CN110747691A - Anti-lip adhesion tipping paper for cigarettes - Google Patents
Anti-lip adhesion tipping paper for cigarettes Download PDFInfo
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- CN110747691A CN110747691A CN201910908582.6A CN201910908582A CN110747691A CN 110747691 A CN110747691 A CN 110747691A CN 201910908582 A CN201910908582 A CN 201910908582A CN 110747691 A CN110747691 A CN 110747691A
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/22—Polyalkenes, e.g. polystyrene
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/64—Inorganic compounds
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/826—Paper comprising more than one coating superposed two superposed coatings, the first applied being pigmented and the second applied being non-pigmented
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
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Abstract
The invention discloses a cigarette tipping paper capable of resisting lip adhesion, which comprises a tipping base paper layer, a coloring layer and a gloss oil layer, wherein the coloring layer is formed by dry coating of lip adhesion-preventing alcohol-soluble ink, and the gloss oil layer is formed by dry coating of water-based lip adhesion-preventing gloss oil. The alcohol-soluble printing ink and the water-based gloss oil are respectively added with an anti-sticking auxiliary agent, and the anti-sticking auxiliary agent is formed by mixing diatomite, sodium oleate or hydroxyl polysiloxane copolymer. The tipping paper for the cigarette resisting lip adhesion has excellent hydrophobic and water-blocking performances, can effectively avoid the lip adhesion of the cigarette filtering lip, improves the quality of cigarette products, and is simple in preparation method and environment-friendly.
Description
Technical Field
The invention belongs to the technical field of cigarette packaging auxiliary materials, and particularly relates to cigarette tipping paper capable of preventing lips of smokers from being adhered to cigarette filters.
Background
In recent years, consumers often receive feedback on the sticking condition of the cigarette lips. The cigarette consists of a filter tip, a tobacco rod and cigarette tipping paper, wherein the tobacco rod and the filter tip are tipped by the cigarette tipping paper. When a smoker article smokes cigarettes, the cigarette tipping paper is in direct contact with the surface of the lips, and along with the prolonging of the contact time, the adhesive layer and the saliva on the lips of the smoker can penetrate through the gap of the coating and generate an adhesive effect with paper fibers, so that the phenomenon of lip adhesion is caused, and poor article smoking experience is brought to the consumer. The cigarette filter tip paper has a slight plot, the surface of the cigarette filter tip paper can be polluted, and the appearance and the smoking experience of cigarettes are influenced; in severe situations, the lips of consumers are stuck by cigarettes, which causes the lips to break skin, bleed and the like. Therefore, improvement of such a situation is urgently required.
Disclosure of Invention
The invention aims to provide the tipping paper for the cigarette, which can effectively avoid lip adhesion between a lip of a smoker and a cigarette filter against the defects of the prior art.
The purpose of the invention is realized by the following technical scheme.
All percentages used herein are by weight unless otherwise indicated.
1. The utility model provides an anti lip adhesion's cigarette is with connecing dress paper, includes china cypress ground paper layer, dyed layer and gloss oil layer, its characterized in that: the coloring layer is formed by coating and drying alcohol-soluble ink for preventing lip adhesion, and the gloss oil layer is formed by coating and drying water-based gloss oil for preventing lip adhesion;
the alcohol-soluble ink for preventing lip adhesion comprises the following raw materials in parts by weight: 5-15 parts of resin binder, 20-60 parts of solvent, 5-45 parts of pigment and filler, 0.1-0.8 part of wax powder and 0.1-10 parts of anti-sticking ink auxiliary agent; the anti-sticking ink auxiliary agent is prepared from diatomite, sodium oleate and hydroxyl polysiloxane copolymer according to the weight ratio of 2: 1: 3 by weight ratio;
the water-based lip adhesion preventing gloss oil is prepared from the following raw materials in parts by weight: 3-15 parts of resin binder, 0.05-0.5 part of wax powder, 75-90 parts of water and 0.1-10 parts of anti-sticking gloss oil auxiliary agent; the anti-sticking gloss oil auxiliary agent is prepared from sodium oleate and hydroxyl polysiloxane copolymer according to the weight ratio of 1: 3 by weight ratio.
