CN110743318A - Purification system combining hollow fiber membrane dust collector and activated carbon gas treatment device - Google Patents
Purification system combining hollow fiber membrane dust collector and activated carbon gas treatment device Download PDFInfo
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- CN110743318A CN110743318A CN201911263684.3A CN201911263684A CN110743318A CN 110743318 A CN110743318 A CN 110743318A CN 201911263684 A CN201911263684 A CN 201911263684A CN 110743318 A CN110743318 A CN 110743318A
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- activated carbon
- hollow fiber
- treatment device
- fiber membrane
- flue gas
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 136
- 239000000428 dust Substances 0.000 title claims abstract description 67
- 239000012510 hollow fiber Substances 0.000 title claims abstract description 52
- 239000012528 membrane Substances 0.000 title claims abstract description 41
- 238000000746 purification Methods 0.000 title claims abstract description 18
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000003546 flue gas Substances 0.000 claims abstract description 43
- 239000007789 gas Substances 0.000 claims abstract description 38
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 20
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 6
- 238000006477 desulfuration reaction Methods 0.000 claims description 18
- 230000023556 desulfurization Effects 0.000 claims description 18
- 239000003463 adsorbent Substances 0.000 claims description 15
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 11
- 238000001179 sorption measurement Methods 0.000 claims description 10
- 229910021529 ammonia Inorganic materials 0.000 claims description 7
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 claims description 6
- 238000002347 injection Methods 0.000 claims description 6
- 239000007924 injection Substances 0.000 claims description 6
- 238000005507 spraying Methods 0.000 claims description 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 5
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 230000000712 assembly Effects 0.000 claims description 3
- 238000000429 assembly Methods 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 238000007664 blowing Methods 0.000 claims description 2
- 238000007599 discharging Methods 0.000 claims description 2
- 238000011010 flushing procedure Methods 0.000 claims description 2
- 239000011159 matrix material Substances 0.000 claims description 2
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 abstract description 3
- 239000002250 absorbent Substances 0.000 abstract 2
- 230000002745 absorbent Effects 0.000 abstract 2
- 230000002035 prolonged effect Effects 0.000 abstract 1
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 239000003344 environmental pollutant Substances 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 2
- 238000004056 waste incineration Methods 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/54—Particle separators, e.g. dust precipitators, using ultra-fine filter sheets or diaphragms
- B01D46/543—Particle separators, e.g. dust precipitators, using ultra-fine filter sheets or diaphragms using membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/20—Halogens or halogen compounds
- B01D2257/204—Inorganic halogen compounds
- B01D2257/2047—Hydrofluoric acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/302—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
The hollow fiber dust remover and the active carbon gas treatment device are combined to form the purification system. And a fixed bed flue gas purification system combining the hollow fiber membrane dust collector and the activated carbon fiber gas treatment device. The dust remover with the hollow fiber membrane filter element purifies the flue gas dust and the absorbent dust to microgram level, and then the flue gas dust and the absorbent dust are sent to an active carbon gas treatment device for treatment, so that the service life of active carbon or active carbon fiber is greatly prolonged, and the purity of emission is improved.
Description
Technical Field
The hollow fiber dust remover and the active carbon gas treatment device are combined to form the purification system. In particular to a flue gas purification system which combines a high-purity dust treatment device of a hollow fiber membrane filter element and a device which integrally removes pollutants such as oxysulfide, nitric oxide, hydrogen fluoride, dioxin, mercury and the like by utilizing active carbon and active carbon fiber.
Background
Although activated carbon has good adsorption and catalytic functions and has been used for treating gas pollutants for a long time, the activated carbon is not generally used for integrally removing pollutants such as sulfur oxides, nitrogen oxides, hydrogen fluoride, dioxin, mercury and the like in industries such as power generation, sintering, cement, electrolytic aluminum, waste incineration and the like on a large scale. One important reason is that the dust blocks the activated carbon, which greatly reduces the service life of the activated carbon.
