CN110774557A - Preparation method of outer rubber tube of tensile compression-resistant high-performance hydraulic oil pipe - Google Patents
Preparation method of outer rubber tube of tensile compression-resistant high-performance hydraulic oil pipe Download PDFInfo
- Publication number
- CN110774557A CN110774557A CN201911123505.6A CN201911123505A CN110774557A CN 110774557 A CN110774557 A CN 110774557A CN 201911123505 A CN201911123505 A CN 201911123505A CN 110774557 A CN110774557 A CN 110774557A
- Authority
- CN
- China
- Prior art keywords
- tensile
- parts
- outer rubber
- vulcanization
- hydraulic oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/09—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/72—Measuring, controlling or regulating
- B29B7/728—Measuring data of the driving system, e.g. torque, speed, power, vibration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/0288—Controlling heating or curing of polymers during moulding, e.g. by measuring temperatures or properties of the polymer and regulating the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92885—Screw or gear
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92904—Die; Nozzle zone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0843—Cobalt
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0862—Nickel
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2275—Ferroso-ferric oxide (Fe3O4)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/01—Magnetic additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Thermal Sciences (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
The invention discloses a preparation method of an external rubber pipe of a tensile compression-resistant high-performance hydraulic oil pipe, which can start from the raw material of the external rubber pipe, not only inherits the excellent use performance of the traditional nitrile rubber pipe, simultaneously obtains more outstanding strength, heat resistance, corrosion resistance and aging resistance, greatly improves the service performance and service life of the hydraulic oil pipe, in addition, in order to strengthen the tensile and compressive properties of the outer rubber tube, after the anti-fiber-drawing is treated by magnetization through a scattering magnetization device, the outer rubber pipe is added and mixed during extrusion molding, and is continuously arranged along the molding direction under the action of an external guide magnetic field, so that the tensile and compression resistance of the outer rubber pipe is 2-3 times higher than that of the outer rubber pipe in the prior art, and compared with a mode of arranging a tensile layer on an outer layer, the outer rubber pipe is directly subjected to performance enhancement, and has long service life under a complex environment.
Description
Technical Field
The invention relates to the technical field of hydraulic fittings, in particular to a preparation method of an outer rubber tube of a tensile compression-resistant high-performance hydraulic oil tube.
Background
Hydraulic is a term used in the mechanical and electromechanical industries. The hydraulic pressure can be in a power transmission mode and becomes hydraulic transmission. The hydraulic pressure may also be used as a control means, called hydraulic control. The hydraulic transmission uses liquid as a working medium and utilizes the pressure energy of the liquid to transmit power. The hydraulic control is a control in which a pressure fluid is transmitted as a control signal. Control systems that are designed with hydraulic technology are referred to as hydraulic control systems. The hydraulic control generally includes hydraulic open-loop control and hydraulic closed-loop control. The hydraulic closed-loop control is also referred to as hydraulic servo control, and it constitutes a hydraulic servo system, and generally includes an electric hydraulic servo system (electro-hydraulic servo system) and a mechanical hydraulic servo system (mechanical-hydraulic servo system, or mechanical-hydraulic servo mechanism).
A complete hydraulic system consists of five parts, namely a power source device, an execution device, a control and regulation device, an auxiliary device and a liquid medium. The hydraulic pressure has the characteristics of large transmission power, easy transmission and configuration and the like, and is widely applied in industrial and civil industries. The actuators (hydraulic cylinder and hydraulic motor) of the hydraulic system function to convert the pressure energy of the fluid into mechanical energy to achieve the desired linear reciprocating or rotary motion. The energy source device (hydraulic pump) of the hydraulic system functions to convert the mechanical energy of the prime mover into pressure energy of the fluid.
The hydraulic equipment is widely applied to large-scale engineering mechanical equipment such as excavators, loaders and road rollers at present, because the working environment when the engineering mechanical equipment operates is relatively bad, a hydraulic oil pipe can be touched with external hard objects besides the oil pressure effect generated by hydraulic oil, because the tensile and compressive properties of the existing hydraulic oil pipe are weak, especially an outer rubber pipe, the service life can be shortened rapidly due to long-term negative pressure work, and the phenomenon that the outer rubber pipe of the hydraulic oil pipe is scratched or cut due to external force factors is easy to directly cause, the service life of the hydraulic oil pipe is shortened, and the normal use of the engineering mechanical equipment is directly influenced.
