CN110903037A - Sweat-resistant and wear-resistant colorful 3D glass panel and film coating method for surface thereof - Google Patents
Sweat-resistant and wear-resistant colorful 3D glass panel and film coating method for surface thereof Download PDFInfo
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- 238000001035 drying Methods 0.000 claims abstract description 3
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 34
- 229910052786 argon Inorganic materials 0.000 claims description 26
- 235000012239 silicon dioxide Nutrition 0.000 claims description 17
- 239000000377 silicon dioxide Substances 0.000 claims description 17
- SQEGLLMNIBLLNQ-UHFFFAOYSA-N 1-ethoxy-1,1,2,3,3,3-hexafluoro-2-(trifluoromethyl)propane Chemical compound CCOC(F)(F)C(F)(C(F)(F)F)C(F)(F)F SQEGLLMNIBLLNQ-UHFFFAOYSA-N 0.000 claims description 13
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/083—Oxides of refractory metals or yttrium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/42—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating of an organic material and at least one non-metal coating
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/0605—Carbon
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/10—Glass or silica
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/12—Organic material
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- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/24—Vacuum evaporation
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/24—Vacuum evaporation
- C23C14/28—Vacuum evaporation by wave energy or particle radiation
- C23C14/30—Vacuum evaporation by wave energy or particle radiation by electron bombardment
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/78—Coatings specially designed to be durable, e.g. scratch-resistant
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/151—Deposition methods from the vapour phase by vacuum evaporation
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- Chemical & Material Sciences (AREA)
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- Health & Medical Sciences (AREA)
- Toxicology (AREA)
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Abstract
The invention relates to a sweat-resistant and wear-resistant colorful 3D glass panel and a film coating method for the surface of the glass panel, and belongs to the technical field of glass panel surface treatment. In order to solve the problem of poor sweat resistance in the prior art, the method for coating the surface of the sweat-resistant and wear-resistant colorful 3D glass panel comprises the steps of plating a colorful coating layer on the surface of a 3D glass panel substrate, plating a nanoscale DLC film layer on the surface of the colorful coating layer, plating a sweat-resistant AF film layer on the surface of the nanoscale DLC film layer, wherein the sweat-resistant AF film layer is mainly formed by depositing a material containing fluorine-silicon polymer and fluorine alkane; the method comprises cleaning and drying the surface of the substrate, and placing into a vacuum coating chamber; vacuumizing and cleaning an ion source; firstly, depositing a colorful coating layer on the surface, and then depositing a nano DLC film layer; and evaporating and depositing the sweat-resistant AF liquid medicine containing the fluorine-silicon polymer and the fluoroalkane material on the surface to form a sweat-resistant AF film layer. The colorful garment has the dual effects of high wear resistance and high sweat resistance.
Description
Technical Field
The invention relates to a sweat-resistant and wear-resistant colorful 3D glass panel and a film coating method for the surface of the glass panel, and belongs to the technical field of glass panel surface treatment.
Background
With the development and increasing popularity of electronic products such as mobile phones, digital products, and mobile electronic devices, the quality requirements of glass panels for these electronic products are higher. At present, with the development and maturity of electronic products, people have higher and higher requirements on the colorful effect of the panel. Therefore, at present, the surface of the glass panel is generally coated with various coating layers with different quality requirements by performing coating treatment on the surface of the glass panel, for example, in order to increase the aesthetic property, a coating material with high refractive index and low refractive index is used to replace coating to plate a colorful coating layer on the surface, and a wear-resistant and anti-fingerprint coating layer is formed on the surface by coating to improve the surface anti-fouling capability of the glass panel. However, the current electronic product is usually a touch screen, and is often contacted with a hand of a person during use, and sweat generated by the person has acidic or alkaline characteristics, so that corrosion is easily caused, and the requirements of a film coating layer are influenced, for example, a colorful film layer influences quality due to corrosion, and the film layer is easy to damage due to damage resistance during use because the wear resistance of the film layer is poor. For example, a reflection reducing anti-fingerprint film disclosed in the Chinese patent (No. CN202782000U) comprises a strengthened glass, a first high refractive index medium layer, a first low refractive index medium layer, a second high refractive index medium layer, a second low refractive index medium layer and an AF film layer. Although the whole coating layer has good permeability enhancing and hydrophobic and sparse fingerprint preventing effects, the surface wear resistance of the coating is poor, and abrasion is easily caused in the using process, however, the acid resistance or alkali resistance of the existing coating layer is poor, the glass panel is frequently contacted with people in the using process, and the acid resistance or alkali resistance of sweat (artificial sweat) generated by a human body can cause corrosion of the coating layer, namely the sweat resistance of the existing product is poor, so that the coating quality of the product is influenced.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides a sweat-resistant and wear-resistant colorful 3D glass panel and a coating method for the surface thereof, and solves the problem of how to prevent the abrasion and corrosion of a film layer and realize the double performances of sweat resistance and wear resistance.
