CN110699983B - Reactive dye dyeing promoter composition and preparation method thereof - Google Patents
Reactive dye dyeing promoter composition and preparation method thereof Download PDFInfo
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/645—Aliphatic, araliphatic or cycloaliphatic compounds containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/655—Compounds containing ammonium groups
- D06P1/66—Compounds containing ammonium groups containing quaternary ammonium groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
Abstract
The invention discloses a reactive dye dyeing accelerant composition and a preparation method thereof. The reactive dye dyeing promoter composition comprises the following components: 30-50 wt% of alkali carbonate microcapsules, 10-35 wt% of C8‑18Quaternary alkyl ammonium base, 2-10 wt% trihydroxy C1‑3Alkyl amino methane, 0.5-5 wt% of thiocarbamate modified starch and 20-45 wt% of water, based on the total weight of the reactive dye dyeing promoter composition. The reactive dye accelerant prepared by the invention has the advantages of good color fixing effect, no dust pollution, convenient and safe production, and excellent level-dyeing property and various fastnesses.
Description
Technical Field
The invention relates to a dyeing accelerant and a preparation method thereof, in particular to a reactive dye dyeing accelerant composition and a preparation method thereof.
Background
Cotton fabrics are popular with consumers because of their moisture absorption and air permeability, and reactive dyes are the main dye types for dyeing cotton fabrics. In the dyeing process of the reactive dye on the cotton fabric, a color fixing alkaline agent is needed to be used, and the reactive dye and the hydroxyl of the cotton fabric are crosslinked under an alkaline condition to achieve the purpose of color fixing.
In the traditional inorganic color-fixing alkaline agent, the advantages of good color-obtaining effect of sodium carbonate on dyed fabrics, stable pH value of dye liquor, no hydrolysis of a large amount of reactive dyes and the like are most commonly applied, but the inorganic color-fixing alkaline agent also has some defects: the dosage is large, the concentration is high, and dust pollution is easy to generate; the material melting is inconvenient, hard blocks are easy to form to scratch fabrics, the pipeline is easy to block, and the problem of uneven dyeing is solved; after dyeing is finished, the concentration of an alkaline agent in the residual liquid is high, and the wastewater treatment cost is high. In order to solve the problems, researchers develop a series of novel substitute alkalis to replace traditional alkaline agents such as sodium carbonate and the like to be applied to reactive dye fixation. For example, chinese patent application No. 200610034187.2, "liquid dyeing alkali for reactive dye dyeing", discloses a liquid dyeing alkali SN composed of alkali metal hydroxide, alkali metal carbonate, alkali metal borate, organic carboxylate and water, which can be used for reactive dye dyeing with the amount of sodium carbonate 1/9, and has no dust pollution, the dyeing effect and various color fastnesses also reach the effect of sodium carbonate, but the preparation process is cumbersome, and the high temperature of 130 ℃ is kept, there is a production safety hazard; for example, the chinese patent with application number 201710151284.8, "a new substitute alkali and its preparation method", describes a new substitute alkali prepared from organic alkali, potassium carbonate, buffering agent and additive, the preparation process is simple, the fabric dyed and fixed by using it instead of soda has good color fastness, but the fabric leveling problem is not solved yet, which makes its application greatly limited.
Therefore, the development of the reactive dye dyeing promoter which has good color fixing effect, no dust pollution, convenient and safe production and excellent level dyeing property and various fastnesses has very important significance.
Disclosure of Invention
One aspect of the present invention provides a reactive dye dyeing promoter composition, which comprises the following components:
based on the total weight of the reactive dye dyeing promoter composition.
Another aspect of the present invention is to provide a method for preparing a reactive dye dyeing promoter composition, which comprises the steps of:
1) mixing alkali metal carbonate microcapsules with trihydroxy C at room temperature1-3Adding alkyl aminomethane into water, and uniformly stirring to obtain a first solution;
2) at room temperature, adding C8-18Adding alkyl quaternary ammonium base into the first solution, and uniformly stirring to obtain a second solution; and
3) and adding the thiocarbamate modified starch into the second solution at room temperature, and uniformly stirring to obtain the reactive dye dyeing promoter.