Disclosure of Invention
1. Technical problem to be solved
Aiming at the problems in the prior art, the invention aims to provide a preparation method of an outer rubber pipe of a tensile and compression resistant high-performance hydraulic oil pipe, which can realize that the raw materials of the outer rubber pipe are used, not only the excellent service performance of the traditional nitrile rubber pipe is inherited, but also more outstanding strength, heat resistance, corrosion resistance and aging resistance are obtained, the service performance and the service life of the hydraulic oil pipe are greatly improved, in addition, in order to strengthen the tensile and compression resistance of the outer rubber pipe, after the fiber-pulling fiber is subjected to magnetization treatment innovatively through a flying magnetization device, mixing is added during extrusion molding of the outer rubber pipe, the outer rubber pipe is continuously arranged along the molding direction under the action of an external guiding magnetic field, the tensile and compression resistance which is 2-3 times higher than that of the prior art is given to the outer rubber pipe, compared with the mode of arranging a tensile layer on the outer layer, the performance of the outer rubber pipe is directly strengthened, the service life of the cable is long under the complex environment.
2. Technical scheme
In order to solve the above problems, the present invention adopts the following technical solutions.
A preparation method of an outer rubber tube of a tensile compression-resistant high-performance hydraulic oil tube comprises the following steps:
step one, raw material preparation: the outer rubber tube material is prepared from the following raw materials in parts by weight: 25-35 parts of nitrile rubber, 20-25 parts of crude fluororubber, 20-40 parts of methyl vinyl silicone rubber, 5-15 parts of triallyl isocyanurate, 5-12 parts of dioctyl sebacate, 3-9 parts of polyoxyethylene, 1-5 parts of 2-mercaptoimidazoline, 3-10 parts of calcium oxide, 2-8 parts of zeolite powder, 1-5 parts of barium sulfate, 5-15 parts of polytetrafluoroethylene micro powder, 2-6 parts of naphthenic oil, 1-3 parts of an anti-aging agent, 1-3 parts of an accelerator and 3-6 parts of a vulcanizing agent;
step two, preparing the magnetic tensile fiber: taking the tensile fiber, fully contacting and dispersing the tensile fiber with oil after blowing the tensile fiber in a flying magnetization device, simultaneously adding the nano magnetic particles and the oleic acid, stirring and dispersing the mixture, and drying the mixture at high temperature to obtain the magnetic tensile fiber;
step three, mixing: firstly, putting triallyl isocyanurate, dioctyl sebacate, polyoxyethylene, 2-mercaptoimidazoline, polytetrafluoroethylene micro powder and naphthenic oil into a double-roll rubber mixing mill, uniformly stirring for 5-10min, then adding nitrile rubber, fluororubber crude rubber and methyl vinyl silicone rubber, continuously stirring for 15-30min, then sequentially adding an anti-aging agent, calcium oxide, zeolite powder and barium sulfate, continuously stirring for 3-5min, finally sequentially adding a vulcanizing agent and an accelerant, stirring for 10-15min, and then putting the mixture on a discharge tablet press for sheet discharge;
step four, extrusion molding: uniformly mixing the gelatinized raw material and the magnetic tensile fiber in a ratio of 1:0.1-0.3, extruding by a double-screw extruder, applying a guiding magnetic field at a machine head die, and cooling and shaping to obtain an oil pipe initial product;
step five, vulcanization treatment: the first-stage vulcanization and the second-stage vulcanization are divided, the temperature of the first-stage vulcanization is controlled to be 90-100 ℃, and the treatment time is 4-5 hours; the temperature of the secondary vulcanization treatment is controlled to be 110-120 ℃, and the time is 2-3 h;
step six, finished product treatment: the method comprises the steps of standing treatment at normal temperature, quality inspection, storage, packaging and the like.
Further, the accelerator is accelerator M, the anti-aging agent is anti-aging agent 4010NA, and the vulcanizing agent is sulfur.
Further, the average particle size of the calcium oxide and the zeolite powder is 400-500 meshes, and the average particle size of the barium sulfate and the polytetrafluoroethylene micro powder is 200-250 meshes.
Further, magnetization unit flies apart includes the inlet pipe, inlet pipe lower extreme fixedly connected with erlenmeyer flask, the equal fixed intercommunication in both ends has oblique pipe about the inlet pipe, inlet pipe one end is kept away from to one side to the pipe and the power fan is installed to the power fan one end fixedly connected with flow distribution plate, a plurality of evenly distributed's of inlet pipe and erlenmeyer flask junction fixedly connected with separation baffle, the magnetism agitator is installed to the erlenmeyer flask lower extreme.
Furthermore, the inclined guide pipe is inclined upwards by an angle of 60-80 degrees, and a plurality of diversion holes are drilled on the flow distribution plate.
Furthermore, the diameters of the plurality of heterodromous holes are gradually reduced upwards, and the axial lead directions of the plurality of heterodromous holes are not consistent.
Furthermore, the temperature of a front roller of the double-roller rubber mixing mill is controlled to be 45-50 ℃, the temperature of a rear roller is controlled to be about 45 ℃, the roller speed ratio is controlled to be 1:1.2, and the roller spacing is controlled to be 2.5-3 mm.
