CN110696223A - Cleaning and recycling equipment and method for waste filter bags - Google Patents
Cleaning and recycling equipment and method for waste filter bags Download PDFInfo
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- 238000004140 cleaning Methods 0.000 title claims abstract description 87
- 239000002699 waste material Substances 0.000 title claims abstract description 71
- 238000000034 method Methods 0.000 title claims abstract description 46
- 238000004064 recycling Methods 0.000 title claims abstract description 36
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 46
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 46
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
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- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 6
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 6
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
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- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
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- 239000000428 dust Substances 0.000 abstract description 6
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- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 6
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- 239000004642 Polyimide Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
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- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
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- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
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- DAFIBNSJXIGBQB-UHFFFAOYSA-N perfluoroisobutene Chemical group FC(F)=C(C(F)(F)F)C(F)(F)F DAFIBNSJXIGBQB-UHFFFAOYSA-N 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
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Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/04—Disintegrating plastics, e.g. by milling
- B29B17/0412—Disintegrating plastics, e.g. by milling to large particles, e.g. beads, granules, flakes, slices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B2017/001—Pretreating the materials before recovery
- B29B2017/0015—Washing, rinsing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
- B29K2027/12—Use of polyvinylhalogenides or derivatives thereof as moulding material containing fluorine
- B29K2027/18—PTFE, i.e. polytetrafluorethene, e.g. ePTFE, i.e. expanded polytetrafluorethene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
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- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
本发明公开了一种废旧滤袋的清洗回收设备及方法,属于材料回收技术领域。本方法通过对废旧聚四氟乙烯微孔膜滤袋进行预清洗、表面活性剂清洗、酸洗、分类、加热淬火、机械粉碎的过程,将废旧滤袋清洗干净,解决了传统技术对废旧滤袋清洗不彻底的问题;其在表面活性剂清洗时使用的清洗设备通过传送带传送废旧滤袋,依次通过上货区、清洗区、喷淋区、烘干区和下货区,该设备在清洗区和喷淋区通过设置的供水干管、供水支管和喷嘴,利用高压去除废旧滤袋表面的灰尘和有机污渍,再在烘干区通过热风进行烘干,反复清洗若干次,可完全清除滤袋表面灰尘和有机物;本发明对废旧滤袋清洗彻底,因此聚四氟乙烯颗粒回收纯度高。
The invention discloses a cleaning and recycling device and a method for waste filter bags, and belongs to the technical field of material recycling. The method cleans the waste filter bags through the processes of pre-cleaning, surfactant cleaning, pickling, sorting, heating and quenching, and mechanical pulverization of waste polytetrafluoroethylene microporous membrane filter bags, which solves the problem of traditional technology for waste filter bags. The problem of incomplete bag cleaning; the cleaning equipment used in surfactant cleaning conveys waste filter bags through a conveyor belt, and passes through the loading area, cleaning area, spraying area, drying area and unloading area in turn. Through the water supply main pipe, water supply branch pipe and nozzle set in the area and spray area, the dust and organic stains on the surface of the waste filter bag are removed by high pressure, and then dried by hot air in the drying area. Repeated cleaning for several times can completely remove the filter bag. Dust and organic matter on the surface of the bag; the present invention thoroughly cleans the waste filter bag, so the recovery purity of polytetrafluoroethylene particles is high.
Description
技术领域technical field
本发明涉及材料回收技术领域,更具体地说,涉及一种废旧滤袋的清洗回收设备及方法。The invention relates to the technical field of material recovery, and more particularly, to a cleaning and recycling device and method for waste filter bags.
背景技术Background technique
垃圾焚烧厂、燃煤电厂和钢铁生产等企业的烟尘排放是大气的主要污染源。袋式除尘器有着除尘效率高、处理风量范围广、对粉尘特性不敏感、可在高温环境下运行等特性,其在燃煤电厂锅炉除尘、采矿业除尘、垃圾焚烧尾气净化等领域有着广泛的应用。Soot emissions from enterprises such as waste incineration plants, coal-fired power plants and steel production are the main sources of air pollution. The bag filter has the characteristics of high dust removal efficiency, wide range of processing air volume, insensitive to dust characteristics, and can operate in high temperature environment. application.