Compared with the prior disclosed reactive dye dyeing promoter composition and the preparation method thereof, the invention has the advantages that the invention has the originality in the following aspects: (1) according to the invention, the sodium carbonate microcapsule is adopted, and the sodium carbonate is slowly released in the color fixing reaction of the reactive dye and the fiber, so that the color fixing reaction is slowly carried out, and the dyeing is uniform; (2) by C8-18Alkyl quaternary ammonium base with strong alkalinity, less dosage and C8-18The alkyl quaternary ammonium base has the function of a surfactant, can effectively disperse and reduce dye agglomeration, and has uniform dyeing; (3) adding trihydroxy C1-3The alkyl aminomethane such as tris (hydroxymethyl) aminomethane has excellent buffering effect and can maintain the color fixing reaction to be carried out in a stable pH range; (4) the added thiocarbamate modified starch has excellent chelation effect on metal ions, reduces the hydrolysis catalysis effect of the metal ions on the dye, and obviously improves the color fixation efficiency of the reactive dye and the fiber.
The reactive dye accelerator composition prepared according to the invention has the advantages of good color fixing effect, no dust pollution, convenient and safe production, and excellent level-dyeing property and various fastness.
Detailed Description
In a preferred embodiment, the present invention provides a reactive dye dyeing promoter composition comprising the following components:
based on the total weight of the reactive dye dyeing promoter composition.
In a more preferred embodiment, the embedding rate of the alkali carbonate microcapsules is 40-50%, and the alkali carbonate comprises sodium carbonate, potassium carbonate or a mixture thereof.
In a more preferred embodiment, said C8-18The quaternary alkylammonium base being C8-18Alkyl tri C1-4Alkyl quaternary ammonium bases, preferably C10-16Alkyl tri C1-2An alkyl quaternary ammonium base.
In a most preferred embodiment, said C8-18The alkyl quaternary ammonium hydroxide includes dodecyl trimethyl ammonium hydroxide, tetradecyl trimethyl ammonium hydroxide, decyl trimethyl ammonium hydroxide, hexadecyl trimethyl ammonium hydroxide, or combinations thereof.
In a more preferred embodiment, trihydroxy C1-3The alkylaminomethane includes trishydroxyethylaminomethane, trishydroxymethylaminomethane, or mixtures thereof.
In a more preferred embodiment, the dithiocarbamate modified starch is a dithiocarbamate modified starch. Preferred are alkali metal thiocarbamate modified starches, more preferred are alkali metal dithiocarbamate modified starches, such as sodium dithiocarbamate modified starches, potassium dithiocarbamate modified starches, ammonium dithiocarbamate modified starches or mixtures thereof.
In a most preferred embodiment, the thiocarbamate-modified starch is a sodium dithiocarbamate-modified tapioca starch having a sulphur content of 5-8 wt%.
In a more preferred embodiment, the water is water commonly used in the art, such as deionized water.
In a preferred embodiment, the preparation process of the present invention is carried out at room temperature of about 15-30 ℃.
Examples
The invention will be further illustrated with reference to the following specific examples. It should be understood that these examples are for illustrative purposes only and are not intended to limit the scope of the present invention. Further, it should be understood that various changes or modifications of the present invention may be made by those skilled in the art after reading the teaching of the present invention, and such equivalents may fall within the scope of the present invention as defined in the appended claims.
In each example, all the materials and fabrics were commercially available.
The application and performance of the prepared product on the textile are determined as follows:
1) the application process in the textile comprises the following steps:
sample preparation: half-floating all-cotton knitted fabric
The process comprises the following steps: the dye dosage is 6% o.w.f., the bath ratio is 1:20, and 60g/L Na is added in batches at the initial stage of dyeing at the temperature of 60-80 DEG C2SO4And (3) accelerating dyeing, adding 20g/L sodium carbonate or 2g/L reactive dye dyeing accelerator after dyeing for 30min, keeping the temperature for 30min, and performing soap boiling after dyeing.