One of the purposes of the invention is realized by the following technical scheme that the sweat-resistant and wear-resistant colorful 3D glass panel comprises a 3D glass panel substrate, wherein a colorful coating layer is plated on the surface of the 3D glass panel substrate, a nanoscale DLC film layer is plated on the surface of the colorful coating layer, a sweat-resistant AF film layer is plated on the surface of the nanoscale DLC film layer, and the sweat-resistant AF film layer is mainly formed by plating and depositing a sweat-resistant AF liquid medicine containing fluorine-silicon polymer and fluorine alkane materials.
According to the invention, the nanoscale DLC film layer is firstly plated and deposited on the surface of the colorful coating layer, the coating has the characteristic of diamond-like carbon and has high wear resistance, the problem of wearing of the film layer in the use process can be avoided, and the characteristic of the colorful coating layer on the bottom layer is effectively ensured. Therefore, through long-term research, the invention discovers that the surface of the AF film layer is plated with a sweat-resistant AF film layer, and the film layer contains fluorine-silicon polymer and fluorine alkane material, so that the AF film layer has high-efficiency fingerprint-resistant and stain-resistant effects, and more importantly, the fluorine alkane material (polyfluoro substituted alkane material) is added into the AF film layer, so that the AF film layer has the advantage of good curing effect, the formation of the film layer with high compactness can be effectively promoted in the deposition process of the AF film layer, the corrosion phenomenon caused by the permeation and the formation resistance of artificial sweat can be avoided, and the high sweat-resistant effect can be effectively achieved.
In the sweat-resistant and wear-resistant colorful 3D glass panel, preferably, the content of the fluoroalkane material in the sweat-resistant AF liquid medicine is 10% to 12%. The main function of the fluoroalkane is to form a high-compactness film layer to prevent sweat from permeating, and the adoption of the materials with the contents is more favorable for promoting the curing of the film layer so as to promote the formation of the high-compactness film layer and more effectively realize the effect of high sweat resistance. Therefore, the requirement of the addition amount can realize high sweat resistance to the maximum extent, and the effect of preventing fingerprints and resisting pollution of the film layer is ensured. As a further preference, the fluoroalkane-based material is selected from 1,1,1,2,3,3, 3-heptafluoro-2- (ethoxydifluoromethyl) -propane and/or 1,1,2,2,3,3,4,4, 4-nonafluoro-1-ethoxy-hexane. The curing effect is good, the formation of a high-compactness film layer is promoted, and the corrosion problem caused by sweat permeation is prevented, so that the high sweat resistance is realized.
In the sweat-resistant and wear-resistant colorful 3D glass panel, preferably, the sweat-resistant AF liquid mainly comprises the following raw materials by mass:
fluorine-silicon polymer: 2.0% -3.0%;
1,1,1,2,3,3, 3-heptafluoro-2- (ethoxydifluoromethyl) -propane: 5.0% -6.0%;
1,1,2,2,3,3,4,4, 4-nonafluoro-1-ethoxy-hexane: 5.0% -6.0%;
the balance being solvent. The fluorine-silicon-containing polymer material can ensure the characteristics of fingerprint resistance and pollution resistance; meanwhile, under the synergistic effect of 1,1,1,2,3,3, 3-heptafluoro-2- (ethoxy difluoro methyl) -propane and 1,1,2,2,3,3,4,4, 4-nonafluoro-1-ethoxy-hexane, the curing of the film layer can be better promoted, and the high-compactness film layer can be formed; and the surface tension of the sweat-resistant composite material is effectively reduced to be lower, the sweat-resistant composite material has better high hydrophobicity, the contact area of sweat droplets and the surface of the sweat-resistant composite material is reduced to be lower, the sweat penetration is better avoided, and the effect of high sweat resistance is realized.
