CN110790558A - Moisture-proof light plastering gypsum capable of releasing negative oxygen ions and preparation method thereof - Google Patents

Moisture-proof light plastering gypsum capable of releasing negative oxygen ions and preparation method thereof Download PDF

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Publication number
CN110790558A
CN110790558A CN201911122623.5A CN201911122623A CN110790558A CN 110790558 A CN110790558 A CN 110790558A CN 201911122623 A CN201911122623 A CN 201911122623A CN 110790558 A CN110790558 A CN 110790558A
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component
negative oxygen
moisture
oxygen ion
gypsum
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Inventor
陈小平
李军
付伯平
刘永
雷勇
杨再祥
何金泉
王涵
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Guizhou Housing Industry Co Ltd Fuquan Blueprint
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Guizhou Housing Industry Co Ltd Fuquan Blueprint
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C04B28/145Calcium sulfate hemi-hydrate with a specific crystal form
    • C04B28/147Calcium sulfate hemi-hydrate with a specific crystal form beta-hemihydrate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/10Mortars, concrete or artificial stone characterised by specific physical values for the viscosity
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Building Environments (AREA)

Abstract

The invention discloses moistureproof light plastering gypsum capable of releasing negative oxygen ions and a preparation method thereof, wherein the plastering gypsum comprises β semi-hydrated gypsum components, light aggregate components, pH regulator components, water retention agent components, modifier components, retarder components, waterproof agents and negative oxygen ion powder components, wherein β semi-hydrated gypsum components are 60-85 parts, light aggregate components are 8-15 parts, pH regulator components are 0-5 parts, water retention agent components are 0.1-0.5 part, modifier components are 0.01-0.1 part, waterproof agent components are 0.05-0.5 part, retarder components are 0.1-0.4 part and negative oxygen ion powder components are 1-10 parts.

