CN110862690A - Formula of graphene rolled film - Google Patents

Formula of graphene rolled film Download PDF

Info

Publication number
CN110862690A
CN110862690A CN201910966929.2A CN201910966929A CN110862690A CN 110862690 A CN110862690 A CN 110862690A CN 201910966929 A CN201910966929 A CN 201910966929A CN 110862690 A CN110862690 A CN 110862690A
Authority
CN
China
Prior art keywords
parts
additive
calendered film
graphene
formulation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910966929.2A
Other languages
Chinese (zh)
Inventor
缪新颖
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WENZHOU XINYI SPECIAL PAPER Co Ltd
Original Assignee
WENZHOU XINYI SPECIAL PAPER Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WENZHOU XINYI SPECIAL PAPER Co Ltd filed Critical WENZHOU XINYI SPECIAL PAPER Co Ltd
Priority to CN201910966929.2A priority Critical patent/CN110862690A/en
Publication of CN110862690A publication Critical patent/CN110862690A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/04—Polysiloxanes
    • C08J2383/05—Polysiloxanes containing silicon bound to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5425—Silicon-containing compounds containing oxygen containing at least one C=C bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5435—Silicon-containing compounds containing oxygen containing oxygen in a ring

Abstract

The invention discloses a formula of a graphene calendered film, which is characterized by comprising the following raw materials in parts by weight: 80 parts of solvent oil, 3 parts of an increment additive, 5 parts of main agent silicon, 3 parts of a curing assistant, 3 parts of a cross-linking agent, 1 part of an adhesion additive and 5 parts of a catalyst. The film prepared by the invention has high wear resistance and thermal stability, long service life and high economic benefit.

Description

Formula of graphene rolled film
Technical Field
The invention relates to the improvement of the field of film forming, in particular to an improvement of a formula of a graphene calendered film.
Background
Graphite alkene calender is including steel band calendering device, heating furnace and material collecting device, at the during operation, provides graphite raw materials to steel band calendering device by feed bin and smooth silo, and calendering into the graphite flake with graphite raw materials through steel band calendering device, the graphite flake heats in order to discharge inside gas in the heating furnace, then convolutes the graphite flake through material collecting device. And graphite flake surface tension that graphite alkene calender produced is relatively poor, and the graphite flake rugosity appears easily at the in-process of convoluteing, the follow-up processing of being not convenient for, consequently need provide a membrane and be used for supporting the graphite flake, makes things convenient for it to wind up.
Disclosure of Invention
The technical problem to be solved by the invention is to overcome the defects of the prior art and provide a formula of a graphene calendered film.
In order to solve the technical problems, the invention is realized by adopting the following technical scheme: the formula of the graphene calendered film is characterized by comprising the following raw materials in parts by weight: 80 parts of solvent oil, 3 parts of an increment additive, 5 parts of main agent silicon, 3 parts of a curing assistant, 3 parts of a cross-linking agent, 1 part of an adhesion additive and 5 parts of a catalyst.
The increment additive is titanium dioxide.
The curing auxiliary agent is tertiary amine.
The adhesive force additive is a mixture of (3- (2, 3-epoxypropoxy) propyl) trimethoxy silane and vinyl triacetoxy silane.
The catalyst is a platinum catalyst.
The cross-linking agent is polydisiloxane with silicon-hydrogen bonds.
The preparation method has the beneficial effects that the formula of the improved graphene calendered film is improved, and the prepared film is high in wear resistance and thermal stability, long in service life and high in economic benefit.
Detailed Description
Further details are provided below. The formula of the graphene calendered film comprises the following raw materials in parts by weight: 80 parts of solvent oil, 3 parts of an increment additive, 5 parts of main agent silicon, 3 parts of a curing assistant, 3 parts of a cross-linking agent, 1 part of an adhesion additive and 5 parts of a catalyst.
The increment additive is titanium dioxide, and plays a role in increment.
The curing auxiliary agent is tertiary amine and plays a role in curing.
The adhesive force additive is a mixture of (3- (2, 3-epoxypropoxy) propyl) trimethoxysilane and vinyl triacetoxysilane, so that the adhesive force is enhanced.
The catalyst is a platinum catalyst and plays a role in acceleration.
The cross-linking agent is polydisiloxane with silicon-hydrogen bonds, and chemical bonds are generated among linear molecules, so that the linear molecules are mutually connected to form a net structure, and the strength and the elasticity of the film are improved.
In summary, the above description is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (6)