In the sweat-resistant and wear-resistant colorful 3D glass panel, the thickness of the nano DLC film layer is preferably 10-15 nm. The phenomenon that wears appears in avoiding the use that can be better, further improvement wear resistance, and the nanometer DLC rete in the middle of making has certain thickness, has the infiltration of avoiding the sweat concurrently, realizes dual safeguard function to the various rete is dazzled by the sweat to further assurance inlayer is not corroded, keeps its effect of dazzling the color. To dazzling various coating film layer accessible adopt high refracting index rete and low refracting index rete to carry out the alternative coating and establish the rete that the deposit formed, because the alternative coating of height of refracting index is established, make the light that shines the surface form many times refraction and reflection, form the effect of dazzling various. As a further preferred option, the glare coating layer sequentially comprises the following film layers from the surface of the 3D glass panel substrate to the outside:
the thickness of the titanium pentoxide film layer is 25 nm; a silicon dioxide film layer with the thickness of 20 nm;
the thickness of the titanium pentoxide film layer is 35 nm; and the thickness of the silicon dioxide film layer is 47 nm.
The film layers with high refractive index and the film layers with low refractive index are alternately plated, and the thickness requirement of each film layer is strictly controlled, so that the characteristic of dazzling colors is effectively achieved.
The second purpose of the invention is realized by the following technical scheme, and the method for coating the surface of the sweat-resistant and wear-resistant colorful 3D glass panel is characterized by comprising the following steps of:
A. cleaning and drying the surface of a 3D glass panel substrate to be coated, and then putting the substrate into a vacuum coating chamber of a coating machine; after vacuumizing, cleaning an ion source;
B. after cleaning, depositing a colorful coating layer on the surface by vacuum coating treatment, and depositing a nano DLC film layer on the surface of the colorful coating layer;
C. and evaporating and depositing the sweat-resistant AF liquid medicine containing the fluorine-silicon polymer and the fluoroalkane material on the surface of the nano DLC film layer to form a sweat-resistant AF film layer, and obtaining the corresponding coated 3D glass panel.
The method comprises the following steps of firstly, cleaning by an ion source, improving the roughness of the surface of the glass, improving the surface adhesive force of the glass, facilitating the adhesion and combination of a coating layer on the surface, plating a deposited colorful coating layer on the surface, and improving the wear resistance of the surface by depositing a nanoscale DLC film layer on the surface of the colorful film layer, so that the characteristic of the colorful film layer is protected, and the failure of the colorful characteristic caused by abrasion is avoided; and a sweat-resistant AF film layer is evaporated and deposited on the surface of the DLC film layer, and a sweat-resistant AF liquid medicine containing fluorine-silicon polymer and fluoroalkane materials is evaporated and deposited, and the addition of the fluoroalkane materials can effectively improve the characteristics of the film layer, so that the film layer has the advantage of good curing effect, and the formed film layer has the characteristic of high compactness, thereby effectively avoiding sweat permeation and realizing the effect of high sweat resistance.
In the above method for coating the surface of the sweat-resistant and wear-resistant colorful 3D glass panel, preferably, step C specifically comprises:
after the nano-scale DLC film layer is coated, controlling the vacuum value in the vacuum coating chamber to be less than or equal to 2.0x10-5And supporting, continuously introducing argon, and carrying out evaporation deposition on the evaporation source sweat-resistant AF liquid medicine on the surface of the nanoscale DLC film layer to form a sweat-resistant AF film layer, wherein the sweat-resistant AF liquid medicine mainly comprises the following raw materials in percentage by mass:
fluorine-silicon polymer: 2.0% -3.0%;
1,1,1,2,3,3, 3-heptafluoro-2- (ethoxydifluoromethyl) -propane: 5.0% -6.0%;
1,1,2,2,3,3,4,4, 4-nonafluoro-1-ethoxy-hexane: 5.0% -6.0%;
the balance being solvent. The anti-sweat AF film layer can be effectively formed on the surface in a deposition mode, and under the synergistic effect of the dosage proportion of the 1,1,1,2,3, 3-heptafluoro-2- (ethoxy difluoro methyl) -propane and the 1,1,2,2,3,3,4,4, 4-nonafluoro-1-ethoxy-hexane, the film layer is more favorably solidified, the anti-sweat AF film layer has high compactness and the effect of high sweat resistance is achieved.
