CN110629584A - Lip adhesion-preventing water-based gloss oil for tipping paper for cigarettes - Google Patents
Lip adhesion-preventing water-based gloss oil for tipping paper for cigarettes Download PDFInfo
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- CN110629584A CN110629584A CN201910908460.7A CN201910908460A CN110629584A CN 110629584 A CN110629584 A CN 110629584A CN 201910908460 A CN201910908460 A CN 201910908460A CN 110629584 A CN110629584 A CN 110629584A
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- parts
- tipping paper
- water
- lip adhesion
- preventing water
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/12—Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
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- Paper (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
The invention discloses lip adhesion preventing water-based varnish for tipping paper for cigarettes, which is prepared from 3-15 parts of resin binder, 0.05-0.5 part of wax powder, 75-90 parts of water and 0.1-10 parts of anti-sticking auxiliary agent by adding the resin binder into water, stirring and dissolving, adding the wax powder and the anti-sticking auxiliary agent, dispersing at a high speed for 60 minutes, taking out and filtering to obtain a product. Wherein the anti-sticking auxiliary agent is prepared from sodium oleate and hydroxyl polysiloxane copolymer according to the weight ratio of 1: 3 by weight ratio. The lip adhesion preventing water-based varnish for the cigarette tipping paper has excellent printing adaptability, has excellent water resistance after being dried into a film, can effectively avoid the occurrence of lip adhesion of the cigarette tipping paper, and is simple in preparation method, green and environment-friendly.
Description
Technical Field
The invention belongs to the technical field of cigarette materials, and particularly relates to water-based varnish capable of preventing lips of smokers from being adhered to tipping paper on the surface of a cigarette filter.
Background
In recent years, consumers often receive feedback on the sticking condition of the cigarette lips. The cigarette consists of a filter tip, a tobacco rod and cigarette tipping paper, wherein the tobacco rod and the filter tip are tipped by the cigarette tipping paper. When a smoker article smokes cigarettes, the cigarette tipping paper is in direct contact with the surface of the lips, and along with the prolonging of the contact time, the adhesive layer and the saliva on the lips of the smoker can penetrate through the gap of the coating and generate an adhesive effect with paper fibers, so that the phenomenon of lip adhesion is caused, and poor article smoking experience is brought to the consumer. The cigarette filter tip paper has a slight plot, the surface of the cigarette filter tip paper can be polluted, and the appearance and the smoking experience of cigarettes are influenced; in severe situations, the lips of consumers are stuck by cigarettes, which causes the lips to break skin, bleed and the like. Therefore, improvement of such a situation is urgently required.
Disclosure of Invention
The invention aims to provide lip adhesion preventing water-based varnish for cigarette tipping paper, which has excellent water resistance after being dried into a film and can effectively avoid the occurrence of lip adhesion of the cigarette tipping paper, aiming at overcoming the defects of the prior art.
The purpose of the invention is realized by the following technical scheme.
All percentages used herein are by weight unless otherwise indicated.
The lip adhesion preventing water-based varnish for the tipping paper for the cigarettes is prepared from the following raw materials in parts by weight: 3-15 parts of resin binder, 0.05-0.5 part of wax powder, 75-90 parts of water and 0.1-10 parts of anti-sticking auxiliary agent;
wherein the resin binder is one or more of acrylic acid-styrene copolymer resin, rosin modified acrylic resin and polyurethane modified acrylic resin; the anti-sticking auxiliary agent is prepared from sodium oleate and hydroxyl polysiloxane copolymer according to the weight ratio of 1: 3 by weight ratio;
the method for preparing the lip adhesion preventing water-based varnish for the tipping paper for the cigarettes comprises the following steps:
(1) slowly adding the resin binder into water, stirring and dissolving to obtain a prefabricated material;
(2) and adding the wax powder and the anti-sticking auxiliary agent into the prefabricated material, dispersing at a high speed for 60 minutes, taking out and filtering to obtain the required lip adhesion preventing water-based gloss oil.
The preferable using amount of the anti-sticking auxiliary agent is 1-5 parts.
The wax powder is preferably aqueous polyethylene wax powder with the particle size of 1-8 microns.
In the step (2), the viscosity value of the final water-based gloss oil is controlled to be 13-20 seconds, and an British 2# cup test is adopted.