The soap boiling process comprises the following steps: cold water washing → Hot Water washing → soaping (soap flakes 2g/L, Na)2CO32g/L, bath ratio 1:30, 95 ℃ x 10min) → hot water washing → cold water washing → drying
2) Dyeing performance and textile performance measurement standards:
and (3) fixation rate: the higher the fixation, the better the fixation. The fixation rate is indirectly expressed by the change of K/S value of the fabric before and after the dyeing and soap boiling, the K/S value of the dyed fabric before and after the soap boiling is respectively measured at the position of lambda max, and the K/S value is calculated by the following formula:
percent fixation ═ K/SAfter soap is boiled×E)/(K/SBefore soap boiling)×100％
Dye uptake E: measuring the absorbance of the dye solution before and after dyeing at the maximum absorption wavelength of the dye by using a V-1200 visible spectrophotometer according to the following formula:
in the formula: a. the0The absorbance of the dye solution before dyeing after being diluted by m times; a. the1The absorbance of the dye solution after dyeing is diluted by n times.
K/S value: color measuring and matching System of Datacolor, D65 light source, Large aperture, measurement
Leveling property: the leveling property can be characterized by measuring the unevenness of a dyed sample, and the smaller the unevenness, the better the leveling property is represented; otherwise, the worse. The specific method is to measure K/S values of any 8 points on a dyed sample, calculate the variance of the K/S values of each point to the average value, namely the relative unevenness, and calculate according to the following formula:
wherein S (r) is dyeing unevenness; x is the number ofiThe K/S value of any point is 1-8;
the K/S value is the average value of 8 points;
and (3) fastness to water bubbles: heating the cocoon washing powder to 90 ℃ at a bath ratio of 1:50, placing a cloth sample treated by a color fixing agent, oscillating the cloth sample in a dyeing oscillator for 5min, taking out the cloth sample, and determining the color depth of the working solution according to a grey sample card for color change evaluation of GB/T250 + 2008 textile color fastness test;
fastness to soaping: measured according to GB/T3921-;
color fastness to rubbing: the determination is carried out according to GB/T3920 and 2008 textile color fastness test rubbing color fastness;
example 1
40g of deionized water, 45g of sodium carbonate microcapsules (the embedding rate is 42.6 percent, refer to Chenjie and Wangpo, and the like) (research on preparing sodium carbonate microcapsules by a complex phase emulsion method, proceedings of Henan university of Industrial science (Nature edition), 2009,30 (2): 5-7) and 7g of tris (hydroxymethyl) aminomethane are added into a four-neck flask provided with a stirrer and a thermometer, stirred for 20-30 minutes at room temperature, then 10g of dodecyl trimethyl ammonium hydroxide and 10g of hexadecyl trimethyl ammonium hydroxide are added, the mixture is stirred for 10-20 minutes at room temperature, finally 2g of sodium dithiocarbamate modified cassava starch (the sulfur content is 6.2%, refer to synthesis and characterization of a DTC modified cassava starch heavy metal chelating agent, 2010,29 (7): 1330 and 1333) is added, and the mixture is stirred for 10 minutes at room temperature, so that the reactive dye dyeing promoter 1 is obtained. The application effect is shown in table 1.
Example 2
35g of deionized water, 40g of sodium carbonate microcapsules (embedding rate is 48.6%, refer to Chenjie and Wangpo, and the like) are added into a four-neck flask provided with a stirrer and a thermometer, and the four-neck flask is stirred for 10 minutes at room temperature, and finally, 1g of sodium dithiocarbamate modified cassava starch (sulfur content is 6.8%, refer to Shang Xiaoqin, Luo nan, and the like) is added, so that the active dye dyeing accelerant 2 is obtained. The application effect is shown in table 1.
