CN110951457B - Ceramic tile anti-slip agent and application thereof - Google Patents
Ceramic tile anti-slip agent and application thereof Download PDFInfo
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- CN110951457B CN110951457B CN201911269420.9A CN201911269420A CN110951457B CN 110951457 B CN110951457 B CN 110951457B CN 201911269420 A CN201911269420 A CN 201911269420A CN 110951457 B CN110951457 B CN 110951457B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
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- C09K3/14—Anti-slip materials; Abrasives
- C09K3/149—Antislip compositions
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/08—Flooring or floor layers composed of a number of similar elements only of stone or stone-like material, e.g. ceramics, concrete; of glass or with a top layer of stone or stone-like material, e.g. ceramics, concrete or glass
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Abstract
The invention relates to the technical field of tile antiskid, in particular to a tile antiskid agent and application thereof. The tile anti-slip agent comprises 0.1-1 part of corrosion inhibitor, 30-45 parts of dispersant, 0.1-1 part of humectant, 3-10 parts of surfactant, 0.1-1 part of anti-aging agent, 10-20 parts of filler and 40-60 parts of water. The anti-slip agent can react with silicate in the ceramic tile to form a large number of nano micropores on the surface of the ceramic tile, so that the lower friction force with the ground is greatly enhanced, and the nano material can be distributed on the surfaces of the micropores to form new friction points, so that the large friction force is increased; the nano micropores formed by the anti-slip agent do not damage the appearance of the ceramic tile, are safe and non-toxic, have excellent stability and durability, and have a long service life. The anti-skid agent disclosed by the invention is good in anti-skid effect, strong in stain resistance, high in glossiness and good in cold and hot cycle resistance stability.
Description
Technical Field
The invention relates to the technical field of tile antiskid, in particular to a tile antiskid agent and application thereof.
Background
With the demand of urban construction, more and more construction places adopt bright and hard materials such as marble, ceramic tile and mosaic, and the materials are essential for hospitals, schools, exhibition halls, hotels, supermarkets, shopping centers, restaurants, gymnasiums, swimming pools, bathrooms and kitchens. But the following problems are that some slipping accidents happen continuously due to the smoothness of the ground, and even the human body is injured. According to statistics, the casualties caused by slip accidents in daily life are only second to car accidents, wherein children, old people, pregnant women and people with inconvenient actions are the most serious, so that ground slip prevention becomes a great problem of public safety. Therefore, the anti-skid agent is a commonly used object.
The anti-slip agent is a liquid capable of preventing slipping, and can be used on the surfaces of natural stones or hard tiles. The development accords with the anti-skidding brick product of masses demand and becomes the mainstream, and current anti-skidding ceramic tile is through being provided with fold stripe or concave-convex point on the ceramic tile surface to increase the frictional force of floor brick face and human sole or sole, prevent to skid and fall down. The method has higher requirements on the processing method, and increases the difficulty of processing the ceramic tile.
The prior anti-slip agent has low anti-slip coefficient, no luster, poor stability of cold and hot cycle resistance, poor antifouling property and difficult ceramic tile cleaning, and can generate a dry cracking phenomenon after a long time; meanwhile, the raw materials of the anti-slip agent adopt toxic substances such as oxalic acid, hydrofluoric acid and the like, so that the anti-slip agent not only can corrode the ground, but also can cause environmental pollution, and is poor in environmental protection.
Disclosure of Invention
In order to solve the problems, the invention provides a tile anti-slip agent in a first aspect, which comprises, by weight, 0.1-1 part of a corrosion inhibitor, 30-45 parts of a dispersant, 0.1-1 part of a humectant, 3-10 parts of a surfactant, 0.1-1 part of an anti-aging agent, 10-20 parts of a filler and 40-60 parts of water.
In a preferred embodiment, the dispersant is a high molecular water-based polymer.
In a preferred embodiment, the high molecular water-based polymer includes a water-based resin.
As a preferable technical scheme, the water-based resin is one or more selected from water-based acrylic polyol, cellulose derivative, modified polybutadiene resin, epoxy resin, alkyd resin, amino resin, polyester resin, phenolic resin, polyurethane resin and water-based organic fluorine resin.
As a preferable technical scheme, the humectant is selected from one or more of polyalcohol, modified silicone oil, organic acid, amino acid, pyrrolidone carboxylic acid and lactate.
As a preferable technical solution, the modified silicone oil is one or more selected from amino-modified silicone oil, epoxy-modified silicone oil, alcoholic hydroxyl-modified silicone oil, mercapto-modified silicone oil, carboxyl-modified silicone oil, phenol-modified silicone oil, silanol-modified silicone oil, and carboxylic anhydride-modified silicone oil.
As a preferable technical solution, the epoxy modified silicone oil is one or more selected from epoxy polyether modified silicone oil, epoxy aralkyl modified silicone oil, alicyclic epoxy modified silicone oil, and epoxy branched phenyl modified silicone oil.
In a preferred embodiment, the filler is one or more selected from clay, bentonite, carbon black, silica, titanium dioxide, zirconium dioxide, alumina, graphene, mica powder, boron nitride, aluminum nitride, zinc oxide, carbon nanotubes and carbon nanofibers.
The invention also provides a preparation method of the tile anti-slip agent, which comprises the following steps:
(1) dissolving the corrosion inhibitor in water, and uniformly stirring;
(2) sequentially adding a dispersing agent and a filling agent into the mixed solution obtained in the step (1), and uniformly stirring;
(3) and (3) sequentially adding a humectant, an anti-aging agent and a surfactant into the mixed solution obtained in the step (2), and uniformly stirring to obtain the tile anti-slip agent.
The third aspect of the present invention provides the use of the above tile slip-preventing agent, which can be applied to tiles in hospitals, schools, exhibition halls, hotels, supermarkets, shopping centers, restaurants, gymnasiums, swimming pools, bathrooms, kitchens.