目前,袋式除尘器中滤袋的原料主要有聚苯硫醚(PPS)、聚四氟乙烯(PTFE)、聚酰亚胺(PI)和玻璃纤维等。其中,聚四氟乙烯(PTFE)俗称“塑料王”,具有耐高温、耐腐蚀、电绝缘性好、密封性好等优良性能,其制品能在-190~250℃的温度下长期工作。凭借其优良的性能,聚四氟乙烯微孔膜滤袋广泛应用于除尘器中。目前,废旧聚四氟乙烯滤袋的处理方法有:(1)深度填埋;(2)焚烧处理。聚四氟乙烯极其稳定,自然环境下难以降解。填埋废旧聚四氟乙烯滤袋会严重污染生态环境。此外,聚四氟乙烯在焚烧时会产生四氟乙烯、六氟丙烯、全氟异丁烯等剧毒物质以及PM2.5以下的微细颗粒物,污染大气。因此深度填埋和焚烧均不是其最佳的处理方法。聚四氟乙烯价格较高,因此,回收利用废旧聚四氟乙烯滤袋不但具有环保意义,还有很高的经济价值。At present, the main raw materials of filter bags in bag filter are polyphenylene sulfide (PPS), polytetrafluoroethylene (PTFE), polyimide (PI) and glass fiber. Among them, polytetrafluoroethylene (PTFE), commonly known as "the king of plastics", has excellent properties such as high temperature resistance, corrosion resistance, good electrical insulation, and good sealing. Its products can work for a long time at temperatures of -190 to 250 °C. With its excellent performance, PTFE microporous membrane filter bags are widely used in dust collectors. At present, the disposal methods of waste polytetrafluoroethylene filter bags are: (1) deep landfill; (2) incineration. PTFE is extremely stable and difficult to degrade in the natural environment. Landfilling waste PTFE filter bags will seriously pollute the ecological environment. In addition, when polytetrafluoroethylene is incinerated, highly toxic substances such as tetrafluoroethylene, hexafluoropropylene, perfluoroisobutylene, and fine particulate matter below PM2.5 are produced, polluting the atmosphere. Therefore, neither deep landfill nor incineration is the best disposal method. The price of polytetrafluoroethylene is relatively high, so recycling waste polytetrafluoroethylene filter bags not only has environmental protection significance, but also has high economic value.
在回收聚四氟乙烯滤袋过程中,传统的清洗工艺常存在清洗不彻底的问题,滤袋表面易出现残留。究其原因,一方面是由于滤袋表面的污渍成分较多,导致使用传统的表面活性剂溶液难以去除。另一方面,传统放置于盐酸溶液中漂洗的方式仍难以去除滤袋表面的金属氧化物残余。In the process of recycling PTFE filter bags, the traditional cleaning process often has the problem of incomplete cleaning, and residues are prone to appear on the surface of the filter bags. The reason is that, on the one hand, there are many stains on the surface of the filter bag, which makes it difficult to remove with traditional surfactant solutions. On the other hand, the traditional way of rinsing in hydrochloric acid solution is still difficult to remove the residual metal oxides on the surface of the filter bag.
目前,国内关于聚四氟乙烯的回收方法还主要包括以下三种:机械粉碎法、辐射裂解法和热分解法。热分解法就是利用较高的温度,使聚四氟乙烯发生分解。此方法很难控制分解产物的种类,而且还会产生很多有毒的副产物。辐射法裂解法处理得到的聚四氟乙烯超细粉凝聚性较差,且成本较高。At present, the domestic recycling methods of PTFE mainly include the following three methods: mechanical pulverization method, radiation cracking method and thermal decomposition method. Thermal decomposition method is to use higher temperature to decompose polytetrafluoroethylene. This method is difficult to control the types of decomposition products, and also produces many toxic by-products. The polytetrafluoroethylene ultrafine powder obtained by the radiation cracking method has poor cohesion and high cost.
经检索,中国专利号CN201610115214.2,申请日为2016年3月1日,发明创造名称为:一种废旧聚四氟乙烯和聚苯硫醚混纺滤袋的清洗回收方法,该申请案先将聚四氟乙烯和聚苯硫醚混纺的废旧混纺滤袋依次采用表面活性剂溶液清洗、热处理和强酸溶液清洗,得到纯净的废旧混纺滤袋,再进行高温处理、粉碎和筛分,将聚四氟乙烯短纤维和聚苯硫醚颗粒分离,然后用高温处理和粉碎筛分的方法,分别得到聚四氟乙烯粉料和聚苯硫醚粉料;该方法简便易行,成本较低;但其使用的表面活性剂组分单一,不能同时去除滤袋上的多种污渍。After retrieval, the Chinese patent number CN201610115214.2 was filed on March 1, 2016, and the name of the invention is: a cleaning and recycling method for waste polytetrafluoroethylene and polyphenylene sulfide blended filter bags. The waste and old blended filter bags of polytetrafluoroethylene and polyphenylene sulfide are successively cleaned with surfactant solution, heat treatment and strong acid solution to obtain pure waste and old blended filter bags, which are then subjected to high temperature treatment, crushing and sieving. The vinyl fluoride short fibers and the polyphenylene sulfide particles are separated, and then the polytetrafluoroethylene powder and the polyphenylene sulfide powder are obtained by high temperature treatment and crushing and screening. It uses a single surfactant component and cannot remove multiple stains on the filter bag at the same time.
