CN110845919A - Double-coating protection system powder coating for highway guardrail - Google Patents
Double-coating protection system powder coating for highway guardrail Download PDFInfo
- Publication number
- CN110845919A CN110845919A CN201911115152.5A CN201911115152A CN110845919A CN 110845919 A CN110845919 A CN 110845919A CN 201911115152 A CN201911115152 A CN 201911115152A CN 110845919 A CN110845919 A CN 110845919A
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- coating
- protection system
- system powder
- highway
- powder coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2251—Oxides; Hydroxides of metals of chromium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a double-coating protection system powder coating for a highway guardrail, which comprises a first coating and a second coating; the first coating comprises the components: acrylic resin, metal oxide particles, an inorganic pigment, an ultraviolet absorber, a leveling agent and deionized water; the second coating comprises the following components: acrylic resin, glass beads; the second coating is coated on the surface of the first coating; the first coating is applied to the surface of the substrate. The guardrail is sprayed in a double-coating mode, the first coating is directly contacted with the guardrail, the ground color is provided, and the service life is good; the second coating provides both light reflection and scattering, greatly enhancing the road-pointing effect at low light levels.
Description
Technical Field
The invention belongs to the technical field of coatings, and particularly relates to a double-coating protection system powder coating for a highway guardrail.
Background
The highway guardrail is an important facility for maintaining the order of the highway and guaranteeing the driving safety, and has the first function of preventing the casualties caused by the accident rush of the automobile out of the highway; the second function is to guide the vehicle in the opening direction.
To enhance the guiding function of the guardrail, paint is often applied to the surface of the guardrail. The paint is required to have high reflectivity, weather resistance and obvious color.
The high reflectivity is used for reflecting the light of the vehicle lamp to remind a driver of the position of the road surface under the condition of insufficient illumination.
The weather resistance is to ensure that the coating still can play a role after long-term use.
Color conspicuity means that the coating typically needs to be sufficiently contrasting with its own color in an outdoor environment to prevent it from melting into the background; high saturation colors, which are relatively rare in nature, such as orange, white, pink, etc., are often used.
Disclosure of Invention
The invention aims to provide a double-coating protection system powder coating for a highway guardrail.
The technical scheme adopted by the invention for solving the technical problem is as follows:
a double-coating protection system powder coating for a highway guardrail comprises a first coating and a second coating;
the first coating comprises the following components in percentage by weight:
the second coating comprises the following components in percentage by weight:
acrylic resin 30-60
40-70 parts of glass beads;
the second coating is coated on the surface of the first coating; the first coating is coated on the surface of the substrate.
Preferably, the metal oxide particles comprise at least one of titania, alumina, zirconia, and zinc oxide.
Preferably, the metal oxide particles are titanium dioxide which is rutile and/or anatase.
Preferably, the leveling agent is an organic silicon leveling agent.
Preferably, the inorganic pigment includes at least one of iron oxide yellow, transparent iron yellow, titanium yellow, iron oxide red, chromium oxide green, iron blue and cobalt blue.
Preferably, the glass beads are solid glass beads.
Preferably, the diameter of the glass beads is 30 to 200 μm.
Preferably, the diameter of the metal oxide is 15 μm or less.
The guardrail is sprayed in a double-coating mode, the first coating is directly contacted with the guardrail, the ground color is provided, and the service life is good; the second coating provides both light reflection and scattering, greatly enhancing the road-pointing effect at low light levels.
The acrylic resin used in the present invention is a water-soluble thermoplastic acrylic resin, and is a main component of the coating material of the present invention. The metal oxide particles are used to provide sufficient covering power and to adjust the brightness of the inorganic colorant, and have a certain resistance to weathering. Although the inorganic pigment is not much in color richness, the use scene of the invention has low requirements on the richness of the color, and more requirements on color firmness and durability are higher; in this case, the inorganic coloring material has outstanding advantages of fastness in color, high durability and unsuitability for reaction with other components. Ultraviolet light absorbers and leveling agents are used to increase the weatherability of the coating. Deionized water is used to adjust the viscosity of the coating. The glass beads are used for increasing the light reflecting and scattering capacity of the coating, so that the driving of the vehicle can still be correctly guided in a dark environment.