Has the advantages that: the invention provides a tile anti-slip agent, which adopts laureth-5-carboxylic acid as a corrosion inhibitor, adopts vinyl fluoride vinyl ether aqueous resin and aqueous acrylic polyol to compound as a dispersing agent, adopts epoxy polyether modified silicone oil and glycerol as a humectant, and adds nano silicon dioxide and nano silicon dioxide as fillers, thereby improving the anti-slip effect, the anti-pollution property, the glossiness and the stability of cold and heat cycle resistance of the tile anti-slip agent; the anti-slip agent can react with silicate in the ceramic tile to form a large number of nano micropores on the surface of the ceramic tile, so that the lower friction force with the ground is greatly enhanced, and the nano material can be distributed on the surfaces of the micropores to form new friction points, so that the large friction force is increased; the nano micropores formed by the anti-slip agent do not damage the appearance of the ceramic tile, are safe and non-toxic, have excellent stability and durability, and have a long service life.
Detailed Description
The technical features of the technical solutions provided by the present invention are further clearly and completely described below with reference to the specific embodiments, and the scope of protection is not limited thereto.
The term "prepared from …" as used herein is synonymous with "comprising". The terms "comprises," "comprising," "includes," "including," "has," "having," "contains," "containing," or any other variation thereof, as used herein, are intended to cover a non-exclusive inclusion. For example, a composition, process, method, article, or apparatus that comprises a list of elements is not necessarily limited to only those elements but may include other elements not expressly listed or inherent to such composition, process, method, article, or apparatus.
The conjunction "consisting of …" excludes any unspecified elements, steps or components. If used in a claim, the phrase is intended to claim as closed, meaning that it does not contain materials other than those described, except for the conventional impurities associated therewith. When the phrase "consisting of …" appears in a clause of the subject matter of the claims rather than immediately after the subject matter, it defines only the elements described in the clause; other elements are not excluded from the claims as a whole.
When an amount, concentration, or other value or parameter is expressed as a range, preferred range, or as a range of upper preferable values and lower preferable values, this is to be understood as specifically disclosing all ranges formed from any pair of any upper range limit or preferred value and any lower range limit or preferred value, regardless of whether ranges are separately disclosed. For example, when the range "1 to 5" is disclosed, the described range should be construed as including the ranges "1 to 4", "1 to 3", "1 to 2", "2 to 3" and "3 to 4", "4 to 5" and "3 to 5", etc. When a range of values is described herein, unless otherwise stated, the range is intended to include the endpoints thereof and all integers and fractions within the range.
The singular forms "a", "an" and "the" include plural referents unless the context clearly dictates otherwise. "optional" or "any" means that the subsequently described event or events may or may not occur, and that the description includes instances where the event occurs and instances where it does not.
In addition, the indefinite articles "a" and "an" preceding an element or component of the invention are not intended to limit the number requirement (i.e., the number of occurrences) of the element or component. Thus, "a" or "an" should be read to include one or at least one, and the singular form of an element or component also includes the plural unless the stated number clearly indicates that the singular form is intended.
In order to solve the technical problem, the invention provides a tile anti-slip agent in a first aspect, which comprises, by weight, 0.1-1 part of a corrosion inhibitor, 30-45 parts of a dispersant, 0.1-1 part of a humectant, 3-10 parts of a surfactant, 0.1-1 part of an anti-aging agent, 10-20 parts of a filler and 40-60 parts of water.
In a preferred embodiment, the tile anti-slip agent comprises 0.5 part of corrosion inhibitor, 38 parts of dispersing agent, 0.6 part of humectant, 6 parts of surfactant, 0.5 part of anti-aging agent, 15 parts of filler and 50 parts of water in parts by weight.
Corrosion inhibitor
In the present invention, the corrosion inhibitor is a chemical substance or compound that can prevent or slow the corrosion of a material, and thus the corrosion inhibitor may also be referred to as a corrosion inhibitor.
In one embodiment, the corrosion inhibitor is selected from one or more of fluoride salts, nitrate salts, corrosion resistant greases, chromates, propylthioethers, urotropine, acetates, sulfates, polyether carboxylic acids.
In a preferred embodiment, the corrosion inhibitor is a polyether carboxylic acid.
In a preferred embodiment, the polyether carboxylic acid is laureth carboxylic acid.
In a preferred embodiment, the laureth carboxylic acid is selected from one or more of laureth-3-carboxylic acid, laureth-4-carboxylic acid, laureth-5-carboxylic acid, laureth-6-carboxylic acid, laureth-11-carboxylic acid, laureth-13-carboxylic acid.
In a more preferred embodiment, the laureth carboxylic acid is laureth-5 carboxylic acid (CAS number 21127-45-7).
Dispersing agent
In the present invention, the dispersant is a surfactant having two opposite properties of lipophilicity and hydrophilicity in a molecule.
In one embodiment, the dispersant is a high molecular weight aqueous polymer.
In a preferred embodiment, the high molecular weight aqueous polymer comprises an aqueous resin.
In a preferred embodiment, the aqueous resin is selected from one or more of aqueous acrylic polyol, cellulose derivative, modified polybutadiene resin, epoxy resin, alkyd resin, amino resin, polyester resin, phenolic resin, polyurethane resin, and aqueous organic fluorine resin.
In a preferred embodiment, the aqueous resin is a compound of an aqueous organic fluororesin and an aqueous acrylic polyol, and the mass ratio of the aqueous organic fluororesin to the aqueous acrylic polyol is 1: (2-4).
In a preferred embodiment, the aqueous organic fluororesin is selected from one or more of polyvinyl fluoride polymer, polyvinylidene fluoride polymer, vinylidene fluoride/hexafluoropropylene copolymer, tetrafluoroethylene/hexafluoropropylene/vinylidene fluoride copolymer, tetrafluoroethylene/propylene copolymer, tetrafluoroethylene/hexafluoropropylene/propylene copolymer, ethylene/tetrafluoroethylene copolymer, ethylene/chlorotrifluoroethylene copolymer, hexafluoropropylene/tetrafluoroethylene copolymer, perfluoro (alkyl vinyl ether)/tetrafluoroethylene copolymer, vinyl fluoride vinyl ether aqueous resin.