发明内容SUMMARY OF THE INVENTION
1.发明要解决的技术问题1. The technical problem to be solved by the invention
针对现有技术中废旧聚四氟乙烯滤袋表面污渍无法彻底清洗干净,影响聚四氟乙烯滤袋的回收利用的问题,本发明提供了一种废旧滤袋的清洗回收设备及方法;本发明使用表面活性剂,对滤袋表面污渍进行清洗,同时对清洗后的滤袋进行酸洗,清除滤袋表面的金属氧化物,较好的去除了滤袋表面的污渍,可以获得较为纯净的聚四氟乙烯颗粒。Aiming at the problem that the surface stains on the waste and old polytetrafluoroethylene filter bags in the prior art cannot be thoroughly cleaned, which affects the recycling and utilization of the polytetrafluoroethylene filter bags, the present invention provides a cleaning and recycling equipment and method for the waste and old filter bags; the present invention Use surfactant to clean the surface stains of the filter bag, and at the same time, pickle the cleaned filter bag to remove the metal oxides on the surface of the filter bag. Tetrafluoroethylene particles.
2.技术方案2. Technical solutions
为达到上述目的,本发明提供的技术方案为:In order to achieve the above object, the technical scheme provided by the invention is:
本发明的一种废旧滤袋清洗回收设备,包括传送带和滚筒,滚筒带动传送带运动;传送带输送废旧滤袋,沿传送带的输送方向依次设置五个区域,分别为上货区、清洗区、喷淋区、烘干区和下货区。The waste filter bag cleaning and recycling equipment of the present invention includes a conveyor belt and a drum, the drum drives the conveyor belt to move; the conveyor belt transports the waste filter bags, and five areas are arranged in sequence along the conveying direction of the conveyor belt, namely the loading area, the cleaning area, and the spraying area. area, drying area and unloading area.
更进一步地,所述的清洗区和喷淋区内部设置有清洗组件,该清洗组件包括供水干管和供水支管,供水支管与供水干管相连,且供水支管沿供水干管的长度方向并排设置有多根。Further, a cleaning component is arranged inside the cleaning area and the spraying area, and the cleaning component includes a water supply main pipe and a water supply branch pipe, the water supply branch pipe is connected with the water supply main pipe, and the water supply branch pipes are arranged side by side along the length direction of the water supply main pipe. There are multiple roots.
更进一步地,所述的供水支管上间隔设置有多个喷嘴,其中,设置于清洗区的喷嘴为扇形喷嘴,设置于喷淋区的喷嘴为实心锥喷嘴。Further, a plurality of nozzles are arranged at intervals on the water supply branch pipe, wherein the nozzles arranged in the cleaning area are fan-shaped nozzles, and the nozzles arranged in the spray area are solid cone nozzles.
更进一步地,所述的烘干区内部设置有喷吹组件,该喷吹组件包括多根风管,所述的风管上间隔设置有多个风口。Furthermore, a blowing assembly is arranged inside the drying area, and the blowing assembly includes a plurality of air ducts, and a plurality of air openings are arranged on the air ducts at intervals.
更进一步地,所述的清洗区的喷嘴距滤袋300~500mm,每个喷嘴的压力为0.3~0.5MPa;喷淋区的喷嘴距滤袋300~500mm,每个喷嘴的压力为1~3MPa;所述的烘干区的风口距滤袋的距离为300~500mm,风口风速5~10m/s。Further, the nozzles in the cleaning area are 300-500mm away from the filter bag, and the pressure of each nozzle is 0.3-0.5MPa; the nozzles in the spraying area are 300-500mm away from the filter bag, and the pressure of each nozzle is 1-3MPa The distance between the air outlet of the drying area and the filter bag is 300-500 mm, and the air velocity of the air outlet is 5-10 m/s.
本发明的一种利用上述回收设备对废旧滤袋进行清洗回收的方法,其步骤为:A method of the present invention for cleaning and recycling waste and old filter bags by utilizing the above-mentioned recycling equipment, the steps of which are:
步骤一、对废旧聚四氟乙烯微孔膜滤袋进行预清洗并烘干;Step 1, pre-cleaning and drying the waste polytetrafluoroethylene microporous membrane filter bag;
步骤二、使用表面活性剂溶液对废旧滤袋进行清洗并烘干;
步骤三、将烘干后的滤袋放置于酸溶液中浸泡并漂洗,获得纯净的废旧滤袋;
步骤四、对漂洗后废旧滤袋进行分类,分为有破损滤袋和无破损滤袋,无破损滤袋回收;Step 4, classify the waste filter bags after rinsing, and divide them into damaged filter bags and non-damaged filter bags, and non-damaged filter bags are recycled;
步骤五、将有破损的滤袋进行加热处理并淬火;
步骤六、将淬火后的滤袋机械粉碎,筛分,制得聚四氟乙烯颗粒。Step 6: Mechanically pulverize and sieve the quenched filter bag to obtain polytetrafluoroethylene particles.
