CN110923010A - Coal staged gasification method and device based on chemical looping combustion - Google Patents
Coal staged gasification method and device based on chemical looping combustion Download PDFInfo
- Publication number
- CN110923010A CN110923010A CN201911262455.XA CN201911262455A CN110923010A CN 110923010 A CN110923010 A CN 110923010A CN 201911262455 A CN201911262455 A CN 201911262455A CN 110923010 A CN110923010 A CN 110923010A
- Authority
- CN
- China
- Prior art keywords
- carbon dioxide
- oxygen carrier
- generate
- coal
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002309 gasification Methods 0.000 title claims abstract description 63
- 239000003245 coal Substances 0.000 title claims abstract description 58
- 238000000034 method Methods 0.000 title claims abstract description 40
- 239000000126 substance Substances 0.000 title claims abstract description 32
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 22
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 151
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 74
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 74
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 73
- 239000001301 oxygen Substances 0.000 claims abstract description 61
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 61
- 239000000571 coke Substances 0.000 claims abstract description 52
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 51
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 42
- 229910052751 metal Inorganic materials 0.000 claims abstract description 37
- 239000002184 metal Substances 0.000 claims abstract description 37
- 239000003546 flue gas Substances 0.000 claims abstract description 27
- 239000001257 hydrogen Substances 0.000 claims abstract description 22
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 22
- 238000010438 heat treatment Methods 0.000 claims abstract description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000007789 gas Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 230000003647 oxidation Effects 0.000 claims abstract description 5
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 5
- 230000009467 reduction Effects 0.000 claims abstract description 5
- 238000006243 chemical reaction Methods 0.000 claims description 47
- 239000000446 fuel Substances 0.000 claims description 16
- 238000003763 carbonization Methods 0.000 claims description 10
- 238000012546 transfer Methods 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 150000002431 hydrogen Chemical class 0.000 claims description 5
- 230000008569 process Effects 0.000 description 21
- 238000005516 engineering process Methods 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 238000000926 separation method Methods 0.000 description 7
- 230000008901 benefit Effects 0.000 description 5
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000011084 recovery Methods 0.000 description 3
- 238000006722 reduction reaction Methods 0.000 description 3
- 239000002918 waste heat Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003034 coal gas Substances 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Industrial Gases (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The invention provides a coal staged gasification method based on chemical looping combustion, which comprises the following steps: s1, heating coal by adopting first heat to generate coke and coke oven gas; s2, heating the coke and the first part of carbon dioxide by using second heat so that the coke and the first part of carbon dioxide react to generate carbon monoxide; s3, reacting part of the carbon monoxide with the oxidation state metal oxygen carrier to generate a second part of carbon dioxide and reduction state metal oxygen carrier; s4, reacting the reduced metal oxygen carrier with hot air to generate an oxidized metal oxygen carrier and high-temperature flue gas; s5, reacting the other part of carbon monoxide with water vapor to generate hydrogen and a third part of carbon dioxide; wherein the first portion of carbon dioxide comprises at least a second portion of carbon dioxide and a third portion of carbon dioxide. On the other hand still provides a coal staged gasification device based on chemical looping combustion.
Description
Technical Field
The invention relates to the technical field of energy power, in particular to a coal staged gasification method and device based on chemical looping combustion.
Background
Compared with gas fuel, coal has the disadvantages of low utilization efficiency, serious pollution and the like, and the high-efficiency clean utilization of the coal can be realized by converting the coal into the gas fuel. Coal gasification, i.e. the process of obtaining coal gas by hot processing coal through a hot carbon layer by a gasification agent. The gasification agent mainly comprises oxygen (air, oxygen-enriched air and pure oxygen), water vapor, hydrogen and carbon dioxide, wherein the water and the pure oxygen are commonly used as the gasification agent for gasification. The coal gasification process is the core of development of coal-based chemical synthesis, liquid alternative fuel synthesis, advanced IGCC power generation systems and poly-generation systems, and is also one of the units with the largest loss of chemical energy in the process of efficient and clean utilization of coal. The low energy utilization efficiency is mainly caused by the fact that the irreversible loss is large due to violent reaction in the gasification process, and the energy consumption of an air separation device required for preparing pure oxygen is high because the pure oxygen is used as a gasification agent. In the existing gasification technology, the gasification cold gas efficiency is about 65-80%.