2. In the lip adhesion prevention alcohol-soluble ink, the resin binder is preferably one or two of polyvinyl butyral resin and modified rosin resin; the solvent is preferably ethanol; the pigment and filler is preferably one or more of benzidine yellow, lithol carmine, fast scarlet, light calcium carbonate and rutile type titanium dioxide;
in the water-based lip adhesion preventing gloss oil, the resin binder is preferably one or more of acrylic acid-styrene copolymer resin, rosin modified acrylic resin and polyurethane modified acrylic resin; the wax powder is preferably aqueous polyethylene wax powder with the particle size of 1-8 microns.
3. The method for preparing the lip adhesion prevention alcohol-soluble ink is characterized by comprising the following steps: adding the resin binder into a solvent, stirring and dissolving, sequentially adding the pigment filler, the wax powder and the anti-sticking printing ink auxiliary agent, and dispersing for 30-60 minutes at 1000rpm to obtain a mixed dispersion liquid; and then adding the mixed dispersion liquid into a sand mill, grinding for 1.5-3.0 hours, taking out and filtering to obtain the required lip adhesion prevention alcohol-soluble ink.
When the used pigment and filler contains light calcium carbonate or rutile type titanium dioxide, 0.5-3 parts of BYK-770 dispersing agent is further added while the pigment and filler is added.
4. The preparation method of the water-based lip adhesion preventing gloss oil is characterized by comprising the following steps: and slowly adding the resin binder into water, stirring and dissolving, then adding the wax powder and the anti-sticking gloss oil auxiliary agent, dispersing the mixture at a high speed for 60 minutes, taking out and filtering to obtain the required water-based lip adhesion prevention gloss oil.
5. The dry coating weight of the lip adhesion preventing alcohol soluble ink is 0.8-4.0 g/m2The dry coating weight of the water-based lip adhesion preventing gloss oil is 0.5-1.2 g/m2。
6. The tipping base paper layer adopts single-sided smooth common base paper or double-sided smooth common base paper, and the gram weight of the base paper is 32-40 g/m2。
The tipping paper for the cigarette resisting lip adhesion has excellent hydrophobic and water-blocking performances, can effectively avoid the lip adhesion of the cigarette filtering lip, improves the quality of cigarette products, and is simple in preparation method and environment-friendly.
Drawings
FIG. 1 is a schematic structural diagram of tipping paper for cigarette with lip adhesion resistance.
Detailed Description
The present invention is further described in detail with reference to the drawings and examples, which are not intended to limit the technical scope of the present invention, and all changes and equivalents that are made based on the teachings of the present invention should fall within the scope of the present invention.
Example 1
As shown in figure 1, the tipping paper for the cigarette resisting lip adhesion comprises a tipping base paper layer (gram weight is 32 g/m)2Single-side glossy common base paper) 1, a coloring layer 2 and a gloss oil layer 3; the color layer 2 was coated at a dry coating weight of 0.8g/m2The lip adhesion preventing alcohol-soluble ink is obtained by coating and drying, and the coating weight of the gloss oil layer 3 is 0.5g/m2The water-based lip adhesion preventing gloss oil is obtained by coating and drying.
The lip adhesion preventing alcohol-soluble ink comprises the following raw materials: 5 parts of polyvinyl butyral resin, 5 parts of benzidine yellow, 0.1 part of wax powder, 20 parts of ethanol, 2 parts of kieselguhr, 1 part of sodium oleate and 3 parts of hydroxyl polysiloxane copolymer. The preparation method comprises the following steps: adding polyvinyl butyral resin into ethanol, stirring and dissolving, sequentially adding benzidine yellow, wax powder, diatomite, sodium oleate and hydroxyl polysiloxane copolymer, and dispersing for 30 minutes at 1000rpm to obtain a mixed dispersion liquid; and adding the mixed dispersion liquid into a sand mill for sand milling, wherein the grinding time is 1.5 hours, and taking out and filtering to obtain the lip adhesion prevention alcohol-soluble ink.