The common devices are treated by a bag-type dust collector and then enter the activated carbon integrated desulfurization and denitrification device. Whereas the dust concentration after bag-type dust removal is generally 10-20 mg/m, for a system with an air volume of 100 ten thousand m for high speed dry harvest, 10kg of dust leaks every hour, 240kg per day, 86.4-172 tons of dust per year, and the dust is the finest dust which can penetrate through a dust remover, so that thousands of tons of activated carbon are blocked and failed. For example, the flue gas treatment of a certain power plant consumes 2.5 million tons of activated carbon every year, and the value is billion yuan. The method becomes a key obstacle for limiting the wide application of the activated carbon in flue gas desulfurization and denitrification in the heavy pollution industry.
The core for solving the problems is to reduce the content of dust in the flue gas entering the activated carbon desulfurization and denitrification device, and the content is preferably less than 10-100 micrograms. It has not been possible to accomplish this task with existing bag-type dust collectors.
Disclosure of Invention
The self-Guoshaohua technology for treating flue gas by using the hollow fiber membrane filter element at high purity improves the dust treatment precision by 1000 times compared with the best bag-type dust remover under the condition of equivalent wind resistance, and stably reaches microgram level. The invention aims to combine the hollow fiber membrane dust removal technology with the activated carbon desulfurization and denitrification technology, solve the problem that the activated carbon is blocked, and form a novel flue gas treatment device integrating dust, sulfur, nitrate, mercury and dioxin removal.
The purification system combining the hollow fiber membrane dust remover and the activated carbon gas treatment device comprises a hollow fiber membrane filter element dust remover and an activated carbon gas treatment device;
the hollow fiber membrane filter element dust remover comprises a flue gas inlet pipe, a mixer, an adsorption powder spraying port, a hollow fiber membrane filter element assembly, a back flushing device and an air outlet valve;
the activated carbon gas treatment device comprises an activated carbon desulfurization part, an activated carbon SCR denitration part, an ammonia injection port, a steam generator, an acid gas condensation recoverer, an activated carbon feeding port and an activated carbon discharging port;
the purification system of the combination of the hollow fiber dust remover and the active carbon gas treatment device is characterized in that: the hollow fiber membrane filter element deduster is arranged in front of the activated carbon gas treatment device, dust in flue gas and the adsorbent which adsorbs harmful gas-phase substances are filtered by the hollow fiber membrane filter element deduster to below 0.5-100 ug/m for flowering, and then the flue gas is sent to the activated carbon gas treatment device for desulfurization, denitration and demercuration;
the front end of the hollow fiber membrane filter element dust remover is sequentially provided with a flue gas inlet pipe and a mixer, the mixer is provided with an adsorption powder spraying inlet, an activated carbon adsorbent or an alumina powder adsorbent is sprayed into the mixer from the adsorption powder spraying inlet, flue gas is mixed with the adsorbent in the mixer and then enters the hollow fiber membrane filter element dust remover, a cabinet of the hollow fiber membrane filter element dust remover is internally provided with a matrix consisting of hollow fiber membrane filter element assemblies, the activated carbon adsorbent absorbs most dioxin in the flue gas, the alumina powder adsorbent absorbs most hydrogen fluoride in the flue gas, the adsorbent absorbing harmful gases and dust in the flue gas are intercepted by the hollow fiber membrane filter element, deposited on the surface of membrane wires of the hollow fiber membrane filter element and blown down by a back blowing device arranged at the end part of the hollow fiber membrane filter element assembly;
description of the drawings: therefore, the adsorbent is introduced into the mixer to adsorb most dioxin or hydrogen fluoride in advance, but not to be reserved for the following activated carbon to be treated together, and leakage and diffusion can be avoided only by intercepting and collecting the high-risk substances with the hollow fiber membrane filter element at high precision.
The air outlet end of the hollow fiber membrane filter element dust remover outputs flue gas with dust content lower than 0.5-100 ug/m, the flue gas is connected with an active carbon desulfurization part of the active carbon gas treatment device through an air outlet valve, the active carbon desulfurization part is connected with an active carbon SCR denitration part through a pipeline, and the flue gas after desulfurization is in contact with and reacts with ammonia entering from the ammonia injection port in the active carbon SCR denitration part to realize denitration;
the activated carbon gas treatment device is an activated carbon fixed bed or a fluidized bed.