Example 3
30g of deionized water, 43g of sodium carbonate microcapsules (the embedding rate is 45.9 percent, refer to Chenjie and Wangpo, and the like) are added into a four-neck flask provided with a stirrer and a thermometer, the research on the preparation of the sodium carbonate microcapsules by a complex-phase emulsion method, the school newspaper of Henan university of Industrial science (Nature science edition), 2009,30 (2): 5-7 preparation), 8g of trihydroxymethyl aminomethane is stirred for 20-30 minutes at room temperature, then 23g of decyl trimethyl ammonium hydroxide is added, the stirring is carried out for 10-20 minutes at room temperature, finally 3g of sodium dithiocarbamate modified starch (the sulfur content is 6.5 percent, refer to the synthesis and characterization of heavy metal chelating agents of cassava starch, 2010,29 (7): 1330-. The application effect is shown in table 1.
The application effect of each example is compared with the application effect of the commercial substituted alkali and active dye accelerator, and is shown in table 1.
TABLE 1 Effect of application
As can be seen from Table 1, when the reactive dye dyeing promoter prepared by the invention is applied, the fixation rate and the level-dyeing property are better than those of calcined soda, commercially available substituted alkali A and commercially available reactive dye promoter B, and the color fastness of the reactive dye dyeing promoter is also better than those of calcined soda, commercially available substituted alkali A and commercially available reactive dye promoter B.
Claims (12)
1. A reactive dye dyeing promoter composition comprises the following components:
based on the total weight of the reactive dye dyeing promoter composition.
2. The reactive dye dyeing promoter composition of claim 1, comprising the following components:
based on the total weight of the reactive dye dyeing promoter composition.
3. The reactive dye dyeing promoter composition according to claim 1 or 2, wherein the embedding rate of the alkali carbonate microcapsules is 40 to 50%, and the alkali carbonate comprises sodium carbonate, potassium carbonate or a mixture thereof.
4. The reactive dye dyeing promoter composition according to claim 1 or 2, wherein C is8-18The quaternary alkylammonium base being C8-18Alkyl tri C1-4An alkyl quaternary ammonium base.
5. The reactive dye dyeing promoter composition according to claim 1 or 2, wherein C is8-18The quaternary alkylammonium base being C10-16Alkyl tri C1-2An alkyl quaternary ammonium base.
6. The reactive dye dyeing promoter composition according to claim 1 or 2, wherein C is8-18The alkyl quaternary ammonium base includes dodecyl trimethyl ammonium hydroxide, tetradecyl trimethyl ammonium hydroxide, decyl trimethyl ammonium hydroxide, hexadecyl trimethyl ammonium hydroxide orCombinations thereof.
7. Dyeing promoter composition according to reactive dyes according to claim 1 or 2, characterized by trihydroxy C1-3The alkylaminomethane includes trishydroxyethylaminomethane, trishydroxymethylaminomethane, or mixtures thereof.
8. A reactive dye dyeing promoter composition according to claim 1 or 2 characterized in that the thiocarbamate modified starch is a dithiocarbamate modified starch.
9. The reactive dye dyeing promoter composition according to claim 1 or 2, characterized in that the thiocarbamate modified starch is a dithiocarbamate modified tapioca starch having a sulphur content of 5-8% by weight.
10. The reactive dye dyeing promoter composition according to claim 1 or 2, wherein the water is deionized water.
11. A process for preparing a reactive dye dyeing promoter composition as claimed in claim 1 or 2, which comprises the steps of:
1) mixing alkali metal carbonate microcapsules with trihydroxy C at room temperature1-3Adding alkyl aminomethane into water, and uniformly stirring to obtain a first solution;
2) at room temperature, adding C8-18Adding alkyl quaternary ammonium base into the first solution, and uniformly stirring to obtain a second solution; and
3) and adding the thiocarbamate modified starch into the second solution at room temperature, and uniformly stirring to obtain the reactive dye dyeing promoter.
12. The method of claim 11, wherein the room temperature is 15-30 ℃.
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