The water-based lip adhesion preventing gloss oil comprises the following raw materials: 3 parts of acrylic acid-styrene copolymer resin, 0.05 part of wax powder, 75 parts of water, 0.2 part of sodium oleate and 0.6 part of hydroxyl polysiloxane copolymer. The preparation method comprises the following steps: slowly adding acrylic acid-styrene copolymer resin into water, stirring and dissolving, then adding wax powder, sodium oleate and hydroxyl polysiloxane copolymer, dispersing for 60 minutes at high speed, taking out and filtering to obtain the water-based lip adhesion preventing gloss oil.
Example 2
Example 1 was repeated with the following differences:
a tipping paper for cigarette with anti-lip adhesion comprises a tipping base paper layer (gram weight of 40 g/m)2Double-sided glossy common base paper) 1, a coloring layer 2 and a gloss oil layer 3; the color layer 2 was coated at a dry coating weight of 4.0g/m2The lip adhesion preventing alcohol soluble ink is obtained by coating and drying, and the coating weight of the gloss oil layer 3 is 1.2g/m2And coating and drying the water-based lip adhesion preventing gloss oil to obtain the lip adhesion preventing gloss oil.
The lip adhesion preventing alcohol-soluble ink comprises the following raw materials: 5 parts of polyvinyl butyral resin, 10 parts of modified rosin resin, 25 parts of lithol carmine, 0.8 part of wax powder, 60 parts of ethanol, 1 part of diatomite, 0.5 part of sodium oleate and 1.5 parts of hydroxyl polysiloxane copolymer. The water-based lip adhesion preventing gloss oil comprises the following raw materials: 10 parts of rosin modified acrylic resin, 0.25 part of wax powder, 80 parts of water, 1 part of sodium oleate and 3 parts of hydroxyl polysiloxane copolymer.
Example 3
Example 1 was repeated with the following differences:
a tipping paper for cigarette with anti-lip adhesion comprises a tipping base paper layer (with a gram weight of 36 g/m)2Single-side glossy common base paper) 1, a coloring layer 2 and a gloss oil layer 3; the color layer 2 was coated at a dry coating weight of 2.0g/m2The lip adhesion preventing alcohol soluble ink is obtained by coating and drying, and the coating weight of the gloss oil layer 3 is 0.8g/m2And coating and drying the water-based lip adhesion preventing gloss oil to obtain the lip adhesion preventing gloss oil.
The lip adhesion preventing alcohol-soluble ink comprises the following raw materials: 5 parts of polyvinyl butyral resin, 5 parts of modified rosin resin, 25 parts of light calcium carbonate, 15 parts of rutile titanium dioxide, 1.5 parts of BYK-770 dispersing agent, 0.4 part of wax powder, 40 parts of ethanol, 2 parts of diatomite, 1 part of sodium oleate and 3 parts of hydroxyl polysiloxane copolymer. The water-based lip adhesion preventing gloss oil comprises the following raw materials: 15 parts of polyurethane modified acrylic resin, 0.5 part of water-based polyethylene wax powder with the particle size of 5-6 microns, 90 parts of water, 2.5 parts of sodium oleate and 7.5 parts of hydroxyl polysiloxane copolymer.
Example 4
Example 1 was repeated with the following differences:
a tipping paper for cigarette with anti-lip adhesion comprises a tipping base paper layer (gram weight of 38 g/m)2Double-sided glossy common base paper) 1, a coloring layer 2 and a gloss oil layer 3; the color layer 2 was coated at a dry coating weight of 3.0g/m2The lip adhesion preventing alcohol soluble ink is obtained by coating and drying, and the coating weight of the gloss oil layer 3 is 1.0g/m2And coating and drying the water-based lip adhesion preventing gloss oil to obtain the lip adhesion preventing gloss oil.
