CN110911713A - Aeration humidifying device for high-power fuel cell - Google Patents

Aeration humidifying device for high-power fuel cell Download PDF

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Publication number
CN110911713A
CN110911713A CN201911367691.8A CN201911367691A CN110911713A CN 110911713 A CN110911713 A CN 110911713A CN 201911367691 A CN201911367691 A CN 201911367691A CN 110911713 A CN110911713 A CN 110911713A
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China
Prior art keywords
aeration
closed container
fuel cell
water
water pump
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Pending
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CN201911367691.8A
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Chinese (zh)
Inventor
高鹏
董义文
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Dalian Sharp Amperex Technology Ltd
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Dalian Sharp Amperex Technology Ltd
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Priority to CN201911367691.8A priority Critical patent/CN110911713A/en
Publication of CN110911713A publication Critical patent/CN110911713A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04119Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
    • H01M8/04126Humidifying
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

The invention relates to an aeration humidifying device of a high-power fuel cell, belonging to the field of fuel cells. The main technical scheme is as follows: a high-power fuel cell aeration humidifying device comprises a closed container, a drain pipe, a circulating water pump, an electric heater, a temperature controller, a check valve and an air outlet pipe; the device is characterized in that a water sprayer, an upper filler, a lower filler and an aeration device are arranged in the closed container from top to bottom, the lower filler and the aeration device are placed in deionized water, the aeration device is connected with an air inlet pipe, a water replenishing control valve, a circulating water pump and a water drain pipe are connected below the closed container, the circulating water pump, an electric heater and a check valve are sequentially connected to form a loop, and an air outlet pipe is connected above the closed container. The invention can make the reaction gas reach the required temperature and humidity quickly, and the aeration humidifying device is constructed by utilizing the conventional devices, thus having good economical efficiency.