Chemical looping reforming is a new fuel reforming technology, and oxygen carrier alternately performs oxidation-reduction reaction between air and fuel to realize oxygen transfer and release heat, so that direct contact between air and fuel is avoided. According to the characteristics of the chemical chain conversion technology, the oxygen carrier is utilized to realize the transfer of oxygen between air and coal, so that the coal gasification can be completed while the air separation energy consumption is avoided. The conventional chemical chain conversion technology is suitable for the fuel which is generally gaseous fuel, and if the coal gasification is realized by using the conventional chemical chain conversion technology, the oxygen carrier is required to be in direct contact with solid particles of the coal, so that the solid-solid reaction problem exists. The solid-solid reaction can not realize higher coal conversion rate, and simultaneously also relates to the difficult problems of solid-solid separation, oxygen carrier pollution and the like. Avoiding solid-solid reaction is a main problem to be considered in chemical chain coal gasification.
Disclosure of Invention
Technical problem to be solved
The application provides a coal staged gasification method and device based on chemical looping combustion, which at least solve the technical problems.
(II) technical scheme
The invention provides a coal staged gasification method based on chemical looping combustion, which comprises the following steps: s1, heating coal by adopting first heat to generate coke and coke oven gas; s2, heating the coke and the first part of carbon dioxide by using second heat so that the coke and the first part of carbon dioxide react to generate carbon monoxide; s3, reacting part of the carbon monoxide with the oxidation state metal oxygen carrier to generate a second part of carbon dioxide and reduction state metal oxygen carrier; s4, reacting the reduced metal oxygen carrier with hot air to generate an oxidized metal oxygen carrier and high-temperature flue gas; s5, reacting the other part of carbon monoxide with water vapor to generate hydrogen and a third part of carbon dioxide; wherein the first portion of carbon dioxide comprises at least a second portion of carbon dioxide and a third portion of carbon dioxide.
Optionally, the high temperature flue gas releases the first heat and the second heat.
Optionally, the high temperature flue gas heats the air to generate hot air after releasing the first heat and the second heat.
Optionally, the reaction temperature of part of the carbon monoxide reacting with the oxidized form metal oxygen carrier in step S3 is 1200-1700 ℃.
Optionally, the reaction temperature of the reduced metal oxygen carrier and the hot air in the step S4 is 1100-1500 ℃.
The invention provides a coal grading gasification device based on chemical looping combustion, which comprises: the carbonization unit is used for heating coal by adopting first heat to generate coke and coke oven gas; the coke gasification unit is used for heating the coke and the first part of carbon dioxide by adopting second heat so as to enable the coke and the first part of carbon dioxide to react to generate carbon monoxide; a fuel reaction unit for reacting a portion of the carbon monoxide with the oxidized form of the metal-oxygen carrier to produce a second portion of carbon dioxide and a reduced form of the metal-oxygen carrier; the air reaction unit is used for reacting the reduced metal oxygen carrier with hot air to generate an oxidized metal oxygen carrier and high-temperature flue gas; the shift hydrogen production unit is used for reacting the other part of carbon monoxide with water vapor to generate hydrogen and a third part of carbon dioxide; wherein the first portion of carbon dioxide comprises at least the second portion of carbon dioxide and a third portion of carbon dioxide.
Optionally, the device further comprises a heat transfer unit for releasing the first heat and the second heat from the high-temperature flue gas.
Optionally, the device further comprises an air preheating unit for heating the air to generate hot air after the high-temperature flue gas releases the first heat and the second heat.
Optionally, the reaction temperature of the carbonization unit is 700-1100 ℃.
Optionally, the reaction temperature of the hydrogen conversion unit is 200-400 ℃.