更进一步地,所述的步骤二中使用的表面活性剂为多组分表面活性剂,其成分包括:十二烷基苯磺酸钠9~11份;脂肪醇聚氧乙烯醚硫酸钠6~8份;烷基醇酰胺1.5~3份;凯松0.06~0.08份;氢氧化钠0.9~1.3份;脂肪醇聚氧乙烯醚5~10份;乙二胺四乙酸二钠0.1~0.3份;无机增稠剂0.8~1.2份;去离子水90~100份。Further, the surfactant used in the second step is a multi-component surfactant, and its components include: 9-11 parts of sodium dodecylbenzene sulfonate; 6-11 parts of sodium aliphatic alcohol
更进一步地,所述的步骤三中,酸溶液采用质量百分比浓度为10%~16%的盐酸溶液,浸泡温度为20~40℃,浸泡时间为1~3天;所述的漂洗为使用桶式波轮清洗机对废旧滤袋清洗20~40min。Further, in the
更进一步地,所述的步骤五中,加热处理的过程为,先将纯净废旧滤袋缓慢升温至300~350℃,保温1~3h,其中,升温速率为3~5℃/min;淬火的过程为将加热后的滤袋放置于温度为10~30℃的水中并降至常温。Further, in the
更进一步地,所述的步骤六中,机械粉碎是使用超细粉碎机将淬火后的滤袋粉碎1~2小时;粉碎后经过筛选,获得粒径为100~300目的聚四氟乙烯颗粒。Further, in the step 6, the mechanical pulverization is to pulverize the quenched filter bag for 1-2 hours by using an ultrafine pulverizer;
3.有益效果3. Beneficial effects
采用本发明提供的技术方案,与已有的公知技术相比,具有如下显著效果:Adopting the technical scheme provided by the present invention, compared with the existing known technology, has the following remarkable effects:
(1)本发明的一种废旧滤袋的清洗回收方法,鉴于废旧聚四氟乙烯滤袋表面的污渍多,现有的清洗方法无法将滤袋表面污渍彻底清洗干净,影响滤袋的回收利用,其设计了一种多组分表面活性剂,能够彻底清除滤袋表面的污渍;该表面活性剂中的十二烷基苯磺酸钠和脂肪醇聚氧乙烯醚硫酸钠为工业常用的阴离子表面活性剂,价格低廉;凯松的加入则延长了其保存时间。(1) a cleaning and recycling method of a waste filter bag of the present invention, in view of the many stains on the surface of the waste polytetrafluoroethylene filter bag, the existing cleaning method cannot thoroughly clean the surface stains of the filter bag, which affects the recycling of the filter bag. , which designed a multi-component surfactant, which can completely remove the stains on the surface of the filter bag; the sodium dodecyl benzene sulfonate and sodium aliphatic alcohol polyoxyethylene ether sulfate in the surfactant are commonly used anions in the industry Surfactant, low price; the addition of Kaysong prolongs its storage time.
(2)本发明的一种废旧滤袋的清洗回收方法,由于废旧聚四氟乙烯滤袋表面含有较多的金属氧化物,传统的清洗方式仅将滤袋经盐酸溶液浸泡漂洗,无法彻底清除滤袋表面金属氧化物,其采用将废旧滤袋经过盐酸浸泡后,放入套桶式波轮清洗机清洗的方式,更加彻底的清除了金属氧化物。(2) The cleaning and recycling method of a waste filter bag of the present invention, since the surface of the waste polytetrafluoroethylene filter bag contains a lot of metal oxides, the traditional cleaning method only soaks and rinses the filter bag in a hydrochloric acid solution, which cannot be completely removed The metal oxide on the surface of the filter bag is cleaned by soaking the waste filter bag in hydrochloric acid, and then putting it into a barrel-type pulsator cleaning machine to clean the metal oxide more thoroughly.
(3)本发明的一种废旧滤袋的清洗回收方法,由于现有的袋式除尘器大多数是将滤袋与框架集成一个整体,制作成一个板式过滤元件,然后再进行模块化组装,制成组合框架;在实际中,个别滤袋损坏会影响整体的性能,组合框架便被丢弃;因此被回收的组合式框架内可能含有未破损滤袋,本发明的清洗回收方法将清洗后的滤袋分为有破损滤袋和无破损滤袋,无破损滤袋回收重复利用,避免了资源的浪费。(3) The cleaning and recycling method of a waste filter bag of the present invention, because most of the existing bag filter is to integrate the filter bag and the frame as a whole, make a plate filter element, and then carry out modular assembly, A combined frame is made; in practice, damage to individual filter bags will affect the overall performance, and the combined frame will be discarded; therefore, the recovered combined frame may contain unbroken filter bags, and the cleaning and recycling method of the present invention will Filter bags are divided into damaged filter bags and non-damaged filter bags. Non-damaged filter bags are recycled and reused, avoiding the waste of resources.