Description

Aeration humidifying device for high-power fuel cell
Technical Field
The invention relates to the field of fuel cells, in particular to a high-power fuel cell aeration humidifying device.
Background
Fuel cells are clean, efficient, and long-lived power generation devices. Compared with the conventional power generation technology, the fuel cell has great advantages in the aspects of efficiency, safety, reliability, flexibility, cleanness, operating performance and the like, and has a very wide application prospect. As one of the fuel cells, the proton exchange membrane fuel cell also has the advantages of low operation temperature, high specific energy, long service life, high response speed, no electrolyte leakage and the like, and has good application prospects in the aspects of national defense, energy, traffic, environmental protection, communication and the like. Humidity control of cathode inlet air (air) is one of the most important links in the operation of pem fuel cells.
In the current practical application, the humidifiers for humidifying the reaction gas of the fuel cell are mainly the following, namely the membrane humidifier: humidifying the gas by diffusion of moisture in the membrane; enthalpy wheel humidifier: humidifying through enthalpy wheel dry-wet conversion; spraying and humidifying: heating and spraying reaction gas; bubbling and humidifying: the reaction gas is humidified by a vessel containing heated liquid water and glass beads at the bottom.
The membrane humidifier has the characteristics of compact structure, low pressure drop and the like, and the typical structure of the membrane humidifier comprises a wet plate, a polymer membrane, a diffusion layer and a dry plate, wherein a flow channel on the dry plate is used for circulating and humidifying dry gas, and a humidifying channel is arranged on the wet plate. The membrane material is permeable to water but not to air, and has one side in contact with the wet plate and the other side provided with a diffusion layer made of an elastic, electrically conductive, air permeable material. However, the membrane humidifier has the problems of sealing and pressure bearing, because the polymer membrane swells when meeting water, and the membrane repeatedly swells and shrinks between a dry state and a wet state, so that the membrane can be separated from a sealing surface, and leakage can occur; in addition, the polymer film is an organic material, is easily deformed, has poor pressure resistance, and may be broken by air pressure during use.
The heating and humidifying means that the reaction gas is humidified by a water temperature control bubbler, which is also called bubbling and humidifying; the bubbler is a container filled with liquid water and glass beads at the bottom, the inlet gas is directly communicated to the bottom of the container through a straight pipe, and is contacted with a small ball capable of increasing the evaporation area, and finally, the nearly saturated gas is discharged through another pipeline on the liquid surface. The humidifying method has the advantages that the equipment is simple and convenient, high humidity can be obtained at a small flow, the temperature and the humidity are difficult to accurately control, the humidifying cannot timely and synchronously respond to the battery when the battery is quickly started or the load is suddenly and greatly changed, and in addition, excessive liquid water is brought out after the gas is bubbled through the water container at a large flow, so that the liquid water at the outlet of the water lifting container is accumulated.
Disclosure of Invention
The invention provides an aeration humidifying device for a high-power fuel cell, aiming at solving the problem that a bubbling humidifier for the fuel cell is difficult to be used for the high-power fuel cell. The main technical scheme is as follows: a high-power fuel cell aeration humidifying device comprises a closed container, a drain pipe, a circulating water pump, an electric heater, a temperature controller, a check valve and an air outlet pipe;
the device is characterized in that a water sprayer, an upper filler, a lower filler and an aeration device are arranged in the closed container from top to bottom, the lower filler and the aeration device are arranged in deionized water, the aeration device is connected with an air inlet pipe, a water supplementing control valve, a circulating water pump and a water discharge pipe are connected below the closed container, the circulating water pump, an electric heater and a check valve are sequentially connected to form a loop, an air outlet pipe is connected above the closed container, the water supplementing control valve is connected with the closed container through a liquid level meter, and the electric heater is connected with a temperature controller.
Further, the material of the upper filler and the lower filler is fiber, metal sintered, graphite or ceramic.
Furthermore, the drain pipe is a waste liquid discharge port.
The invention has the following beneficial effects:
1) the invention can make the reaction gas quickly reach the required temperature and humidity;
2) the aeration humidifying device skillfully utilizes the conventional devices to construct, so that the economy is good;
3) the invention solves the problem that the aeration humidification can be used for humidifying the reaction gas of the high-power fuel cell.
Drawings
FIG. 1 is a schematic structural view of the present invention;
wherein: 1. the device comprises a closed container, 2 parts of upper packing, 3 parts of a liquid level meter, 4 parts of an air inlet pipe, 5 parts of a water supplementing control valve, 6 parts of a water outlet pipe, 7 parts of a circulating water pump, 8 parts of an electric heater, 9 parts of a temperature sensor, 10 parts of a check valve, 11 parts of an air outlet pipe, 12 parts of a water shower, 13 parts of lower packing, 14 parts of an aeration device, 15 parts of deionized water.
Detailed Description
The invention will be further explained and explained with reference to the drawings.
As shown in fig. 1, the aeration and humidification device for the high-power fuel cell comprises a closed container 1, a drain pipe 6, a circulating water pump 7, an electric heater 8, a temperature controller 9, a check valve 10 and an air outlet pipe 11; a water sprayer 12, an upper filler 2, a lower filler 13 and an aeration device 14 are arranged in the closed container 1 from top to bottom, the lower filler 13 and the aeration device 14 are placed in deionized water 15, the aeration device 14 is connected with an air inlet pipe 4, a water supplementing control valve 5, a circulating water pump 7 and a water discharge pipe 6 are connected below the closed container 1, the circulating water pump 7, an electric heater 8 and a check valve 10 are sequentially connected to form a loop, an air outlet pipe 11 is connected above the closed container 1, the water supplementing control valve 5 is connected with the closed container 1 through a liquid level meter 3, and the electric heater 8 is connected with a temperature controller 9. The upper filler 2 and the lower filler 13 are made of fibers. The drain pipe 6 is a waste liquid discharge port.
The using method of the invention is as follows: hydrogen or air as a reaction gas of the fuel cell enters the closed container 1 through the air inlet pipe 4, enters the deionized water 15 after being aerated by the aeration device 14 for humidification and heat exchange, further humidifies and exchanges heat through the deionized water 15 in the lower packing 13 and the upper packing 2, and then is discharged through the air outlet pipe 11 after reaching the temperature and humidity requirements. The deionized water 15 is provided with circulating power by the circulating water pump 7, heated by the electric heater 8, the temperature of the deionized water 15 heated by the electric heater 8 is controlled by the temperature controller 9, the heated deionized water 15 enters the closed container 1 through the check valve 10, is uniformly sprayed to the upper filler 2 through the water sprayer 12, and flows to the lower part of the closed container 1 after wetting the upper filler 2.
The foregoing examples are provided for illustration and description of the invention only and are not intended to limit the invention to the scope of the described examples. Furthermore, it will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, and that many variations and modifications may be made in accordance with the teachings of the present invention, which variations and modifications are within the scope of the present invention as claimed.