(III) advantageous effects
The chemical chain conversion technology is combined with the coal gasification technology, so that carbon dioxide generated by carbon monoxide chemical chain combustion is used as a non-metallic oxide oxygen carrier, solid-solid reaction between an oxygen carrier and coke in the coal gasification process is avoided, the problems of solid-solid separation and oxygen carrier pollution are solved, the coal gasification efficiency is improved, and the coal gasification device has wide social benefits and industrial application prospects.
Drawings
FIG. 1 schematically illustrates a schematic diagram of the steps of a coal staged gasification method based on chemical looping combustion in an embodiment of the disclosure;
fig. 2 schematically illustrates a flow chart of a coal staged gasification method based on chemical looping combustion in an embodiment of the disclosure.
Detailed Description
The invention provides a coal staged gasification method based on chemical looping combustion, which comprises the following steps of: s1, heating coal by adopting first heat to generate coke and coke oven gas; s2, heating the coke and the first part of carbon dioxide by using second heat so that the coke and the first part of carbon dioxide react to generate carbon monoxide; s3, reacting part of the carbon monoxide with the oxidation state metal oxygen carrier to generate a second part of carbon dioxide and reduction state metal oxygen carrier; s4, reacting the reduced metal oxygen carrier with hot air to generate an oxidized metal oxygen carrier and high-temperature flue gas; s5, reacting the other part of carbon monoxide with water vapor to generate hydrogen and a third part of carbon dioxide; wherein the first portion of carbon dioxide comprises at least a second portion of carbon dioxide and a third portion of carbon dioxide.
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is described in further detail below with reference to the accompanying drawings 1 in conjunction with specific embodiments.
And S1, heating coal by adopting the first heat to generate coke and coke oven gas.
The process can be expressed as a carbonization process of coal, the carbonization and purification of raw material coal can be realized through the process, the required heat can be provided by the following steps S3 and S4, and chemical products such as crude coke, coke oven gas, tar and the like can be obtained. The reaction temperature in the process is preferably 700-1100 ℃, and when the temperature is reduced to 600-900 ℃, the products are coke, coke oven gas, tar and the like. The process can be realized in a heating furnace, a soaking furnace or a calcining furnace in the metallurgical industry.
And S2, heating the coke and the first part of carbon dioxide by using the second heat so that the coke and the first part of carbon dioxide react to generate carbon monoxide.
The process can realize gasification of the coke, the coke obtained in the step S1 reacts with carbon dioxide to generate carbon monoxide, the carbon monoxide can be realized in the coke gasification unit, the hot coke (about 1000 ℃) obtained in the step S1 enters from the top of the coke gasification unit, the carbon dioxide enters from the bottom of the coke gasification unit, the coke and the carbon dioxide meet to generate gasification reaction, the coke is gasified into the carbon monoxide, and the carbon monoxide is discharged from the upper part of the coke gasification unit. The required amount of heat may also be provided by the following steps S3 and S4 processes. The carbon dioxide required for this can be provided at least by steps S3 and S5. The coke gasification reaction temperature is 1100 ℃, and the carbon conversion rate is 95%.
Part of carbon monoxide generated in the process participates in the chemical looping combustion process, and the other part of carbon monoxide participates in the hydrogen conversion process. Wherein, the chemical looping combustion process includes a fuel reaction process and an air reaction process, which can be respectively realized by the following steps S3 and S4. The shift hydrogen production process may be implemented by step S5.
And S3, reacting part of the carbon monoxide with the oxidation state metal oxygen carrier to generate a second part of carbon dioxide and reduction state metal oxygen carrier.
The process is a fuel reaction process in a chemical looping combustion process. A portion of the carbon monoxide produced by the char gasification process reacts with the oxidized form of the metal-oxygen carrier to produce a second portion of carbon dioxide and reduced form of the metal-oxygen carrier. The metal oxygen carrier may be Fe2O3With Fe3O4. The reaction temperature in the fuel reaction process is preferably 1200-1700 ℃.
