CN110790945A - 一种阳离子化腐殖酸及其制备方法和应用 - Google Patents
一种阳离子化腐殖酸及其制备方法和应用 Download PDFInfo
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- CN110790945A CN110790945A CN201911173104.1A CN201911173104A CN110790945A CN 110790945 A CN110790945 A CN 110790945A CN 201911173104 A CN201911173104 A CN 201911173104A CN 110790945 A CN110790945 A CN 110790945A
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- humic acid
- cationized
- fertilizer
- acid
- centrifuging
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- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title claims abstract description 88
- 239000004021 humic acid Substances 0.000 title claims abstract description 88
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000003337 fertilizer Substances 0.000 claims abstract description 57
- 239000007788 liquid Substances 0.000 claims abstract description 34
- 239000002686 phosphate fertilizer Substances 0.000 claims abstract description 24
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000006243 chemical reaction Methods 0.000 claims abstract description 20
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000001035 drying Methods 0.000 claims abstract description 12
- 239000002244 precipitate Substances 0.000 claims abstract description 12
- 238000005406 washing Methods 0.000 claims abstract description 12
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 6
- 238000005507 spraying Methods 0.000 claims abstract description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000011574 phosphorus Substances 0.000 claims abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 239000003077 lignite Substances 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 9
- 239000002689 soil Substances 0.000 abstract description 7
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 6
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 abstract description 4
- 229910000389 calcium phosphate Inorganic materials 0.000 abstract description 4
- 230000007547 defect Effects 0.000 abstract description 4
- 235000019691 monocalcium phosphate Nutrition 0.000 abstract description 4
- 239000002688 soil aggregate Substances 0.000 abstract description 4
- 235000015097 nutrients Nutrition 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 238000003786 synthesis reaction Methods 0.000 description 5
- 241000233679 Peronosporaceae Species 0.000 description 3
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 3
- 244000046052 Phaseolus vulgaris Species 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 238000012271 agricultural production Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000021049 nutrient content Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical group OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H6/00—Macromolecular compounds derived from lignin, e.g. tannins, humic acids
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
- C05F11/02—Other organic fertilisers from peat, brown coal, and similar vegetable deposits
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07G—COMPOUNDS OF UNKNOWN CONSTITUTION
- C07G99/00—Subject matter not provided for in other groups of this subclass
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Fertilizers (AREA)
Abstract
Description
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CN110790945A true CN110790945A (zh) | 2020-02-14 |
CN110790945B CN110790945B (zh) | 2021-06-18 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115093405A (zh) * | 2022-05-20 | 2022-09-23 | 河北萌帮生物科技有限公司 | 一种抗高硬水磺化腐植酸及其制备方法 |
Citations (12)