1. The formula of the graphene calendered film is characterized by comprising the following raw materials in parts by weight: 80 parts of solvent oil, 3 parts of an increment additive, 5 parts of main agent silicon, 3 parts of a curing assistant, 3 parts of a cross-linking agent, 1 part of an adhesion additive and 5 parts of a catalyst.
2. The formulation of a calendered film of graphene according to claim 1, wherein: the increment additive is titanium dioxide.
3. The formulation of a calendered film of graphene according to claim 1, wherein: the curing auxiliary agent is tertiary amine.
4. The formulation of a calendered film of graphene according to claim 1, wherein: the adhesive force additive is a mixture of (3- (2, 3-epoxypropoxy) propyl) trimethoxy silane and vinyl triacetoxy silane.
5. The formulation of a calendered film of graphene according to claim 1, wherein: the catalyst is a platinum catalyst.
6. The formulation of a calendered film of graphene according to claim 1, wherein: the cross-linking agent is polydisiloxane with silicon-hydrogen bonds.
CN201910966929.2A 2019-10-12 2019-10-12 Formula of graphene rolled film Pending CN110862690A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910966929.2A CN110862690A (en) 2019-10-12 2019-10-12 Formula of graphene rolled film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910966929.2A CN110862690A (en) 2019-10-12 2019-10-12 Formula of graphene rolled film

Publications (1)

Publication Number Publication Date
CN110862690A true CN110862690A (en) 2020-03-06

Family

ID=69652218

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910966929.2A Pending CN110862690A (en) 2019-10-12 2019-10-12 Formula of graphene rolled film

Country Status (1)

Country Link
CN (1) CN110862690A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111423828A (en) * 2020-04-30 2020-07-17 江苏耀昇新材料有限公司 Low-cost high-environmental-protection release film

Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101160340A (en) * 2004-12-29 2008-04-09 通用电气公司 Transparent compositions, methods for the preparation thereof, and articles derived therefrom
CN102120884A (en) * 2011-04-29 2011-07-13 常州天马集团有限公司 Organosilicon composition, and preparation method and application thereof
CN102549047A (en) * 2009-08-25 2012-07-04 道康宁公司 Process for the preparation of a silicone pressure-sensitive adhesive
CN103436094A (en) * 2013-08-27 2013-12-11 华南理工大学 Thermosetting high temperature resisting printing ink for touch screen as well as preparation method of printing ink
CN103619981A (en) * 2010-12-22 2014-03-05 道康宁公司 Silicone composition, silicone adhesive, coated and laminated substrates
CN105505298A (en) * 2015-12-11 2016-04-20 烟台德邦先进硅材料有限公司 Organic silica gel with high self-adsorption property and preparation method thereof
CN105764993A (en) * 2013-10-21 2016-07-13 Az电子材料（卢森堡）有限公司 Silicon-containing heat- or photo-curable composition
CN105838192A (en) * 2016-05-12 2016-08-10 武汉赫斯特涂层材料股份有限公司 Epoxy polysiloxane paint and preparing method
CN206124272U (en) * 2016-09-23 2017-04-26 陶旋 Graphite alkene calender
CN107254252A (en) * 2017-06-09 2017-10-17 常州市展明薄膜科技有限公司 A kind of graphite calendering mould release membrance mixed liquor and preparation method thereof
CN108276655A (en) * 2018-02-05 2018-07-13 合肥华盖光伏科技有限公司 A kind of high light transmittance asepsis environment-protecting encapsulating material
CN108541269A (en) * 2016-11-21 2018-09-14 日东电工株式会社 Bonding sheet
CN108530663A (en) * 2018-04-16 2018-09-14 皇冠（太仓）胶粘制品有限公司 A kind of graphite calendering release film
CN109096513A (en) * 2018-07-10 2018-12-28 温州新意特种纸业有限公司 A kind of PET release film and its manufacturing method
CN109401111A (en) * 2018-09-03 2019-03-01 李永平 A kind of high-performance calendering composite material method for shaping
CN209063650U (en) * 2018-11-02 2019-07-05 深圳市鑫银环保橡塑制品有限公司 A kind of heat sealable silicon rubber elastic body thin film and its production equipment
CN110256776A (en) * 2019-05-14 2019-09-20 佛山唯尔塑胶制品有限公司 A kind of environmental protection land protection film and its production technology