And S4, reacting the reduced metal oxygen carrier with hot air to generate an oxidized metal oxygen carrier and high-temperature flue gas.
The process is an air reaction process in a chemical looping combustion process. And (4) reacting the reduced metal oxygen carrier obtained in the step (S3) with hot air to generate an oxidized metal oxygen carrier and high-temperature flue gas. After the high temperature flue gas is coarsely dedusted, the heat transfer unit can provide the first heat and the second heat required by steps S1 and S2. The high-temperature flue gas releases the first heat and the second heat and then heats air to generate hot air required by the step, the temperature is about 1050 ℃, and the flue gas is discharged below 200 ℃ after waste heat recovery. The temperature in the air reaction process can be 1100-1500 ℃.
S5, reacting the other part of carbon monoxide with water vapor to generate hydrogen and a third part of carbon dioxide; wherein the first portion of carbon dioxide comprises at least a second portion of carbon dioxide and a third portion of carbon dioxide.
And reacting the other part of carbon monoxide with water vapor to generate hydrogen and a third part of carbon dioxide, separating by using a separation device to obtain carbon dioxide and pure hydrogen, and returning the separated carbon dioxide to the carbon monoxide production process to continuously react with coke. The temperature of the transformation reaction in the transformation hydrogen production process is about 200-400 ℃. The third portion of carbon dioxide participates in step S2 along with the second portion of carbon dioxide generated in step S3. A part of the carbon monoxide generated in step S2 participates in step S3, another part thereof participates in step S5, and a part thereof is outputted as carbon monoxide.
The three gases of coke oven gas, carbon monoxide and hydrogen can be obtained by the process.
The chemical chain conversion technology is combined with the coal gasification technology, and a novel coal gasification mode of 'component alignment and graded conversion' of coal is realized. The carbon dioxide generated by the combustion of the carbon monoxide chemical chain is taken as the oxygen carrier of the non-metallic oxide, so that the solid-solid reaction between the oxygen carrier and the coke in the coal gasification process is avoided, the problems of solid-solid separation and oxygen carrier pollution are avoided, the coal gasification efficiency is improved, and the method has wide social benefits and industrial application prospects.
Another aspect of the present application provides a coal staged gasification device based on chemical looping combustion, as shown in fig. 2, including a carbonization unit 1, a coke gasification unit 2, an air reaction unit 4, a fuel reaction unit 5, and a conversion hydrogen production unit 3, wherein:
the carbonization unit 1 can be implemented, for example, as step S1, for heating coal 10 with a first heat to generate coke 13 and coke oven gas 12. Tar 11 may also be produced.
The char gasification unit 2, for example, may be implemented as step S2 for heating the char 13 and the first portion of carbon dioxide with the second heat to react the char 13 and the first portion of carbon dioxide to generate carbon monoxide. The reaction temperature of the carbonization unit is 700-1100 ℃.
The fuel reaction unit 5 may, for example, be realized as step S3 for reacting a portion of the carbon monoxide 17 with the oxidized form of the metal-oxygen carrier 19 to produce a second portion of carbon dioxide 16 and a reduced form of the metal-oxygen carrier 18.
The air reaction unit 4, for example, can be implemented as step S4, for reacting the reduced metal-oxygen carrier 18 with the hot air 21 to generate the oxidized metal-oxygen carrier 19 and the high temperature flue gas 20.
The shift hydrogen-producing unit 3 may be implemented, for example, as step S5 for reacting another portion of the carbon monoxide 14 with the water vapor 25 to produce hydrogen 24 and a third portion of the carbon dioxide 15. The carbon monoxide 14 reacts with the steam 25 to produce hydrogen 24 and a third portion of carbon dioxide 15.
Wherein the first portion of carbon dioxide comprises at least a second portion of carbon dioxide 16 and a third portion of carbon dioxide 15.