In a preferred embodiment, the aqueous organic fluororesin is a vinyl fluoride vinyl ether aqueous resin.
In a preferred embodiment, the hydroxyl value of the vinyl fluoride vinyl ether aqueous resin is 80 to 90mg KOH/g.
Preferably, the hydroxyl value of the vinyl fluoride vinyl ether aqueous resin is 85mg KOH/g, and the trade mark of the vinyl fluoride vinyl ether aqueous resin is
Purchased from AGC Chemicals americas inc.
In a preferred embodiment, the aqueous acrylic polyol is selected from one or more of Akuapol AL 2200, Akuapol AL 2300, Akuapol AL 2400, Akuapol AL 4500.
Preferably, the aqueous acrylic polyol is Akuapol AL 2200, available from the Polymer technology center of T & L, Inc.
In a preferred embodiment, the mass ratio of the vinyl fluoride vinyl ether aqueous resin to the aqueous acrylic polyol is 1: (2-4).
Preferably, the mass ratio of the vinyl fluoride vinyl ether aqueous resin to the aqueous acrylic polyol is 1: 3.
the inventor of the invention adopts the water-based acrylic polyol to improve the dispersibility of the system and improve the stability of the anti-slip agent, and in addition, the inventor unexpectedly finds that the anti-slip agent adopting the vinyl fluoride vinyl ether water-based resin and the water-based acrylic polyol together also improves the surface gloss of the ceramic tile; and the inventor finds in subsequent researches that when the hydroxyl value of the vinyl fluoride vinyl ether water-based resin is different, the vinyl fluoride vinyl ether water-based resin also has influence on the glossiness and the antifouling property of the anti-skid agent. The inventors found that when the hydroxyl value is 80 to 90mg KOH/g, and the mass ratio to the aqueous acrylic polyol is 1: (2-4) the abrasion resistance and stain resistance are the best, and conversely, the abrasion resistance and stain resistance are reduced; the inventor speculates that the possible reasons are that the hydroxyl value is too large, the compatibility of the hydroxyl value and nano silicon dioxide is good, the difference of the surface energy of the vinyl fluoride vinyl ether aqueous resin is small, a small amount of the vinyl fluoride vinyl ether aqueous resin can be transferred to an interface, and when the hydroxyl value is too low, the compatibility of the vinyl fluoride vinyl ether aqueous resin and acrylic polyol is reduced, the water vapor carried in the process of transferring to the surface is limited, and the leveling is poor.
Moisture-retaining agent
In the invention, the humectant has a special molecular structure and can adsorb and retain water.
In one embodiment, the humectant is selected from one or more of polyhydric alcohols, modified silicone oils, organic acids, amino acids, pyrrolidone carboxylic acid, lactates.
In a preferred embodiment, the humectant is a polyhydric alcohol and a modified silicone oil.
In a preferred embodiment, the polyol is selected from one or more of butylene glycol, butanetriol, maltol, polypropylene glycol, propylene glycol, glycerol, polyethylene glycol, hexylene glycol, xylitol, sorbitol.
Preferably, the polyol is glycerol.
In a preferred embodiment, the modified silicone oil is selected from one or more of amino-modified silicone oil, epoxy-modified silicone oil, alcoholic hydroxyl-modified silicone oil, mercapto-modified silicone oil, carboxyl-modified silicone oil, phenol-modified silicone oil, silanol-modified silicone oil, and carboxylic anhydride-modified silicone oil.
Preferably, the modified silicone oil is epoxy modified silicone oil.
In a preferred embodiment, the epoxy-modified silicone oil is selected from one or more of epoxy polyether-modified silicone oil, epoxy aralkyl-modified silicone oil, alicyclic epoxy-modified silicone oil, and epoxy branched phenyl-modified silicone oil.
Preferably, the epoxy modified silicone oil is epoxy polyether modified silicone oil.
In a preferred embodiment, the epoxy polyether modified silicone oil is present in an amount of less than 0.8 parts by weight.
Preferably, the weight part of the epoxy polyether modified silicone oil is 0.48.
In a preferred embodiment, the epoxy polyether modified silicone oil is KF1002 and/or X-22-4741.
Preferably, the epoxy polyether modified silicone oil is KF1002, available from Jiandao electronics, Inc., Suzhou.
In a preferred embodiment, the humectant is a mixture of glycerin and epoxy polyether modified silicone oil KF1002, and the mass ratio of glycerin to epoxy polyether modified silicone oil KF1002 is 1: 4.
the inventor conjectures that the active sites are formed on the surface of the ceramic tile due to the addition of the epoxy polyether modified silicone oil, the bonding force between the active sites and the ceramic tile is enhanced, and the brightness is increased on the surface of the ceramic tile; the inventor speculates that the titanium dioxide is easy to catalyze the epoxy polyether modified silicone oil and the acrylic polyol to react and partially crosslink, so that the thermal stability of the system is improved, the system is quickly infiltrated into the ceramic tile under the coordination of the rest components, the reaction is promoted, and the weight part of the epoxy polyether modified silicone oil in the components is less than 0.8 to ensure the anti-slip agent effect.
Surface active agent
In the invention, the surfactant is a substance which is added in a small amount and can cause the interface state of a solution system to change obviously.
In one embodiment, the surfactant is selected from one or more of triethanolamine dodecylbenzene sulfonate, sodium isooctyl alcohol sulfate, sodium dodecylbenzene sulfonate, stearic acid, polyethylene glycol ethoxylated fatty acids, ethylene oxide/propylene oxide copolymers, polyoxyethylene castor oil, polyoxyethylene sorbitan fatty acid esters, sodium lauryl sulfate, sodium cetyl sulfate, sodium stearyl sulfate, triethanolamine lauryl sulfate, disodium lauryl polyoxyethylene ether sulfosuccinate, sodium lauryl polyoxyethylene ether sulfate, ammonium lauryl sulfate, and triethanolamine lauryl phosphate.