(4)本发明的一种废旧滤袋的清洗回收设备,其将滤袋以平铺的方式放置于清洗设备上,使清洗溶液和滤袋表面充分接触并进行清洗,且喷淋区的高压喷嘴可进一步去除滤袋表面的灰尘、有机污染物等污渍。(4) The cleaning and recycling equipment of a waste filter bag of the present invention, which places the filter bag on the cleaning equipment in a flat manner, so that the cleaning solution and the surface of the filter bag are fully contacted and cleaned, and the high pressure in the spray area The nozzle can further remove dust, organic pollutants and other stains on the surface of the filter bag.
(5)本发明的一种废旧滤袋的清洗回收方法,其对破损滤袋进行缓慢升温,能在不使滤袋表面发生烧结的基础上破坏聚四氟乙烯分子之间的引力;将高温处理过后的滤袋进行淬火,使聚四氟乙烯分子来不及重新排序,从而便于后续步骤的粉碎。(5) The cleaning and recycling method of a waste filter bag of the present invention, which slowly heats up the damaged filter bag, can destroy the attraction between polytetrafluoroethylene molecules on the basis that the surface of the filter bag is not sintered; The treated filter bag is quenched, so that the polytetrafluoroethylene molecules have no time to reorder, so as to facilitate the crushing of the subsequent steps.
附图说明Description of drawings
图1为本发明中清洗设备的结构示意图;Fig. 1 is the structural representation of cleaning equipment in the present invention;
图2为本发明中喷淋管布置图;Fig. 2 is the spray pipe arrangement diagram in the present invention;
图3为本发明中喷淋管的结构示意图;Fig. 3 is the structural representation of the spray pipe in the present invention;
图4为本发明中喷吹管的结构示意图;Fig. 4 is the structural representation of the blowing pipe in the present invention;
图5为本发明中喷吹管布置图;Fig. 5 is the arrangement diagram of blowing pipe in the present invention;
图6为本发明的回收流程图。Fig. 6 is the recycling flow chart of the present invention.
附图中的标号说明:Description of the symbols in the drawings:
1、清洗区;2、喷淋区;3、烘干区;4、下货区;5、传送带;6、滚筒;7、上货区;8、供水干管;9、供水支管;10、喷嘴;11、风口;12、风管。1. Cleaning area; 2. Spraying area; 3. Drying area; 4. Unloading area; 5. Conveyor belt; 6. Drum; 7. Loading area; 8. Water supply main pipe; 9. Water supply branch pipe; 10. Nozzle; 11. Air outlet; 12. Air duct.
具体实施方式Detailed ways
为进一步了解本发明的内容,结合附图和实施例对本发明作详细描述。In order to further understand the content of the present invention, the present invention will be described in detail with reference to the accompanying drawings and embodiments.
本发明的目的在于提供一种废旧聚四氟乙烯微孔膜滤袋的清洗回收设备及方法,该方法先将废旧聚四氟乙烯微孔膜滤袋依次采用预清洗、表面活性剂溶液清洗和强酸溶液清洗,得到纯净的废旧滤袋。再将废旧滤袋进行分类,若滤袋表面并无破损,可以直接再利用,若滤袋破损,则将破损的废旧滤袋进行高温处理、淬火、粉碎和筛分,得到聚四氟乙烯颗粒。现结合实施例进行具体说明:The object of the present invention is to provide a cleaning and recycling equipment and method for waste and old polytetrafluoroethylene microporous membrane filter bags. In this method, the waste and old polytetrafluoroethylene microporous membrane filter bags are sequentially used for pre-cleaning, surfactant solution cleaning and Washed with strong acid solution to obtain pure waste filter bags. The waste filter bags are then classified. If the surface of the filter bags is not damaged, they can be reused directly. If the filter bags are damaged, the damaged waste filter bags are subjected to high temperature treatment, quenching, crushing and screening to obtain PTFE particles. . Now specifically describe in conjunction with the embodiment:
实施例1Example 1