Detailed Description
The following specific examples are provided to further illustrate the present invention so that those skilled in the art may better understand the invention and practice it, but the examples are not intended to limit the invention.
Highway barriers are in most cases made of metal, but in a few cases also cement-based. However, the surface of the guardrail is uneven and rough whether metal or cement is adopted, so that the surface of the guardrail needs to be filled by the first coating attached to the guardrail; and preferably the surface of the guard rail is properly ground flat prior to application.
Then, in order to extend the useful life of the coating, ultraviolet light absorbers are used to reduce the sun's damage to the coating.
The first coating is the key point of the coating system, and plays roles in protecting the guardrail, providing ground color and smoothing the surface of the guardrail.
In order to protect the first coating and to enhance the light reflecting and scattering capabilities of the coating, a second coating is provided. Therefore, the second coating layer must be transparent or otherwise obscure the undertone of the first coating layer.
In the invention:
the leveling agent is basf BYK-355 or BYK-3455; the ultraviolet light absorber is either a basf Tinuvin 5151 or Tinuvin 292; yellow iron oxide, transparent yellow iron oxide are produced by BAYFERROX company, yellow titanium is basf K2001FG, and red iron oxide is BAYFERROX 4130; chromium oxide green is produced by Bohai sea chemical group in Tianjin city, iron blue is produced by Zhejiang Yonghua chemical company, and cobalt blue is produced by Hunan Jufa scientific and technological company; the titanium dioxide is basf (basf) PA 6; the alumina is defluorination alumina of Shanghai Liangjiang titanium white chemical products, Inc.; zirconium oxide is produced by Yino chemical technology, Inc. of Guangzhou city; zinc oxide is produced by basf; the acrylic resin is Japanese mitsubishi BR-113 water-based acrylic resin; the glass beads are produced by Oncorhynchus Korea company, Tianjin City, Port, Germany and trade Co.
The manufacturing method of the invention is as follows:
a first coating layer:
heating the acrylic resin to a viscous state according to the measurement, wherein the acrylic resin shows the mechanical characteristics of the fluid; adding the metal oxide particles and the inorganic pigment at least 600rpm under the condition of keeping the temperature, and then adding the ultraviolet absorber and the leveling agent; finally adding deionized water and continuously rotating for a period of time; the entire mixing process remains sealed.
And (3) second coating:
before being mixed with acrylic resin, the glass beads need to be cleaned by distilled water and dried; then heating the acrylic resin to viscous state according to the measurement, adding the glass beads, uniformly mixing, and stopping after the rotation speed of 1500rpm is used for 20-60 minutes at 500rpm in the first 20 minutes after the addition.
Powder coatings were made according to the above-described manufacturing method, with the specific components listed in tables 1 and 2:
table 1: composition of the first coating
Table 2: components of the second coating
| Numbering | 1 | 2 | 3 | 4 | 5 | 6 |
| Acrylic resin | 30 | 40 | 45 | 50 | 55 | 60 |
| Glass micro-beads | 70 | 60 | 55 | 50 | 45 | 40 |
Wherein the units of the resins in tables 1 and 2 are weight percent.
When the tests are carried out according to the paint samples prepared in the tables 1 and 2, the industrial standard of the powder paint for the metal guardrail is still in the drafting stage during the tests, so that part of indexes and part of additional performance indexes in road marking paint JT/T280-2004 are used as performance test items of the invention, and hot-melt type reflective paint is used as the standard.
TABLE 3 paint Performance test results
The above-described embodiments of the present invention are not intended to limit the scope of the present invention, and the embodiments of the present invention are not limited thereto, and various other modifications, substitutions, or alterations made to the above-described structure of the present invention according to the general technical knowledge and conventional means of the art without departing from the basic technical idea of the present invention are intended to fall within the scope of the present invention.