In the above method for coating the surface of the sweat-resistant and wear-resistant colorful 3D glass panel, preferably, the specific coating mode of the nanoscale DLC film layer in step B is as follows:
after the coating of the colorful coating layer is finished, controlling the vacuum value in the vacuum coating chamber to be less than or equal to 2.0x10-5And supporting, continuously introducing argon and oxygen, and evaporating the film material of the nanoscale DLC film layer in a mode of electron gun evaporation to deposit the film material on the surface of the colorful film layer in a nanoscale molecule mode to form the nanoscale DLC film layer. By usingThe electron gun evaporates to enable the film material to form a nano-scale molecule form, so that a nano-scale film layer is formed on the surface of the colorful coating film layer by deposition, and the film has the effect of high wear resistance.
In summary, compared with the prior art, the invention has the following advantages:
1. the DLC film layer is deposited on the surface of the colorful coating layer, so that the integral wear resistance of the surface is improved, and the wearing phenomenon is avoided, so that the colorful film is protected from being worn; meanwhile, the material containing the fluorine-silicon polymer and the fluoroalkane is adopted, and the fluoroalkane material is added, so that the advantage of good curing effect is achieved, a film layer with high compactness can be effectively promoted to be formed in the deposition process of the AF film, the corrosion phenomenon caused by artificial sweat permeation is avoided, the high sweat resistance effect is achieved, and the double plating of the DLC film layer and the sweat resistance AF film layer is adopted, so that the double effects of high wear resistance and high sweat resistance are achieved.
2. By adopting the synergistic effect of 1,1,1,2,3,3, 3-heptafluoro-2- (ethoxydifluoromethyl) -propane and 1,1,2,2,3,3,4,4, 4-nonafluoro-1-ethoxy-hexane, the film layer can be better promoted to be cured, the high-compactness film layer is favorably formed, the surface tension of the film layer is effectively reduced to be lower, the film layer has better high hydrophobicity, the contact area of sweat droplets and the surface of the sweat droplets is reduced to be lower, the sweat permeation is better avoided, and the effect of high sweat resistance is realized.
Drawings
Fig. 1 is a schematic structural diagram of the sweat-resistant abrasion-resistant colorful 3D glass panel.
In the figure, 1, 3D glass panel substrates; 2. a colorful coating layer; 21. a titanium pentoxide coating layer; 22. a silicon dioxide coating; 3. a nanoscale DLC film layer; 4. a sweat resistant AF film layer.
Detailed Description
The technical solutions of the present invention will be further specifically described below with reference to specific examples and drawings, but the present invention is not limited to these examples.
Example 1
The anti-sweat, wear-resistant and colorful 3D glass panel comprises a 3D glass panel substrate 1, a colorful coating layer 2 is plated on the surface of the 3D glass panel substrate 1, a nanoscale DLC film layer 3 is plated on the surface of the colorful coating layer 2, a sweat-resistant AF film layer 4 is plated on the surface of the nanoscale DLC film layer 3, and the sweat-resistant AF film layer 4 is mainly formed by deposition of fluorine-silicon-containing polymers and fluorine alkane materials. The content of the fluoroalkane material in the sweat-resistant AF membrane layer 4 is 10% -12%, and the fluoroalkane material is selected from 1,1,1,2,3,3, 3-heptafluoro-2- (ethoxy difluoro methyl) -propane or 1,1,2,2,3,3,4,4, 4-nonafluoro-1-ethoxy-hexane.
The processing of the sweat-resistant, wear-resistant and colorful 3D glass panel can be performed by adopting a general vacuum coating (such as vapor deposition coating). Of course, it is preferable to use a method of processing by:
the method comprises the steps of carrying out dust removal and oil removal cleaning on a 3D glass panel substrate 1 to be coated, carrying out ultrasonic cleaning to obtain a clean coating surface, putting the corresponding 3D glass panel substrate 1 to be coated into a vacuum coating cavity of an electron beam evaporation machine (2050 coating machine), vacuumizing, and when the vacuum value in the vacuum coating cavity is smaller than or equal to 2.0x10-5Supporting, starting an ion source to perform plasma cleaning, namely turning on a power supply, controlling the target power to be about 5kw, introducing argon gas to generate plasma, performing ion source cleaning treatment, wherein the flow of the argon gas is 200ssm, cleaning for 2 minutes, closing the argon gas after the ion source cleaning treatment is finished, vacuumizing a vacuum chamber to be less than or equal to 2.0x10-5Opening oxygen and argon to lead in oxygen and argon, leading the partial pressure of the oxygen to be 0.5Pa and