In a preferred embodiment, the surfactant is a mixture of triethanolamine dodecylbenzene sulfonate and sodium isooctyl sulfate.
In a preferred embodiment, the mass ratio of the triethanolamine dodecylbenzene sulfonate to the sodium isooctyl sulfate is (5-10): 1.
preferably, the mass ratio of the triethanolamine dodecylbenzene sulfonate (CAS number 27323-41-7) to the sodium isooctanol sulfate (CAS number 126-92-1) is 8: 1.
anti-aging agent
In the present invention, the anti-aging agent is a substance capable of delaying the aging of the polymer compound.
In one embodiment, the antioxidant is selected from one or more of a ketoamine antioxidant, a p-phenylenediamine antioxidant, a thiourea antioxidant, a phenol antioxidant, and a carbonate.
The ketoamine antioxidant includes but is not limited to any one of antioxidant A and antioxidant D.
The p-phenylenediamine anti-aging agent comprises but is not limited to any one of anti-aging agent 4010NA and anti-aging agent 4010.
The thiourea antioxidant comprises but is not limited to any one of di-n-octyl thiourea, di-n-butyl thiourea, tributyl thiourea, dialkyl thiourea, difurfuryl thiourea, 1, 2-ethylene thiourea and diethyl thiourea.
The phenolic antioxidant includes, but is not limited to, any one of antioxidant 264, antioxidant BHT, antioxidant 2246, and antioxidant 425.
The carbonate includes but is not limited to any one of potassium carbonate, sodium carbonate and ammonium carbonate.
In a preferred embodiment, the antioxidant agent is a carbonate.
In view of the technical effect of the present invention, the antioxidant is preferably potassium carbonate.
Filler
In the invention, the filler (English name) is also named as filler, additive and filler, and the filler is added into the material to improve the material performance, or can increase the volume and weight and reduce the material cost.
In one embodiment, the filler is selected from one or more of clay, bentonite, carbon black, silica, titanium dioxide, zirconium dioxide, alumina, graphene, mica powder, boron nitride, aluminum nitride, zinc oxide, carbon nanotubes, and carbon nanofibers.
In a preferred embodiment, the fillers are silica and titania.
In a preferred embodiment, the silica is selected from one or more of diatomaceous earth, precipitated silica, fumed silica, nanosilica.
Preferably, the silica is nanosilica.
In a preferred embodiment, the nanosilica has a particle size of 10-35 nm.
Preferably, the nano silicon dioxide has the particle size of 10-20nm and the mark of VK-S01B, and is purchased from Hangzhou Tengjing new materials Co.
In a preferred embodiment, the titanium dioxide is nano titanium dioxide.
In a preferred embodiment, the nano titanium dioxide is rutile type nano titanium dioxide and/or anatase type nano titanium dioxide.
Preferably, the nano titanium dioxide is rutile type nano titanium dioxide.
In a preferred embodiment, the particle size of the rutile type nano titanium dioxide is 10-50 nm.
Preferably, the rutile type nano titanium dioxide has the particle size of 25-35nm and the mark of VK-T25, and is purchased from Hangzhou Wanjing new material Co.
In a preferred embodiment, the mass ratio of the nano silicon dioxide to the nano titanium dioxide is 1: (0.6-1).
Preferably, the mass ratio of the nano silicon dioxide to the nano titanium dioxide is 1: 0.8.
in the invention, the surface friction and polishing effect are improved by adopting the nano silicon dioxide and the nano titanium dioxide in the system, but the area for adsorbing pollutants is increased, and the pollution resistance is reduced, but the inventor finds that when the mass ratio of the nano silicon dioxide to the nano titanium dioxide is 1: (0.6-1) the addition of the corrosion inhibitor laureth-5 carboxylic acid resulted in a significant improvement in stain resistance, presumably because it readily hydrophobically associates in water and the carboxyl group readily associates with Ti4+Coordination, titanium dioxide is wrapped in the ceramic tile, an inner hydrophilic and outer hydrophobic structure is formed, the space repellency is better, the loss of the titanium dioxide is reduced, and in addition, the inventor finds that the ceramic tile has better oil stain removing effect particularly, so the ceramic tile is very suitable for treating kitchen tiles.
The invention also provides a preparation method of the tile anti-slip agent, which comprises the following steps:
(1) dissolving the corrosion inhibitor in water, and uniformly stirring;
(2) sequentially adding a dispersing agent and a filling agent into the mixed solution obtained in the step (1), and uniformly stirring;
(3) and (3) sequentially adding a humectant, an anti-aging agent and a surfactant into the mixed solution obtained in the step (2), and uniformly stirring to obtain the tile anti-slip agent.
The third aspect of the present invention provides the use of the above tile slip-preventing agent, which can be applied to tiles in hospitals, schools, exhibition halls, hotels, supermarkets, shopping centers, restaurants, gymnasiums, swimming pools, bathrooms, kitchens.
The present invention will be specifically described below by way of examples. It should be noted that the following examples are only for illustrating the present invention and should not be construed as limiting the scope of the present invention, and that the insubstantial modifications and adaptations of the present invention by those skilled in the art based on the above disclosure are still within the scope of the present invention.
In addition, the starting materials used are all commercially available, unless otherwise specified.