Further, the screw temperature of the double-screw extruder is controlled to be 50-60 ℃, the temperature of a film opening is controlled to be 85-90 ℃, and the temperature of a machine head is controlled to be 95-105 ℃.
Further, the direction of the guiding magnetic field in the third step is consistent with the forming direction of the outer rubber tube.
Further, the first-stage vulcanization can adopt any one of steam pressure vulcanization, hot air continuous vulcanization, liquid vulcanization tank continuous vulcanization, drum vulcanization or radiation vulcanization, and the second-stage vulcanization is vulcanized in an oven at high temperature.
3. Advantageous effects
Compared with the prior art, the invention has the advantages that:
the scheme can be used for starting from raw materials of the external rubber pipe, the excellent service performance of the traditional nitrile rubber pipe is inherited, meanwhile, more outstanding strength, heat resistance, corrosion resistance and aging resistance are obtained, the service performance and the service life of the hydraulic oil pipe are greatly improved, in addition, in order to strengthen the tensile and compressive performance of the external rubber pipe, after the fiber is resisted by the aid of a scattering magnetizer in an innovative mode, mixing is added during extrusion molding of the external rubber pipe, the external rubber pipe is continuously arranged along the molding direction under the action of an external guiding magnetic field, the tensile and compressive performance of the external rubber pipe exceeds 2-3 times that of the prior art, compared with a mode that the tensile layer is arranged on the external layer, the performance of the external rubber pipe is directly strengthened, and the service life of the external rubber pipe is long under a complex environment.
Drawings
FIG. 1 is a schematic flow chart of the present invention;
FIG. 2 is a schematic structural diagram of a flying magnetizer according to the present invention;
FIG. 3 is a cross-sectional view of a diverter plate portion of the present invention;
FIG. 4 is a schematic diagram of the distribution of the magnetic tensile fibers in the magnetic field guiding state according to the present invention.
The reference numbers in the figures illustrate:
1 feeding pipe, 2 conical flasks, 3 magnetic stirrers, 4 inclined guide pipes, 5 power fans, 6 separating partition plates, 7 flow distribution plates and 8 anisotropic holes.
Detailed Description
The technical solution in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention; it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments, and all other embodiments obtained by those skilled in the art without any inventive work are within the scope of the present invention.
In the description of the present invention, it should be noted that the terms "upper", "lower", "inner", "outer", "top/bottom", and the like indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience of description and simplification of description, but do not indicate or imply that the referred device or element must have a specific orientation, be constructed in a specific orientation, and be operated, and thus should not be construed as limiting the present invention. Furthermore, the terms "first" and "second" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance.
In the description of the present invention, it should be noted that, unless otherwise specifically stated or limited, the terms "mounted," "disposed," "sleeved/connected," "connected," and the like are used in a broad sense, and for example, "connected" may be a fixed connection, a detachable connection, an integral connection, a mechanical connection, an electrical connection, a direct connection, an indirect connection through an intermediate medium, and a communication between two elements.
Example 1:
referring to fig. 1, a method for preparing an external rubber tube of a tensile compression-resistant high-performance hydraulic oil tube includes the following steps:
step one, raw material preparation: the outer rubber tube material is prepared from the following raw materials in parts by weight: 25 parts of nitrile rubber, 20 parts of crude fluororubber, 20 parts of methyl vinyl silicone rubber, 5 parts of triallyl isocyanurate, 5 parts of dioctyl sebacate, 3 parts of polyoxyethylene, 1 part of 2-thiol imidazoline, 3 parts of calcium oxide, 2 parts of zeolite powder, 1 part of barium sulfate, 5 parts of polytetrafluoroethylene micropowder, 2 parts of naphthenic oil, 4010NA1 parts of anti-aging agent, 1 parts of accelerator M and 3 parts of sulfur;
step two, preparing the magnetic tensile fiber: taking the tensile fiber, fully contacting and dispersing the tensile fiber with oil after blowing the tensile fiber in a flying magnetization device, simultaneously adding the nano magnetic particles and the oleic acid, stirring and dispersing the mixture, and drying the mixture at high temperature to obtain the magnetic tensile fiber;
step three, mixing: firstly, putting triallyl isocyanurate, dioctyl sebacate, polyoxyethylene, 2-thiol imidazoline, polytetrafluoroethylene micro powder and naphthenic oil into a double-roller rubber mixing mill, controlling the temperature of a front roller at 45 ℃, controlling the temperature of a rear roller at about 45 ℃, controlling the roller speed ratio at 1:1.2 and the roller distance at 2.5mm, uniformly stirring for 5min, then adding nitrile rubber, fluororubber raw rubber and methyl vinyl silicone rubber, continuously stirring for 15min, then sequentially adding an anti-aging agent 4010NA, calcium oxide, zeolite powder and barium sulfate, continuously stirring for 3min, finally sequentially adding sulfur and an accelerator M, stirring for 10min, discharging materials to a tablet press, and discharging tablets;
step four, extrusion molding: uniformly mixing the gelatinized raw material and magnetic tensile fiber in a ratio of 1:0.1, extruding the mixture by a double-screw extruder, controlling the temperature of a screw at 50 ℃, the temperature of a film opening at 85 ℃, the temperature of a machine head at 95 ℃, applying a guiding magnetic field at a machine head die, keeping the direction of the guiding magnetic field consistent with the forming direction of the outer rubber tube, guiding the magnetic tensile fiber to be arranged along the forming direction of the outer rubber tube through magnetic field force, further exerting the tensile and compressive effects of the magnetic tensile fiber, greatly reducing the tensile and compressive effects if the arrangement sequence is disordered, and cooling and shaping to obtain an oil tube primary product;
step five, vulcanization treatment: the method comprises the steps of first-stage vulcanization and second-stage vulcanization, wherein the temperature of the first-stage vulcanization is controlled at 90 ℃, the treatment time is 4 hours, and steam is adopted for pressurization vulcanization; controlling the temperature of the secondary vulcanization treatment at 110 ℃ for 2h, and carrying out high-temperature vulcanization in an oven;
step six, finished product treatment: the method comprises the steps of standing treatment at normal temperature, quality inspection, storage, packaging and the like.