The lip adhesion preventing water-based varnish for the cigarette tipping paper has excellent printing adaptability, has excellent water resistance after being dried into a film, and can effectively avoid the occurrence of lip adhesion of the cigarette tipping paper. The preparation method is simple and environment-friendly.
Detailed Description
The present invention is further described in detail by the following examples, which are not intended to limit the technical scope of the present invention, and all changes and equivalents made based on the teaching of the present invention shall fall within the scope of the present invention.
Example 1
The lip adhesion preventing water-based gloss oil for the cigarette tipping paper comprises the following raw materials in parts by weight: 3 parts of acrylic acid-styrene copolymer resin, 0.05 part of wax powder, 75 parts of water, 0.2 part of sodium oleate and 0.6 part of hydroxyl polysiloxane copolymer.
Slowly adding acrylic acid-styrene copolymer resin into water, stirring and dissolving to obtain a prefabricated material; adding wax powder, sodium oleate and hydroxyl polysiloxane copolymer into the prefabricated material, dispersing at high speed for 60 minutes, taking out and filtering to obtain the lip adhesion preventing water-based gloss oil with the viscosity of 13 seconds.
Example 2
The lip adhesion preventing water-based gloss oil for the cigarette tipping paper comprises the following raw materials in parts by weight: 10 parts of rosin modified acrylic resin, 0.25 part of wax powder, 80 parts of water, 1 part of sodium oleate and 3 parts of hydroxyl polysiloxane copolymer.
Slowly adding the rosin modified acrylic resin into water, stirring and dissolving to prepare a prefabricated material; adding wax powder, sodium oleate and hydroxyl polysiloxane copolymer into the prefabricated material, dispersing at high speed for 60 minutes, taking out and filtering to obtain the lip adhesion preventing water-based gloss oil with the viscosity of 16 seconds.
Example 3
The lip adhesion preventing water-based gloss oil for the cigarette tipping paper comprises the following raw materials in parts by weight: 15 parts of polyurethane modified acrylic resin, 0.5 part of water-based polyethylene wax powder with the particle size of 5-6 microns, 90 parts of water, 2.5 parts of sodium oleate and 7.5 parts of hydroxyl polysiloxane copolymer.
Slowly adding the polyurethane modified acrylic resin into water, stirring and dissolving to obtain a prefabricated material; adding wax powder, sodium oleate and hydroxyl polysiloxane copolymer into the prefabricated material, dispersing at high speed for 60 minutes, taking out and filtering to obtain the lip adhesion preventing water-based gloss oil with the viscosity of 14 seconds.
Example 4
The lip adhesion preventing water-based gloss oil for the cigarette tipping paper comprises the following raw materials in parts by weight: 5 parts of rosin modified acrylic resin, 5 parts of polyurethane modified acrylic resin, 0.4 part of waterborne polyethylene wax powder with the particle size of 5-6 microns, 85 parts of water, 2 parts of sodium oleate and 6 parts of hydroxyl polysiloxane copolymer.
Slowly adding rosin modified acrylic resin and polyurethane modified acrylic resin into water, stirring and dissolving to prepare a prefabricated material; adding wax powder, sodium oleate and hydroxyl polysiloxane copolymer into the prefabricated material, dispersing at high speed for 60 minutes, taking out and filtering to obtain the lip adhesion preventing water-based gloss oil with the viscosity of 18 seconds.
Comparative example 1
An aqueous gloss oil for cigarette tipping paper comprises the following raw materials in parts by weight: 3 parts of acrylic acid-styrene copolymer resin, 0.05 part of wax powder and 75 parts of water.
Comparative example 2
An aqueous gloss oil for cigarette tipping paper comprises the following raw materials in parts by weight: 10 parts of rosin modified acrylic resin, 0.25 part of wax powder and 80 parts of water.
Comparative example 3
An aqueous gloss oil for cigarette tipping paper comprises the following raw materials in parts by weight: 15 parts of polyurethane modified acrylic resin, 0.5 part of wax powder and 90 parts of water.
Comparative example 4
An aqueous gloss oil for cigarette tipping paper comprises the following raw materials in parts by weight: 5 parts of rosin modified acrylic resin, 5 parts of polyurethane modified acrylic resin, 0.4 part of wax powder and 85 parts of water.