the partial pressure of the argon to be 0.2Pa, controlling the temperature to be about 55 ℃ after the air pressure is stabilized, evaporating the film material target source of the trititanium pentoxide film layer 21 by using an electron gun, evaporating and depositing the film material on the front surface of the 3D glass panel in a nano-scale molecular form to form the corresponding trititanium pentoxide film layer 21 under the action of an ion source, keeping the deposition rate of the film layer to be 0.2-3 nm/s and the thickness to be 25nm, closing the corresponding film material target source of the trititanium pentoxide film layer 21 after finishing, evaporating the film material target source of the silicon dioxide film layer 22 by using the electron gun, and evaporating and depositing the film material on the trititanium pentoxide film in the nano-scale molecular form under the action of the ion sourceThe surface of the layer 21, the thickness is controlled at 20nm, and the target source of the silicon dioxide film layer 22 is closed; and repeating the previous two steps to alternately form a corresponding coating film, namely depositing a trititanium pentoxide film layer 21 on the surface of the silicon dioxide film layer 22 in the previous step, wherein the thickness is controlled to be 35nm, then depositing the silicon dioxide film layer 22 on the surface of the trititanium pentoxide film layer 21, wherein the thickness is controlled to be 47nm, and finally obtaining a corresponding colorful coating film layer 2, wherein the colorful coating film layer 2 sequentially comprises the following components from the surface of the 3D glass panel to the outside:
the thickness of the titanium pentoxide film layer is 25 nm; a silicon dioxide film layer with the thickness of 20 nm;
the thickness of the titanium pentoxide film layer is 35 nm; and the thickness of the silicon dioxide film layer is 47 nm.
And then, carrying out a nano-scale DLC film layer 3, which specifically comprises the following steps: continuously vacuumizing the vacuum coating cavity until the vacuum value is less than or equal to 2.0x10-5Supporting, introducing argon, keeping the partial pressure of the argon at 0.1-3.0 Pa, after the air pressure is stable, starting to perform electric film plating at the temperature of 30-150 ℃, forming plasma by argon ions, depositing nano-scale carbon atoms separated from the DLC target on the surface of the colorful film coating layer 2 by adopting an electron gun under the action of the plasma source to form a nano-scale DLC film layer 3, keeping the deposition rate at 0.5-2.5 nm/s and controlling the thickness at 10-15 nm in the film coating process, and closing the DLC target after the film coating is finished; and (3) entering the next step of plating the sweat-resistant AF film layer 4, which specifically comprises the following steps: opening the crucible containing the sweat-resistant AF liquid medicine, and continuing to vacuumize to less than or equal to 2.0x10-5Hold in the palm, let in argon gas and oxygen to keep the partial pressure of argon gas to be 0.1 ~ 3.0Pa, the partial pressure of oxygen is 0.2 ~ 1.0Pa, after the atmospheric pressure is stable, adopt resistance evaporation's evaporation plating mode with sweat-resistant AF liquid medicine evaporation deposit and form sweat-resistant AF rete on the surface of nanometer DLC rete, control thickness is 15nm, after the coating film, the cooling, after the evacuation, take out corresponding product sweat-resistant wear-resisting dazzle various 3D glass.
Carrying out corresponding performance tests on the obtained product, wherein the test result shows that the friction-resistant times reach more than 5000 times; the sweat resistance of the artificial sweat can reach at least 48 hours without corrosion no matter in acid and alkaline artificial sweat, and the performance of the colorful coating layer is stable.
Example 2
The anti-sweat, wear-resistant and colorful 3D glass panel comprises a 3D glass panel substrate 1, a colorful coating layer 2 is plated on the surface of the 3D glass panel substrate 1, a nanoscale DLC film layer 3 is plated on the surface of the colorful coating layer 2, a sweat-resistant AF film layer 4 is plated on the surface of the nanoscale DLC film layer 3, and the sweat-resistant AF film layer 4 is mainly formed by deposition of fluorine-silicon-containing polymers and fluorine alkane materials. The sweat-resistant AF film layer 4 is formed by evaporating and depositing a sweat-resistant AF liquid medicine which mainly comprises the following raw materials in percentage by mass:
fluorine-silicon polymer: 2.0 percent;
1,1,1,2,3,3, 3-heptafluoro-2- (ethoxydifluoromethyl) -propane: 5.0 percent;
1,1,2,2,3,3,4,4, 4-nonafluoro-1-ethoxy-hexane: 6.0 percent;
the balance is solvent, and the solvent can be acetone or ethanol or their mixed solvent with water.
Corresponding to the total content of the fluoroalkane material of 11 percent.