结合图1,本实施的一种废旧滤袋的清洗回收设备,包括传送带5和滚筒6,滚筒6带动传送带5运动;传送带5输送废旧滤袋,沿传送带5的输送方向依次设置五个区域,分别为上货区7、清洗区1、喷淋区2、烘干区3和下货区4。其中,清洗区1长度为2m,宽度为1.2m。喷淋区2长度为2m,宽度为1m。传送带5的传送速率可为0.8~1.2m/min,本实施例设置为0.8m/min。1, a cleaning and recycling equipment for waste filter bags in this implementation includes a
结合图2,所述的清洗区1和喷淋区2内部设置有清洗组件,该清洗组件包括供水干管8和供水支管9,供水支管9与供水干管8相连,且供水支管9沿供水干管8的长度方向并排设置有多根。具体到本实施例,清洗区1和喷淋区2均设置了11根直径6cm的供水支管9。所述的供水支管9上可间隔设置多个喷嘴10,具体到本实施例,每根支管上等间隔布置了7个喷嘴10(参看图3)。设置于清洗区1的喷嘴10为扇形喷嘴,设置于喷淋区2的喷嘴10为实心锥喷嘴。喷嘴10和供水支管9采用螺纹进行连接。2, the cleaning area 1 and the
结合图5,所述的烘干区3内部设置有喷吹组件,该喷吹组件包括多根风管12,具体到本实施例,该喷吹组件设置了5根风管12。所述的风管12上可间隔设置有多个风口11,具体到本实施例,每根风管12上等间隔设置了7个风口11(参看图4)。Referring to FIG. 5 , the drying
所述的清洗区1的喷嘴10距滤袋300~500mm,每个喷嘴10的压力为0.3~0.5MPa;喷淋区2的喷嘴10距滤袋300~500mm,每个喷嘴10的压力为1~3MPa。所述的烘干区3的风口11距滤袋的距离为300~500mm,风口风速5~10m/s。在本实施例中,设置清洗区1的喷嘴10距滤袋300mm,喷嘴10的压力为0.3MPa。喷淋区2的喷嘴10距滤袋300mm,喷嘴10的压力为1MPa。烘干区3的风口11距滤袋的距离为300mm,风口风速5m/s。传统技术的清洗工艺较为繁琐且易出现无法彻底清除污渍的现象,利用本发明的设备进行平铺式清洗能够避免局部污渍无法去除的问题,且设备简单,使用方便。The
实施例2Example 2
本实施的一种废旧聚四氟乙烯微孔膜滤袋的清洗回收设备,其设计与实施例1基本相同,不同之处在于:本实施例设置传送带5的传送速率为1.2m/min。设置清洗区1的喷嘴10距滤袋500mm,喷嘴10的压力为0.5MPa。喷淋区2的喷嘴10距滤袋500mm,喷嘴10的压力为3MPa。烘干区3的风口11距滤袋的距离为500mm,风口11风速为10m/s。The design of the cleaning and recycling equipment for waste polytetrafluoroethylene microporous membrane filter bags in this embodiment is basically the same as that in Embodiment 1, except that the conveying speed of the
实施例3Example 3
本实施的一种废旧聚四氟乙烯微孔膜滤袋的清洗回收设备,其设计与实施例1基本相同,不同之处在于:本实施例设置传送带5的传送速率为1.0m/min。设置清洗区1的喷嘴10距滤袋400mm,喷嘴10的压力为0.4MPa。喷淋区2的喷嘴10距滤袋400mm,喷嘴10的压力为2MPa。烘干区3的风口11距滤袋的距离为400mm,风口11风速为7m/s。The design of the cleaning and recycling equipment for waste polytetrafluoroethylene microporous membrane filter bags in this embodiment is basically the same as that in Embodiment 1, except that the conveying speed of the
实施例4Example 4
结合图6,本实施例利用实施例1-3任一实施例所述的设备进行滤袋清洗回收,步骤如下:6, the present embodiment utilizes the equipment described in any one of Embodiments 1-3 to clean and recycle the filter bag, and the steps are as follows:
步骤一、对废旧聚四氟乙烯微孔膜滤袋进行预清洗并烘干。Step 1: Pre-cleaning and drying the waste polytetrafluoroethylene microporous membrane filter bag.
步骤二、使用表面活性剂溶液对废旧滤袋进行清洗并烘干。先将滤袋在上货区7平铺于传送带5上。然后调节传送速度、喷嘴10压力和风口11风速。传送带5带动滤袋依次通过清洗区1和喷淋区2进行清洗。清洗后将滤袋翻面清洗,反复清洗多次,最后在烘干区3处烘干。将滤袋平铺于传送带5上,便于清洗,同时双面反复清洗,保证滤袋表面无污渍残余。Step 2: Use the surfactant solution to clean and dry the waste filter bags. First lay the filter bags on the
本实施例的表面活性剂溶液为多组分表面活性剂,其成分包括:十二烷基苯磺酸钠9份;脂肪醇聚氧乙烯醚硫酸钠6份;烷基醇酰胺1.5份;凯松0.06份;氢氧化钠0.9份;脂肪醇聚氧乙烯醚5份;乙二胺四乙酸二钠0.1份;无机增稠剂0.8份;去离子水90份。滤袋表面污渍组分较为复杂,传统的清洗溶液大多采用单成分溶液,难以清洗滤袋表面污渍。The surfactant solution of this embodiment is a multi-component surfactant, and its components include: 9 parts of sodium dodecylbenzene sulfonate; 6 parts of fatty alcohol polyoxyethylene ether sodium sulfate; 1.5 parts of alkyl alcohol amide; 0.06 part of pine; 0.9 part of sodium hydroxide; 5 parts of fatty alcohol polyoxyethylene ether; 0.1 part of disodium EDTA; 0.8 part of inorganic thickener; 90 parts of deionized water. The components of the dirt on the surface of the filter bag are relatively complex. Most of the traditional cleaning solutions use a single-component solution, which is difficult to clean the surface of the filter bag.
