CN110903705A - Composition for manufacturing solid water powder stick, solid water powder stick and preparation method of solid water powder stick - Google Patents

Composition for manufacturing solid water powder stick, solid water powder stick and preparation method of solid water powder stick Download PDF

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Publication number
CN110903705A
CN110903705A CN201911108884.1A CN201911108884A CN110903705A CN 110903705 A CN110903705 A CN 110903705A CN 201911108884 A CN201911108884 A CN 201911108884A CN 110903705 A CN110903705 A CN 110903705A
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China
Prior art keywords
pigment
solid
stick
water
powder stick
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CN201911108884.1A
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Chinese (zh)
Inventor
何继局
陈晓凯
何恺
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Shanghai Picture Lebao Cultural Media Co ltd
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Shanghai Picture Lebao Cultural Media Co ltd
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Priority to CN201911108884.1A priority Critical patent/CN110903705A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D13/00Pencil-leads; Crayon compositions; Chalk compositions

Abstract

The invention discloses a composition for manufacturing a solid water-powder stick, which comprises the following components in parts by weight: 10 to 20 percent of stearic acid; 7% -16% of glycerol; 0.1% -0.6% of polydimethylsiloxane; MIT 0.1% -0.2%; 0.1 to 5 percent of pigment; the balance being water. The invention also discloses a solid water powder stick prepared from the composition and a preparation method of the solid water powder stick. The solid gouache stick has the comprehensive properties of smoothness, quick drying, water solubility, compatibility of various painting materials, strong adhesive force, pure color, fastness, easy cleaning and the like.

