CN110777018A - Engine cleaning agent and preparation method thereof - Google Patents

Engine cleaning agent and preparation method thereof Download PDF

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Publication number
CN110777018A
CN110777018A CN201911150428.3A CN201911150428A CN110777018A CN 110777018 A CN110777018 A CN 110777018A CN 201911150428 A CN201911150428 A CN 201911150428A CN 110777018 A CN110777018 A CN 110777018A
Authority
CN
China
Prior art keywords
parts
cleaning agent
preparation
engine
engine cleaning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911150428.3A
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Chinese (zh)
Inventor
邵将
王亚君
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henan Minefield Oil Co Ltd
Original Assignee
Henan Minefield Oil Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henan Minefield Oil Co Ltd filed Critical Henan Minefield Oil Co Ltd
Priority to CN201911150428.3A priority Critical patent/CN110777018A/en
Publication of CN110777018A publication Critical patent/CN110777018A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • C11D1/831Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0073Anticorrosion compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/24Organic compounds containing halogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Lubricants (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses an engine cleaning agent and a preparation method thereof, wherein the engine cleaning agent is prepared from the following raw materials in parts by weight: 32-60 parts of dipropylene glycol ether, 20-40 parts of dichloromethane, 16-23 parts of ethanol, 15-18 parts of fatty alcohol-polyoxyethylene ether, 14-16 parts of trichloroethylene, 1-2 parts of corrosion inhibitor hexadecylamine, 0.5-2 parts of antiwear additive calcium borate, 0.5-2 parts of metal deactivator N.N' -methylene propylene diamine and 0.1-1 part of surfactant sodium dodecyl sulfate. The cleaning agent is simple to prepare, can effectively remove substances in an automobile engine, prolongs the service life of the automobile, does not need to be added with a protective agent after being cleaned, and does not have the phenomenon of oil leakage around a crankshaft oil seal and a valve chamber cover.