值得说明的是,使用本实施例的多组分表面活性剂清洗废旧滤袋表面污渍的好处在于:单一的十二烷基苯磺酸钠虽然能去除污渍,但清洗时难以有效的与污渍接触且污渍被洗出后易发生再沉淀。而烷基醇酰胺能很好的润湿滤袋,使本实施例的表面活性剂有效的接触污渍。脂肪醇聚氧乙烯醚和脂肪醇聚氧乙烯醚硫酸钠易溶于水,能对溶解出的污渍进行充分的乳化作用,使其形成稳定的乳液并迅速分散,有效防止污渍再沉淀,提高清洗质量。乙二胺四乙酸二钠能迅速将金属离子络合并随水冲走,有效去除滤袋表面的无机金属盐。无机增稠剂为NaCl,可以提高物系粘度,使多组分表面活性剂各个物系保持均匀且稳定的悬浮状态,不易发生沉淀。It is worth noting that the advantage of using the multi-component surfactant of this embodiment to clean the surface stains of waste filter bags is that although a single sodium dodecyl benzene sulfonate can remove the stains, it is difficult to effectively contact the stains during cleaning. And the stains are prone to re-precipitation after being washed out. The alkyl alcohol amide can well wet the filter bag, so that the surfactant of this embodiment can effectively contact the stains. Fatty alcohol polyoxyethylene ether and fatty alcohol polyoxyethylene ether sodium sulfate are easily soluble in water, and can fully emulsify the dissolved stains to form a stable emulsion and quickly disperse, effectively prevent the re-precipitation of the stains, and improve the cleaning performance. quality. Disodium EDTA can quickly complex metal ions and wash them away with water, effectively removing inorganic metal salts on the surface of the filter bag. The inorganic thickener is NaCl, which can increase the viscosity of the system, so that each system of the multi-component surfactant maintains a uniform and stable suspension state, and is not prone to precipitation.
步骤三、将烘干后的滤袋平铺于酸溶液中浸泡并漂洗,获得纯净的废旧聚四氟乙烯微孔膜滤袋;该酸溶液采用质量百分比浓度为10%的盐酸溶液,浸泡温度为20℃,浸泡时间为3天。所述的漂洗为使用桶式波轮清洗机对废旧滤袋清洗20min。传统方法仅将滤袋经盐酸溶液浸泡漂洗,无法彻底清除滤袋表面金属氧化物,本实施例采用了套桶式波轮清洗机,将初步清洗过的滤袋放置于盐酸溶液浸泡,可使附着在滤袋表面的金属及其氧化物溶解、松动,再使用套桶式波轮清洗机可更加彻底的清除金属氧化物。
步骤四、对漂洗后废旧滤袋进行分类,分为有破损滤袋和无破损滤袋,无破损滤袋回收。现有的袋式除尘器大多数是将滤袋与框架集成一个整体,制作成一个板式过滤元件,然后再进行模块化组装,制成组合框架。在实际中,个别滤袋损坏会影响整体的性能,组合框架便被丢弃。因此被回收的组合式框架内可能含有未破损滤袋,将其清洗后可重复利用,避免了资源的浪费。Step 4: Classify the waste filter bags after rinsing, and divide them into damaged filter bags and non-damaged filter bags, and non-damaged filter bags are recycled. Most of the existing bag filter is to integrate the filter bag and the frame as a whole, to make a plate filter element, and then to make a modular assembly to make a combined frame. In practice, damage to individual filter bags affects overall performance and the combined frame is discarded. Therefore, the recovered combined frame may contain unbroken filter bags, which can be reused after cleaning, avoiding the waste of resources.
步骤五、将有破损的滤袋进行加热处理并淬火。所述的加热处理的过程为,先将纯净废旧滤袋放置于马弗炉中缓慢升温至300℃,升温速率为3℃/min,再保温1h。之后将滤袋放入10℃的水中并降至常温淬火。聚四氟乙烯微孔膜滤袋经过缓慢升温,能在不使滤袋表面发生烧结的基础上破坏聚四氟乙烯分子之间的引力。由“兰纳-琼斯”势(参看式1)可知,分子势能越大,分子间距离r越大,当分子间距离达到一定程度后,增加分子势能,分子间距离增加幅度大幅减小。
其中V为分子间势能,ε等于势能阱的深度,σ是互相作用的势能正好为零时的两体距离。where V is the intermolecular potential energy, ε is equal to the depth of the potential energy well, and σ is the distance between the two bodies when the potential energy of the interaction is exactly zero.