The average particle size of the calcium oxide and the zeolite powder is 400-500 meshes, and the average particle size of the barium sulfate and the polytetrafluoroethylene micro powder is 200-250 meshes.
Referring to fig. 2, the scattering magnetizer includes a feeding pipe 1, a conical flask 2 is fixedly connected to the lower end of the feeding pipe 1, an inclined duct 4 is fixedly connected to both the left and right ends of the feeding pipe 1, a power fan 5 is installed at one end of the inclined duct 4 away from the feeding pipe 1 to provide wind power for blowing away tensile fiber, a splitter plate 7 is fixedly connected to one end of the inclined duct 4 away from the power fan 5, a plurality of separating plates 6 are fixedly connected to the joint of the feeding pipe 1 and the conical flask 2 and uniformly distributed to separate the blown away tensile fiber and prevent the tensile fiber from being attracted together in the falling process, the tensile fiber can be uniformly dispersed into oil, the tensile fiber can be fully contacted and prevented from being difficult to be continuously arranged in the subsequent guiding process due to agglomeration, a magnetic stirrer 3 is installed at the lower end of the conical flask 2 to provide a rotating uniform magnetic field, the inclined angle of the inclined duct 4 is 60-80 degrees, the diversion plate 7 is provided with a plurality of heterodromous holes 8, the diameters of the heterodromous holes 8 are gradually reduced upwards, the axial lead directions of the heterodromous holes 8 are different, and the tensile fibers which are agglomerated together can be blown away to a greater extent after the wind blown out by the power fan 5 is subjected to non-directional dispersion.
When magnetizing, firstly pouring oil into the conical flask 2, wherein the oil just submerges the bottom end of the conical flask 2, then starting a pair of power fans 5, pouring 2-5cm tensile fibers into the feeding pipe 1, after the wind blown by the power fans 5 is guided and accumulated by the inclined guide pipe 4 and passes through the flow distribution plate 7, the tensile fiber is blown in a non-directional way through the heterodromous holes 8, the dispersion of the tensile fiber is realized, the blown tensile fiber falls into the oil without mutual interference under the isolation of the separation baffle 6 and is fully contacted with the oil, then pouring nano magnetic particles which can be Fe3O4, Fe2O3, Ni, Co and the like as magnetic particles, the nano magnetic particles are dispersed by the separation partition plate 6 and uniformly fall into the oil, the magnetic stirrer 3 is started to heat and stir, the nano magnetic particles drive the tensile fibers to synchronously rotate and stir in a rotating uniform magnetic field, and the contact and load of the nano magnetic particles and the tensile fibers can be obviously improved while the dispersity is improved.
