CN110724578A - 一种茂金属合成汽油机油及其制备方法 - Google Patents

一种茂金属合成汽油机油及其制备方法 Download PDF

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CN110724578A
CN110724578A CN201810775171.XA CN201810775171A CN110724578A CN 110724578 A CN110724578 A CN 110724578A CN 201810775171 A CN201810775171 A CN 201810775171A CN 110724578 A CN110724578 A CN 110724578A
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engine oil
oil
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gasoline engine
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王槐令
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Shandong Mega Lubricating Oil Co Ltd
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Shandong Mega Lubricating Oil Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/045—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108—Residual fractions, e.g. bright stocks
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/144—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/086—Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066—Thiocarbamic type compounds
    • C10M2219/068—Thiocarbamate metal salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/088—Neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/08—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having metal-to-carbon bonds
    • C10M2227/081—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having metal-to-carbon bonds with a metal carbon bond belonging to a ring, e.g. ferocene

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

本发明涉及车用润滑油领域，特别涉及一种茂金属合成汽油机油及其制备方法，具体如下：(1)投料混合：将丁二酰亚胺3.6wt％、水杨酸镁1.5wt％、硫化烷基酚钙1wt％、二戌基二硫代氨甲酸镁2wt％、烷基化二苯胺0.6wt％、光亮油15wt％、基础油74.9wt％投入调和釜；(2)加温混合：将步骤(1)中的物料加温至75℃，气动脉冲30分钟，搅拌1.5小时；(3)化验校准。本发明的有益效果是：降低了车主的用车成本，减少了废机油的产生量，降低燃油油耗，起到节能效果。

Description

一种茂金属合成汽油机油及其制备方法
技术领域
本发明涉及车用润滑油领域，特别涉及一种茂金属合成汽油机油及其制备方法。
背景技术
现阶段矿物油调和的汽油机油换油一般换油周期为5000公里，合成机油换油周期为10000公里，现有的汽油机油的换油周期短，造成频繁的保养维护，造成车主用车费用的增加，换下来的废机油还会对环境造成影响。
发明内容
为了解决现有技术的问题，本发明提供了一种降低用车成本，减少废机油产生量的茂金属合成汽油机油及其制备方法。
本发明所述技术方案如下：
一种茂金属合成汽油机油及其制备方法，具体如下：
(1)投料混合：将丁二酰亚胺3.6wt％、水杨酸镁1.5wt％、硫化烷基酚钙1wt％、二戌基二硫代氨甲酸镁2wt％、烷基化二苯胺0.6wt％、光亮油15wt％、基础油74.9wt％投入调和釜；
(2)加温混合：将步骤(1)中的物料加温至75℃，气动脉冲30分钟，搅拌1.5小时；
(3)化验校准：在步骤(2)搅拌结束后，取样化验，按照GB 11121-2006化验校准。
所述的基础油是茂金属PAO。
本发明提供的技术方案带来的有益效果是：
通过茂金属合成汽油机油，依托先进的基础油以及添加剂，超高的抗剪切性能，极佳的抗氧化性，足以达到30000公里换油里程，经过实车实验，行驶30000公里后，油样指标依然远远没有达到机油报废国家标准。超高的粘温性，有效的降低了燃油油耗，清净分散性效果极佳。延长换油周期的机油，一方面降低了车主的用车成本，减少了废机油的产生量，新产品的特性，还能降低燃油油耗，起到节能效果。
具体实施方式
为使本发明的目的、技术方案和优点更加清楚，下面对本发明实施方式作进一步地详细描述。
一种茂金属合成汽油机油及其制备方法，具体如下：
(1)投料混合：将丁二酰亚胺3.6wt％、水杨酸镁1.5wt％、硫化烷基酚钙1wt％、二戌基二硫代氨甲酸镁2wt％、烷基化二苯胺0.6wt％、光亮油15wt％、茂金属PAO74.9wt％投入调和釜；
(2)加温混合：将步骤(1)中的物料加温至75℃，气动脉冲30分钟，搅拌1.5小时；
(3)化验校准：在步骤(2)搅拌结束后，取样化验，按照GB 11121-2006化验校准。
根据GB11121-2006实验方法与标准得出以下数据：
实车实验：
车型：雪铁龙C4L 1.6T 2013款，发动机:PSA
实验里程：里程表23553-53555KM
实验结束后油样检测数据：GB/T 8028-94
100℃运动粘度：9.86
碱值：16
闪点：213
水分：0.01
结果证明：油品还远未达到换油标准。
以上所述仅为本发明的较佳实施例，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (2)

1.一种茂金属合成汽油机油及其制备方法，其特征在于，具体如下：
(1)投料混合：将丁二酰亚胺3.6wt％、水杨酸镁1.5wt％、硫化烷基酚钙1wt％、二戌基二硫代氨甲酸镁2wt％、烷基化二苯胺0.6wt％、光亮油15wt％、基础油74.9wt％投入调和釜；
(2)加温混合：将步骤(1)中的物料加温至75℃，气动脉冲30分钟，搅拌1.5小时；
(3)化验校准：在步骤(2)搅拌结束后，取样化验，按照GB 11121-2006化验校准。
2.根据权利要求1所述的一种茂金属合成汽油机油及其制备方法，其特征在于，所述的基础油是茂金属PAO。
CN201810775171.XA 2018-07-16 2018-07-16 一种茂金属合成汽油机油及其制备方法 Pending CN110724578A (zh)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1415714A (zh) * 2001-11-02 2003-05-07 中国石油天然气股份有限公司 一种添加剂组合物
CN1523091A (zh) * 2003-02-20 2004-08-25 中国石油天然气股份有限公司 高档汽油机油组合物
CN101768497A (zh) * 2008-12-26 2010-07-07 比亚迪股份有限公司 一种润滑油
CN101851549A (zh) * 2010-07-05 2010-10-06 中国人民解放军后勤工程学院 一种长寿命汽油发动机机油
CN103254986A (zh) * 2013-06-11 2013-08-21 刘玉鹏 一种双燃料发动机润滑油及其制备方法
CN104160003A (zh) * 2011-10-10 2014-11-19 埃克森美孚研究工程公司 高效发动机油组合物
CN104479820A (zh) * 2014-11-17 2015-04-01 山东永泰化工有限公司 一种润滑油及其制备方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1415714A (zh) * 2001-11-02 2003-05-07 中国石油天然气股份有限公司 一种添加剂组合物
CN1523091A (zh) * 2003-02-20 2004-08-25 中国石油天然气股份有限公司 高档汽油机油组合物
CN101768497A (zh) * 2008-12-26 2010-07-07 比亚迪股份有限公司 一种润滑油
CN101851549A (zh) * 2010-07-05 2010-10-06 中国人民解放军后勤工程学院 一种长寿命汽油发动机机油
CN104160003A (zh) * 2011-10-10 2014-11-19 埃克森美孚研究工程公司 高效发动机油组合物
CN103254986A (zh) * 2013-06-11 2013-08-21 刘玉鹏 一种双燃料发动机润滑油及其制备方法
CN104479820A (zh) * 2014-11-17 2015-04-01 山东永泰化工有限公司 一种润滑油及其制备方法

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Application publication date: 20200124