Examples
Example 1
Embodiment 1 provides a tile anti-slip agent, which comprises, by weight, 0.1 part of a corrosion inhibitor, 30 parts of a dispersant, 0.1 part of a humectant, 3 parts of a surfactant, 0.1 part of an anti-aging agent, 10 parts of a filler and 40 parts of water;
the corrosion inhibitor is laureth-5 carboxylic acid (CAS number is 21127-45-7);
the dispersing agent is a compound of vinyl fluoride vinyl ether water-based resin and water-based acrylic polyol, and the mass ratio of the vinyl fluoride vinyl ether water-based resin to the water-based acrylic polyol is 1: 2; the grade of the vinyl fluoride vinyl ether water-based resin is
Hydroxyl number 85mg KOH/g, purchased from AGC Chemicals americas inc; the waterborne acrylic polyol is available under the trademark Akuapol AL 2200 and is purchased from T&L ltd polymer technology center;
the humectant is a compound of glycerol and epoxy polyether modified silicone oil, and the mass ratio of the glycerol to the epoxy polyether modified silicone oil is 1: 4; the epoxy polyether modified silicone oil is KF1002, and is purchased from Suzhou Jiandao electronics Co., Ltd;
the surfactant is a compound of triethanolamine dodecyl benzene sulfonate (CAS number 27323-41-7) and isooctyl alcohol sodium sulfate (CAS number 126-92-1), and the mass ratio of the triethanolamine dodecyl benzene sulfonate to the isooctyl alcohol sodium sulfate is 5: 1;
the anti-aging agent is potassium carbonate;
the filler is a compound of nano silicon dioxide and nano titanium dioxide, and the mass ratio of the nano silicon dioxide to the nano titanium dioxide is 1: 0.6; the particle size of the nano silicon dioxide is 10-20nm, the mark is VK-S01B, and the nano silicon dioxide is purchased from Hangzhou Tengjing new material company; the nano titanium dioxide is rutile type nano titanium dioxide, the particle size of the rutile type nano titanium dioxide is 25-35nm, the mark is VK-T25, and the rutile type nano titanium dioxide is purchased from Hangzhou Wanjing new material company Limited.
The preparation method of the tile anti-slip agent comprises the following steps:
(1) dissolving the corrosion inhibitor in water, and uniformly stirring;
(2) sequentially adding a dispersing agent and a filling agent into the mixed solution obtained in the step (1), and uniformly stirring;
(3) and (3) sequentially adding a humectant, an anti-aging agent and a surfactant into the mixed solution obtained in the step (2), and uniformly stirring to obtain the tile anti-slip agent.
Example 2
Embodiment 2 provides a tile anti-slip agent, which comprises, by weight, 1 part of a corrosion inhibitor, 45 parts of a dispersant, 1 part of a humectant, 10 parts of a surfactant, 1 part of an anti-aging agent, 20 parts of a filler, and 60 parts of water;
the corrosion inhibitor is laureth-5 carboxylic acid (CAS number is 21127-45-7);
the dispersing agent is a compound of vinyl fluoride vinyl ether water-based resin and water-based acrylic polyol, and the mass ratio of the vinyl fluoride vinyl ether water-based resin to the water-based acrylic polyol is 1: 4; the grade of the vinyl fluoride vinyl ether water-based resin is
Hydroxyl number 85mg KOH/g, purchased from AGC Chemicals America Inc; the waterborne acrylic polyol is available under the trademark Akuapol AL 2200 and is purchased from T&L ltd polymer technology center;
the humectant was the same as in example 1;
the surfactant is a compound of triethanolamine dodecyl benzene sulfonate (CAS number 27323-41-7) and isooctyl alcohol sodium sulfate (CAS number 126-92-1), and the mass ratio of the triethanolamine dodecyl benzene sulfonate to the isooctyl alcohol sodium sulfate is 10: 1;
the anti-aging agent is potassium carbonate;
the filler is a compound of nano silicon dioxide and nano titanium dioxide, and the mass ratio of the nano silicon dioxide to the nano titanium dioxide is 1: 1; the particle size of the nano silicon dioxide is 10-20nm, the mark is VK-S01B, and the nano silicon dioxide is purchased from Hangzhou Tengjing new material company; the nano titanium dioxide is rutile type nano titanium dioxide, the particle size of the rutile type nano titanium dioxide is 25-35nm, the mark is VK-T25, and the rutile type nano titanium dioxide is purchased from Hangzhou Wanjing new material company Limited.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Example 3
Embodiment 3 provides a tile anti-slip agent, which comprises, by weight, 0.5 part of a corrosion inhibitor, 38 parts of a dispersant, 0.6 part of a humectant, 6 parts of a surfactant, 0.5 part of an anti-aging agent, 15 parts of a filler and 50 parts of water;
the corrosion inhibitor is laureth-5 carboxylic acid (CAS number is 21127-45-7);
the dispersant is vinyl fluoride vinyl ether water-based resin and water-based propyleneThe compound of acid polyol, and the mass ratio of the vinyl fluoride vinyl ether aqueous resin to the aqueous acrylic polyol is 1: 3; the grade of the vinyl fluoride vinyl ether water-based resin is
Hydroxyl number 85mg KOH/g, purchased from AGC Chemicals America Inc; the waterborne acrylic polyol is available under the trademark Akuapol AL 2200 and is purchased from T&L ltd polymer technology center;
the humectant was the same as in example 1;
the surfactant is a compound of triethanolamine dodecyl benzene sulfonate (CAS number 27323-41-7) and isooctyl alcohol sodium sulfate (CAS number 126-92-1), and the mass ratio of the triethanolamine dodecyl benzene sulfonate to the isooctyl alcohol sodium sulfate is 8: 1;
the anti-aging agent is potassium carbonate;
the filler is a compound of nano silicon dioxide and nano titanium dioxide, and the mass ratio of the nano silicon dioxide to the nano titanium dioxide is 1: 0.8; the particle size of the nano silicon dioxide is 10-20nm, the mark is VK-S01B, and the nano silicon dioxide is purchased from Hangzhou Tengjing new material company; the nano titanium dioxide is rutile type nano titanium dioxide, the particle size of the rutile type nano titanium dioxide is 25-35nm, the mark is VK-T25, and the rutile type nano titanium dioxide is purchased from Hangzhou Wanjing new material company Limited.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Example 4
Embodiment 4 provides a tile anti-slip agent, which comprises, by weight, 0.5 part of a corrosion inhibitor, 38 parts of a dispersant, 0.6 part of a humectant, 6 parts of a surfactant, 0.5 part of an anti-aging agent, 15 parts of a filler, and 50 parts of water;