Example 2:
referring to fig. 1, a method for preparing an external rubber tube of a tensile compression-resistant high-performance hydraulic oil tube includes the following steps:
step one, raw material preparation: the outer rubber tube material is prepared from the following raw materials in parts by weight: 30 parts of nitrile rubber, 22 parts of crude fluororubber, 30 parts of methyl vinyl silicone rubber, 8 parts of triallyl isocyanurate, 10 parts of dioctyl sebacate, 5 parts of polyoxyethylene, 3 parts of 2-thiol imidazoline, 5 parts of calcium oxide, 5 parts of zeolite powder, 3 parts of barium sulfate, 10 parts of polytetrafluoroethylene micro powder, 4 parts of naphthenic oil, 4010NA2 parts of anti-aging agent, 2 parts of accelerator M and 4 parts of sulfur;
step two, preparing the magnetic tensile fiber: taking the tensile fiber, fully contacting and dispersing the tensile fiber with oil after blowing the tensile fiber in a flying magnetization device, simultaneously adding the nano magnetic particles and the oleic acid, stirring and dispersing the mixture, and drying the mixture at high temperature to obtain the magnetic tensile fiber;
step three, mixing: firstly, putting triallyl isocyanurate, dioctyl sebacate, polyoxyethylene, 2-thiol imidazoline, polytetrafluoroethylene micro powder and naphthenic oil into a double-roller rubber mixing mill, controlling the temperature of a front roller at 50 ℃, controlling the temperature of a rear roller at about 45 ℃, controlling the roller speed ratio at 1:1.2 and the roller distance at 3mm, uniformly stirring for 8min, then adding nitrile rubber, fluororubber raw rubber and methyl vinyl silicone rubber, continuously stirring for 20min, then sequentially adding an anti-aging agent 4010NA, calcium oxide, zeolite powder and barium sulfate, continuously stirring for 4min, finally sequentially adding sulfur and an accelerator M, stirring for 12min, discharging materials to a tablet press, and taking tablets out;
step four, extrusion molding: uniformly mixing the gelatinized raw material and magnetic tensile fiber in a ratio of 1:0.2, extruding the mixture by a double-screw extruder, controlling the temperature of a screw at 55 ℃, controlling the temperature of a film opening at 90 ℃, controlling the temperature of a machine head at 100 ℃, applying a guiding magnetic field at a machine head die, keeping the direction of the guiding magnetic field consistent with the forming direction of the outer rubber tube, guiding the magnetic tensile fiber to be arranged along the forming direction of the outer rubber tube through magnetic field force, further exerting the tensile and compressive effects of the magnetic tensile fiber, greatly reducing the tensile and compressive effects if the arrangement sequence is disordered, and cooling and shaping to obtain an oil tube primary product;
step five, vulcanization treatment: the method comprises the following steps of first-stage vulcanization and second-stage vulcanization, wherein the temperature of the first-stage vulcanization is controlled at 100 ℃, the treatment time is 5 hours, and steam is adopted for pressurization vulcanization; controlling the temperature of the secondary vulcanization treatment at 120 ℃ for 2h, and carrying out high-temperature vulcanization in an oven;
step six, finished product treatment: the method comprises the steps of standing treatment at normal temperature, quality inspection, storage, packaging and the like.
The remainder was in accordance with example 1.
Example 3:
referring to fig. 1, a method for preparing an external rubber tube of a tensile compression-resistant high-performance hydraulic oil tube includes the following steps:
step one, raw material preparation: the outer rubber tube material is prepared from the following raw materials in parts by weight: 35 parts of nitrile rubber, 25 parts of crude fluororubber, 40 parts of methyl vinyl silicone rubber, 15 parts of triallyl isocyanurate, 12 parts of dioctyl sebacate, 9 parts of polyoxyethylene, 5 parts of 2-thiol imidazoline, 10 parts of calcium oxide, 8 parts of zeolite powder, 5 parts of barium sulfate, 15 parts of polytetrafluoroethylene micro powder, 6 parts of naphthenic oil, 4010NA3 parts of anti-aging agent, M3 parts of accelerator and 6 parts of sulfur;
step two, preparing the magnetic tensile fiber: taking the tensile fiber, fully contacting and dispersing the tensile fiber with oil after blowing the tensile fiber in a flying magnetization device, simultaneously adding the nano magnetic particles and the oleic acid, stirring and dispersing the mixture, and drying the mixture at high temperature to obtain the magnetic tensile fiber;
step three, mixing: firstly, putting triallyl isocyanurate, dioctyl sebacate, polyoxyethylene, 2-thiol imidazoline, polytetrafluoroethylene micro powder and naphthenic oil into a double-roller rubber mixing mill, controlling the temperature of a front roller at 50 ℃, controlling the temperature of a rear roller at about 45 ℃, controlling the roller speed ratio at 1:1.2, controlling the roller distance at 3mm, uniformly stirring for 10min, then adding nitrile rubber, fluororubber raw rubber and methyl vinyl silicone rubber, continuously stirring for 30min, then sequentially adding an anti-aging agent 4010NA, calcium oxide, zeolite powder and barium sulfate, continuously stirring for 5min, finally sequentially adding sulfur and an accelerator M, stirring for 15min, discharging materials to a tablet press, and taking tablets out;
step four, extrusion molding: uniformly mixing the gelatinized raw material and magnetic tensile fiber in a ratio of 1:0.3, extruding the mixture by a double-screw extruder, controlling the temperature of a screw at 60 ℃, controlling the temperature of a film opening at 90 ℃, controlling the temperature of a machine head at 105 ℃, applying a guiding magnetic field at the position of a machine head die, keeping the direction of the guiding magnetic field consistent with the forming direction of the outer rubber tube, guiding the magnetic tensile fiber to be arranged along the forming direction of the outer rubber tube through magnetic field force, further playing the tensile and compressive effects, greatly reducing the tensile and compressive effects if the arrangement sequence is disordered, and cooling and sizing to obtain an oil tube primary product;
step five, vulcanization treatment: the method comprises the following steps of first-stage vulcanization and second-stage vulcanization, wherein the temperature of the first-stage vulcanization is controlled at 100 ℃, the treatment time is 5 hours, and steam is adopted for pressurization vulcanization; controlling the temperature of the secondary vulcanization treatment at 120 ℃ for 3h, and carrying out high-temperature vulcanization in an oven;
step six, finished product treatment: the method comprises the steps of standing treatment at normal temperature, quality inspection, storage, packaging and the like.