Further, the purification system combining the hollow fiber dust collector and the activated carbon gas treatment device according to the present invention is characterized in that: the activated carbon gas treatment device and the hollow fiber dust scrubber jointly form a flue gas treatment system, and is a fixed bed flue gas treatment device using activated carbon fibers as filler, and the fixed bed flue gas treatment device and the activated carbon fiber gas treatment device jointly form a fixed bed flue gas purification system combining the hollow fiber dust scrubber and the activated carbon fiber gas treatment device.
Description of the drawings: the activated carbon fiber is activated carbon-containing fiber, has a very large specific surface area (1000-3000 square meters per gram) and abundant micropores, and the volume of the micropores accounts for more than 90% of the total pore volume. Activated carbon fibers have a greater adsorption capacity and faster adsorption kinetics than conventional granular activated carbon. However, it is more prone to clogging by dust and cannot be used in a fluidized bed. The permanent operation can be realized only under two working conditions of microgram level and fixed bed. The invention aims to combine the purification treatment precision of the hollow fiber dust collector with the excellent performance of the activated carbon fiber, avoid the damage of the fluidized bed to the activated carbon fiber and form a novel flue gas purification system combining the hollow fiber dust collector and the activated carbon fiber gas treatment device.
Drawings
Fig. 1 is a schematic view showing an example of a purification system in which a hollow fiber dust collector and an activated carbon gas treatment device are combined according to the present invention. Wherein: (1) an ash conveying device; (2) a hollow fiber membrane filter element dust remover; (3) a flue gas inlet pipe; (4) a mixer; (5) an adsorption powder injection port; (6) an ammonia injection port; (7) an activated carbon SCR denitration part; wherein the filler is granular activated carbon or activated carbon fiber; (8) an air outlet valve; (9) an activated carbon feed port; (10) a gas-liquid valve; (11) the active carbon desulfurization part, wherein the filler is granular active carbon or active carbon fiber; (12) an acid gas condensation and recovery device; (13) a steam generator; (14) a discharge hole of the activated carbon; (17) hollow fiber membrane cartridge assemblies.
Detailed description of the invention
The desulfurization, denitrification and demercuration of the activated carbon are mature technologies, and 99 percent of desulfurization and 90 percent of denitrification can be realized in a laboratory. However, large-scale on-site implementation of power generation, coking, cement, sintering, electrolytic aluminum, waste incineration and the like has considerable difficulty, and the main problem is dust blockage.
The essence of the invention is that the hollow fiber film dust collector replaces the original cloth bag dust collector, and the precision of dust treatment is improved to microgram level.
1-2 ug/m, for a system with an air volume of 100 ten thousand m, 1g leaks out every hour, 24g each day, 8-17 kg dust each year, and only accounts for 4 ten thousandths of 2 ten thousand tons of activated carbon, which is negligible.
According to the small experimental device manufactured according to the principle of the invention, the dust content actually sent to the active carbon link is 0.5-2 ug/m for high speed cultivation, which is close to the purity of standard gas in a laboratory.
Thus, the life of the activated carbon is already independent of the dust content of the flue gas and a fixed bed can be used. Not only the covering and the blocking of the dust to the activated carbon are avoided, but also the abrasion consumption of the fluidized bed to the activated carbon is greatly reduced, the process flow and the energy consumption are reduced, and the activated carbon, especially the activated carbon fiber, is applied to the flue gas treatment on a large scale, thereby opening up a road.
The novel small-sized experimental device of the purification system combining the hollow fiber membrane dust collector and the activated carbon fiber gas treatment device manufactured according to the principle of the invention has the desulfurization efficiency of 99 percent and the denitration efficiency of 90 percent and longer service life.