The coal grading gasification device also comprises a heat transfer unit 7 and an air preheating unit 6. The heat transfer unit 7 is used for releasing the first heat and the second heat from the high-temperature flue gas 20, and the air preheating unit 6 is used for heating the air 23 to generate hot air 21 after the first heat and the second heat are released from the high-temperature flue gas 20. By the surface type heat transfer unit 7, the heat loss in the heat transfer process is about 9% of the heat release. The air preheating unit 6 comprises a heat accumulating type waste heat recovery unit and a dividing wall type waste heat recovery unit.
After high-temperature flue gas generated in the chemical looping combustion process is subjected to coarse dust removal, the high-temperature flue gas passes through the heat transfer unit 7 and releases first heat and second heat to the carbonization unit 1 and the coke gasification unit 2 through the partition walls 8 and 9 respectively. The high-temperature flue gas 20 after releasing heat exchanges heat with air 23 in the air preheating unit 6 to obtain low-temperature flue gas 22 and hot air 21, the hot air 21 enters the air reactor 4 to react with the reduced-state metal oxygen carrier 18, and the low-temperature flue gas 22 is directly discharged. The reduced metal oxygen carrier 18 is oxidized into an oxidized metal oxygen carrier 19 in the air reactor 4, the oxidized metal oxygen carrier 19 is separated and then enters the fuel reactor 5 to react with carbon monoxide 17 generated in the coke gasification process to generate the reduced metal oxygen carrier 18 and carbon dioxide 16, wherein the reduced metal oxygen carrier 18 is recycled to the air reactor 4, and the carbon dioxide 16 returns to the coke gasification unit 2 to react with the crude coke 13.
Table 1 shows the energy input and output under the conditions of the examples, wherein the carbon dioxide separation work required by the shift unit is small in proportion due to the large part of the carbon dioxide provided by the chemical looping combustion technique.
TABLE 1
The coal grading gasification method based on chemical chain conversion provided by the application has the advantages that the cold coal gas efficiency can reach 89.8% under the embodiment, the gasification efficiency is 92.7%, and the coal grading gasification method is relatively high in improvement compared with the traditional gasification method.
The above-mentioned embodiments are intended to illustrate the objects, technical solutions and advantages of the present invention in further detail, and it should be understood that the above-mentioned embodiments are only exemplary embodiments of the present invention, and are not intended to limit the present invention, and any modifications, equivalents, improvements and the like made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (10)
1. A coal staged gasification method based on chemical looping combustion comprises the following steps:
s1, heating coal by adopting first heat to generate coke and coke oven gas;
s2, heating the coke and the first part of carbon dioxide by using second heat so as to enable the coke and the first part of carbon dioxide to react to generate carbon monoxide;
s3, reacting part of the carbon monoxide with the oxidation state metal oxygen carrier to generate a second part of carbon dioxide and reduction state metal oxygen carrier;
s4, reacting the reduced metal oxygen carrier with hot air to generate the oxidized metal oxygen carrier and high-temperature flue gas;
s5, reacting another part of the carbon monoxide with water vapor to generate hydrogen and a third part of carbon dioxide;
wherein the first portion of carbon dioxide comprises at least the second portion of carbon dioxide and a third portion of carbon dioxide.
2. The coal staged gasification method of claim 1, the high temperature flue gas releasing the first and second heat.
3. The coal staged gasification method of claim 2, wherein the high temperature flue gas heats air after releasing the first and second heat to generate the hot air.
4. The coal staged gasification method as recited in claim 1, wherein the reaction temperature of the partial carbon monoxide and the oxidized form metal oxygen carrier in step S3 is 1200-1700 ℃.
5. The coal staged gasification method as recited in claim 1, wherein the reaction temperature of the reduced metal oxygen carrier and hot air in step S4 is 1100-1500 ℃.