Patent Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101160340A (en) * 2004-12-29 2008-04-09 通用电气公司 Transparent compositions, methods for the preparation thereof, and articles derived therefrom
CN102549047A (en) * 2009-08-25 2012-07-04 道康宁公司 Process for the preparation of a silicone pressure-sensitive adhesive
CN103619981A (en) * 2010-12-22 2014-03-05 道康宁公司 Silicone composition, silicone adhesive, coated and laminated substrates
CN102120884A (en) * 2011-04-29 2011-07-13 常州天马集团有限公司 Organosilicon composition, and preparation method and application thereof
CN103436094A (en) * 2013-08-27 2013-12-11 华南理工大学 Thermosetting high temperature resisting printing ink for touch screen as well as preparation method of printing ink
CN105764993A (en) * 2013-10-21 2016-07-13 Az电子材料（卢森堡）有限公司 Silicon-containing heat- or photo-curable composition
CN105505298A (en) * 2015-12-11 2016-04-20 烟台德邦先进硅材料有限公司 Organic silica gel with high self-adsorption property and preparation method thereof
CN105838192A (en) * 2016-05-12 2016-08-10 武汉赫斯特涂层材料股份有限公司 Epoxy polysiloxane paint and preparing method
CN206124272U (en) * 2016-09-23 2017-04-26 陶旋 Graphite alkene calender
CN108541269A (en) * 2016-11-21 2018-09-14 日东电工株式会社 Bonding sheet
CN107254252A (en) * 2017-06-09 2017-10-17 常州市展明薄膜科技有限公司 A kind of graphite calendering mould release membrance mixed liquor and preparation method thereof
CN108276655A (en) * 2018-02-05 2018-07-13 合肥华盖光伏科技有限公司 A kind of high light transmittance asepsis environment-protecting encapsulating material
CN108530663A (en) * 2018-04-16 2018-09-14 皇冠（太仓）胶粘制品有限公司 A kind of graphite calendering release film
CN109096513A (en) * 2018-07-10 2018-12-28 温州新意特种纸业有限公司 A kind of PET release film and its manufacturing method
CN109401111A (en) * 2018-09-03 2019-03-01 李永平 A kind of high-performance calendering composite material method for shaping
CN209063650U (en) * 2018-11-02 2019-07-05 深圳市鑫银环保橡塑制品有限公司 A kind of heat sealable silicon rubber elastic body thin film and its production equipment
CN110256776A (en) * 2019-05-14 2019-09-20 佛山唯尔塑胶制品有限公司 A kind of environmental protection land protection film and its production technology

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
无: "中国专利", 《合成树脂及塑料》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111423828A (en) * 2020-04-30 2020-07-17 江苏耀昇新材料有限公司 Low-cost high-environmental-protection release film

Similar Documents

Publication Publication Date Title
CN104974530B (en) A kind of high-performance anti creepage trace silicon rubber and preparation method thereof
CN103642097B (en) A kind of preparation method of the nitrile rubber for preparing high abrasion float grease seal sealing ring
CN107011855A (en) Normal temperature cure sealant composition and preparation method thereof
CN110157376A (en) Transparent two-component silane modified polyether seal glue and preparation method thereof
CN110862690A (en) Formula of graphene rolled film
CN111819255B (en) Organosilicon materials
CN105802229A (en) Low-temperature-resistant mixed silicone rubber and preparation method thereof
CN109722216A (en) A kind of Silante terminated liquid polybutadiene modified organic silicon sealant and preparation method thereof
CN102133989A (en) Steel mesh conveying belt
CN102585728B (en) Adhesive for heat-resistant conveying belt and preparation method thereof
CN107189131B (en) Rubber composition, preparation method and its product of a kind of total wind hose internal layer of railway for braided steel wire structure
JP5714828B2 (en) Rubber composition for high damping bearing and high damping bearing
CN109292363A (en) A kind of thermostable planar band
CN104845570B (en) A kind of preparation method of high-strength adhesive composition
CN109266270A (en) A kind of adhesive and preparation method and application
CN103408950A (en) Oilproof high-temperature resistant rubber compound and preparation method thereof
Zhu et al. Functionalized silica as an eco-friendly vulcanization accelerator to enhance the interfacial interaction in NR/silica composites
KR20130035548A (en) Development of spray materials for pool runner by using silicon slurry
RU2009144010A (en) NANOSTRUCTURED FUNCTIONAL-GRADIENT COMPOSITE MATERIAL AND METHOD FOR ITS PRODUCTION
CN112625381A (en) Preparation method of wear-resistant mud pump acid baffle plate
CN107789919A (en) A kind of high temperature resistant dust-removal cloth-bag
Zhao et al. Preparation and properties of SBR/PPTA nanocomposite via in‐situ interfacial polycondensation
CN103665694A (en) Oxygen rubber hose
KR101558846B1 (en) Heat-resistant joint sheet using waste fiber
CN206552671U (en) A kind of seamless polytetrafluoroethylglass glass fiber Compound Fabric conveyer belt

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20200306

RJ01 Rejection of invention patent application after publication