The remainder was in accordance with example 1.
The invention can realize starting from the raw materials of the external rubber tube, not only inherits the excellent service performance of the traditional nitrile rubber tube, but also obtains more outstanding strength, heat resistance, corrosion resistance and aging resistance, greatly improves the service performance and the service life of the hydraulic oil tube, in addition, in order to strengthen the tensile and compressive performance of the external rubber tube, after the fiber drawing fiber is subjected to magnetization treatment by a scatter magnetization device creatively, the external rubber tube is added and mixed during extrusion molding, and is continuously arranged along the molding direction by utilizing the action of an external guide magnetic field, so that the tensile and compressive performance of the external rubber tube is more than 2-3 times of that of the prior art, compared with the mode that the tensile layer is arranged on the external layer, the external rubber tube is directly subjected to performance strengthening, and has long service life under the complex environment.
The foregoing is only a preferred embodiment of the present invention; the scope of the invention is not limited thereto. Any person skilled in the art should be able to cover the technical scope of the present invention by equivalent or modified solutions and modifications within the technical scope of the present invention.
Claims (10)
1. A preparation method of an outer rubber tube of a tensile compression-resistant high-performance hydraulic oil tube is characterized by comprising the following steps: the method comprises the following steps:
step one, raw material preparation: the outer rubber tube material is prepared from the following raw materials in parts by weight: 25-35 parts of nitrile rubber, 20-25 parts of crude fluororubber, 20-40 parts of methyl vinyl silicone rubber, 5-15 parts of triallyl isocyanurate, 5-12 parts of dioctyl sebacate, 3-9 parts of polyoxyethylene, 1-5 parts of 2-mercaptoimidazoline, 3-10 parts of calcium oxide, 2-8 parts of zeolite powder, 1-5 parts of barium sulfate, 5-15 parts of polytetrafluoroethylene micro powder, 2-6 parts of naphthenic oil, 1-3 parts of an anti-aging agent, 1-3 parts of an accelerator and 3-6 parts of a vulcanizing agent;
step two, preparing the magnetic tensile fiber: taking the tensile fiber, fully contacting and dispersing the tensile fiber with oil after blowing the tensile fiber in a flying magnetization device, simultaneously adding the nano magnetic particles and the oleic acid, stirring and dispersing the mixture, and drying the mixture at high temperature to obtain the magnetic tensile fiber;
step three, mixing: firstly, putting triallyl isocyanurate, dioctyl sebacate, polyoxyethylene, 2-mercaptoimidazoline, polytetrafluoroethylene micro powder and naphthenic oil into a double-roll rubber mixing mill, uniformly stirring for 5-10min, then adding nitrile rubber, fluororubber crude rubber and methyl vinyl silicone rubber, continuously stirring for 15-30min, then sequentially adding an anti-aging agent, calcium oxide, zeolite powder and barium sulfate, continuously stirring for 3-5min, finally sequentially adding a vulcanizing agent and an accelerant, stirring for 10-15min, and then putting the mixture on a discharge tablet press for sheet discharge;
step four, extrusion molding: uniformly mixing the gelatinized raw material and the magnetic tensile fiber in a ratio of 1:0.1-0.3, extruding by a double-screw extruder, applying a guiding magnetic field at a machine head die, and cooling and shaping to obtain an oil pipe initial product;
step five, vulcanization treatment: the first-stage vulcanization and the second-stage vulcanization are divided, the temperature of the first-stage vulcanization is controlled to be 90-100 ℃, and the treatment time is 4-5 hours; the temperature of the secondary vulcanization treatment is controlled to be 110-120 ℃, and the time is 2-3 h;
step six, finished product treatment: the method comprises the steps of standing treatment at normal temperature, quality inspection, storage, packaging and the like.