And (3) comparison test:
and in comparative examples 1 to 4, gloss oil is prepared by adopting the same process as that of the examples 1 to 4, cigarette tipping paper is prepared by printing according to the same process, a conventional yellow ink is printed on the base paper printing surface of the cigarette tipping paper, the gloss oil prepared in the examples 1 to 4 and the comparative examples 1 to 4 is printed, and the cigarette tipping paper is obtained after drying. The cigarette tipping paper was tested for lip blocking and the test results are shown in table 1 below.
The test procedure was as follows:
1. putting the tipping paper sample for the cigarette on a shearing plate, and cutting 6 parts of 30 cm-length samples (all counted in the width direction), wherein 3 parts are used as a control group sample, and 3 parts are used as a test group sample;
2. flatly placing the cut test group sample on an impression bed, enabling the printing surface to face upwards, sucking 1.0mL of artificial saliva by using a liquid transfer device, and placing the artificial saliva at a proper position at one end of the surface of the sample;
3. scraping artificial saliva on the surface of a test group sample within 0.5s by using a color spreading bar, wherein the thickness of a scraped wet film is 22.9 mu m, the scraping length is not less than 20cm, a stopwatch is started for timing when the scraping is finished, a piece of absorbent paper is placed on the surface of the test group sample when the specified time is 10s, and then the artificial saliva is immediately rolled back and forth within 4s by using a metal compression roller without pressure to suck away the excessive artificial saliva on the surface of the test group sample;
4. the control sample was not subjected to artificial saliva penetration;
5. respectively placing a control group sample and a test group sample on a shear plate, taking the longitudinal central line of the cigarette tipping paper as a central axis, the longitudinal direction as the length direction, the transverse direction as the width direction, cutting a rectangular wide strip (the size deviation should be within +/-0.5 mm) with the length of 150mm and the width of 20mm, and weighing;
6. after the artificial saliva permeates the surface of the cigarette tipping paper, the mass growth percentage of the cigarette tipping paper is calculated according to the formula (1):
in the formula:
omega-percent mass growth;
Mmeasuring-the arithmetic mean of the masses of the test group samples, measured in triplicate, in grams (g);
Mto pair-the arithmetic mean of the masses of the control samples, in grams (g), of the triplicates.
The test result judgment criteria are as follows:
1. when the mass growth percentage is less than 4.0%, the lip adhesion grade result is judged to be 0 grade, and the lip adhesion is not shown.
2. When the mass growth percentage is 4.0-7.0%, the lip adhesion grade result is judged to be grade 1, which is expressed as slight lip adhesion.
3. When the mass growth percentage is 7.0-10.0%, the lip adhesion grade result is judged to be grade 2, and the moderate lip adhesion is shown.
4. When the mass growth percentage is 10.0-13.0%, the lip adhesion grade result is judged to be grade 3, which shows that the lip adhesion is severe.
5. When the mass growth percentage is more than 13.0%, the lip adhesion grade result is judged to be 4 grade, and severe lip adhesion is shown.
TABLE 1
As can be seen from Table 1: the anti-sticking auxiliary agent is added on the basis of the existing water-based gloss oil system, so that the lip adhesion grade of the cigarette tipping paper is reduced from 4 grade to 1-3 grade, and the condition that the lip adhesion of the cigarette tipping paper is effectively reduced is shown.
The above-mentioned embodiments only express some specific embodiments of the present invention, and the description thereof is specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention.
Claims (4)
1. The lip adhesion preventing water-based varnish for the tipping paper for the cigarettes is prepared from the following raw materials in parts by weight: 3-15 parts of resin binder, 0.05-0.5 part of wax powder, 75-90 parts of water and 0.1-10 parts of anti-sticking auxiliary agent;
wherein the resin binder is one or more of acrylic acid-styrene copolymer resin, rosin modified acrylic resin and polyurethane modified acrylic resin; the anti-sticking auxiliary agent is prepared from sodium oleate and hydroxyl polysiloxane copolymer according to the weight ratio of 1: 3 by weight ratio;
the method for preparing the lip adhesion preventing water-based varnish for the tipping paper for the cigarettes comprises the following steps:
(1) slowly adding the resin binder into water, stirring and dissolving to obtain a prefabricated material;
(2) and adding the wax powder and the anti-sticking auxiliary agent into the prefabricated material, dispersing at a high speed for 60 minutes, taking out and filtering to obtain the required lip adhesion preventing water-based gloss oil.