Claims (2)
1. The purification system combining the hollow fiber membrane dust remover and the activated carbon gas treatment device comprises a hollow fiber membrane filter element dust remover and an activated carbon gas treatment device;
the hollow fiber membrane filter element dust remover comprises a flue gas inlet pipe, a mixer, an adsorption powder spraying port, a hollow fiber membrane filter element assembly, a back flushing device and an air outlet valve;
the activated carbon gas treatment device comprises an activated carbon desulfurization part, an activated carbon SCR denitration part, an ammonia injection port, a steam generator, an acid gas condensation recoverer, an activated carbon feeding port and an activated carbon discharging port;
the purification system of the combination of the hollow fiber dust remover and the active carbon gas treatment device is characterized in that: the hollow fiber membrane filter element deduster is arranged in front of the activated carbon gas treatment device, dust in flue gas and the adsorbent which adsorbs harmful gas-phase substances are filtered by the hollow fiber membrane filter element deduster to below 0.5-100 ug/m for flowering, and then the flue gas is sent to the activated carbon gas treatment device for desulfurization, denitration and demercuration;
the front end of the hollow fiber membrane filter element dust remover is sequentially provided with a flue gas inlet pipe and a mixer, the mixer is provided with an adsorption powder spraying inlet, an activated carbon adsorbent or an alumina powder adsorbent is sprayed into the mixer from the adsorption powder spraying inlet, flue gas is mixed with the adsorbent in the mixer and then enters the hollow fiber membrane filter element dust remover, a cabinet of the hollow fiber membrane filter element dust remover is internally provided with a matrix consisting of hollow fiber membrane filter element assemblies, the activated carbon adsorbent absorbs most dioxin in the flue gas, the alumina powder adsorbent absorbs most hydrogen fluoride in the flue gas, the adsorbent absorbing harmful gases and dust in the flue gas are intercepted by the hollow fiber membrane filter element, deposited on the surface of membrane wires of the hollow fiber membrane filter element and blown down by a back blowing device arranged at the end part of the hollow fiber membrane filter element assembly;
the air outlet end of the hollow fiber membrane filter element dust remover outputs flue gas with dust content lower than 0.5-100 ug/m, the flue gas is connected with an active carbon desulfurization part of the active carbon gas treatment device through an air outlet valve, the active carbon desulfurization part is connected with an active carbon SCR denitration part through a pipeline, and the flue gas after desulfurization is in contact with and reacts with ammonia entering from the ammonia injection port in the active carbon SCR denitration part to realize denitration.
2. The purification system of claim 1 in combination with an activated carbon gas treatment device, wherein: the activated carbon gas treatment device and the hollow fiber dust scrubber jointly form a flue gas treatment system, and is a fixed bed flue gas treatment device using activated carbon fibers as filler, and the fixed bed flue gas treatment device and the activated carbon fiber gas treatment device jointly form a fixed bed flue gas purification system combining the hollow fiber dust scrubber and the activated carbon fiber gas treatment device.
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CN201911263684.3A CN110743318A (en) | 2019-12-11 | 2019-12-11 | Purification system combining hollow fiber membrane dust collector and activated carbon gas treatment device |
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CN201911263684.3A CN110743318A (en) | 2019-12-11 | 2019-12-11 | Purification system combining hollow fiber membrane dust collector and activated carbon gas treatment device |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111467906A (en) * | 2020-05-18 | 2020-07-31 | 广东风和洁净工程有限公司 | Improved structure of VOC (volatile organic compound) treatment system |
CN115105944A (en) * | 2022-07-05 | 2022-09-27 | 广东风和洁净工程有限公司 | Hollow fiber membrane bed manganese method SOx/NOx control device |
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CN211216073U (en) * | 2019-12-11 | 2020-08-11 | 广东风和洁净工程有限公司 | Purification system combining hollow fiber membrane dust collector and activated carbon gas treatment device |
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2019
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Patent Citations (6)
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CN203540225U (en) * | 2013-11-11 | 2014-04-16 | 陕西理工学院 | Indoor air purifying integrated device |
CN105597531A (en) * | 2016-02-17 | 2016-05-25 | 中国科学院过程工程研究所 | Desulfurization and denitration device and technology used for purifying coke oven smoke |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111467906A (en) * | 2020-05-18 | 2020-07-31 | 广东风和洁净工程有限公司 | Improved structure of VOC (volatile organic compound) treatment system |
CN115105944A (en) * | 2022-07-05 | 2022-09-27 | 广东风和洁净工程有限公司 | Hollow fiber membrane bed manganese method SOx/NOx control device |
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