Description

Moisture-proof light plastering gypsum capable of releasing negative oxygen ions and preparation method thereof
Technical Field
The invention belongs to the field of building materials, and particularly relates to moisture-proof light plastering gypsum capable of releasing negative oxygen ions and a preparation method thereof.
Background
In recent years, with the improvement of the living standard of people, people have higher and higher requirements on indoor decoration standards, and indoor air pollution has diversity, which includes both the diversity of pollutant types and the diversity of indoor pollutant sources, namely, physical pollution (dust particles and the like), chemical pollution (formaldehyde and the like), and microbial pollution (bacteria, viruses and the like). Because the indoor environment is a relatively closed space, the air circulation is poor, pollutants entering the room are easy to accumulate indoors, the pollution index is increased, the pollutant concentration is increased, and the harm to human bodies is further caused.
Generally, people need about 130 million negative oxygen ions per day, and our environment such as bedrooms, offices, entertainment places, etc. can only provide about 1-20 million negative oxygen ions. This large contrast between supply and demand often leads to respiratory diseases such as pneumonia and tracheitis.
At present, negative oxygen ions are often expelled due to an air conditioning system of central heating and cooling equipment used in a house; the used synthetic fiber and carpet have positive charges and are easy to absorb negative oxygen ions; and the wall body, the reinforcing steel bar and the fiber board of the house all absorb negative oxygen ions, so that the negative oxygen ions in the house are difficult to meet the requirements.
Disclosure of Invention
The invention aims to provide a moisture-proof light plastering gypsum capable of releasing negative oxygen ions.
To achieve the purpose of the invention, the moisture-proof releasable negative oxygen ion light plastering gypsum provided herein comprises β hemihydrate gypsum component, lightweight aggregate component, pH regulator component, water retention agent component, modifier component, retarder component, water repellent component and negative oxygen ion powder component.
Wherein the β hemihydrate gypsum component, the lightweight aggregate component, the pH regulator component, the water-retaining agent component, the modifier component, the retarder component, the water-proofing agent component and the negative oxygen ion component are in parts by weight:
Figure BDA0002275843490000021
the invention also aims to provide a method for preparing moisture-proof releasable negative oxygen ion light plastering gypsum, which specifically comprises the following steps:
step S01: firstly, mixing and stirring a pH regulator component, a water-retaining agent component, a modifier component, a retarder component and a negative oxygen ion component uniformly for later use;
step S02, adding β hemihydrate gypsum component into the mixture formed in the step S01 and stirring uniformly;
step S03: adding the lightweight aggregate component into the mixture formed in the step S02, and uniformly stirring to obtain a lightweight plastering gypsum powder material capable of releasing negative oxygen ions;
step S04: and (4) measuring the water consumption for the standard consistency of the light plastering gypsum powder material capable of releasing negative oxygen ions obtained in the step (S03), adding a waterproof agent into water in proportion, adding the light plastering gypsum powder material capable of releasing negative oxygen ions obtained in the step (S03), stirring into paste, and performing construction and drying to obtain the moisture-proof light plastering gypsum capable of releasing negative oxygen ions.
The invention has the beneficial effects that: the gypsum plaster provided by the invention is added with negative oxygen ion powder, and the negative oxygen ion powder can generate negative oxygen ions due to the pyroelectricity and piezoelectricity; the negative oxygen ions can promote the human body to synthesize and store vitamins, and strengthen and activate the physiological activities of the human body.
The plastering gypsum provided by the invention also comprises a gypsum component, so that the plastering gypsum has better flame retardance; the plastering gypsum provided by the invention also has the characteristics of heat insulation, sound absorption, impact resistance, moisture resistance and the like under the action of the water retention agent component, the modifier component, the retarder component and the waterproof agent component.
Detailed Description
In order to better understand the technical solutions provided by the present invention, the following embodiments are further illustrated, but the technical solutions claimed by the present invention are not limited to the following embodiments.
The invention provides moisture-proof light plastering gypsum capable of releasing negative oxygen ions, which comprises β semi-hydrated gypsum component, light aggregate component, pH regulator component, water retention agent component, modifier component, retarder component, waterproof agent component and negative oxygen ion powder component, wherein the weight proportions of the components are as follows.
Example one
The moisture-proof light plastering gypsum capable of releasing negative oxygen ions provided by the embodiment comprises β hemihydrate gypsum component, a light aggregate component, a pH regulator component, a water-retaining agent component, a modifier component, a retarder component, a waterproof agent component and negative oxygen ion powder component, wherein the components are as follows by weight:
Figure BDA0002275843490000031
Figure BDA0002275843490000041
weighing a pH regulator component, a water-retaining agent component, a modifier component, a retarder component and a negative oxygen ion powder component according to the weight parts of the formula, stirring the components in a stirrer for 3min to be used, weighing β semi-hydrated gypsum component according to the weight parts, pouring the weighed components into a gravity-free stirrer, adding the uniformly stirred pH regulator component, the water-retaining agent component, the modifier component, the retarder component and the negative oxygen ion component, stirring the components together with β semi-hydrated gypsum component in the gravity-free stirrer for 3min, finally adding a light aggregate component weighed according to the weight parts, stirring for 5min to prepare a uniformly stirred plastering gypsum powder material capable of releasing negative oxygen ions, measuring the standard water consumption of the powder material, adding a waterproof agent into water, adding the powder material, stirring the mixture into paste, and constructing and drying to obtain the moisture-proof type plastering gypsum capable of releasing negative oxygen ions.
Example two
The moisture-proof light plastering gypsum capable of releasing negative oxygen ions provided by the embodiment comprises β hemihydrate gypsum component, a light aggregate component, a pH regulator component, a water-retaining agent component, a modifier component, a retarder component, a waterproof agent component and negative oxygen ion powder component, wherein the components are as follows by weight:
Figure BDA0002275843490000042
Figure BDA0002275843490000051