The lip adhesion preventing alcohol-soluble ink comprises the following raw materials: 5 parts of polyvinyl butyral resin, 10 parts of modified rosin resin, 5 parts of light fast scarlet, 10 parts of light calcium carbonate, 15 parts of rutile titanium dioxide, 1 part of BYK-770 dispersant, 0.3 part of wax powder, 55 parts of ethanol, 1.6 parts of diatomite, 0.8 part of sodium oleate and 2.4 parts of hydroxyl polysiloxane copolymer. The water-based lip adhesion preventing gloss oil comprises the following raw materials: 5 parts of rosin modified acrylic resin, 5 parts of polyurethane modified acrylic resin, 0.4 part of waterborne polyethylene wax powder with the particle size of 5-6 microns, 85 parts of water, 2 parts of sodium oleate and 6 parts of hydroxyl polysiloxane copolymer.
And (3) comparison test:
adopting the same tipping base paper and the same printing process, and replacing the lip adhesion prevention alcohol soluble ink and the lip adhesion prevention water-based varnish in example 1 with alcohol soluble ink and water-based varnish without anti-adhesion auxiliaries to print to prepare tipping paper for cigarettes as a comparative example 1-1; the alcohol-soluble ink without the anti-sticking auxiliary agent is used for replacing the alcohol-soluble ink for preventing lip adhesion in example 1 to print to prepare tipping paper for cigarettes, and the tipping paper is used as a comparative example 1-2; the tipping paper for cigarettes was prepared by printing with an aqueous varnish containing no anti-blocking auxiliary instead of the lip adhesion-preventing aqueous varnish of example 1, as comparative examples 1 to 3.
Adopting the same tipping base paper and the same printing process, and replacing the lip adhesion prevention alcohol soluble ink and the lip adhesion prevention water-based varnish in the example 2 with the alcohol soluble ink without the anti-adhesion auxiliary agent and the water-based varnish without the anti-adhesion auxiliary agent to print to prepare the tipping paper for the cigarette as a comparative example 2-1; the alcohol-soluble ink without the anti-sticking auxiliary agent is used for replacing the alcohol-soluble ink for preventing lip adhesion in the example 2 to print to prepare tipping paper for cigarettes, and the tipping paper is used as a comparative example 2-2; the tipping paper for cigarettes was prepared by printing with the aqueous varnish containing no anti-blocking auxiliary instead of the lip adhesion-preventing aqueous varnish of example 2, as comparative examples 2 to 3.
Adopting the same tipping base paper and the same printing process, and replacing the lip adhesion prevention alcohol soluble ink and the lip adhesion prevention water-based varnish in example 3 with alcohol soluble ink and water-based varnish without anti-adhesion auxiliaries to print to prepare tipping paper for cigarettes as a comparative example 3-1; the alcohol-soluble ink without the anti-sticking auxiliary agent is used for replacing the alcohol-soluble ink for preventing lip adhesion in the example 3 to print to prepare tipping paper for cigarettes, and the tipping paper is used as a comparative example 3-2; the tipping paper for cigarettes was prepared by printing with the aqueous varnish containing no anti-blocking auxiliary instead of the lip adhesion-preventing aqueous varnish of example 3, as comparative example 3-3.
Adopting the same tipping base paper and the same printing process, and replacing the lip adhesion prevention alcohol soluble ink and the lip adhesion prevention water-based varnish in example 4 with the alcohol soluble ink without the anti-adhesion auxiliary agent and the water-based varnish without the anti-adhesion auxiliary agent to print to prepare the tipping paper for the cigarette as a comparative example 4-1; the alcohol-soluble ink without the anti-sticking auxiliary agent is used for replacing the alcohol-soluble ink for preventing lip adhesion in the example 4 to print to prepare tipping paper for cigarettes, and the tipping paper is used as a comparative example 4-2; the tipping paper for cigarettes was prepared by printing with the aqueous varnish containing no anti-blocking auxiliary instead of the lip adhesion-preventing aqueous varnish of example 4, as comparative example 4-3.