2. The preparation method of the outer rubber tube of the tensile and compression resistant high-performance hydraulic oil tube according to claim 1, characterized in that: the accelerator is accelerator M, the anti-aging agent is anti-aging agent 4010NA, and the vulcanizing agent is sulfur.
3. The preparation method of the outer rubber tube of the tensile and compression resistant high-performance hydraulic oil tube according to claim 1, characterized in that: the average particle size of the calcium oxide and the zeolite powder is 400-500 meshes, and the average particle size of the barium sulfate and the polytetrafluoroethylene micro powder is 200-250 meshes.
4. The preparation method of the outer rubber tube of the tensile and compression resistant high-performance hydraulic oil tube according to claim 1, characterized in that: the magnetization device that flies includes inlet pipe (1), inlet pipe (1) lower extreme fixedly connected with erlenmeyer flask (2), the equal fixed intercommunication in both ends has pipe (4) to one side about inlet pipe (1), inlet pipe (1) one end is kept away from to one side pipe (4) and power fan (5) are installed, power fan (5) one end fixedly connected with flow distribution plate (7) are kept away from to one side pipe (4), a plurality of evenly distributed's of fixedly connected with separation baffle (6) of inlet pipe (1) and erlenmeyer flask (2) junction, magnetism agitator (3) are installed to erlenmeyer flask (2) lower extreme.
5. The preparation method of the outer rubber tube of the tensile and compression resistant high-performance hydraulic oil tube according to claim 4, characterized in that: the inclined guide pipe (4) inclines upwards at an angle of 60-80 degrees, and the flow distribution plate (7) is provided with a plurality of diversion holes (8).
6. The preparation method of the outer rubber tube of the tensile and compression resistant high-performance hydraulic oil tube according to claim 5, characterized in that: the diameters of the plurality of heterodromous holes (8) are gradually reduced upwards, and the axial lead directions of the plurality of heterodromous holes (8) are not consistent.
7. The preparation method of the outer rubber tube of the tensile and compression resistant high-performance hydraulic oil tube according to claim 1, characterized in that: the temperature of the front roller of the double-roller rubber mixing machine is controlled to be 45-50 ℃, the temperature of the rear roller is controlled to be about 45 ℃, the roller speed ratio is controlled to be 1:1.2, and the roller spacing is controlled to be 2.5-3 mm.
8. The preparation method of the outer rubber tube of the tensile and compression resistant high-performance hydraulic oil tube according to claim 1, characterized in that: the screw temperature of the double-screw extruder is controlled to be 50-60 ℃, the film opening temperature is controlled to be 85-90 ℃, and the head temperature is controlled to be 95-105 ℃.
9. The preparation method of the outer rubber tube of the tensile and compression resistant high-performance hydraulic oil tube according to claim 1, characterized in that: and in the third step, the direction of the guide magnetic field is consistent with the forming direction of the outer rubber tube.
10. The preparation method of the outer rubber tube of the tensile and compression resistant high-performance hydraulic oil tube according to claim 1, characterized in that: the first-stage vulcanization can adopt any one of steam pressure vulcanization, hot air continuous vulcanization, liquid vulcanization tank continuous vulcanization, drum vulcanization or radiation vulcanization, and the second-stage vulcanization is carried out at high temperature in an oven.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201911123505.6A CN110774557A (en) | 2019-11-16 | 2019-11-16 | Preparation method of outer rubber tube of tensile compression-resistant high-performance hydraulic oil pipe |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201911123505.6A CN110774557A (en) | 2019-11-16 | 2019-11-16 | Preparation method of outer rubber tube of tensile compression-resistant high-performance hydraulic oil pipe |
Publications (1)
Publication Number | Publication Date |
---|---|
CN110774557A true CN110774557A (en) | 2020-02-11 |
Family
ID=69391734
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201911123505.6A Withdrawn CN110774557A (en) | 2019-11-16 | 2019-11-16 | Preparation method of outer rubber tube of tensile compression-resistant high-performance hydraulic oil pipe |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN110774557A (en) |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6015132A (en) * | 1983-07-08 | 1985-01-25 | Toyota Motor Corp | Manufacture of composite material reinforced with fiber |
CN1056370A (en) * | 1989-03-18 | 1991-11-20 | 帝国化学工业公司 | The pressing mold that is used for extrusion modling |