Description

Composition for manufacturing solid water powder stick, solid water powder stick and preparation method of solid water powder stick
Technical Field
The invention relates to the technical field of paintbrushes, in particular to a composition for manufacturing a solid water powder stick, the solid water powder stick and a preparation method thereof.
Background
The existing solid painting brush mainly comprises a crayon, a chalk and the like, wherein the crayon mainly comprises paraffin, oil and pigment, and is not easy to erase and bright in color because the crayon is strong in adhesive force and not easy to dissolve in water. The chalk is easy to erase and has the defect of dust.
CN1634719A discloses a painting brush which is prepared from a fatty acid soap, a humectant and a pigment in proportion. The painting brush adopts fatty acid soap as a main raw material to replace paraffin, and the fatty acid soap is easy to dissolve in water and has a washing effect, so that the painting brush is easy to erase and can remove other stains.
CN101412868A discloses a solid fluorescent painting brush, which comprises the following components in parts by weight: 10-50 parts of sodium soap; 2-20 parts of sodium stearate; 0.1-10 parts of fluorescent dye; 1-4 parts of a surfactant; 1-5 parts of a connecting material; 1-4 parts of a plasticizer; 0.1-3% of sucrose; 1-6 parts of ethanol; 8-55% of distilled water. The painting brush has no dust, can be cleaned by water, and has smooth writing, bright handwriting color and fluorescence.
CN101033354A discloses a composition for making an aqueous multi-purpose drawing pen, comprising the following components: 2-24 parts of stearic acid; 5-25 parts by weight of hydrogenated oil; 1-10 parts of wax; 5-40 parts of an emulsifier; 1-20 parts by weight of pigment; 15-35% by weight of filler; the total weight of the above components accounts for 90-100 wt% of the total weight of the composition. This waterborne multipurpose drawing pen, have water-soluble, can wash with the water, can be used in glass, brick, the smooth surface of plastics, EVA material and smooth article on drawing, it is convenient to wash moreover, just can wipe cleanly with wet cloth and can draw again, has the advantage that anti breaking force is high moreover.
CN103059644A discloses a water-based drawing pen, which comprises the following raw materials in percentage by weight: 10-50% of high molecular film forming matter, 5-60% of filler, 3-20% of excipient, 0.5-10% of film forming aid, 0.01-3% of pigment, 1-15% of humectant and 10-50% of water. The water-based painting brush does not need to be added with a wetting agent, a dispersing agent and an anti-settling agent, is odorless, environment-friendly and low in cost, has good color retention, water resistance and ultraviolet resistance, is easy to clean when being stuck on the skin, and is not easy to flush after being smeared on a wall to form a film.
The formulas of the various prior disclosed paintbrushes are comprehensively analyzed, although the respective technical effects can be realized. However, the combination of properties such as the required quick-drying property, compatibility, strong adhesion, etc. is still an unexplored property. To achieve these combinations, adjustments to the various formulations disclosed in the prior art are not readily achievable, and this can still be achieved with the use of creative efforts.
Disclosure of Invention
In view of the above, the first objective of the present invention is to provide a composition for manufacturing solid gouache sticks, which has the comprehensive properties of smoothness, quick drying, water solubility, compatibility of various painting materials, strong adhesion, pure color, fastness, easy cleaning, etc.
The second object of the present invention is to provide a solid water stick which has all the comprehensive properties of the composition and is also easy to handle and carry.
The third purpose of the invention is to provide a preparation method of the solid water-powder stick.
The adopted technical scheme is as follows:
the invention relates to a composition for manufacturing a solid water-powder stick, which comprises the following components in parts by weight:
10 to 20 percent of stearic acid;
7% -16% of glycerol;
0.1% -0.6% of polydimethylsiloxane;
MIT 0.1%-0.2%;
0.1 to 5 percent of pigment;
the balance being water.
Further, in the composition, the pigment is any one of a blue pigment, a light blue pigment, a violet pigment, a green pigment, a white pigment, a black pigment, a red pigment, a pink pigment, an orange pigment, a yellow pigment, a light green pigment, and a brown pigment.
The invention relates to a solid water-powder stick which is prepared from the following components in percentage by weight:
10 to 20 percent of stearic acid;
7% -16% of glycerol;
0.1% -0.6% of polydimethylsiloxane;
MIT 0.1%-0.2%;
0.1 to 5 percent of pigment;
the balance being water.
Further, in the solid gouache stick, the pigment is any one of a blue pigment, a light blue pigment, a purple pigment, a green pigment, a white pigment, a black pigment, a red pigment, a pink pigment, an orange pigment, a yellow pigment, a light green pigment and a brown pigment.
The invention relates to a preparation method of a solid water-powder stick, which comprises the following steps: weighing the components according to the weight ratio, adding stearic acid, glycerol, polydimethylsiloxane, MIT and pigment into water, heating and stirring until the mixture is in a molten state, filling into a mold, and cooling and forming to obtain the solid gouache stick.
Further, the temperature of the mixture in a molten state is 60 to 80 ℃.
In the composition for manufacturing the solid gouache stick, stearic acid and polydimethylsiloxane have a smoothing effect on a final product, stearic acid has a softening and softening effect on the final product (the solid gouache stick), and polydimethylsiloxane has a lubricating effect on the final product (the solid gouache stick); stearic acid and polydimethylsiloxane act together to give the final product (solid water stick) a smooth character.
The glycerin has a plasticizing effect on the polydimethylsiloxane in the formula, and the glycerin and the polydimethylsiloxane jointly act to enable the final product (solid gouache stick) to have quick-drying characteristics, which is probably because the polydimethylsiloxane can permeate into the substrate under the modification of the glycerin, so that the substrate is easy to dry quickly on the surface and moisturizes the inside of the substrate.
And because of the permeability and moisture retention of the polydimethylsiloxane, the glycerol, the polydimethylsiloxane and the stearic acid enable the final product to have the characteristics of strong adhesion and compatibility of various painting materials.
Since each component is a water-soluble component, the final product (solid water powder stick) has the property of being water-soluble, and thus is easy to clean with water.
MIT is a bactericidal preservative that can make the final product sterile and prevent decay, ensuring the end product's life.
The final product (solid water powder stick) is in the shape of a solid stick, so that the product is easy to hold by a palm and carry.
The pigment used in the invention can be selected only by being matched with other components, so that the final product can achieve the characteristics of pure color and fastness. As a preference, the blue pigment (blue) can be selected from the group consisting of food color brilliant blue having CAS number 3844-45-9; light blue pigment (light blue) can be prepared by blending titanium dioxide with CAS number 13463-67-7 and food pigment brilliant blue with CAS number 3844-45-9; the purple pigment can be prepared by blending acid red 18 with CAS number of 2611-82-7 and food pigment brilliant blue with CAS number of 3844-45-9; the green pigment (green) can be prepared from edible pigment Brilliant blue with CAS number of 3844-45-9 and food yellow 3 with CAS number of 2783-94-0; the white pigment can be titanium dioxide with CAS number 13463-67-7; the black pigment can be selected from activated carbon with CAS number 7440-44-0; the red pigment can be acid red 18 with CAS number 2611-82-7; the pink pigment can be pink obtained by blending acid red 18 with CAS number of 2611-82-7 and food pigment brilliant blue with CAS number of 3844-45-9; the orange pigment can be orange after being prepared by selecting acid red 18 with CAS number 2611-82-7 and food yellow 3 with CAS number 2783-94-0; yellow can be selected from food yellow 3 with CAS number 2783-94-0; the light green pigment can be prepared from food yellow 3 of 2783-94-0, food pigment brilliant blue of CAS number 3844-45-9, and titanium dioxide of CAS number 13463-67-7; the brown color can be obtained by blending activated carbon with CAS number 7440-44-0, acid red 18 with CAS number 2611-82-7, food yellow 3 with CAS number 2783-94-0, and food pigment brilliant blue with CAS number 3844-45-9.
In conclusion, the beneficial effects of the invention are as follows:
the solid gouache stick disclosed by the invention has multiple characteristics or characteristics of smoothness, quick drying, water solubility, compatibility of multiple painting materials, strong adhesive force, pure color, fastness, easiness in cleaning, easiness in mastering, portability and the like.
Detailed Description
The present invention is described in detail below with reference to specific examples, but the use and purpose of these exemplary embodiments are merely to exemplify the present invention, and do not set forth any limitation on the actual scope of the present invention in any form, and the scope of the present invention is not limited thereto. The following examples are conducted under conditions not specified, and usually conducted according to a conventional method or conditions recommended by the manufacturer. All percentages are by weight unless otherwise indicated.
Example 1
The solid gouache stick is prepared from the following components:
10% of stearic acid;
7% of glycerol;
0.1% of polydimethylsiloxane;
MIT 0.1%;
2% of red pigment;
80.8 percent of water.
The preparation method of the solid water powder stick comprises the following steps: weighing the components in proportion, adding stearic acid, glycerol, polydimethylsiloxane, MIT and red pigment into water, heating and stirring until the mixture is in a molten state at 60-80 ℃, filling into a mold, and cooling and forming to obtain the solid gouache stick.
Example 2
The solid gouache stick is prepared from the following components:
20% of stearic acid;
16% of glycerol;
0.6% of polydimethylsiloxane;
MIT 0.2%;
3.5% of black pigment;
the balance is 59.7 percent of water.
Preparation method referring to example 1, a black solid water powder bar was prepared.
Example 3
The solid gouache stick is prepared from the following components:
17% of stearic acid;
13% of glycerol;
0.3% of polydimethylsiloxane;
MIT 0.1%;
2% of blue pigment;
and (5) 67.6 percent of water.
Preparation method referring to example 1, a blue solid water powder stick was prepared.
Performance observation:
the solid gouache sticks prepared in examples 1-3 were colored on kraft paper, and the solid gouache sticks of 3 colors were colored in different regions of the kraft paper, and as a result, it was found that the solid gouache sticks of the present invention had both smooth and quick-drying characteristics, and the kraft paper surface was substantially dried for 3-4 seconds.
The solid gouache sticks of 3 colors are used for color printing in the same area of kraft paper, and as a result, multiple painting materials are found to be compatible. For example, a blue solid pastille stick may be painted blue over black.
The solid gouache sticks with 3 colors are respectively painted on kraft paper, a wooden table and an iron sheet box, and the results show that the gouache sticks can be covered on different base materials, have strong adhesive force and pure color and are not faded.
The color of the solid gouache stick on the veneer pasting box is cleaned by water, so that the color is easy to clean.
The whole solid gouache stick is easy to master in the hand in the using process and is convenient to carry.
The above-listed detailed description is only a specific description of a possible embodiment of the present invention, and they are not intended to limit the scope of the present invention, and equivalent embodiments or modifications made without departing from the technical spirit of the present invention should be included in the scope of the present invention.