The processing method is preferably adopted and is processed by the following method:
the method comprises the steps of carrying out dust removal and oil removal cleaning on a 3D glass panel substrate 1 to be coated, carrying out ultrasonic cleaning to obtain a clean coating surface, putting the corresponding 3D glass panel substrate 1 to be coated into a vacuum coating cavity of an electron beam evaporation machine (2050 coating machine), vacuumizing, and when the vacuum value in the vacuum coating cavity is less than or equal to 2.5x10-5Supporting, starting an ion source to perform plasma cleaning, namely turning on a power supply, controlling the target power to be about 5kw, introducing argon gas to generate plasma, performing ion source cleaning treatment, wherein the flow of the argon gas is 200ssm, cleaning for 2 minutes, closing the argon gas after the ion source cleaning treatment is finished, vacuumizing a vacuum chamber to be less than or equal to 2.5x10-5Ask, then, open oxygen and argon gas, make and let in oxygen and argon gas to make the partial pressure of oxygen be 0.5Pa, the partial pressure of argon gas is 0.2Pa, treat that atmospheric pressure is stable after, the controlled temperature is about 55 ℃, then, dazzle various coating film layer 2's evaporation coating messenger and dazzle various coating film layer 2 in the front surface deposit formation of 3D glass panels, dazzle various coating film hereThe specific evaporation method of the layer 2 is the same as that of the embodiment 1, and is not repeated here, and the finally formed colorful coating layer 2 is sequentially from the surface of the 3D glass panel to the outside
The thickness of the titanium pentoxide film layer is 25 nm; a silicon dioxide film layer with the thickness of 20 nm;
the thickness of the titanium pentoxide film layer is 35 nm; and the thickness of the silicon dioxide film layer is 47 nm.
And then, carrying out a nano-scale DLC film layer 3, which specifically comprises the following steps: continuously vacuumizing the vacuum coating cavity until the vacuum value is less than or equal to 2.5x10-5Supporting, introducing argon, keeping the partial pressure of the argon at 0.1-2.5 Pa, after the air pressure is stable, starting to electrify and plate the film at the temperature of 30-150 ℃, forming plasma by argon ions, depositing nano-scale carbon atoms separated from the DLC target material on the surface of the colorful plated film layer 2 by adopting an electron gun under the action of the plasma source to form a nano-scale DLC film layer 3, keeping the deposition rate at 0.5-2.5 nm/s and controlling the thickness at 12nm in the film plating process, and closing the DLC target material after the film plating is finished; and (3) entering the next step of plating the sweat-resistant AF film layer 4, which specifically comprises the following steps: after the crucible containing the anti-sweat AF liquid medicine is opened, the anti-sweat AF liquid medicine is the corresponding liquid medicine of the embodiment, and the vacuum is continuously pumped until the liquid medicine is less than or equal to 2.5x10-5Hold in the palm, let in argon gas and oxygen to keep the partial pressure of argon gas to be 0.1 ~ 3.0Pa, the partial pressure of oxygen is 0.2 ~ 1.0Pa, after the atmospheric pressure is stable, adopt resistance evaporation's evaporation plating mode with sweat-resistant AF liquid medicine evaporation deposit and form sweat-resistant AF rete on the surface of nanometer DLC rete, control thickness is 20nm, after the coating film, the cooling, after the evacuation, take out corresponding product sweat-resistant wear-resisting dazzling various 3D glass panels.
Carrying out corresponding performance tests on the obtained product, wherein the test result shows that the friction-resistant times reach more than 5000 times; the sweat resistance of the artificial sweat can reach 72 hours without corrosion no matter in acid and alkaline artificial sweat, and the performance of the colorful coating layer is stable.
Example 3
The various 3D glass panels of dazzling of resistant wearing of sweat of this embodiment includes 3D glass panel base plate 1, and the surface plating of 3D glass panel base plate 1 is equipped with dazzles various coating layer 2, and the surface plating of dazzling various coating layer 2 is established the deposit and is had nanometer DLC rete 3 that thickness is 10nm, and the surface plating of nanometer DLC rete 3 is established the deposit and is had the resistant sweat AF rete 4 that thickness is 15nm, and resistant sweat AF rete 4 is mainly formed by containing fluorine silicon polymer and the deposition of fluorine alkane class material. The sweat-resistant AF film layer 4 is formed by evaporating and depositing a sweat-resistant AF liquid medicine which mainly comprises the following raw materials in percentage by mass:
fluorine-silicon polymer: 3.0 percent;
1,1,1,2,3,3, 3-heptafluoro-2- (ethoxydifluoromethyl) -propane: 6.0 percent;
1,1,2,2,3,3,4,4, 4-nonafluoro-1-ethoxy-hexane: 6.0 percent;
the balance is solvent, and the solvent can be acetone or ethanol or their mixed solvent with water.