the corrosion inhibitor is laureth-5 carboxylic acid (CAS number is 21127-45-7);
the dispersing agent is a compound of vinyl fluoride vinyl ether water-based resin and water-based acrylic polyol, and the mass ratio of the vinyl fluoride vinyl ether water-based resin to the water-based acrylic polyol is 1: 3; the vinyl fluorideThe vinyl ether water-based resin has the mark number of
Hydroxyl number 52mg KOH/g, purchased from AGC Chemicals America Inc; the waterborne acrylic polyol is available under the trademark Akuapol AL 2200 and is purchased from T&L ltd polymer technology center;
the humectant was the same as in example 1;
the surfactant was the same as in example 3;
the anti-aging agent is potassium carbonate;
the filler was the same as in example 3.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Example 5
Embodiment 5 provides a tile anti-slip agent, which comprises, by weight, 0.5 part of a corrosion inhibitor, 38 parts of a dispersant, 0.6 part of a humectant, 6 parts of a surfactant, 0.5 part of an anti-aging agent, 15 parts of a filler, and 50 parts of water;
the corrosion inhibitor is laureth-5 carboxylic acid (CAS number is 21127-45-7);
the dispersing agent is a compound of vinyl fluoride vinyl ether water-based resin and water-based acrylic polyol, and the mass ratio of the vinyl fluoride vinyl ether water-based resin to the water-based acrylic polyol is 1: 0.1; the grade of the vinyl fluoride vinyl ether water-based resin is
Hydroxyl number 85mg KOH/g, purchased from AGC Chemicals America Inc; the waterborne acrylic polyol is available under the trademark Akuapol AL 2200 and is purchased from T&L ltd polymer technology center;
the humectant was the same as in example 1;
the surfactant was the same as in example 3;
the anti-aging agent is potassium carbonate;
the filler was the same as in example 3.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Example 6
Embodiment 6 provides a tile anti-slip agent, which comprises, by weight, 0.5 part of a corrosion inhibitor, 38 parts of a dispersant, 0.6 part of a humectant, 6 parts of a surfactant, 0.5 part of an anti-aging agent, 15 parts of a filler, and 50 parts of water;
the corrosion inhibitor is laureth-5 carboxylic acid (CAS number is 21127-45-7);
the dispersing agent is a compound of vinyl fluoride vinyl ether water-based resin and water-based acrylic polyol, and the mass ratio of the vinyl fluoride vinyl ether water-based resin to the water-based acrylic polyol is 1: 10; the grade of the vinyl fluoride vinyl ether water-based resin is
Hydroxyl number 85mg KOH/g, purchased from AGC Chemicals America Inc; the waterborne acrylic polyol is available under the trademark Akuapol AL 2200 and is purchased from T&L ltd polymer technology center;
the humectant was the same as in example 1;
the surfactant was the same as in example 3;
the anti-aging agent is potassium carbonate;
the filler was the same as in example 3.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Example 7
Embodiment 7 provides a tile anti-slip agent, which comprises, by weight, 0.5 part of a corrosion inhibitor, 38 parts of a dispersant, 0.6 part of a humectant, 6 parts of a surfactant, 0.5 part of an anti-aging agent, 15 parts of a filler, and 50 parts of water;
the corrosion inhibitor is laureth-5 carboxylic acid (CAS number is 21127-45-7);
the dispersant is water-based acrylic polyol with the mark of Akuapol AL 2200 and is purchased from the polymer technology center of T & L company Limited;
the humectant was the same as in example 1;
the surfactant was the same as in example 3;
the anti-aging agent is potassium carbonate;
the filler was the same as in example 3.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Example 8
Embodiment 8 provides a tile anti-slip agent, which comprises, by weight, 0.5 part of a corrosion inhibitor, 38 parts of a dispersant, 0.6 part of a humectant, 6 parts of a surfactant, 0.5 part of an anti-aging agent, 15 parts of a filler, and 50 parts of water;
the corrosion inhibitor is laureth-5 carboxylic acid (CAS number is 21127-45-7);
the dispersant is vinyl fluoride vinyl ether water-based resin with the brand number of
Hydroxyl number 85mg KOH/g, purchased from AGC Chemicals America Inc;
the humectant was the same as in example 1;
the surfactant was the same as in example 3;
the anti-aging agent is potassium carbonate;
the filler was the same as in example 3.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Example 9
Embodiment 9 provides a tile anti-slip agent, which comprises, by weight, 0.5 part of a corrosion inhibitor, 5 parts of a dispersant, 0.6 part of a humectant, 6 parts of a surfactant, 0.5 part of an anti-aging agent, 15 parts of a filler, and 50 parts of water;
the corrosion inhibitor is laureth-5 carboxylic acid (CAS number is 21127-45-7);
the dispersant was the same as in example 3;
the humectant was the same as in example 1;
the surfactant was the same as in example 3;
the anti-aging agent is potassium carbonate;
the filler was the same as in example 3.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Example 10
Embodiment 10 provides a tile anti-slip agent, which comprises, by weight, 0.5 part of a corrosion inhibitor, 38 parts of a dispersant, 5 parts of a humectant, 6 parts of a surfactant, 0.5 part of an anti-aging agent, 15 parts of a filler, and 50 parts of water;
the corrosion inhibitor is laureth-5 carboxylic acid (CAS number is 21127-45-7);
the dispersant was the same as in example 3;
the humectant was the same as in example 1;
the surfactant was the same as in example 3;
the anti-aging agent is potassium carbonate;
the filler was the same as in example 3.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Example 11
Embodiment 11 provides a tile anti-slip agent, which comprises, by weight, 0.5 part of a corrosion inhibitor, 38 parts of a dispersant, 0.6 part of a humectant, 6 parts of a surfactant, 0.5 part of an anti-aging agent, 15 parts of a filler, and 50 parts of water;
the corrosion inhibitor is laureth-5 carboxylic acid (CAS number is 21127-45-7);
the dispersant was the same as in example 3;
the humectant is a compound of glycerol and secondary amino modified silicone oil, and the mass ratio of the glycerol to the secondary amino modified silicone oil is 1: 4; the secondary amino modified silicone oil is KF-8004, and is purchased from Suzhou Jiandao electronics Co., Ltd;
the surfactant was the same as in example 3;
the anti-aging agent is potassium carbonate;