The tipping papers for lip adhesion-resistant cigarettes prepared in examples 1 to 4 were tested for lip adhesion under the same test conditions, and the test results are shown in table 1 below.
The test procedure was as follows:
1. putting the tipping paper sample for the cigarette on a shearing plate, and cutting 6 parts of 30 cm-length samples (all counted in the width direction), wherein 3 parts are used as a control group sample, and 3 parts are used as a test group sample;
2. flatly placing the cut test group sample on an impression bed, enabling the printing surface to face upwards, sucking 1.0mL of artificial saliva by using a liquid transfer device, and placing the artificial saliva at a proper position at one end of the surface of the sample;
3. scraping artificial saliva on the surface of a test group sample within 0.5s by using a color spreading bar, wherein the thickness of a scraped wet film is 22.9 mu m, the scraping length is not less than 20cm, a stopwatch is started for timing when the scraping is finished, a piece of absorbent paper is placed on the surface of the test group sample when the specified time is 10s, and then the artificial saliva on the surface of the test group sample is sucked away by immediately rolling the artificial saliva back and forth within 4s by using a metal compression roller without pressure;
4. the control sample was not subjected to artificial saliva penetration;
5. respectively placing a control group sample and a test group sample on a shear plate, taking the longitudinal central line of the cigarette tipping paper as a central axis, the longitudinal direction as the length direction, the transverse direction as the width direction, cutting a rectangular wide strip (the size deviation should be within +/-0.5 mm) with the length of 150mm and the width of 20mm, and weighing;
6. after the artificial saliva permeates the surface of the cigarette tipping paper, the mass growth percentage of the cigarette tipping paper is calculated according to the formula (1):
in the formula:
omega-percent mass growth;
m test-the arithmetic mean of the masses of the test group specimens measured in triplicate, in grams (g);
m pairs-the arithmetic mean of the mass of control samples measured in triplicate, in grams (g).
The test result judgment criteria are as follows:
1. when the mass growth percentage is less than 4.0%, the lip adhesion grade result is judged to be 0 grade, and the lip adhesion is not shown.
2. When the mass growth percentage is 4.0-7.0%, the lip adhesion grade result is judged to be grade 1, which is expressed as slight lip adhesion.
3. When the mass growth percentage is 7.0-10.0%, the lip adhesion grade result is judged to be grade 2, and the moderate lip adhesion is shown.
4. When the mass growth percentage is 10.0-13.0%, the lip adhesion grade result is judged to be grade 3, which shows that the lip adhesion is severe.
5. When the mass growth percentage is more than 13.0%, the lip adhesion grade result is judged to be 4 grade, and severe lip adhesion is shown.
TABLE 1
As can be seen from table 1: the anti-sticking auxiliary agent is added into the alcohol-soluble ink and the water-based varnish, so that the adhesion condition of the filter lips of the cigarette can be remarkably reduced, particularly, when the alcohol-soluble ink and the water-based varnish act synergistically, the adhesion grade of the filter lips can be reduced to 0 grade, and the condition that the filter tips of the cigarette are adhered to the filter lips is truly avoided.
The above-mentioned embodiments only express some specific embodiments of the present invention, and the description thereof is specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention.