weighing a pH regulator component, a water-retaining agent component, a modifier component, a retarder component and a negative oxygen ion powder component according to the weight parts of the formula, stirring the components in a stirrer for 3min to be used, weighing β semi-hydrated gypsum component according to the weight parts, pouring the weighed components into a gravity-free stirrer, adding the uniformly stirred pH regulator component, the water-retaining agent component, the modifier component, the retarder component and the negative oxygen ion component, stirring the components together with β semi-hydrated gypsum component in the gravity-free stirrer for 3min, finally adding a light aggregate component weighed according to the weight parts, stirring for 5min to prepare a uniformly stirred plastering gypsum powder material capable of releasing negative oxygen ions, measuring the standard water consumption of the powder material, adding a waterproof agent into water, adding the powder material, stirring the mixture into paste, and constructing and drying to obtain the moisture-proof type plastering gypsum capable of releasing negative oxygen ions.
EXAMPLE III
The moisture-proof light plastering gypsum capable of releasing negative oxygen ions provided by the embodiment comprises β hemihydrate gypsum component, a light aggregate component, a pH regulator component, a water-retaining agent component, a modifier component, a retarder component, a waterproof agent component and negative oxygen ion powder component, wherein the components are as follows by weight:
Figure BDA0002275843490000052
Figure BDA0002275843490000061
weighing a pH regulator component, a water-retaining agent component, a modifier component, a retarder component and a negative oxygen ion powder component according to the weight parts of the formula, stirring the components in a stirrer for 3min to be used, weighing β semi-hydrated gypsum component according to the weight parts, pouring the weighed components into a gravity-free stirrer, adding the uniformly stirred pH regulator component, the water-retaining agent component, the modifier component, the retarder component and the negative oxygen ion component, stirring the components together with β semi-hydrated gypsum component in the gravity-free stirrer for 3min, finally adding a light aggregate component weighed according to the weight parts, stirring for 5min to prepare a uniformly stirred plastering gypsum powder material capable of releasing negative oxygen ions, measuring the standard water consumption of the powder material, adding a waterproof agent into water, adding the powder material, stirring the mixture into paste, and constructing and drying to obtain the moisture-proof type plastering gypsum capable of releasing negative oxygen ions.
The moisture-proof releasable negative oxygen ion plastering gypsum provided in the first, second and third embodiments is placed in a standard laboratory for 24 hours, and is tested according to the national standards GB/T9775-2008 and GB/T26827-2012 for the performances of water absorption, oven dry breaking strength, oven dry compressive strength, tensile bond strength, actual coating area, negative oxygen ion release amount and the like for 2 hours, and the test results are as follows:
table 1 table of performance test results
Testing performance Example one Example two EXAMPLE III
Negative oxygen ion release amount/cm before test3 40 40 40
Negative oxygen ion release amount per cm after test3 2300 4700 7100
Absolute dry rupture strength/Mpa 2.0 1.8 1.6
Absolute dry compressive strength/Mpa 4.2 4.0 3.6
Tensile bond strength/MPa 0.58 0.49 0.40
Actual application area/m 2 130 130 130
2h water absorption/%) 5 4 2
As can be seen from the table, the water absorption rate was gradually decreased and the negative oxygen ion release amount was gradually increased for 2 hours as the addition amounts of the waterproofing agent and the negative oxygen ion powder were gradually increased.
The β semi-hydrated gypsum described in the first, second and third embodiments is β semi-hydrated gypsum, which is prepared by calcining dihydrate gypsum at 140-150 ℃ for 2-6h and aging for 72h, and has a pH value of 6-7, and meets the 3.0 grade standard of building gypsum.
The lightweight aggregate components described in the first, second and third examples are closed-cell vitrified microspheres of 50-70 mesh, a water absorption of less than 10%, and a volume weight of 110-3(ii) a Of course, other lightweight aggregates may be used.
The components of the pH regulator described in the first, second and third embodiments are sierozem powder of 100-120 meshes; of course, other pH adjusting agents may be used.
The water retention agent described in the first embodiment, the second embodiment and the third embodiment is hydroxypropyl methyl cellulose ether, the viscosity is 50000-100000 Pa.s; of course, other water-retaining agents may be used.
Any of the modifiers described in examples one, two and three can be used, and starch ether is used herein.
The retarder components described in examples one, two and three may be any retarder, and here, a protein retarder is used.
The water repellent components described in examples one, two and three can be any water repellent, and methyl hydrogen silicone oil emulsion is used herein.
The oxygen anion powder described in the first, second and third embodiments may be any oxygen anion powder, and the oxygen anion powder is prepared by mixing 65% of rare earth, 30% of tourmaline powder, 5% of other mineral substances and 40000 negative oxygen ion release amount/cm3
The moisture-proof light plastering gypsum capable of releasing negative oxygen ions provided by the invention has the advantages that the absolute dry breaking strength is more than 1.3MPa, the compressive strength is more than 2.5MPa, the tensile bonding strength is more than 0.3MPa, and the volume density is less than 1000Kg/m3The water absorption rate is less than or equal to 2h5% of negative oxygen ion releasing amount>2000 pieces/cm3The coating has the characteristics of good moisture resistance, large negative oxygen ion release amount, light weight, high strength, no hollowing, no cracking, environmental protection and the like, belongs to a functional plastering gypsum material, has market competitiveness compared with the traditional plastering gypsum material, and has important significance for promoting the comprehensive utilization of gypsum.
The first embodiment, the second embodiment and the third embodiment are stirred in the gravity-free stirrer, and the gravity-free stirrer can prevent the lightweight aggregate from being damaged in the stirring process, so that the coating area of the material can be increased.
When the plastering gypsum provided by the invention is used for plastering a house, the house can generate negative oxygen ions, the requirement of people on the negative oxygen ions is met, the respiratory diseases such as pneumonia and tracheitis are reduced, and healthy living is realized.
Plastering is a traditional construction method for plastering the surfaces of walls, floors and ceilings of house buildings by mortar; the plastering engineering comprises internal plastering and external plastering. Plastering at various indoor parts is generally called inner plastering, such as floor, ceiling, dado, skirting line, inner stairs and the like; the plastering at various outdoor positions is called external plastering, such as external walls, rainsheds, balconies, roofs and the like.
The inner plastering mainly protects the wall, improves the indoor sanitary condition, enhances the light reflection and beautifies the environment; in rooms which are easily corroded by moisture or acid and alkali, the protective layer mainly plays a role in protecting wall bodies, ceilings and floors.
The external plastering is mainly used for protecting the wall from being eroded by wind, rain and snow, improving the capabilities of moisture protection, weathering resistance and heat insulation of the wall and improving the durability of the wall, and is also one of measures for carrying out artistic treatment on the surfaces of various buildings.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.