2. The lip adhesion preventing water-based varnish for the cigarette tipping paper, according to claim 1, is characterized in that the amount of the anti-sticking auxiliary agent is 1-5 parts.
3. The lip adhesion preventing water-based varnish for the cigarette tipping paper according to claim 1, characterized in that the wax powder is water-based polyethylene wax powder with the particle size of 1-8 microns.
4. The lip adhesion preventing water-based varnish for the cigarette tipping paper according to claim 1, wherein in the step (2), the viscosity value of the final water-based varnish is controlled to be 13-20 seconds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910908460.7A CN110629584A (en) | 2019-09-25 | 2019-09-25 | Lip adhesion-preventing water-based gloss oil for tipping paper for cigarettes |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910908460.7A CN110629584A (en) | 2019-09-25 | 2019-09-25 | Lip adhesion-preventing water-based gloss oil for tipping paper for cigarettes |
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| CN110629584A true CN110629584A (en) | 2019-12-31 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112051177A (en) * | 2020-08-26 | 2020-12-08 | 云南中烟工业有限责任公司 | Method for detecting lip adhesion force of cigarette tipping paper |
| WO2022099899A1 (en) * | 2020-11-10 | 2022-05-19 | 云南中烟工业有限责任公司 | Environmentally friendly water-based adhesive, preparation method therefor, and use thereof |
| WO2022099900A1 (en) * | 2020-11-10 | 2022-05-19 | 云南中烟工业有限责任公司 | Non-lip-sticking tipping paper, preparation method therefor and use thereof |
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| CN103483908A (en) * | 2013-09-13 | 2014-01-01 | 哈尔滨大东方新材料科技股份有限公司 | Method for preparing water-based cigarette tipping paper gloss oil and application of water-based cigarette tipping paper gloss oil |
| CN104213461A (en) * | 2014-08-05 | 2014-12-17 | 江守仲 | Uniformly-coated non-lip-sticking base paper of tipping paper and preparation method thereof |
| CN107903704A (en) * | 2017-12-01 | 2018-04-13 | 云南红塔油墨有限公司 | A kind of water-based gravure varnish and preparation method thereof |
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2019
- 2019-09-25 CN CN201910908460.7A patent/CN110629584A/en active Pending
Patent Citations (3)
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| CN103483908A (en) * | 2013-09-13 | 2014-01-01 | 哈尔滨大东方新材料科技股份有限公司 | Method for preparing water-based cigarette tipping paper gloss oil and application of water-based cigarette tipping paper gloss oil |
| CN104213461A (en) * | 2014-08-05 | 2014-12-17 | 江守仲 | Uniformly-coated non-lip-sticking base paper of tipping paper and preparation method thereof |
| CN107903704A (en) * | 2017-12-01 | 2018-04-13 | 云南红塔油墨有限公司 | A kind of water-based gravure varnish and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112051177A (en) * | 2020-08-26 | 2020-12-08 | 云南中烟工业有限责任公司 | Method for detecting lip adhesion force of cigarette tipping paper |
| WO2022041624A1 (en) * | 2020-08-26 | 2022-03-03 | 云南中烟工业有限责任公司 | Method for measuring lip sticking force of cigarette tipping paper |
| WO2022099899A1 (en) * | 2020-11-10 | 2022-05-19 | 云南中烟工业有限责任公司 | Environmentally friendly water-based adhesive, preparation method therefor, and use thereof |
| WO2022099900A1 (en) * | 2020-11-10 | 2022-05-19 | 云南中烟工业有限责任公司 | Non-lip-sticking tipping paper, preparation method therefor and use thereof |
| US11591496B2 (en) | 2020-11-10 | 2023-02-28 | China Tobacco Yunnan Industrial Co., Ltd. | Non-sticking tipping paper, preparation method and application method of the same |
| EP4063562A4 (en) * | 2020-11-10 | 2023-06-28 | China Tobacco Yunnan Industrial Co., Ltd | Non-lip-sticking tipping paper, preparation method therefor and use thereof |
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Application publication date: 20191231 |