Claims (8)
1. The utility model provides an anti lip adhesion's cigarette is with connecing dress paper, includes china cypress ground paper layer, dyed layer and gloss oil layer, its characterized in that: the coloring layer is formed by coating and drying alcohol-soluble ink for preventing lip adhesion, and the gloss oil layer is formed by coating and drying water-based gloss oil for preventing lip adhesion;
the alcohol-soluble ink for preventing lip adhesion comprises the following raw materials in parts by weight: 5-15 parts of resin binder, 20-60 parts of solvent, 5-45 parts of pigment and filler, 0.1-0.8 part of wax powder and 0.1-10 parts of anti-sticking ink auxiliary agent; the anti-sticking ink auxiliary agent is prepared from diatomite, sodium oleate and hydroxyl polysiloxane copolymer according to the weight ratio of 2: 1: 3 by weight ratio;
the water-based lip adhesion preventing gloss oil is prepared from the following raw materials in parts by weight: 3-15 parts of resin binder, 0.05-0.5 part of wax powder, 75-90 parts of water and 0.1-10 parts of anti-sticking gloss oil auxiliary agent; the anti-sticking gloss oil auxiliary agent is prepared from sodium oleate and hydroxyl polysiloxane copolymer according to the weight ratio of 1: 3 by weight ratio.
2. The tipping paper for cigarette resistant to lip adhesion according to claim 1, characterized in that: in the lip adhesion prevention alcohol-soluble ink, the resin binder is one or two of polyvinyl butyral resin and modified rosin resin; the solvent is ethanol; the pigment and filler is one or more of benzidine yellow, lithol carmine, fast bright red, light calcium carbonate and rutile type titanium dioxide.
3. The tipping paper for cigarette resistant to lip adhesion according to claim 1, characterized in that: in the water-based lip adhesion preventing gloss oil, the resin binder is one or more of acrylic acid-styrene copolymer resin, rosin modified acrylic resin and polyurethane modified acrylic resin; the wax powder is aqueous polyethylene wax powder with the particle size of 1-8 microns.
4. The tipping paper for the cigarette resistant to lip adhesion according to claim 1, characterized in that the method for preparing the alcohol-soluble ink resistant to lip adhesion is as follows: adding the resin binder into a solvent, stirring and dissolving, sequentially adding the pigment filler, the wax powder and the anti-sticking printing ink auxiliary agent, and dispersing for 30-60 minutes at 1000rpm to obtain a mixed dispersion liquid; and then adding the mixed dispersion liquid into a sand mill, grinding for 1.5-3.0 hours, taking out and filtering to obtain the required lip adhesion prevention alcohol-soluble ink.
5. The tipping paper for cigarette resistant to lip adhesion according to claim 4, characterized in that: when the used pigment and filler contains light calcium carbonate or rutile type titanium dioxide, 0.5-3 parts of BYK-770 dispersing agent is further added while the pigment and filler is added.
6. The tipping paper for the cigarette resistant to lip adhesion according to claim 1, characterized in that the method for preparing the water-based lip adhesion-resistant gloss oil is as follows: and slowly adding the resin binder into water, stirring and dissolving, then adding the wax powder and the anti-sticking gloss oil auxiliary agent, dispersing the mixture at a high speed for 60 minutes, taking out and filtering to obtain the required water-based lip adhesion prevention gloss oil.
7. The tipping paper for cigarette resistant to lip adhesion according to claim 1, characterized in that: the dry coating weight of the lip adhesion preventing alcohol-soluble ink is 0.8-4.0 g/m2The dry coating weight of the water-based lip adhesion preventing gloss oil is 0.5-1.2 g/m2。
8. The tipping paper for cigarette resistant to lip adhesion according to claim 1, characterized in that: the tipping base paper layer adopts single-sided smooth common base paper or double-sided smooth common base paper, and the gram weight of the base paper is 32-40 g/m2。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910908582.6A CN110747691A (en) | 2019-09-25 | 2019-09-25 | Anti-lip adhesion tipping paper for cigarettes |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910908582.6A CN110747691A (en) | 2019-09-25 | 2019-09-25 | Anti-lip adhesion tipping paper for cigarettes |
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| Publication Number | Publication Date |
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| CN110747691A true CN110747691A (en) | 2020-02-04 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201910908582.6A Pending CN110747691A (en) | 2019-09-25 | 2019-09-25 | Anti-lip adhesion tipping paper for cigarettes |
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