Claims (6)

1. The composition for manufacturing the solid gouache stick is characterized by comprising the following components in parts by weight:
Figure FDA0002272135340000011
2. the composition for making a solid gouache stick according to claim 1, wherein the pigment is any one of blue pigment, light blue pigment, purple pigment, green pigment, white pigment, black pigment, red pigment, pink pigment, orange pigment, yellow pigment, light green pigment and brown pigment.
3. A solid water-powder stick is characterized by being prepared from the following components in percentage by weight:
Figure FDA0002272135340000012
4. the solid gouache stick of claim 1, wherein said pigment is any one of blue pigment, light blue pigment, purple pigment, green pigment, white pigment, black pigment, red pigment, pink pigment, orange pigment, yellow pigment, light green pigment, brown pigment.
5. A method of making a solid powdered water bar according to claim 1, comprising the steps of: weighing the components according to the weight ratio, adding stearic acid, glycerol, polydimethylsiloxane, MIT and pigment into water, heating and stirring until the mixture is in a molten state, filling into a mold, and cooling and forming to obtain the solid gouache stick.
6. The method of claim 1, wherein the temperature of the mixture in the molten state is 60-80 ℃.
CN201911108884.1A 2019-11-13 2019-11-13 Composition for manufacturing solid water powder stick, solid water powder stick and preparation method of solid water powder stick Pending CN110903705A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115093753A (en) * 2022-07-29 2022-09-23 宜春市彩辰文具有限公司 Preparation method of quick-drying hand-cleaning-free gouache pigment and quick-drying solid gouache stick

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101412868A (en) * 2008-11-14 2009-04-22 山西大学 Solid fluorescent paintbrush
CN106433321A (en) * 2016-06-17 2017-02-22 江苏兴达文具集团有限公司 Production method of erasable crayon
CN107033677A (en) * 2016-11-18 2017-08-11 江南大学 A kind of washable three-in-one wax crayon and its manufacture method
CN108690406A (en) * 2018-07-28 2018-10-23 裴泽民 A kind of children's environment-protecting color wax crayon and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101412868A (en) * 2008-11-14 2009-04-22 山西大学 Solid fluorescent paintbrush
CN106433321A (en) * 2016-06-17 2017-02-22 江苏兴达文具集团有限公司 Production method of erasable crayon
CN107033677A (en) * 2016-11-18 2017-08-11 江南大学 A kind of washable three-in-one wax crayon and its manufacture method
CN108690406A (en) * 2018-07-28 2018-10-23 裴泽民 A kind of children's environment-protecting color wax crayon and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115093753A (en) * 2022-07-29 2022-09-23 宜春市彩辰文具有限公司 Preparation method of quick-drying hand-cleaning-free gouache pigment and quick-drying solid gouache stick

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