6. A coal staged gasification device based on chemical looping combustion comprises:
a carbonization unit (1) for heating coal (10) with a first heat to generate coke (13) and coke oven gas (12);
a char gasification unit (2) for heating the char (13) and a first portion of the carbon dioxide with a second heat to react the char (13) and the first portion of the carbon dioxide to produce carbon monoxide;
a fuel reaction unit (5) for reacting a portion of said carbon monoxide (17) with an oxidized form of a metal-oxygen carrier (19) to produce a second portion of carbon dioxide (16) and a reduced form of a metal-oxygen carrier (18);
the air reaction unit (4) is used for reacting the reduced metal oxygen carrier (18) with hot air (21) to generate the oxidized metal oxygen carrier (19) and high-temperature flue gas (20);
a shift hydrogen production unit (3) for reacting another part of the carbon monoxide (14) with water vapor (25) to produce hydrogen (24) and a third part of carbon dioxide (15);
wherein the first portion of carbon dioxide comprises at least the second portion of carbon dioxide (16) and a third portion of carbon dioxide (15).
7. Coal staged gasification device according to claim 6, further comprising a heat transfer unit for the high temperature flue gas (20) to release the first and second heat.
8. Coal staged gasification device according to claim 7, further comprising an air preheating unit (6) for heating air (23) after the high temperature flue gas (20) releases the first and second heat to generate the hot air (21).
9. The coal staged gasification device of claim 6, wherein the reaction temperature of the carbonization unit (1) is 700-1100 ℃.
10. The coal staged gasification device of claim 6, wherein the reaction temperature of the hydrogen conversion and production unit (3) is 200-400 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911262455.XA CN110923010A (en) | 2019-12-10 | 2019-12-10 | Coal staged gasification method and device based on chemical looping combustion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911262455.XA CN110923010A (en) | 2019-12-10 | 2019-12-10 | Coal staged gasification method and device based on chemical looping combustion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110923010A true CN110923010A (en) | 2020-03-27 |
Family
ID=69858801
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911262455.XA Pending CN110923010A (en) | 2019-12-10 | 2019-12-10 | Coal staged gasification method and device based on chemical looping combustion |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110923010A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116119610A (en) * | 2023-01-11 | 2023-05-16 | 北京理工大学 | Hydrogen production system and method by four-step coal gasification and solar thermochemical coupling |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1298926A (en) * | 1999-11-04 | 2001-06-13 | 株式会社日立制作所 | Process and system for prodn. of hydrogen/carbon mono oxide mixture, and fuel/electric power combination installation |
| CN201309913Y (en) * | 2008-11-05 | 2009-09-16 | 张鹏 | Device for producing and heating carbonic fuel gasifying agent |
| CN101774542A (en) * | 2010-03-04 | 2010-07-14 | 华北电力大学 | Biomass gasification hydrogen-producing system and method |
| CN103060012A (en) * | 2012-12-29 | 2013-04-24 | 中国科学院工程热物理研究所 | Gasification method for classification conversion of hydrocarbon components of coal |
| CN203096004U (en) * | 2012-12-29 | 2013-07-31 | 中国科学院工程热物理研究所 | Power generation system based on classification and transformation of hydrocarbon components of coal |
| CN103758592A (en) * | 2014-01-22 | 2014-04-30 | 中国科学院工程热物理研究所 | CO2 gas coke chemical-looping combustion power generating system and method |
| CN104848207B (en) * | 2015-04-07 | 2017-09-01 | 东南大学 | The chemical chain combustion apparatus and its method of a kind of solid fuel classification oxidation |
| KR20180034033A (en) * | 2016-09-27 | 2018-04-04 | 청우에이스(주) | System for gasification of biomass, gasification process using thereof and power system using thereof |
-
2019
- 2019-12-10 CN CN201911262455.XA patent/CN110923010A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1298926A (en) * | 1999-11-04 | 2001-06-13 | 株式会社日立制作所 | Process and system for prodn. of hydrogen/carbon mono oxide mixture, and fuel/electric power combination installation |