分子总能量(E)=动能(Ek)+势能(V),温度升高,动能(Ek)增加,分子总能量(E)增加,当分子间距离达到一定程度后,增加分子总能量(E),分子间距离增加幅度大幅减小。根据式2模拟仿真计算得出当温度在300~350℃范围时,分子间距离足够大,足以破坏聚四氟乙烯分子之间的引力,且继续增加温度并不能使分子间距大幅增加。本实施例设定马弗炉温度为300℃。The total molecular energy (E) = kinetic energy (E k ) + potential energy (V), the temperature increases, the kinetic energy (E k ) increases, and the total molecular energy (E) increases. When the intermolecular distance reaches a certain level, the total molecular energy increases (E), the increase in the intermolecular distance is greatly reduced. According to the simulation calculation of
将高温处理过后的滤袋进行淬火,使聚四氟乙烯分子来不及重新排序,从而便于后续步骤的粉碎。Quenching the filter bag after high temperature treatment, so that the polytetrafluoroethylene molecules have no time to reorder, so as to facilitate the crushing of the subsequent steps.
步骤六、将淬火后的滤袋放入超细粉碎机粉碎1小时,然后进行筛分,制得粒径为100~300目的聚四氟乙烯颗粒。所得的聚四氟乙烯颗粒灰份为0.28%、挥发份为0.10%。Step 6: Putting the quenched filter bag into an ultrafine pulverizer for 1 hour, and then sieving to obtain polytetrafluoroethylene particles with a particle size of 100-300 meshes. The ash content of the obtained polytetrafluoroethylene particles was 0.28%, and the volatile content was 0.10%.
实施例5Example 5
本实施例方法基本同于实施例4,不同之处在于:步骤二中所述的表面活性剂溶液为多组分表面活性剂,其成分包括:十二烷基苯磺酸钠11份;脂肪醇聚氧乙烯醚硫酸钠8份;烷基醇酰胺3份;凯松0.08份;氢氧化钠1.3份;脂肪醇聚氧乙烯醚10份;乙二胺四乙酸二钠0.3份;无机增稠剂1份;去离子水100份。The method of this example is basically the same as that of Example 4, the difference is: the surfactant solution described in
步骤三中,酸溶液采用质量百分比浓度为16%的盐酸溶液,浸泡温度为40℃,浸泡时间为1天。所述的漂洗为使用桶式波轮清洗机对废旧滤袋清洗40min。In
步骤五中,加热处理的过程为,先将纯净废旧滤袋放置于马弗炉中缓慢升温至350℃,升温速率为5℃/min,再保温3h。之后将滤袋放入10℃的水中并降至常温淬火。In
步骤六中,将淬火后的滤袋放入超细粉碎机粉碎2小时,然后进行筛分,制得粒径为100~300目的聚四氟乙烯颗粒。In step 6, the quenched filter bag is put into an ultrafine pulverizer for 2 hours, and then sieved to obtain polytetrafluoroethylene particles with a particle size of 100-300 meshes.
实施例6Example 6
本实施例方法基本同于实施例4,不同之处在于:步骤二中所述的表面活性剂溶液为多组分表面活性剂,其成分包括:十二烷基苯磺酸钠10份;脂肪醇聚氧乙烯醚硫酸钠7份;烷基醇酰胺2份;凯松0.07份;氢氧化钠1.1份;脂肪醇聚氧乙烯醚7份;乙二胺四乙酸二钠0.2份;无机增稠剂0.9份;去离子水95份。The method of this example is basically the same as that of Example 4, except that the surfactant solution described in
步骤三中,酸溶液采用质量百分比浓度为13%的盐酸溶液,浸泡温度为30℃,浸泡时间为2天。所述的漂洗为使用桶式波轮清洗机对废旧滤袋清洗30min。In the third step, the acid solution adopts a hydrochloric acid solution with a concentration of 13% by mass, the soaking temperature is 30° C., and the soaking time is 2 days. The rinsing is to use a barrel-type pulsator cleaning machine to clean the waste filter bags for 30 minutes.
步骤五中,加热处理的过程为,先将纯净废旧滤袋放置于马弗炉中缓慢升温至320℃,升温速率为4℃/min,再保温2h。之后将滤袋放入20℃的水中并降至常温淬火。In
步骤六中,将淬火后的滤袋放入超细粉碎机粉碎1.5小时,然后进行筛分,制得粒径为100~300目的聚四氟乙烯颗粒。In step 6, the quenched filter bag is put into an ultrafine pulverizer for 1.5 hours, and then sieved to obtain polytetrafluoroethylene particles with a particle size of 100-300 meshes.
以上示意性的对本发明及其实施方式进行了描述,该描述没有限制性,附图中所示的也只是本发明的实施方式之一,实际的结构并不局限于此。所以,如果本领域的普通技术人员受其启示,在不脱离本发明创造宗旨的情况下,不经创造性的设计出与该技术方案相似的结构方式及实施例,均应属于本发明的保护范围。The present invention and its embodiments have been described above schematically, and the description is not restrictive, and what is shown in the accompanying drawings is only one of the embodiments of the present invention, and the actual structure is not limited thereto. Therefore, if those of ordinary skill in the art are inspired by it, without departing from the purpose of the present invention, any structural modes and embodiments similar to this technical solution are designed without creativity, which shall belong to the protection scope of the present invention. .
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