Corresponding to the total content of the fluoroalkane material of 12 percent.
The colorful coating layer 2 is sequentially from the surface of the 3D glass panel to the outside:
the thickness of the titanium pentoxide film layer is 25 nm; a silicon dioxide film layer with the thickness of 20 nm;
the thickness of the titanium pentoxide film layer is 35 nm; and the thickness of the silicon dioxide film layer is 47 nm.
The specific coating method of this embodiment is the same as that of embodiment 1, and will not be described herein.
Carrying out corresponding performance tests on the obtained product, wherein the test result shows that the friction-resistant times reach more than 5000 times; the sweat resistance of the artificial sweat can reach 48 hours without corrosion no matter in acid and alkaline artificial sweat, and the performance of the colorful coating layer is stable.
Example 4
The various 3D glass panels of dazzling is resisted to sweat-resistant wear-resisting of this embodiment includes 3D glass panels base plate 1, and the surface plating of 3D glass panels base plate 1 is equipped with dazzles various coating layer 2, and the surface plating of dazzling various coating layer 2 is established the deposit and is had nanometer DLC rete 3 that thickness is 13nm, and the surface plating of nanometer DLC rete 3 is established the deposit and is had the sweat-resistant AF rete 4 that thickness is 14nm, and sweat-resistant AF rete 4 here adopts the sweat-resistant AF liquid medicine evaporation deposition of the raw materials that mainly includes following mass percent to form:
fluorine-silicon polymer: 2.5 percent;
1,1,1,2,3,3, 3-heptafluoro-2- (ethoxydifluoromethyl) -propane: 5.0 percent;
1,1,2,2,3,3,4,4, 4-nonafluoro-1-ethoxy-hexane: 5.0 percent;
the balance is solvent, and the solvent can be acetone or ethanol or their mixed solvent with water.
Corresponding to a total content of fluoroalkane-based materials 1,1,1,2,3,3, 3-heptafluoro-2- (ethoxydifluoromethyl) -propane and 1,1,2,2,3,3,4,4, 4-nonafluoro-1-ethoxy-hexane of 12%.
The colorful coating layer 2 is sequentially from the surface of the 3D glass panel to the outside:
the thickness of the titanium pentoxide film layer is 25 nm; a silicon dioxide film layer with the thickness of 20 nm;
the thickness of the titanium pentoxide film layer is 35 nm; and the thickness of the silicon dioxide film layer is 47 nm.
The specific coating method of this embodiment is the same as that of embodiment 1, and will not be described herein.
Carrying out corresponding performance tests on the obtained product, wherein the test result shows that the friction-resistant times reach more than 5000 times; the sweat resistance of the artificial sweat can reach 48 hours without corrosion no matter in acid and alkaline artificial sweat, and the performance of the colorful coating layer is stable.
The wear resistance in the above embodiments specifically adopts the following relevant test modes:
abrasion resistance: adopt the wearing and tearing machine to test, friction material is 0000# steel wool, friction head area 2cm x2cm, and the load is 1kg to the reciprocal mode of circulation rubs, and reciprocal motion cycle counts 1 time, rubs and utilizes electron water droplet contact angle tester to carry out water droplet angle size test after certain number of times, and the number of times of rub resistance that tests the rete with the water droplet angle is greater than 110 degrees and rete surface no friction trace.
Sweat resistance: and (3) putting a product to be tested into artificial sweat, soaking for a certain time, taking the maximum time of not corroding the product after soaking as the sweat resistance of the product, controlling the testing temperature to be 45 ℃, controlling the environmental humidity to be 55RH percent, and respectively setting the pH values of the artificial sweat to be an acid system of 4.7 and an alkaline system of 9.5.
The specific embodiments described herein are merely illustrative of the spirit of the invention. Various modifications or additions may be made to the described embodiments or alternatives may be employed by those skilled in the art without departing from the spirit or ambit of the invention as defined in the appended claims.
While the invention has been described in detail and with reference to specific embodiments thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope thereof.