JPH09275028A (en) * | 1996-04-05 | 1997-10-21 | Ricoh Co Ltd | Magnet roller and its manufacturing apparatus |
CN1306472A (en) * | 1998-06-24 | 2001-08-01 | 比约恩·斯韦德伯格 | Method and device for magnetic alignment of fibres |
CN102001861A (en) * | 2009-09-02 | 2011-04-06 | 通用电气公司 | Composite material with fiber alignment |
CN102720900A (en) * | 2012-06-25 | 2012-10-10 | 浙江峻和橡胶科技有限公司 | Fuel rubber pipe and production process thereof |
CN103469462A (en) * | 2013-09-10 | 2013-12-25 | 常熟市国光机械有限公司 | High-position roller rubber pipe and manufacturing method thereof |
CN104961935A (en) * | 2015-06-12 | 2015-10-07 | 苏州市大力电器有限公司 | Production method of high-performance outer rubber pipe for hydraulic oil pipe |
CN106003642A (en) * | 2016-05-12 | 2016-10-12 | 苏州爱盟机械有限公司 | Manufacture method for high abrasion-resistant bicycle brake cable outer rubber hose |
CN107652496A (en) * | 2017-10-27 | 2018-02-02 | 安徽微威环保科技有限公司 | A kind of hydraulic oil pipe elastomeric material and preparation method thereof |
-
2019
- 2019-11-16 CN CN201911123505.6A patent/CN110774557A/en not_active Withdrawn
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6015132A (en) * | 1983-07-08 | 1985-01-25 | Toyota Motor Corp | Manufacture of composite material reinforced with fiber |
CN1056370A (en) * | 1989-03-18 | 1991-11-20 | 帝国化学工业公司 | The pressing mold that is used for extrusion modling |
JPH09275028A (en) * | 1996-04-05 | 1997-10-21 | Ricoh Co Ltd | Magnet roller and its manufacturing apparatus |
CN1306472A (en) * | 1998-06-24 | 2001-08-01 | 比约恩·斯韦德伯格 | Method and device for magnetic alignment of fibres |
CN102001861A (en) * | 2009-09-02 | 2011-04-06 | 通用电气公司 | Composite material with fiber alignment |
CN102720900A (en) * | 2012-06-25 | 2012-10-10 | 浙江峻和橡胶科技有限公司 | Fuel rubber pipe and production process thereof |
CN103469462A (en) * | 2013-09-10 | 2013-12-25 | 常熟市国光机械有限公司 | High-position roller rubber pipe and manufacturing method thereof |
CN104961935A (en) * | 2015-06-12 | 2015-10-07 | 苏州市大力电器有限公司 | Production method of high-performance outer rubber pipe for hydraulic oil pipe |
CN106003642A (en) * | 2016-05-12 | 2016-10-12 | 苏州爱盟机械有限公司 | Manufacture method for high abrasion-resistant bicycle brake cable outer rubber hose |
CN107652496A (en) * | 2017-10-27 | 2018-02-02 | 安徽微威环保科技有限公司 | A kind of hydraulic oil pipe elastomeric material and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN110078995B (en) | Carbon black master batch capable of improving stress characteristic of PE (polyethylene) pipe | |
CN103524950B (en) | PVC extrusion grade particulate material, preparation method and the preparation method of extruded product | |
CN104354301A (en) | Degradable sheet double-stage extrusion calendaring complete equipment | |
CN107263884A (en) | A kind of super large caliber PTFE tube part paste extrusion preparation method and its extrusion equipment | |
CN204222201U (en) | Degraded sheet material two rank extrusion calendaring is molded into complete equipment | |
CN110774557A (en) | Preparation method of outer rubber tube of tensile compression-resistant high-performance hydraulic oil pipe | |
CN111809739A (en) | Ultrahigh-damping rubber support and preparation method thereof | |
CN101864703B (en) | Stone paper film forming technology | |
CN108948499A (en) | A kind of shock resistance high-strength polyethylene communication tube and preparation method thereof | |
CN109895391B (en) | A sealed quick assembly disassembly forming cylinder for 3D printing apparatus | |
CN207549188U (en) | A kind of solid silicone mixing facilities | |
CN111618110A (en) | Rhombus roller press and energy-gathered cutting cable processing device thereof | |
CN204757578U (en) | Aramid fiber honeycomb curing oven | |
CN204275915U (en) | A kind of cooling device for paste mixing machine | |
CN214983062U (en) | Efficient energy-saving screw and extruder | |
CN213618275U (en) | PE tubular product extrusion moulding machine | |
CN207808011U (en) | Molded machinery is prolonged in a kind of production of novel nano micro-crystal plate | |
CN210415432U (en) | Processing equipment for improving performance of heat-conducting particles or electricity-conducting particles | |
WO2018205288A1 (en) | One-time rapid method for use in molding plastic coating of elevator balance compensation chain | |
CN203600645U (en) | Ball press machine | |
CN203507939U (en) | Granulator | |
CN111995804A (en) | High-strength rubber material and processing technology | |
CN209079160U (en) | A kind of chemical blowing extrusion machine host | |
CN102729329B (en) | Technology and device for pug milling of ceramic rod production | |
CN211164797U (en) | Preparation system of tire curing bladder sizing material |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
WW01 | Invention patent application withdrawn after publication | ||
WW01 | Invention patent application withdrawn after publication |
Application publication date: 20200211 |