Claims (12)

1. A moisture-proof light plastering gypsum capable of releasing negative oxygen ions is characterized by comprising β semi-hydrated gypsum component, light aggregate component, pH regulator component, water retention agent component, modifier component, retarder component, waterproofing agent component and negative oxygen ion powder component.
2. The moisture-proof releasable negative oxygen ion light-weight plastering gypsum of claim 1, wherein the β hemihydrate gypsum component, the lightweight aggregate component, the pH regulator component, the water retention agent component, the modifier component, the retarder component, the water repellent component and the negative oxygen ion powder component are in parts by weight:
Figure FDA0002275843480000011
3. the moisture-proof releasable negative oxygen ion light-weight plastering gypsum of claim 1 or 2, wherein the β hemihydrate gypsum component meets the building gypsum 3.0 grade standard.
4. The moisture-proof releasable negative oxygen ion lightweight plastering gypsum according to claim 1 or 2, wherein: the light aggregate component is closed-cell vitrified micro-beads with 50-70 meshes, the water absorption rate is less than 10 percent, and the volume weight is 110-140kg/m3
5. The moisture-proof releasable negative oxygen ion lightweight plastering gypsum according to claim 1 or 2, wherein: the pH regulator comprises ash calcium powder of 100-120 meshes.
6. The moisture-proof releasable negative oxygen ion lightweight plastering gypsum according to claim 1 or 2, wherein: the component of the water retention agent is hydroxypropyl methyl cellulose ether, and the viscosity is 50000-100000Pa & s.
7. The moisture-proof releasable negative oxygen ion lightweight plastering gypsum according to claim 1 or 2, wherein: the modifier component is starch ether.
8. The moisture-proof releasable negative oxygen ion lightweight plastering gypsum according to claim 1 or 2, wherein: the retarder component is a protein retarder.
9. The moisture-proof releasable negative oxygen ion lightweight plastering gypsum according to claim 1 or 2, wherein: the waterproof agent component is methyl hydrogen-containing silicone oil emulsion.
10. The moisture-proof releasable negative oxygen ion lightweight plastering gypsum according to claim 1 or 2, wherein: the negative oxygen ion powder comprises 65% of rare earth, 30% of tourmaline powder, 5% of other mineral substances and 40000 negative oxygen ion release amount/cm which are synthesized by mixing multiple elements3
11. The preparation method of the moisture-proof releasable negative oxygen ion light plastering gypsum of any one of claims 1 to 10, which is characterized in that: the method comprises the following steps:
step S01: firstly, mixing and stirring a pH regulator component, a water-retaining agent component, a modifier component, a retarder component and a negative oxygen ion component uniformly for later use;
step S02, adding β hemihydrate gypsum component into the mixture formed in the step S01 and stirring uniformly;
step S03: adding the lightweight aggregate component into the mixture formed in the step S02, and uniformly stirring to obtain a lightweight plastering gypsum powder material capable of releasing negative oxygen ions;
step S04: and (4) measuring the water consumption for the standard consistency of the light plastering gypsum powder material capable of releasing negative oxygen ions obtained in the step (S03), adding a waterproof agent into water in proportion, adding the light plastering gypsum powder material capable of releasing negative oxygen ions obtained in the step (S03), stirring into paste, and performing construction and drying to obtain the moisture-proof light plastering gypsum capable of releasing negative oxygen ions.
12. The method of claim 11, wherein: the step S02 is to stir in a gravity-free stirrer.
CN201911122623.5A 2019-11-15 2019-11-15 Moisture-proof light plastering gypsum capable of releasing negative oxygen ions and preparation method thereof Pending CN110790558A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113233858A (en) * 2021-05-31 2021-08-10 首建新材料(山东)有限公司 Environment-friendly plastering material for building interior walls and preparation method thereof