Claims (9)
1. The utility model provides a various 3D glass panels is dazzled to resistant wearing of sweat, includes 3D glass panel base plate (1), the surface plating of 3D glass panel base plate (1) is equipped with dazzles various coating film layer (2), its characterized in that, the surface plating of dazzling various coating film layer (2) is equipped with nanometer DLC rete (3), the surface plating of nanometer DLC rete (3) is equipped with resistant sweat AF rete (4), resistant sweat AF rete (4) are mainly formed by the resistant sweat AF liquid medicine coating by vaporization deposition that contains fluorine silicon polymer and fluorine alkane class material.
2. The sweat-resistant abrasion-resistant glare 3D glass panel according to claim 1, wherein the sweat-resistant AF liquid medicine contains 10% to 12% of fluoroalkane materials.
3. The sweat-resistant abrasion-resistant glare 3D glass panel according to claim 1, wherein the fluoroalkane material is selected from 1,1,1,2,3,3, 3-heptafluoro-2- (ethoxydifluoromethyl) -propane and/or 1,1,2,2,3,3,4,4, 4-nonafluoro-1-ethoxy-hexane.
4. The sweat-resistant anti-abrasion colorful 3D glass panel according to claim 3, wherein the sweat-resistant AF liquid medicine mainly comprises the following raw materials in percentage by mass:
fluorine-silicon polymer: 2.0% -3.0%;
1,1,1,2,3,3, 3-heptafluoro-2- (ethoxydifluoromethyl) -propane: 5.0% -6.0%;
1,1,2,2,3,3,4,4, 4-nonafluoro-1-ethoxy-hexane: 5.0% -6.0%;
the balance being solvent.
5. The sweat resistant, abrasion resistant and glare 3D glass panel according to any of claims 1 to 4, wherein the nanoscale DLC film layer (3) has a thickness of 10nm to 15 nm.
6. The sweat-resistant abrasion-resistant glare 3D glass panel according to any one of claims 1 to 4, wherein the glare coating (2) comprises the following layers in sequence from the surface of the 3D glass panel substrate (1) to the outside:
a titanium pentoxide film layer (21) with a thickness of 25 nm; a silicon dioxide film layer (22) with the thickness of 20 nm;
a 35nm thick trititanium pentoxide film layer (21); a silicon dioxide film layer (22) with the thickness of 47 nm.
7. A method for coating a surface of a sweat-resistant and wear-resistant colorful 3D glass panel is characterized by comprising the following steps:
A. cleaning and drying the surface of a 3D glass panel substrate to be coated, and then putting the substrate into a vacuum coating chamber of a coating machine; after vacuumizing, cleaning an ion source;
B. after cleaning, depositing a colorful coating layer (2) on the surface by vacuum coating treatment, and then depositing a nano DLC film layer (3) on the surface of the colorful coating layer (2);
C. and evaporating and depositing the sweat-resistant AF liquid medicine containing the fluorine-silicon polymer and the fluoroalkane material on the surface of the nano DLC film layer (3) to form a sweat-resistant AF film layer (4) so as to obtain the corresponding coated 3D glass panel.
8. The method for coating the surface of the sweat-resistant, abrasion-resistant and glare 3D glass panel according to claim 7, wherein step C specifically comprises:
after the nano-scale DLC film layer (3) is coated, controlling the vacuum value in the vacuum coating chamber to be less than or equal to 2.0x10-5Supporting, introducing argon and oxygen, and evaporating to obtain anti-sweat AF liquid medicineEvaporating and depositing on the surface of the nano-scale DLC film layer (3) to form a sweat-resistant AF film layer (4), wherein the sweat-resistant AF liquid medicine mainly comprises the following raw materials in percentage by mass:
fluorine-silicon polymer: 2.0% -3.0%;
1,1,1,2,3,3, 3-heptafluoro-2- (ethoxydifluoromethyl) -propane: 5.0% -6.0%;
1,1,2,2,3,3,4,4, 4-nonafluoro-1-ethoxy-hexane: 5.0% -6.0%;
the balance being solvent.
9. The method for coating the surface of the sweat-resistant, abrasion-resistant and colorful 3D glass panel according to the claim 7 or 8, wherein the nano-DLC film layer (3) in the step B is coated in the following way:
after the coating of the colorful coating layer (2) is finished, controlling the vacuum value in the vacuum coating chamber to be less than or equal to 2.0x10-5And supporting, continuously introducing argon, and evaporating the film material of the nano DLC film layer (3) in a mode of electron gun evaporation to deposit the nano DLC film layer (3) on the surface of the colorful coating layer (2) in a nano molecule mode.
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Application publication date: 20200324 |