Description

Engine cleaning agent and preparation method thereof
Technical Field
The invention relates to the field of preparation of cleaning agents, in particular to an engine cleaning agent and a preparation method thereof.
Background
The cleaning agent for the interior of the engine is a product developed for solving the problem of oil sludge, colloid, carbon deposition, paint film, dirt and other deposits formed in the lubricating system, consists of a plurality of components with very strong cleaning capability, and is an additive capable of automatically cleaning the internal system of the lubricating system. The cleaning agent for the interior of the engine is added into the crankcase of the engine, and flows along with engine oil during the operation of the engine, so that the cleaning process can be completed, the colloid can be dissolved, and the adhered sediments become loose and then fall off. Paint film, carbon deposit, oil sludge and other deposits on piston rings, piston skirt portions and the like can be thoroughly removed. The cleaned deposits can be filtered by an oil filter along with the circulation of the oil or deposited in an oil pan and removed together when the oil filter and the oil pan are replaced and cleaned.
The existing engine cleaning method is to pour the cleaning agent into the engine oil tank and then to run for about 20 minutes to clean, and because the cleaning time is too short and the cleaning steps are too simple, the cleaning effect is not ideal. The existing cleaning agent basically takes a solvent as a main body and is assisted with other chemicals, and has the advantages of quick and labor-saving engine cleaning, and the defects that the solvent used by some formulas is toxic, and some patents have no actual use methods, so that maintenance personnel of the engine cannot perform cleaning work; the solvents used in most patents are the cellosolve family of products, such as: the use of ethylene glycol butyl ether, ethylene glycol monobutyl ether, propylene glycol methyl ether, ethylene glycol monobutyl ether, and polyethylene oxide-propylene oxide monobutyl ether, as a large amount of these cellosolve solvents, is liable to be flammable and dangerous.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides the engine cleaning agent and the preparation method thereof, the preparation is simple, substances in an automobile engine can be effectively removed, the service life of a vehicle is prolonged, no protective agent needs to be added after cleaning, and the phenomena of oil leakage around a crankshaft oil seal and a valve chamber cover can be avoided.
In order to achieve the aim of the invention, the invention adopts the specific scheme that:
an engine cleaning agent and a preparation method thereof are prepared from the following raw materials in parts by weight: 32-60 parts of dipropylene glycol ether, 20-40 parts of dichloromethane, 16-23 parts of ethanol, 15-18 parts of fatty alcohol-polyoxyethylene ether, 14-16 parts of trichloroethylene, 1-2 parts of corrosion inhibitor hexadecylamine, 0.5-2 parts of antiwear additive calcium borate, 0.5-2 parts of metal deactivator N.N' -methylene propylene diamine and 0.1-1 part of surfactant sodium dodecyl sulfate.
Further, the engine cleaning agent and the preparation method thereof comprise the following steps:
(1) adding dipropylene glycol ether, dichloromethane, ethanol, fatty alcohol-polyoxyethylene ether, trichloroethylene, a corrosion inhibitor hexadecylamine, an antiwear additive calcium borate, a metal passivator N.N' -methylene propylene diamine and a surface active agent sodium dodecyl sulfate into a reaction tank in sequence, heating to 40-60 ℃, and stirring at a constant temperature for 0.8-1.4h to fully fuse all the raw materials;
(2) adding an alkaline solution, adjusting the pH value, measuring the pH value of the product in the reaction tank by using standard test paper, and stopping adding the alkaline solution when the pH value is 7.
The invention has the beneficial effects that:
the cleaning agent is simple to prepare, can effectively remove substances in an automobile engine, prolongs the service life of the automobile, does not need to be added with a protective agent after being cleaned, and does not have the phenomenon of oil leakage around a crankshaft oil seal and a valve chamber cover.
Detailed Description
The present invention is further described below by way of specific examples, but the present invention is not limited to only the following examples. Variations, combinations, or substitutions of the invention, which are within the scope of the invention or the spirit, scope of the invention, will be apparent to those of skill in the art and are within the scope of the invention.
Example 1: an engine cleaning agent and a preparation method thereof are prepared from the following raw materials in parts by weight: the anti-wear coating comprises, by weight, 32 parts of dipropylene glycol ethyl ether, 20 parts of dichloromethane, 16 parts of ethanol, 15 parts of fatty alcohol-polyoxyethylene ether, 14 parts of trichloroethylene, 1 part of corrosion inhibitor hexadecylamine, 0.5 part of anti-wear additive calcium borate, 0.5 part of metal passivator N.N' -dipropylene-based propane diamine and 0.1 part of surfactant sodium dodecyl sulfate.
The engine cleaning agent and the preparation method thereof comprise the following steps:
(1) adding dipropylene glycol ether, dichloromethane, ethanol, fatty alcohol-polyoxyethylene ether, trichloroethylene, a corrosion inhibitor hexadecylamine, an antiwear additive calcium borate, a metal passivator N.N' -methylene propylene diamine and a surface active agent sodium dodecyl sulfate into a reaction tank in sequence, heating to 40-60 ℃, and stirring at a constant temperature for 0.8-1.4h to fully fuse all the raw materials;
(2) adding an alkaline solution, adjusting the pH value, measuring the pH value of the product in the reaction tank by using standard test paper, and stopping adding the alkaline solution when the pH value is 7.
Example 2: an engine cleaning agent and a preparation method thereof are prepared from the following raw materials in parts by weight: 48 parts of dipropylene glycol ethyl ether, 30 parts of dichloromethane, 19.5 parts of ethanol, 16.5 parts of fatty alcohol-polyoxyethylene ether, 15 parts of trichloroethylene, 1.5 parts of corrosion inhibitor hexadecylamine, 1.7 parts of antiwear additive calcium borate, 1.6 parts of metal passivator N, N' -dipropylene-based propane diamine and 0.5 part of surfactant sodium dodecyl sulfate.
The engine cleaning agent and the preparation method thereof comprise the following steps:
(1) adding dipropylene glycol ether, dichloromethane, ethanol, fatty alcohol-polyoxyethylene ether, trichloroethylene, a corrosion inhibitor hexadecylamine, an antiwear additive calcium borate, a metal passivator N.N' -methylene propylene diamine and a surface active agent sodium dodecyl sulfate into a reaction tank in sequence, heating to 40-60 ℃, and stirring at a constant temperature for 0.8-1.4h to fully fuse all the raw materials;
(2) adding an alkaline solution, adjusting the pH value, measuring the pH value of the product in the reaction tank by using standard test paper, and stopping adding the alkaline solution when the pH value is 7.
Example 3: an engine cleaning agent and a preparation method thereof are prepared from the following raw materials in parts by weight: 60 parts of dipropylene glycol ethyl ether, 40 parts of dichloromethane, 23 parts of ethanol, 18 parts of fatty alcohol-polyoxyethylene ether, 16 parts of trichloroethylene, 2 parts of corrosion inhibitor hexadecylamine, 2 parts of antiwear additive calcium borate, 2 parts of metal passivator N, N' -dipropylene-based propane diamine and 1 part of surface active agent sodium dodecyl sulfate.
The engine cleaning agent and the preparation method thereof comprise the following steps:
(1) adding dipropylene glycol ether, dichloromethane, ethanol, fatty alcohol-polyoxyethylene ether, trichloroethylene, a corrosion inhibitor hexadecylamine, an antiwear additive calcium borate, a metal passivator N.N' -methylene propylene diamine and a surface active agent sodium dodecyl sulfate into a reaction tank in sequence, heating to 40-60 ℃, and stirring at a constant temperature for 0.8-1.4h to fully fuse all the raw materials;
(2) adding an alkaline solution, adjusting the pH value, measuring the pH value of the product in the reaction tank by using standard test paper, and stopping adding the alkaline solution when the pH value is 7.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the present invention, and any modifications, equivalents and improvements made within the spirit and principle of the present invention should be included in the scope of the present invention.

