersant and solvent, the two substances are directly mixed and ground into powder with fineness of 5-75 μm; or grinding into powder, mixing, granulating, and spraying directly. Subpackaging into 5-1000 g and packaging.
For the embodiment using the surfactant and/or the dispersant, the components in the embodiment are uniformly mixed, ground into the fineness of 5-75 μm, and prepared into wettable powder, water dispersible granules, dry suspending agent, soluble powder, soluble granules, suspending agent, seed treatment agent and other formulations. Subpackaging into 5-1000 g and packaging.
The crow is cultivated in a greenhouse, wheat, rice, corn seedlings and the like are fed at regular time, and the average feed intake of a single bird is calculated. The wheat is used for testing the repelling effect of the coated seeds; after soaking the rice seeds, carrying out seed dressing treatment for testing the repellent effect of the seed dressing agent; diluting with water, spraying onto corn seedling, air drying, and measuring the feed intake.
Recording the weight difference before and after eating, and calculating the food refusal rate, wherein the food refusal rate is the weight after eating/the original weight multiplied by 100%. And repeating the three steps, and calculating an average value.
Through tests, the test results of the examples 1-7; examples 36 to 49; examples 58-64, the test gave food refusal rates, as shown in Table 16.
TABLE 16
Figure RE-GDA0001853555940000141
Figure RE-GDA0001853555940000151
Through tests, examples 8 to 14; examples 65 to 49; examples 58 to 64, the test gave the food refusal rate, as shown in Table 17.
TABLE 17
Figure RE-GDA0001853555940000152
Through tests, examples 15 to 35; examples 51 to 57; the test gave the food refusal rate as shown in table 18. The overall foliar spray effect is not as good as the seed coating and dressing effect, but also can significantly reduce the loss, and has certain commercial value.
Watch 18
Figure RE-GDA0001853555940000153
Figure RE-GDA0001853555940000161
The above-described embodiments are intended to illustrate the present invention, but not to limit the present invention, and any modifications, equivalents, improvements, etc. made within the spirit of the present invention and the scope of the claims fall within the scope of the present invention.

Claims (7)

1. A bird repellent composition is characterized in that the effective component of the bird repellent composition comprises dipentamethylenethiuram tetrasulfide.
2. A bird repellent composition according to claim 1, further comprising at least one of anthraquinone, dithianon, thiram, ziram, zineb, mancozeb, propineb, methyl anthranilate, zinc dibutyldithiocarbamate, zinc ethylphenyldithiocarbamate.
3. A bird repellent composition according to claim 1 or 2, wherein the dipentamethylenethiuram tetrasulfide is present in an amount of 10 to 90% by mass.
4. A bird repellent composition according to claim 3, wherein the dipentamethylenethiuram tetrasulfide is preferably present in an amount of 10 to 60% by weight.
5. A bird repellent composition according to claim 4, wherein the dipentamethylenethiuram tetrasulfide is most preferably present in an amount of 20 to 50% by weight.
6. A dosage form of the bird repellent composition is characterized in that the dosage form of the bird repellent composition is based on the bird repellent composition of claim 1, and the bird repellent composition is prepared into any one of a seed treatment solid preparation, a seed treatment liquid preparation, a suspending agent, a water dispersible granule, a wettable powder, a granule, a bait preparation, a corrosion inhibitor, a soluble liquid agent, missible oil, a microemulsion, an oil suspending agent and a suspoemulsion.
7. The application of the bird repellent composition is characterized in that the bird repellent composition is prepared into a required dosage form and is used for crops, buildings, gardens and airports to protect plants, buildings and aircrafts from being damaged by birds.
CN201811143549.0A 2018-09-28 2018-09-28 Bird repellent composition and application thereof Pending CN110959625A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114532348A (en) * 2020-11-25 2022-05-27 宁波三江益农化学有限公司 Application of zinc dithiocarbamate compound bird repellent, bird repellent formula and dosage form

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1276156A (en) * 1999-06-07 2000-12-13 广东省林业科学研究院 Dieting agent for mouse and bird
JP2004196684A (en) * 2002-12-17 2004-07-15 Ebara Corp Animal repellent
CN102413696A (en) * 2009-04-22 2012-04-11 拜尔农作物科学股份公司 Use of propineb as bird repellent
CN104285990A (en) * 2014-10-09 2015-01-21 安徽农业大学 Compound bird repellent containing carbosulfan, methyl ortho-aminobenzoate and benzyl acetate
CN107318845A (en) * 2016-04-29 2017-11-07 宁波三江益农作物保护有限公司 A kind of bird repellent containing dithianon
CN110810418A (en) * 2018-08-08 2020-02-21 宁波三江益农化学有限公司 Bird repellent containing dipentamethylenethiuram tetrasulfide

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1276156A (en) * 1999-06-07 2000-12-13 广东省林业科学研究院 Dieting agent for mouse and bird
JP2004196684A (en) * 2002-12-17 2004-07-15 Ebara Corp Animal repellent
CN102413696A (en) * 2009-04-22 2012-04-11 拜尔农作物科学股份公司 Use of propineb as bird repellent
CN104285990A (en) * 2014-10-09 2015-01-21 安徽农业大学 Compound bird repellent containing carbosulfan, methyl ortho-aminobenzoate and benzyl acetate
CN107318845A (en) * 2016-04-29 2017-11-07 宁波三江益农作物保护有限公司 A kind of bird repellent containing dithianon
CN110810418A (en) * 2018-08-08 2020-02-21 宁波三江益农化学有限公司 Bird repellent containing dipentamethylenethiuram tetrasulfide

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114532348A (en) * 2020-11-25 2022-05-27 宁波三江益农化学有限公司 Application of zinc dithiocarbamate compound bird repellent, bird repellent formula and dosage form

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Application publication date: 20200407