the filler was the same as in example 3.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Example 12
Embodiment 12 provides a tile anti-slip agent, which comprises, by weight, 0.5 part of a corrosion inhibitor, 38 parts of a dispersant, 0.6 part of a humectant, 6 parts of a surfactant, 0.5 part of an anti-aging agent, 15 parts of a filler, and 50 parts of water;
the corrosion inhibitor is laureth-5 carboxylic acid (CAS number is 21127-45-7);
the dispersant was the same as in example 3;
the humectant is glycerin;
the surfactant was the same as in example 3;
the anti-aging agent is potassium carbonate;
the filler was the same as in example 3.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Example 13
Embodiment 13 provides a tile anti-slip agent, which comprises, by weight, 0.5 part of a corrosion inhibitor, 38 parts of a dispersant, 0.6 part of a humectant, 6 parts of a surfactant, 0.5 part of an anti-aging agent, 15 parts of a filler, and 50 parts of water;
the corrosion inhibitor is laureth-5 carboxylic acid (CAS number is 21127-45-7);
the dispersant was the same as in example 3;
the humectant is secondary amino modified silicone oil with the brand number of KF-8004 and is purchased from Suzhou Jiandao electronics Co., Ltd;
the surfactant was the same as in example 3;
the anti-aging agent is potassium carbonate;
the filler was the same as in example 3.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Example 14
Embodiment 14 provides a tile anti-slip agent, which comprises, by weight, 0.5 part of a corrosion inhibitor, 38 parts of a dispersant, 0.6 part of a humectant, 6 parts of a surfactant, 0.5 part of an anti-aging agent, 15 parts of a filler, and 50 parts of water;
the corrosion inhibitor is laureth-3 carboxylic acid (CAS number is 20858-24-6);
the dispersant was the same as in example 3;
the humectant was the same as in example 1;
the surfactant was the same as in example 3;
the anti-aging agent is potassium carbonate;
the filler was the same as in example 3.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Example 15
Embodiment 15 provides a tile anti-slip agent, which comprises, by weight, 0.5 part of a corrosion inhibitor, 38 parts of a dispersant, 0.6 part of a humectant, 6 parts of a surfactant, 0.5 part of an anti-aging agent, 15 parts of a filler, and 50 parts of water;
the corrosion inhibitor is ammonium fluoride;
the dispersant was the same as in example 3;
the humectant was the same as in example 1;
the surfactant was the same as in example 3;
the anti-aging agent is potassium carbonate;
the filler was the same as in example 3.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Example 16
Embodiment 16 provides a tile anti-slip agent, which comprises, by weight, 0.5 part of a corrosion inhibitor, 38 parts of a dispersant, 0.6 part of a humectant, 6 parts of a surfactant, 0.5 part of an anti-aging agent, 15 parts of a filler, and 50 parts of water;
the corrosion inhibitor is laureth-5 carboxylic acid (CAS number is 21127-45-7);
the dispersant was the same as in example 3;
the humectant was the same as in example 1;
the surfactant was the same as in example 3;
the anti-aging agent is potassium carbonate;
the filler is a compound of nano silicon dioxide and nano titanium dioxide, and the mass ratio of the nano silicon dioxide to the nano titanium dioxide is 1: 0.1; the particle size of the nano silicon dioxide is 10-20nm, the mark is VK-S01B, and the nano silicon dioxide is purchased from Hangzhou Tengjing new material company; the nano titanium dioxide is rutile type nano titanium dioxide, the particle size of the rutile type nano titanium dioxide is 25-35nm, the mark is VK-T25, and the rutile type nano titanium dioxide is purchased from Hangzhou Wanjing new material company Limited.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Example 17
Embodiment 17 provides a tile anti-slip agent, which comprises, by weight, 0.5 part of a corrosion inhibitor, 38 parts of a dispersant, 0.6 part of a humectant, 6 parts of a surfactant, 0.5 part of an anti-aging agent, 15 parts of a filler, and 50 parts of water;
the corrosion inhibitor is laureth-5 carboxylic acid (CAS number is 21127-45-7);
the dispersant was the same as in example 3;
the humectant was the same as in example 1;
the surfactant was the same as in example 3;
the anti-aging agent is potassium carbonate;
the filler is a compound of nano silicon dioxide and nano titanium dioxide, and the mass ratio of the nano silicon dioxide to the nano titanium dioxide is 1: 0.8; the particle size of the nano silicon dioxide is 10-20nm, the mark is VK-S01B, and the nano silicon dioxide is purchased from Hangzhou Tengjing new material company; the nano titanium dioxide is anatase nano titanium dioxide, the particle size of the anatase nano titanium dioxide is 60nm, the mark is VK-TA60, and the anatase nano titanium dioxide is purchased from Hangzhou Wanjing New Material Co.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Example 18
Embodiment 18 provides a tile anti-slip agent, which comprises, by weight, 0.5 part of a corrosion inhibitor, 38 parts of a dispersant, 0.6 part of a humectant, 6 parts of a surfactant, 0.5 part of an anti-aging agent, 15 parts of a filler, and 50 parts of water;
the corrosion inhibitor is laureth-5 carboxylic acid (CAS number is 21127-45-7);
the dispersant was the same as in example 3;
the humectant was the same as in example 1;
the surfactant was the same as in example 3;
the anti-aging agent is potassium carbonate;
the filler is nano silicon dioxide, has the particle size of 10-20nm and the mark of VK-S01B, and is purchased from Hangzhou Tengjing new material Co.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Example 19
Embodiment 19 provides a tile anti-slip agent, which comprises, by weight, 0.5 part of a corrosion inhibitor, 38 parts of a dispersant, 0.6 part of a humectant, 6 parts of a surfactant, 0.5 part of an anti-aging agent, 15 parts of a filler, and 50 parts of water;
the corrosion inhibitor is laureth-5 carboxylic acid (CAS number is 21127-45-7);
the dispersant was the same as in example 3;
the humectant was the same as in example 1;
the surfactant was the same as in example 3;
the anti-aging agent is potassium carbonate;
the filler is nano titanium dioxide, the nano titanium dioxide is rutile type nano titanium dioxide, the particle size is 25-35nm, the mark is VK-T25, and the filler is purchased from Hangzhou Wanjing new material Co.