Claims (2)

1. The engine cleaning agent and the preparation method thereof are characterized by being prepared from the following raw materials in parts by weight: 32-60 parts of dipropylene glycol ether, 20-40 parts of dichloromethane, 16-23 parts of ethanol, 15-18 parts of fatty alcohol-polyoxyethylene ether, 14-16 parts of trichloroethylene, 1-2 parts of corrosion inhibitor hexadecylamine, 0.5-2 parts of antiwear additive calcium borate, 0.5-2 parts of metal deactivator N.N' -methylene propylene diamine and 0.1-1 part of surfactant sodium dodecyl sulfate.
2. The engine cleaning agent and the preparation method thereof as claimed in claim 1, wherein the engine cleaning agent and the preparation method thereof comprises the following steps:
(1) adding dipropylene glycol ether, dichloromethane, ethanol, fatty alcohol-polyoxyethylene ether, trichloroethylene, a corrosion inhibitor hexadecylamine, an antiwear additive calcium borate, a metal passivator N.N' -methylene propylene diamine and a surface active agent sodium dodecyl sulfate into a reaction tank in sequence, heating to 40-60 ℃, and stirring at a constant temperature for 0.8-1.4h to fully fuse all the raw materials;
(2) adding an alkaline solution, adjusting the pH value, measuring the pH value of the product in the reaction tank by using standard test paper, and stopping adding the alkaline solution when the pH value is 7.
CN201911150428.3A 2019-11-21 2019-11-21 Engine cleaning agent and preparation method thereof Pending CN110777018A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911150428.3A CN110777018A (en) 2019-11-21 2019-11-21 Engine cleaning agent and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911150428.3A CN110777018A (en) 2019-11-21 2019-11-21 Engine cleaning agent and preparation method thereof

Publications (1)

Publication Number Publication Date
CN110777018A true CN110777018A (en) 2020-02-11

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CN201911150428.3A Pending CN110777018A (en) 2019-11-21 2019-11-21 Engine cleaning agent and preparation method thereof

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103695092A (en) * 2012-09-28 2014-04-02 沈阳天亿顺科技有限公司 An automobile engine cleaning agent and a using method thereof
CN103725440A (en) * 2013-12-31 2014-04-16 中国船舶重工集团公司第七一八研究所 Cleaning agent for automobile
CN106281623A (en) * 2016-07-25 2017-01-04 吕静琪 Automobile engine is exempted to disassemble cleaning oil and application thereof
CN106675821A (en) * 2015-11-06 2017-05-17 万淑香 Automobile engine cleansing agent
CN106978274A (en) * 2017-04-21 2017-07-25 黄春华 A kind of automobile engine cleaning agent
CN109652223A (en) * 2018-12-19 2019-04-19 蔡洪涛 A kind of composition, preparation method, application and automobile engine fuel oil box

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103695092A (en) * 2012-09-28 2014-04-02 沈阳天亿顺科技有限公司 An automobile engine cleaning agent and a using method thereof
CN103725440A (en) * 2013-12-31 2014-04-16 中国船舶重工集团公司第七一八研究所 Cleaning agent for automobile
CN106675821A (en) * 2015-11-06 2017-05-17 万淑香 Automobile engine cleansing agent
CN106281623A (en) * 2016-07-25 2017-01-04 吕静琪 Automobile engine is exempted to disassemble cleaning oil and application thereof
CN106978274A (en) * 2017-04-21 2017-07-25 黄春华 A kind of automobile engine cleaning agent
CN109652223A (en) * 2018-12-19 2019-04-19 蔡洪涛 A kind of composition, preparation method, application and automobile engine fuel oil box

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Application publication date: 20200211