| CN201309913Y (en) * | 2008-11-05 | 2009-09-16 | 张鹏 | Device for producing and heating carbonic fuel gasifying agent |
| CN101774542A (en) * | 2010-03-04 | 2010-07-14 | 华北电力大学 | Biomass gasification hydrogen-producing system and method |
| CN103060012A (en) * | 2012-12-29 | 2013-04-24 | 中国科学院工程热物理研究所 | Gasification method for classification conversion of hydrocarbon components of coal |
| CN203096004U (en) * | 2012-12-29 | 2013-07-31 | 中国科学院工程热物理研究所 | Power generation system based on classification and transformation of hydrocarbon components of coal |
| CN103758592A (en) * | 2014-01-22 | 2014-04-30 | 中国科学院工程热物理研究所 | CO2 gas coke chemical-looping combustion power generating system and method |
| CN104848207B (en) * | 2015-04-07 | 2017-09-01 | 东南大学 | The chemical chain combustion apparatus and its method of a kind of solid fuel classification oxidation |
| KR20180034033A (en) * | 2016-09-27 | 2018-04-04 | 청우에이스(주) | System for gasification of biomass, gasification process using thereof and power system using thereof |
Non-Patent Citations (1)
| Title |
|---|
| 施湛青: "《无机物工艺学》", 31 December 1997 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116119610A (en) * | 2023-01-11 | 2023-05-16 | 北京理工大学 | Hydrogen production system and method by four-step coal gasification and solar thermochemical coupling |
| CN116119610B (en) * | 2023-01-11 | 2024-05-28 | 北京理工大学 | Hydrogen production system and method by four-step coal gasification and solar thermochemical coupling |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102850172B (en) | Coal chemical poly-generation process and system | |
| CN103060012B (en) | Gasification method for classification conversion of hydrocarbon components of coal | |
| CN102965131B (en) | Efficient and clean utilization technology for highly volatile young coal | |
| CN101397122A (en) | Polygenerations systeme | |
| CN105567898A (en) | Reformed gas-based reduction method with return of the waste reduction gases and decarbonisation of the waste gas component used as combustion gas for the reformer | |
| RU2011125340A (en) | METHOD AND DEVICE FOR PRODUCING RAW SYNTHESIS GAS | |
| US20230219811A1 (en) | Looping Reaction Hydrogen Production System and Hydrogen Production Method | |
| RU2532757C2 (en) | Method of reduction based on reforming-gas with reduced nox emissions | |
| CN107880938B (en) | Preheating type staged gasification method and device | |
| CN103045308B (en) | Power generation method and system based on step conversion of hydrocarbon components of coal | |
| CN112662830A (en) | Method for pre-heat exchanging hydrogen by utilizing direct reduction iron furnace top gas | |
| CN110923010A (en) | Coal staged gasification method and device based on chemical looping combustion | |
| CN109735369A (en) | A kind of petroleum coke chemical chain gasification produces the device and method of sulphur | |
| US9631553B2 (en) | Process and equipment for coal gasification, and power generation system and power generation process thereof | |
| CN106241735B (en) | A kind of carbide slag prepares the system and method for hydrogen-rich gas and calcium carbide | |
| CN109233910B (en) | System and method for preparing hydrogen from coal based on chemical chain technology | |
| CN216445007U (en) | High-temperature raw gas non-catalytic partial oxidation direct reforming system | |
| CN110923011A (en) | Coal grading conversion gasification method and device | |
| CN113955718B (en) | Direct reforming process and system for non-catalytic partial oxidation of high-temperature raw gas | |
| CN114752418A (en) | Coal quality-based utilization system and process for realizing zero carbon emission | |
| CN107164594A (en) | A kind of BGL gasifying gas produces the system and method for DRI through dual turn over metaplasia | |
| CN116119610B (en) | Hydrogen production system and method by four-step coal gasification and solar thermochemical coupling | |
| CN108302953B (en) | Industrial high-temperature solid bulk waste heat recovery system and method | |
| CN112662824A (en) | Blast furnace hydrogen-rich smelting process for efficiently utilizing metallurgical waste gas | |
| CN101696361B (en) | High-pressure powdered coal gasifier with back-heating system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200327 |
|
| RJ01 | Rejection of invention patent application after publication |