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US3671427A (en) * | 1970-01-15 | 1972-06-20 | Nl Industries Inc | Lignite products and compositions thereof |
CN1434006A (zh) * | 2002-01-21 | 2003-08-06 | 中国科学院山西煤炭化学研究所 | 一种长效腐植酸磷肥及其制备方法 |
US20090199473A1 (en) * | 2008-02-13 | 2009-08-13 | Watson Jr William J | Horticultural Growth Medium |
CN101700986A (zh) * | 2009-11-18 | 2010-05-05 | 陕西科技大学 | 一种具有核壳结构的腐殖酸有机无机多元肥的制备工艺 |
CN102239794A (zh) * | 2011-04-13 | 2011-11-16 | 方宁 | 用煤炭腐植酸生产环保全降解转肥液态地膜的技术 |
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CN106966812A (zh) * | 2017-04-27 | 2017-07-21 | 陕西科技大学 | 一种液体腐殖酸肥料及其制备方法 |
CN107325820A (zh) * | 2017-07-04 | 2017-11-07 | 江苏东珠景观股份有限公司 | 一种适于景观生态系统的土壤修复剂 |
CN107879826A (zh) * | 2017-12-28 | 2018-04-06 | 湖南辰砾新材料有限公司 | 一种高效环保肥料及其制备方法 |
-
2019
- 2019-11-26 CN CN201911173104.1A patent/CN110790945B/zh active Active
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US3671427A (en) * | 1970-01-15 | 1972-06-20 | Nl Industries Inc | Lignite products and compositions thereof |
CN1434006A (zh) * | 2002-01-21 | 2003-08-06 | 中国科学院山西煤炭化学研究所 | 一种长效腐植酸磷肥及其制备方法 |
US20090199473A1 (en) * | 2008-02-13 | 2009-08-13 | Watson Jr William J | Horticultural Growth Medium |
CN101700986A (zh) * | 2009-11-18 | 2010-05-05 | 陕西科技大学 | 一种具有核壳结构的腐殖酸有机无机多元肥的制备工艺 |
CN102239794A (zh) * | 2011-04-13 | 2011-11-16 | 方宁 | 用煤炭腐植酸生产环保全降解转肥液态地膜的技术 |
CN103771930A (zh) * | 2012-10-24 | 2014-05-07 | 大连鹤菲英博科技有限公司 | 一种腐殖酸磷铵的制备方法 |
CN104559959A (zh) * | 2013-10-23 | 2015-04-29 | 中国石油化工股份有限公司 | 一种腐植酸油溶性降滤失剂及其制备方法 |
CN103539575A (zh) * | 2013-11-08 | 2014-01-29 | 南开大学 | 一种黄腐酸类马铃薯专用高效液体复合肥的研制 |
CN106565307A (zh) * | 2016-10-20 | 2017-04-19 | 成都新柯力化工科技有限公司 | 一种改性腐植酸螯合水溶肥及其制备方法 |
CN106966812A (zh) * | 2017-04-27 | 2017-07-21 | 陕西科技大学 | 一种液体腐殖酸肥料及其制备方法 |
CN107325820A (zh) * | 2017-07-04 | 2017-11-07 | 江苏东珠景观股份有限公司 | 一种适于景观生态系统的土壤修复剂 |
CN107879826A (zh) * | 2017-12-28 | 2018-04-06 | 湖南辰砾新材料有限公司 | 一种高效环保肥料及其制备方法 |
Non-Patent Citations (7)
Title |
---|
C. GAMBOA, A.F. OLEA: "Association of cationic surfactants to humic acid Effect on the surface activity", 《COLLOIDS AND SURFACES A: PHYSICOCHEM. ENG. ASPECTS》 * |
CHEN WANG 等: "Interactions between fluorinated cationic guar gum and surfactants inthe dilute and semi-dilute solutions", 《CARBOHYDRATE POLYMERS》 * |
李军 等: "磷肥中腐植酸添加比例对玉米产量、磷素吸收及土壤速效磷含量的影响", 《植物营养与肥料学报》 * |
秦勇: "《化石能源地质学导论》", 30 September 2017, 中国矿业大学出版社 * |
蒋晨义 等: "腐植酸活化改性技术在肥料生产中的应用研究", 《陕西农业科学》 * |
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黄昌勇 等: "《土壤学》", 31 May 2000, 中国农业大学出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115093405A (zh) * | 2022-05-20 | 2022-09-23 | 河北萌帮生物科技有限公司 | 一种抗高硬水磺化腐植酸及其制备方法 |
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Effective date of registration: 20240108 Address after: 466000 meters east of Roulian Factory, Huizu Town, Chengguan, Huaiyang County, Zhoukou City, Henan Province Patentee after: Huaiyang Jinwanda Biotechnology Co.,Ltd. Address before: 710000 No. B49, Xinda Zhongchuang space, 26th Street, block C, No. 2 Trading Plaza, South China City, international port district, Xi'an, Shaanxi Province Patentee before: Xi'an Huaqi Zhongxin Technology Development Co.,Ltd. Effective date of registration: 20240108 Address after: 710000 No. B49, Xinda Zhongchuang space, 26th Street, block C, No. 2 Trading Plaza, South China City, international port district, Xi'an, Shaanxi Province Patentee after: Xi'an Huaqi Zhongxin Technology Development Co.,Ltd. Address before: 710021 Shaanxi province Xi'an Weiyang University Park Patentee before: SHAANXI University OF SCIENCE & TECHNOLOGY |
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