Claims (3)

1. The high-power fuel cell aeration humidifying device is characterized by comprising a closed container (1), a drain pipe (6), a circulating water pump (7), an electric heater (8), a temperature controller (9), a check valve (10) and an air outlet pipe (11);
the device is characterized in that a water sprayer (12), an upper filler (2), a lower filler (13) and an aeration device (14) are arranged in the closed container (1) from top to bottom, the lower filler (13) and the aeration device (14) are arranged in deionized water (15), the aeration device (14) is connected with an air inlet pipe (4), a water replenishing control valve (5), a circulating water pump (7) and a water outlet pipe (6) are connected to the lower portion of the closed container (1), the circulating water pump (7), an electric heater (8) and a check valve (10) are sequentially connected to form a loop, an air outlet pipe (11) is connected to the upper portion of the closed container (1), the water replenishing control valve (5) is connected with the closed container (1) through a liquid level meter (3), and the electric heater (8) is connected with a temperature controller (9.
2. The high-power fuel cell aeration humidification device as claimed in claim 1, wherein the material of the upper filler (2) and the lower filler (13) is fiber, graphite or ceramic.
3. The high power fuel cell aeration humidification device as claimed in claim 1, wherein the drain pipe (6) is a waste liquid discharge port.
CN201911367691.8A 2019-12-26 2019-12-26 Aeration humidifying device for high-power fuel cell Pending CN110911713A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911367691.8A CN110911713A (en) 2019-12-26 2019-12-26 Aeration humidifying device for high-power fuel cell

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CN201911367691.8A CN110911713A (en) 2019-12-26 2019-12-26 Aeration humidifying device for high-power fuel cell

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112310441A (en) * 2020-10-23 2021-02-02 华中科技大学 Temperature and humidity control system for fuel cell reaction gas
CN113363534A (en) * 2021-07-07 2021-09-07 大连锐格新能源科技有限公司 Fuel cell atomization humidification system and humidification method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20070059579A (en) * 2005-12-07 2007-06-12 주식회사 씨엔엘에너지 A humidifier of a fuel cell
CN101165952A (en) * 2006-10-17 2008-04-23 上海博能同科燃料电池系统有限公司 Humidification technology and humidification system for large power PEM fuel battery test platform
CN208173714U (en) * 2017-12-18 2018-11-30 南京大学 A kind of fuel cell testing device air humidification device
CN208767400U (en) * 2018-09-11 2019-04-19 大连锐格新能源科技有限公司 A kind of bubbling humidifying device applied to fuel cell
CN210897484U (en) * 2019-12-26 2020-06-30 大连锐格新能源科技有限公司 High-power fuel cell aeration humidifying device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20070059579A (en) * 2005-12-07 2007-06-12 주식회사 씨엔엘에너지 A humidifier of a fuel cell
CN101165952A (en) * 2006-10-17 2008-04-23 上海博能同科燃料电池系统有限公司 Humidification technology and humidification system for large power PEM fuel battery test platform
CN208173714U (en) * 2017-12-18 2018-11-30 南京大学 A kind of fuel cell testing device air humidification device
CN208767400U (en) * 2018-09-11 2019-04-19 大连锐格新能源科技有限公司 A kind of bubbling humidifying device applied to fuel cell
CN210897484U (en) * 2019-12-26 2020-06-30 大连锐格新能源科技有限公司 High-power fuel cell aeration humidifying device

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112310441A (en) * 2020-10-23 2021-02-02 华中科技大学 Temperature and humidity control system for fuel cell reaction gas
CN112310441B (en) * 2020-10-23 2021-09-07 华中科技大学 Temperature and humidity control system for fuel cell reaction gas
CN113363534A (en) * 2021-07-07 2021-09-07 大连锐格新能源科技有限公司 Fuel cell atomization humidification system and humidification method thereof
CN113363534B (en) * 2021-07-07 2024-04-12 大连锐格新能源科技有限公司 Fuel cell atomizing and humidifying system and humidifying method thereof

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