Claims (8)
1. The utility model provides a highway is double-deck protection system powder coating for guardrail which characterized in that: comprises a first coating layer and a second coating layer;
the first coating comprises the following components in percentage by weight:
the second coating comprises the following components in percentage by weight:
acrylic resin 30-60
40-70 parts of glass beads;
the second coating is coated on the surface of the first coating; the first coating is coated on the surface of the substrate.
2. The dual coating protection system powder coating for highway barriers of claim 1 wherein: the metal oxide particles comprise at least one of titanium dioxide, aluminum oxide, zirconium oxide and zinc oxide.
3. The dual coating protection system powder coating for highway barriers of claim 2, wherein: the metal oxide particles are rutile and/or anatase titanium dioxide when the titanium dioxide is present.
4. The dual coating protection system powder coating for highway barriers of claim 1 wherein: the leveling agent is an organic silicon leveling agent.
5. The dual coating protection system powder coating for highway barriers of claim 1 wherein: the inorganic pigment comprises at least one of iron oxide yellow, transparent iron yellow, titanium yellow, iron oxide red, chromium oxide green, iron blue and cobalt blue.
6. The dual coating protection system powder coating for highway barriers of claim 1 wherein: the glass beads are solid glass beads.
7. The dual coating protection system powder coating for highway guardrails according to claim 1 or 6, wherein: the diameter of the glass beads is 30-200 microns.
8. The dual coating protection system powder coating for highway barriers according to any of claims 1-6, wherein: the diameter of the metal oxide is less than or equal to 15 micrometers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911115152.5A CN110845919A (en) | 2019-11-14 | 2019-11-14 | Double-coating protection system powder coating for highway guardrail |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911115152.5A CN110845919A (en) | 2019-11-14 | 2019-11-14 | Double-coating protection system powder coating for highway guardrail |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110845919A true CN110845919A (en) | 2020-02-28 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911115152.5A Pending CN110845919A (en) | 2019-11-14 | 2019-11-14 | Double-coating protection system powder coating for highway guardrail |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101948658A (en) * | 2010-09-26 | 2011-01-19 | 上海朗琦土木工程技术有限公司 | Road guardrail coating with width marking and warning function and preparation method thereof |
| CN103613698A (en) * | 2013-11-26 | 2014-03-05 | 王鹏飞 | Thermosetting acrylic resin for powder coating as well as synthesis method and applications of thermosetting acrylic resin |
| CN108587366A (en) * | 2018-04-16 | 2018-09-28 | 合肥天沃能源科技有限公司 | A kind of insulating mould coating exposed wall of building and preparation method thereof |
| CN109593469A (en) * | 2018-09-26 | 2019-04-09 | 河南天华交通科技有限公司 | A kind of waterborne road line paint and preparation method thereof |
| CN109897491A (en) * | 2017-12-07 | 2019-06-18 | 洛阳尖端技术研究院 | Heat insulating reflecting coating and its application in the helmet |
-
2019
- 2019-11-14 CN CN201911115152.5A patent/CN110845919A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101948658A (en) * | 2010-09-26 | 2011-01-19 | 上海朗琦土木工程技术有限公司 | Road guardrail coating with width marking and warning function and preparation method thereof |
| CN103613698A (en) * | 2013-11-26 | 2014-03-05 | 王鹏飞 | Thermosetting acrylic resin for powder coating as well as synthesis method and applications of thermosetting acrylic resin |
| CN109897491A (en) * | 2017-12-07 | 2019-06-18 | 洛阳尖端技术研究院 | Heat insulating reflecting coating and its application in the helmet |
| CN108587366A (en) * | 2018-04-16 | 2018-09-28 | 合肥天沃能源科技有限公司 | A kind of insulating mould coating exposed wall of building and preparation method thereof |
| CN109593469A (en) * | 2018-09-26 | 2019-04-09 | 河南天华交通科技有限公司 | A kind of waterborne road line paint and preparation method thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200228 |
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