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JP2008266066A (en) * 2007-04-19 2008-11-06 Eau De Merus Co Ltd Powder for building material and building material containing powder for building material
CN101691292A (en) * 2009-09-30 2010-04-07 谢日清 Lightweight wall plaster
CN107382246A (en) * 2017-07-31 2017-11-24 湖北萨利赫新材料有限公司 With brushing gypsum for eliminating formaldehyde, releasing negative oxygen ion and preparation method thereof
CN108147839A (en) * 2018-01-10 2018-06-12 曹希成 A kind of anion plasterboard
CN108793920A (en) * 2018-07-20 2018-11-13 宁波荣山新型材料有限公司 A kind of ardealite base lightweight plastering gupsum product
CN109626927A (en) * 2018-12-29 2019-04-16 泰山石膏有限公司 A kind of lightweight desulfurization plastering gupsum
CN110423083A (en) * 2019-08-20 2019-11-08 北京建筑材料科学研究总院有限公司 A kind of multi-function plaster base mortar and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008266066A (en) * 2007-04-19 2008-11-06 Eau De Merus Co Ltd Powder for building material and building material containing powder for building material
CN101691292A (en) * 2009-09-30 2010-04-07 谢日清 Lightweight wall plaster
CN107382246A (en) * 2017-07-31 2017-11-24 湖北萨利赫新材料有限公司 With brushing gypsum for eliminating formaldehyde, releasing negative oxygen ion and preparation method thereof
CN108147839A (en) * 2018-01-10 2018-06-12 曹希成 A kind of anion plasterboard
CN108793920A (en) * 2018-07-20 2018-11-13 宁波荣山新型材料有限公司 A kind of ardealite base lightweight plastering gupsum product
CN109626927A (en) * 2018-12-29 2019-04-16 泰山石膏有限公司 A kind of lightweight desulfurization plastering gupsum
CN110423083A (en) * 2019-08-20 2019-11-08 北京建筑材料科学研究总院有限公司 A kind of multi-function plaster base mortar and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113233858A (en) * 2021-05-31 2021-08-10 首建新材料(山东)有限公司 Environment-friendly plastering material for building interior walls and preparation method thereof

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Application publication date: 20200214