The preparation method of the tile anti-slip agent is the same as that of example 1.
Performance testing
1. Coefficient of friction: the Marble Polo tiles treated with the tile slip-preventing agents of examples 1-19 were tested according to the JC/T1050-2007 standard for the coefficient of friction of the Marble Polo tiles treated with the tile slip-preventing agents of examples 1-19 in dry and wet states.
2. Gloss: marble Polo tiles treated with the tile slip-resistant agent of examples 1-19 were tested for gloss in the dry state using a gloss tester manufactured by WGG60-E4 Keshi photo electric Instrument Co.
3. Stability: the marcobrass tiles treated by the tile anti-slip agents of examples 1 to 19 were tested for the stability against cold and hot cycles of the marcobrass tiles treated by the tile anti-slip agents of examples 1 to 19 in reference to the test of GB4893.7-2013, and it was observed whether cracking occurred after 30 cycles.
4. Antifouling property: the Marble Polo tiles treated with the tile anti-slip agents of examples 1 to 19 were dipped in ink containing 2 wt% of ink, soaked at 25 ℃ for 24 hours, taken out, left at 25 ℃ for 24 hours, further soaked in pure water at 25 ℃ for 1 hour, and then taken out, and the ink marks on the surfaces of the Marble Polo tiles treated with the tile anti-slip agents of examples 1 to 19 were observed.
Table 1 results of performance testing
The foregoing examples are merely illustrative and serve to explain some of the features of the method of the present invention. The appended claims are intended to claim as broad a scope as is contemplated, and the examples presented herein are merely illustrative of selected implementations in accordance with all possible combinations of examples. Accordingly, it is applicants' intention that the appended claims are not to be limited by the choice of examples illustrating features of the invention. Also, where numerical ranges are used in the claims, subranges therein are included, and variations in these ranges are also to be construed as possible being covered by the appended claims.
Claims (3)
1. The tile anti-slip agent is characterized by comprising, by weight, 0.1-1 part of a corrosion inhibitor, 30-45 parts of a dispersant, 0.1-1 part of a humectant, 3-10 parts of a surfactant, 0.1-1 part of an anti-aging agent, 10-20 parts of a filler and 40-60 parts of water;
the dispersing agent is a compound of water-based organic fluororesin and water-based acrylic polyol, and the mass ratio of the water-based organic fluororesin to the water-based acrylic polyol is 1: (2-4);
the water-based organic fluororesin is vinyl fluoride vinyl ether water-based resin;
the hydroxyl value of the vinyl fluoride vinyl ether water-based resin is 80-90mg KOH/g;
the corrosion inhibitor is laureth-5 carboxylic acid;
the humectant is a mixture of glycerol and epoxy polyether modified organic silicon oil KF1002, and the mass ratio of the glycerol to the epoxy polyether modified organic silicon oil KF1002 is 1: 4;
the filler is nano silicon dioxide and nano titanium dioxide; the mass ratio of the nano silicon dioxide to the nano titanium dioxide is 1: (0.6-1).
2. A method for preparing a tile anti-slip agent according to claim 1, characterized by comprising the steps of:
(1) dissolving the corrosion inhibitor in water, and uniformly stirring;
(2) sequentially adding a dispersing agent and a filling agent into the mixed solution obtained in the step (1), and uniformly stirring;
(3) and (3) sequentially adding a humectant, an anti-aging agent and a surfactant into the mixed solution obtained in the step (2), and uniformly stirring to obtain the tile anti-slip agent.
3. Use of tile slip-resistant agent according to claim 1, wherein the tile slip-resistant agent can be applied to tiles in hospitals, schools, exhibition halls, hotels, supermarkets, shopping centers, restaurants, gymnasiums, swimming pools, bathrooms, kitchens.
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| CN112608718A (en) * | 2021-01-19 | 2021-04-06 | 郑州聚砼汇实业有限公司 | Anti-slip agent |
| CN113403033B (en) * | 2021-07-06 | 2022-04-19 | 上海世卿防滑防护科技有限公司 | Environment-friendly floor anti-slip agent and preparation method thereof |
| CN113388367A (en) * | 2021-07-12 | 2021-09-14 | 四川中信昊鑫建设工程有限公司 | Environment-friendly long-acting anti-slip agent and preparation method thereof |
| CN115851017A (en) * | 2022-11-30 | 2023-03-28 | 上海帷来信息科技有限公司 | Anti-slip agent for ceramic floor tiles and preparation method thereof |
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| WO1993016016A1 (en) * | 1992-02-14 | 1993-08-19 | The Dow Chemical Company | Moisture-resistant aluminum nitride powder and methods of making and using |
| CN107117990A (en) * | 2017-05-25 | 2017-09-01 | 广东青筑科技有限公司 | A kind of antilubricant of ceramic tile surface and preparation method thereof |
| CN110003699A (en) * | 2019-04-17 | 2019-07-12 | 深圳市盛广天下科技有限公司 | A kind of ceramic tile antilubricant that green is harmless |
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| WO1993016016A1 (en) * | 1992-02-14 | 1993-08-19 | The Dow Chemical Company | Moisture-resistant aluminum nitride powder and methods of making and using |
| CN107117990A (en) * | 2017-05-25 | 2017-09-01 | 广东青筑科技有限公司 | A kind of antilubricant of ceramic tile surface and preparation method thereof |
| CN110003699A (en) * | 2019-04-17 | 2019-07-12 | 深圳市盛广天下科技有限公司 | A kind of ceramic tile antilubricant that green is harmless |
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